Abstract: The invention provides an electrophotographic toner having a crystalline polyester resin; a non-crystalline polyester resin; a colorant; and a releasing agent. A resin (i), that is included in a toluene-soluble component of the toner and having a molecular weight of 30,000 to 100,000 as measured by gel permeation chromatography relative to polystyrene standards, has an acid value A. A resin (ii), that is included in a toluene-soluble component of the toner and having a molecular weight of 8,000 to 12,000 as measured by gel permeation chromatography relative to polystyrene standards, has an acid value B. A resin (iii), that is included in a toluene-insoluble component of the toner, has an acid value C. The acid values A, B, and C satisfy the inequation of B>A>C. The invention further provides an electrophotographic developer using the toner, a toner cartridge storing the toner, and an image forming method using the developer.
Abstract: An electrostatic image developing carrier including at least a core material and a coating resin layer which coats the surface of the core material, the resin layer comprising a thermoplastic resin having an alicyclic group, a thermal reduction in accordance with the TGA method being in the range of 0.5 weight % to 5 weight % of the whole of the carrier in the range of 100° C. to 400° C., and further an endothermic quantity of the whole of the carrier in accordance with the DTA method is in the range of 7 mJ/g to 40 mJ/g in the range of 100° C. to 400° C.
Abstract: An electrophotographic toner includes a latex, a colorant, and a release agent, wherein G?(80) is in a range of about 2.0×105 Pa to about 3.0×106 Pa and G?(80)/G?(140) is in a range of about 2.0×102 to about 3.0×103, wherein in regard to a molecular weight distribution on a gel permeation chromatography (GPC) chromatogram, the molecular weight region of 1.0×104 g/mol or less of a tetrahydrofuran (THF)-soluble component of the electrophotographic toner is about 5% or less, and the molecular weight region of 1.0×105 g/mol or more of the THF-soluble component of the electrophotographic toner is in a range of about 5% to about 20%, where G?(80) and G?(140) respectively denote storage moduli of the electrophotographic toner at temperatures of 80° C. and 140° C. when a dynamic viscoelasticity according to a sine-wave vibration is measured at an angular velocity of 6.28 rad/sec and at a temperature increase rate of 2.0° C./min.
Type:
Grant
Filed:
November 25, 2009
Date of Patent:
August 6, 2013
Assignee:
Samsung Electronics Co., Ltd
Inventors:
Jeong-hyun Lee, Yong-kyun Jung, Kyeong Pang
Abstract: To provide an electrostatic charge developing toner in which resin fine particles and inorganic fine particles are externally added to toner base particles, wherein the toner base particles include at least binder resin and colorant, the resin fine particles are monodispersed and fixed to surfaces of the toner base particles, and following equations are established: a=70 to 160 nm, b/a=0.2 to 0.5, and c/a=0.6 to 0.8, where “a” represents an average of diameters (nm) of circular surfaces of contact between the fixed resin fine particles and toner base particle surfaces, “b” represents an average of heights (nm) of the resin fine particles from the contact surfaces, and “c” represents an average diameter (nm) of the resin fine particle at the height b/2.
Abstract: The present disclosure provides toners having a tunable gloss level, electrophotographic apparatus for suing such toners as well as processes for making such toners.
Abstract: An electrophotographic toner contains an electron donating color former compound, an electron accepting color developing agent, and a polyester binder resin having a weight average molecular weight Mw of 6000 or more and 25000 or less, and the toner is decolorized by heating.
Abstract: A method for producing toner according to one example embodiment includes combining and agglomerating a first polymer emulsion with a colorant dispersion and a release agent dispersion to form toner cores. A borax coupling agent is added to the toner cores. A second polymer emulsion is combined and agglomerated with the toner cores having the borax coupling agent to form toner shells around the toner cores. The aggregated toner cores and toner shells are fused to form toner particles.
Abstract: A method for producing a decolorable toner comprising: forming particles containing a color former compound, a color developing agent, and a binder resin; forming first aggregated particles by aggregating and fusing the particles containing the color former compound, the color developing agent, and the binder resin in a dispersion medium; and forming second aggregated particles by aggregating and fusing the first aggregated particles and a binder resin in a dispersion medium.
