Dry Toner With Chemically Identified Adjuvant (e.g., Charge Control Agent, Colorant, Etc.) Patents (Class 430/108.1)
  • Patent number: 8349531
    Abstract: Compounds and methods of forming compounds useful as a toner or toner precursor are disclosed. The compounds may include an aqueous dispersion, the dispersion including: (A) at least one thermoplastic resin; and (B) 0 to 5 weight percent of a stabilizing agent, based on the total weight of (A) and (B). The dispersion may have an average volume diameter particle size from about 0.05 to about 10 microns. A combined amount of the thermoplastic resin and the stabilizing agent may have an acid number of less than 25 mg KOH/g.
    Type: Grant
    Filed: November 26, 2008
    Date of Patent: January 8, 2013
    Assignee: Dow Global Technologies LLC
    Inventors: Timothy J. Young, Richard A. Lundgard, Michael J. Johnson, Qichun Wan, Matthew J. Kalinowski, Mechelle A. Churchfield, Gary M. Strandburg
  • Publication number: 20120328976
    Abstract: A toner including: a base resin; and charge-controlling resin particles contained in the base resin, wherein the toner is in shape of particles, and the charge-controlling resin particles are present in a region of each toner particle which is 500 nm in depth from a surface of the toner particle and an average of amounts of the charge-controlling resin particles present in the regions of the toner particles is 20% by volume to 70% by volume, wherein an average of embedment rates of the charge-controlling resin particles in the toner particles is 90% or higher, where each embedment rate is an average of embedment rates of the charge-controlling resin particles in each toner particle, and wherein the charge-controlling resin particles have a charge amount of 60 ?C/m2 or more as measured by a blow-off method.
    Type: Application
    Filed: June 18, 2012
    Publication date: December 27, 2012
    Inventors: Masahiro Seki, Yoshitaka Sekiguchi, Ryota Inoue, Kazuoki Fuwa
  • Publication number: 20120315574
    Abstract: A toner is provided that exhibits a high long-term image stability even during high-speed printing and that also exhibits an excellent environmental stability. The toner comprises a binder resin, a colorant, and a nonionic surfactant, wherein the nonionic surfactant has an oxyethylene group (EO) and an oxypropylene group (PO) and has a ratio of the number of moles of the oxypropylene group to the number of moles of the oxyethylene group (PO/EO) of at least 0.01 and not more than 5.00; and when A (?g/g) is defined as a nonionic surfactant content on the surface of the toner that can be extracted by methanol from 1 g of the toner and B (m2/g) is defined as a theoretical specific surface area determined from a toner particle diameter distribution obtained by a precision particle diameter distribution analyzer that operates based on an aperture electrical resistance method, a ratio A/B is at least 100 ?g/m2 and not more than 9000 ?g/m2.
    Type: Application
    Filed: May 12, 2011
    Publication date: December 13, 2012
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Katsuyuki Nonaka, Yasuhiro Hashimoto, Naoya Isono, Akira Sugiyama, Yuhei Terui
  • Patent number: 8329373
    Abstract: A method and an apparatus for producing toner are provided. A fluid comprising a resin and a colorant is supplied to a retention member that includes a film on which multiple discharge openings are formed. The fluid which is supplied to the retention member is resonated so that liquid droplets thereof are discharged from the multiple openings. The liquid droplets which are discharged from the multiple openings are solidified to form mother particles of a toner.
    Type: Grant
    Filed: October 23, 2009
    Date of Patent: December 11, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Yoshihiro Norikane, Shinji Aoki, Masaru Ohgaki, Yohichiroh Watanabe, Takahiro Honda, Andrew Mwaniki Mulwa, Yuko Sekiguchi
  • Patent number: 8329783
    Abstract: The present invention is toner particle that includes a continuous phase of binder polymer and a second phase of hydrocolloid. The particle has a porosity of at least 10 percent.