Abstract: A toner including a mother particle and an external additive covering a surface of the mother particle is provided. The mother particle includes a binder resin, a colorant, and a release agent. The external additive includes a particulate cellulose having a number average particle diameter within a range of 15 to 105 nm.
Abstract: An electrophotographic toner, which is decolorized by heating and a glossiness after decolorization of which is less than 10, comprising an electron donating color former compound, an electron accepting color developing agent, and a polyester binder resin.
Abstract: An electrostatic image developing toner contains a binder resin and at least two different kinds of white pigments, wherein from about 10% by weight to about 30% by weight of the at least two kinds of white pigments is porous titanium oxide having a volume average particle diameter of from about 0.01 ?m to about 1 ?m, a particle size distribution (volume average particle size distribution index GSDv) of from 1.1 to 1.3 and a BET specific surface area of from about 250 m2/g to about 500 m2/g.
Abstract: A process for forming polymer particles with aligned pores and controlled narrow particle size distribution, including: a) forming an oil phase by dissolving a polymeric binder in a solvent; b) dispersing the oil phase into a water phase containing a controlled amount of particulate stabilizer and forming an oil-in-water emulsion of controlled narrow dispersed oil phase droplet size distribution; c) freezing the emulsion to freeze solvent in the oil droplets to form frozen solvent domains within the polymeric binder, and also the water in the continuous water phase; and d) removing the frozen solvent from the polymeric binder and the frozen water in the continuous water phase, thereby forming porous polymer particles of controlled narrow particle size distribution and containing directional aligned non-spherical pore structures. Optionally, the porous particles may contain encapsulated functional ingredients.
Abstract: A transparent electrostatic charge image developing toner satisfies the relationships of the following Formulas (1), (2), and (3) wherein Dt (?m) is a volume average particle diameter, upper GSDv is an upper volume particle size distribution index, and lower GSDp is a lower number particle size distribution index: Formula (1): 18?Dt?30; Formula (2): 1.05?upper GSDv?1.20; and Formula (3): 1.29?lower GSDp?1.50.
Abstract: This invention provides metal oxide particles surface-treated with a cyclic silazane and a hydrophobicity-imparting agent, methods of making such, and toner compositions comprising the same.
Abstract: A radiation curable toner is described having at least a radiation curable binder (e.g. a UV curable polymer), a photoinitiator, and a wax; wherein the wax is present in a concentration ranging from 0.3 to 3% by weight. The ratio of scratch resistance before curing is preferably at least 2. The toner may be used in a developer, e.g. a two-component developer, for printing or copying.
Type:
Grant
Filed:
July 24, 2008
Date of Patent:
June 4, 2013
Assignee:
Xeikon Manufacturing N.V.
Inventors:
Werner Op De Beeck, Michel Vervoort, Lode Deprez
Abstract: A toner for hybrid development, comprising toner particles containing at least a binder resin and a colorant and being charged when made in friction-contact with a carrier; reverse polarity particles that are charged to polarity reversed to the charged polarity of the toner particles when made in friction-contact with the carrier, and have a number-average primary particle size in a range from 95 to 850 nm; and same polarity particles that are charged into the same polarity as the charged polarity of the toner particles when made in friction-contact with the carrier, and have a number-average primary particle size in a range from 80 to 800 nm and a shape factor in a range from 100 to 160; a developer for hybrid development containing the above toner and a carrier; and an image-forming apparatus provided with the developer for hybrid development.
Type:
Grant
Filed:
June 3, 2009
Date of Patent:
May 21, 2013
Assignee:
Konica Minolta Business Technologies, Inc.
Abstract: A developer includes a toner containing at least a binder resin, wherein the toner has a molecular weight distribution Mz/Mw of 2.0 or smaller and a phase angle of viscoelasticity of 65° or greater.
Abstract: An electrostatic image developing toner includes a binding resin and a release agent, wherein an organic silicon compound including a siloxane bond is present in a domain of the release agent.
Type:
Grant
Filed:
August 24, 2010
Date of Patent:
May 14, 2013
Assignee:
Fuji Xerox Co., Ltd.
Inventors:
Masaru Takahashi, Shinya Nakashima, Shuji Sato
Abstract: A magenta toner contains a binder resin; at least one selected from a diimonium compound represented by the following general formula (1) and an aminium compound represented by the following general formula (2); and a monomethylquinacridone: where in the general formulae (1) and (2), Rl, R2, R3, R4, R5, R6, R7 and R8 each independently represent a hydrogen atom, an unsubstituted or substituted and linear alkyl group, an unsubstituted or substituted and branched alkyl group, an unsubstituted or substituted and cyclic alkyl group, an unsubstituted or substituted and linear alkenyl group, an unsubstituted or substituted and branched alkenyl group, an unsubstituted or substituted and cyclic alkenyl group, or an unsubstituted or substituted aralkyl group; and X?represents an anion.
Abstract: The invention provides a toner composition comprising resin particles, a colorant, and a toner additive, wherein the toner additive comprises carbon-silica dual phase particles, wherein the carbon-silica dual phase particles comprise aggregates of carbon black comprising at least one silicon-containing region, and wherein the carbon-silica dual phase particles are distributed on the surface of the resin particles. The invention also provides a method of preparing the aforesaid toner composition.
Abstract: A toner for electrostatic image development containing an external additive comprising composite oxide particles made of titania and silica (external additive A), and hydrophobic silica particles (external additive B), wherein the external additive A has a core-shell structure in which a core portion is made of titania and a shell portion is made of silica, wherein the titania is contained in the external additive A in an amount of from 75 to 95% by weight, and wherein the external additive B has a carbon content of from 2.8 to 6.0% by weight. The toner for electrostatic image development of the present invention is suitably used in, for example, the development or the like of latent image formed in electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.
Abstract: Disclosed are a toner for developing an electrostatic image, a full color toner kit and an image formation method, the toner containing at least a resin and a colorant, wherein the colorant comprises a quinacridone pigment having a number average primary particle size of from 30 to 150 nm and having a ratio of a major axis direction length to a minor axis direction length of from 1.0 to 2.0 and Pigment Red 238.
Type:
Grant
Filed:
July 2, 2010
Date of Patent:
April 30, 2013
Assignee:
Konica Minolta Business Technologies, Inc.
Abstract: Provided is an electrostatic charge image developing toner capable of reproducing color exhibiting high lightness and chroma, and obtaining a wide color reproduction range. Disclosed is the toner possessing a toner particle containing at least a binder resin and a colorant, wherein the colorant possesses a yellowish color nonfluorescent dye exhibiting a peak wavelength of an absorption spectrum being in a wavelength range of 400-480 nm, and a fluorescent dye exhibiting a peak wavelength of an emission spectrum being in a wavelength range of 480-560 nm, wherein the nonfluorescent dye has a content of 2-8 parts by weight, based on 100 parts by weight of the binder resin, and the fluorescent dye has a content of 0.05-0.2 parts by weight, based on 100 parts by weight of the resin, provided that a content ratio of the nonfluorescent dye to the fluorescent dye is 15-150.
Type:
Grant
Filed:
December 7, 2010
Date of Patent:
April 30, 2013
Assignee:
Konica Minolta Business Technologies, Inc.
Abstract: Provided are an electrophotographic toner and a method of preparing the same. The toner includes a latex, a coloring agent, and a release agent, and has a selected amount of wax exposed on the surface of the toner.
Type:
Grant
Filed:
October 16, 2009
Date of Patent:
April 30, 2013
Assignee:
SAMSUNG Electronics Co., Ltd.
Inventors:
Yo-Da Shin, Jun-Young Lee, Jae-Hwan Kim, Tae-Hoe Koo
Abstract: The present disclosure provides toners having a tunable gloss level, electrophotographic apparatuses for using such toners as well as processes for making such toners.
Type:
Grant
Filed:
February 22, 2010
Date of Patent:
April 30, 2013
Assignee:
Xerox Corporation
Inventors:
Edward Graham Zwartz, T. Brian McAneney, Valerie M. Farrugia, Jordan H. Wosnick, Richard P. N. Veregin, Eric Rotberg
Abstract: Provided are a toner and a toner manufacturing method with which high image density and a broad range of color reproduction are obtained, and with which high-quality images are also obtained. The toner is composed of toner particles that comprise a binding resin containing a polyester resin and a colorant, and contains 10-1,500 ppm of a metal element selected from titanium, germanium, and aluminum, and a cyclic phenol sulfide represented by general formula (1) selected from thiacalixarene, sulfinyl thiacalixarene and sulfonyl thiacalixarene.