    Type: Grant
    Filed: December 7, 2010
    Date of Patent: December 11, 2012
    Assignee: Eastman Kodak Company
    Inventors: Mridula Nair, Xiqiang Yang, Tamara K. Jones, Jason Morgan
  • Patent number: 8323864
    Abstract: A toner to develop an electrostatic latent image which includes a latex, a colorant, and a release agent, wherein the toner has a complex viscosity (?*) in a range of about 2.5×102 to about 1.0×103 Pa·s and a loss tangent (tan ?) in a range of about 1.3 to about 2.3 at a temperature of about 160° C. and wherein the ?* is defined by a formula ?*=(G?2+G?2)½/w, and the tan ? is defined by a formula G?/G?, where G? is a storage elastic modulus and G? is a loss elastic modulus as determined under the following conditions of an angular velocity being about 6.28 rad/s and at a temperature increasing at a rate of about 2.0° C./min.
    Type: Grant
    Filed: December 29, 2009
    Date of Patent: December 4, 2012
    Assignee: SAMSUNG Electronics Co., Ltd.
    Inventors: Tae-hoe Koo, Min-young Cheong, Jun-young Lee, Jae-hwan Kim, Yo-da Shin
  • Patent number: 8318397
    Abstract: An electrophotographic toner and a method of preparing the same are provided. The electrophotographic toner includes a latex, a colorant, and a releasing agent, wherein the electrophotographic toner includes silicon (Si) and iron (Fe), each of the Si and Fe is in the range of about 3 to about 1,000 ppm, a mole ratio of Si to Fe (Si/Fe) is in the range of about 0.1 to about 5, an initiation temperature of a maximum heat absorption peak curve when a temperature increases in a heat absorption curve of the toner measured by a differential scanning calorimeter (DSC) is in the range of about 68 to about 89° C., and a peak temperature of the maximum heat absorption peak curve is in the range of about 86 to about 89° C.
    Type: Grant
    Filed: September 17, 2009
    Date of Patent: November 27, 2012
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Min-Young Cheong, Jun-Young Lee, Kyeong Pang, Soon-Cheol Jeong
  • Publication number: 20120295189
    Abstract: A two-component developer including at least a toner and a carrier. The toner includes a coloring particle prepared by agglutinating and fusing a resin particle having colorants and a resin particle having wax, and 0.2-2.0 wt. % hydrophobic silica and 0.01-1.0 wt. % a hydrotalcite-like compound as external additives. A shape coefficient of the toner is 0.93-0.99. The carrier includes at least a magnetic particle coated with a silicone resin layer, with a volume average particle diameter of 20-100 ?m.
    Type: Application
    Filed: July 8, 2011
    Publication date: November 22, 2012
    Applicant: HUBEI DINGLONG CHEMICAL CO., LTD.
    Inventors: Shunquan ZHU, Yubin WANG
  • Patent number: 8313884
    Abstract: A process for making toner particles is provided. In embodiments, a suitable process includes adding a defoamer to an emulsion utilized to form toner particles. Utilization of the defoamer allows for a reduction in the overall aggregation/coalescence cycle time and slurry viscosity, while producing a toner with improved GSDs, low coarse and target circularities.
    Type: Grant
    Filed: July 14, 2010
    Date of Patent: November 20, 2012
    Assignee: Xerox Corporation
    Inventors: Kimberly D. Nosella, Allan K. Chen, Zhen Lai, Zhaoyang Ou, Daryl W. Vanbesien
  • Patent number: 8313879
    Abstract: A full-color toner set including a yellow component, a cyan component, and a magenta component, wherein in each of the color components, resin fine particles are added to a surface of base particles. Further, the yellow component may include a monoazo pigment serving as a colorant in the base particles. In addition, the following formulae (1) and (2) may be satisfied, where the amount of addition of the resin fine particles based on 100 parts by mass of base particles in the yellow component is represented by Wy, the amount of addition of the resin fine particles based on 100 parts by mass of base particles in the cyan component is represented by Wc, and the amount of addition of the resin fine particles based on 100 parts by mass of base particles in the magenta component is represented by Wm, Wy>Wc??(1) Wy>Wm??(2).