Type:
Grant
Filed:
June 26, 2009
Date of Patent:
April 30, 2013
Assignee:
Konica Minolta Business Technologies, Inc.
Abstract: Toner for electrophotography contains toner base particles containing a binder resin, a colorant, and a wax, resin particles containing a binder resin and a wax, but substantially not containing a colorant, and an external additive that is externally added to the toner base particles and the resin particles, with a mean domain diameter of the wax in the resin particles being larger than a mean domain diameter of the wax in the toner base particles.
Abstract: A capsule toner capable of enhancing low temperature fixation property without impairing preservation property under a high temperature environment, a two-component developer, and an image forming apparatus are provided. The capsule toner is constituted of toner particles having toner base particles and a coating layer for coating the surface thereof. The toner base particle includes styrene-acrylic resin or polyester resin as a binder resin, and the coating layer includes styrene-acrylic resin or polyester resin. The capsule toner contains 0.05% by weight or more and 0.70% by weight or less of volatile plasticizer based on a total amount of the capsule toner.
Abstract: Disclosed is a decolorable toner containing a binder resin and a coloring agent which contains a color former compound and a color developing agent and has a capsule structure such that it is covered with an outer shell, and having a volume average particle diameter of from 5.0 to 15.0 ?m and a number-based particle size distribution CV of 35% or less.
Abstract: A developer according to an embodiment includes toner particles, wherein the toner particles contain an amorphous polyester resin, a crystalline polyester resin, a coloring material, and a charge control agent containing metal elements of aluminum and magnesium, and have an endothermic peak temperature as measured by a differential scanning calorimeter (DSC) of from 90 to 100° C. and an acid value of from 9 to 19 mgKOH/g.
Abstract: A toner for developing an electrostatic latent image, the toner comprising: a releasing agent; and a binder resin, wherein: the releasing agent includes at least a first releasing agent material and a second releasing agent material, the first releasing agent material having a different melting point compared to the second releasing agent material; and a differential scanning calorimetric curve, obtained by measuring the toner for developing the electrostatic latent image by means of a differential scanning calorimeter, exhibits a shoulder at a temperature in a range of 50° C. to 53° C. corresponding to a glass transition temperature of the toner for developing the electrostatic latent image, and also exhibits a local maximum point at a temperature in a range of 90° C. to 95° C.
Abstract: A decolorable electrophotographic toner, containing a color former compound, a color developing agent, a binder resin, and a release agent, wherein the toner has a pH of from 6 to 9 when dispersed in water with a pH of from 5.5 to 7 at a mass ratio of toner/water of 1/10.
Abstract: Disclosed are a toner for developing an electrostatic image, a full color toner kit and an image formation method layer, the toner comprising at least a resin and a colorant, wherein the colorant includes quinacridone pigment having a number average primary particle size of from 30 to 150 nm and having a ratio of a long axis length to a short axis length of from 1.0 to 2.0.
Type:
Grant
Filed:
March 20, 2009
Date of Patent:
March 19, 2013
Assignee:
Konica Minolta Business Technologies, Inc.
Inventors:
Mikio Kouyama, Hiroshi Yamazaki, Ken Ohmura, Kenji Hayashi
Abstract: The present invention relates to a toner composition for forming a masking pattern for use e.g. in connection with a method of building up a three-dimensional body from a large number of mutually connected layers of powder particles that are bonded to each other using radiant heat. The toner composition consists of powder particles that arc able to withstand a temperature of at least 200° C. without sticking together. It also relates to a developer that comprises the toner composition and carrier particles and a method in connection with the production of a volume body by using a toner composition or a developer according to the invention.
Abstract: A polymerized toner is provided. The polymerized toner has cores containing polyvinylidene fluoride particles. The polyvinylidene fluoride particles have an average particle diameter of 1.1 to 1.5 ?m and a melting temperature (Tm) of 140 to 160° C. The polyvinylidene fluoride particles are distributed at a higher concentration near the surface of the cores. This distribution improves the affinity of the cores for silica as an external additive to achieve an increased amount of surface charge and improved transfer efficiency of the polymerized toner. Further provided is a method of producing the polymerized toner.
Abstract: There is provided a toner for electrostatic latent image developing, which includes a binder resin; a carbon black-surface treated with an isocyanate compound including a plurality of isocyanate groups which include one or more isocyanate groups that are not bonded to the carbon black; and a release agent having an acid value of about 5 mgKOH/g or higher and/or a hydroxyl value of about 5 mgKOH/g or higher.
Abstract: Coated phosphorescent pigments are provided which may be utilized in toner compositions. In embodiments, the phosphorescent pigment may be coated by a powder coating process. The large pigment particles may be dry blended with dried resin latex particles, thereby coating the pigment surface, followed by heating and shearing in a rotary kiln or extruder to melt the toner resin and fuse it to the pigment surface. The resulting coated particles may be utilized with other toners, in embodiments color toners, to provide phosphorescent images.
Type:
Grant
Filed:
June 29, 2009
Date of Patent:
March 12, 2013
Assignee:
Xerox Corporation
Inventors:
Richard P. N. Veregin, Eric Rotberg, Michael S. Hawkins, Cuong Vong, Jordan H. Wosnick
Abstract: The present invention relates to a polymerized toner and a method for preparing the same, wherein the toner can realize an excellent offset feature, high transfer efficiency, and a uniform image and thus can exhibit excellent performances in the applications of high speed copying, development of transferred photos, etc.
Abstract: A toner set is composed of toners of a plurality of colors that are used in a tandem-type color image forming apparatus. Each of the toners of a plurality of colors includes toner base particles and an external additive. The external additive includes small-diameter silica particles and large-diameter silica particles larger than the small-diameter silica particles. When, of the toners of a plurality of colors, three color toners to be used consecutively for forming the toner image are defined as a first toner, second toner and third toner respectively in order of usage thereof, the average particle diameter of the large-diameter silica particles contained in the second toner is smaller than the average particle diameter of the large-diameter silica particles contained in the first toner and is larger than the average particle diameter of the large-diameter silica particles contained in the third toner.
Abstract: A transparent toner for electrostatic latent image developing, including a binder resin and a release agent, the difference between Tm and Tc being from about 30° C. to about 50° C., wherein Tm is an endothermic peak temperature of the release agent determined in a temperature rising process and Tc is an exothermic peak temperature of the release agent determined in a temperature decreasing process, in a measurement by a differential scanning calorimeter (DSC) according an ASTM method, and the toner having a weight average molecular weight of from about 35,000 to about 70,000.
Abstract: The present disclosure provides an electrographic toner and methods for preparing an electrographic toner. In particular, the present disclosure provides an electrophotographic toner comprising a latex, a colorant and a releasing agent. The electrophotographic toner may further comprise zinc (Zn), iron (Fe), and silicon (Si). The [Zn]/[Fe] ratio may be in the range of about 5.0×10?2 to about 2.0. The [Si]/[Fe] ratio may be in the range of about 5.0×10?4 to about 5.0×10?2. [Zn], [Fe] and [Si] denote the intensities of Zn, Fe and Si, respectively, as measured by X-ray fluorescence spectrometry.
Type:
Grant
Filed:
January 27, 2010
Date of Patent:
February 26, 2013
Assignee:
Samsung Electronics Co., Ltd.
Inventors:
Kyeong Pang, Jae-Hwan Kim, Jin-Mo Hong, Su-Bum Park, Jeong-Hyun Lee, Mi-Rim Cho
Abstract: A toner composition that includes at least one low molecular weight amorphous polyester resin, at least one high molecular weight amorphous polyester resin, at least one crystalline polyester resin, at least one wax, at least one biocide and at least one colorant, and wherein the toner composition has a minimum fusing temperature of from about 100° C. to about 125° C.
Type:
Grant
Filed:
October 8, 2009
Date of Patent:
February 26, 2013
Assignee:
Xerox Corporation
Inventors:
Chieh-Min Cheng, Zhen Lai, Zhaoyang Ou, Dennis A. Mattison, Jr., Phil Dale, Christopher D. Blair, Steven M. Malachowski, Ryan Accetta
Abstract: A toner for non-contacting fusing containing toner matrix particles containing a resin binder and an external additive having an average particle size of from 10 to 100 nm, wherein the external additive is externally added to the toner matrix particles, wherein the resin binder contains one or more polyesters, wherein a carboxylic acid component of the polyester contains one or more isophthalic acid compounds and one or more fumaric acid/maleic acid compounds, wherein the isophthalic acid compound is contained in an amount of from 10 to 35% by weight, the fumaric acid/maleic acid compound is contained in an amount of from 1 to 15% by weight, and the isophthalic acid compound and the fumaric acid/maleic acid compound are contained in a total amount of from 20 to 36% by weight, of a total amount of the entire raw material monomers of the polyester in the resin binder, and wherein the toner has a softening point of from 90° to 120° C.
Abstract: A toner including a binder resin, a coloring agent, and a releasing agent, the toner formed by dispersing a toner liquid material which is prepared by dispersing the binder resin, the prepolymer, an elongation agent and/or a cross-linking agent for the prepolymer, the coloring agent, and the releasing agent in an organic solvent, dispersing the toner liquid material in an aqueous medium to obtain a liquid dispersion in at least one of cross linking reaction and elongation reaction, and removing the organic solvent from the liquid dispersion, and the toner satisfying the following relationship: 1.35< or =M(g)/M(p)< or =1.90, where M(g) represents the content of the gel composition formed in the at least one of cross linking reaction and elongation reaction and M(P) represents the content of the prepolymer in the toner liquid material when the total of M(P) and the content of the binder resin in the toner liquid material is set to be 100 g.
Abstract: To provide a yellow toner satisfying good toner particles and a superior coloring power, the toner has toner base particles having at least a binder resin, a colorant and a wax component, and contains as the colorant at least a coloring matter compound represented by the following general formula (1) and a pigment represented by the following formula (2).
Abstract: The present invention relates to a polymerized toner prepared by suspension polymerization. In particular, the polymerized toner comprises a plurality of toner particles that each comprising a binder resin, a pigment, a pigment stabilizer, a charge control agent, and a wax. The polymerized toner maintains a ratio of toner particles containing at least two wax domains per particle within a defined range. Thereby, the polymerized toner achieves high glossiness and good transfer efficiency.
Type:
Application
Filed:
July 26, 2012
Publication date:
January 31, 2013
Applicant:
LG CHEM, LTD.
Inventors:
Wook JANG, Chang-Soon LEE, Woo-Cheul JUNG, Joo-Yong PARK
Abstract: The present disclosure provides processes for producing images of excellent color fidelity when incorporating a cyan toner with a lower colorant loading in addition to a first cyan toner. In embodiments, the cyan pigmented particles may be cyan emulsion aggregation toners. In accordance with the present disclosure, a pair of cyan toners are matched in color, wherein the color of a first cyan toner printed at a predetermined halftone area coverage on a substrate substantially matches the color of the solid (100%) printed patch of the second cyan toner, which is lighter than the first cyan toner, thus avoiding a visible hue shift on the print that would otherwise be objectionable. In embodiments, the light cyan toner is color matched by adding a hue-adjusting colorant or combination of colorants which absorb wavelengths of light between 500 and 600 nanometers, and optionally adding a shade-adjusting colorant or combination of colorants which absorb wavelengths of light between 400 and 500 nanometers.
Type:
Grant
Filed:
January 19, 2010
Date of Patent:
January 15, 2013
Assignee:
Xerox Corporation
Inventors:
Daryl W. Vanbesien, Karen Ann Moffat, Yi Xin Gong, Edul N. Dalal, Jing Wang, Richard P. N. Veregin, Jordan H. Wosnick, Cuong Vong, Valerie M. Farrugia
Abstract: An electrostatic latent image developing toner includes: a release agent; a pigment; and a binder resin. The content of the pigment is from about 10% by weight to about 50% by weight, the glass transition temperature (Tg) of the toner is in the range of from about ?60° C. to about 20° C., and the Young's modulus at 20° C. is in the range of from about 1×100 MPa to about 1×103 MPa.
Type:
Application
Filed:
January 31, 2012
Publication date:
January 10, 2013
Applicant:
FUJI XEROX CO., LTD.
Inventors:
Satoshi KAMIWAKI, Kiyohiro YAMANAKA, Yusuke IKEDA, Koji SASAKI