    Type: Grant
    Filed: May 11, 2009
    Date of Patent: November 20, 2012
    Assignee: KYOCERA Document Solutions Inc.
    Inventor: Koji Kuramashi
  • Publication number: 20120288789
    Abstract: Environmentally friendly latex particles are provided which include a gelling agent and a pigment encapsulated in an amorphous resin which may be utilized in forming EA super low melt toners. Methods for providing these resins and toners are also provided.
    Type: Application
    Filed: May 11, 2011
    Publication date: November 15, 2012
    Applicant: XEROX CORPORATION
    Inventors: Hadi K. Mahabadi, Ke Zhou, Michelle N. Chrétien, Edward Graham Zwartz, Guerino G. Sacripante
  • Patent number: 8309288
    Abstract: A color toner is provided which has a dielectric strength equal to or lower than that of a black toner containing carbon black, and which has an improved charging rate and charge stability against changes in the environment.
    Type: Grant
    Filed: April 10, 2009
    Date of Patent: November 13, 2012
    Assignee: SAMSUNG Electronics Co., Ltd.
    Inventors: Hisao Okada, Mitsuru Oikawa
  • Patent number: 8304155
    Abstract: Images produced by electrophotography are often subjected to harsh conditions, such as high temperature and high relative humidity conditions. Prints when subjected to face-to-face stacking under these conditions tend to stick and are difficult to separate without damage. Ethylene-bis-stearamide is incorporated in a protective toner formulation employing a toner binder having a higher glass transition temperature than that of the conventional CYMK colored image toners employed to provide a protective layer in fused images. Further, ethylene-bis-stearamide does not interfere with typical oil release additives used in fuser rollers. By combining ethylene-bis-stearamide with polyalkane waxes having a weight average molecular weight of equal to or greater than 2000 and a poly dispersity of less than 2.0, addition protection can be realized.
    Type: Grant
    Filed: May 4, 2009
    Date of Patent: November 6, 2012
    Assignee: Eastman Kodak Company
    Inventors: Dinesh Tyagi, Walter B. Sherwood, Louise Granica
  • Patent number: 8304156
    Abstract: A magenta electrostatic developing toner includes binder resin particles that do not contain a coloring agent or a release agent and has a shape factor SF1 of about 110 or less, the number of the binder resin particles being about 50 or less per 5,000 electrostatic developing toner particles; and inorganic particles that have a median diameter of about 5 nm to about 70 nm in an amount of about 0.01 mass % to about 0.4 mass % based on the mass of the electrostatic developing toner; and a magenta coloring agent that has an azo group.
    Type: Grant
    Filed: November 17, 2009
    Date of Patent: November 6, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hitomi Akiyama, Junichi Tomonaga, Yasunobu Kashima
  • Patent number: 8304042
    Abstract: The present invention provides a recording medium containing a first image formed with a first recording material; and a second image comprising a first region formed with a second recording material having approximately the same light fastness as that of the first recording material, and a second region formed with a third recording material having higher light fastness than that of the first recording material, a color of the second region being a color corresponding to any stage of a process of discoloration of the first region.
    Type: Grant
    Filed: February 3, 2010
    Date of Patent: November 6, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yuka Ito, Takashi Matsubara, Shinji Hasegawa, Suguru Nakaso, Makoto Furuki, Minquan Tian
  • Patent number: 8298737
    Abstract: A white toner for electrostatic charge image development is disclosed. The white toner for electrostatic charge image development includes a binder resin, a first white pigment, a second white pigment, and a release agent, a specific gravity D1 of the first white pigment satisfying a condition of 3.5<D1<6.0, a specific gravity D2 of the second white pigment satisfying a condition of 0.3<D2<1.2, a total content of the first white pigment and the second white pigment being in the range of from about 20% by weight to about 50% by weight with respect to a total weight of the white toner for electrostatic charge image development, and the release agent including a metal salt.
    Type: Grant
    Filed: September 1, 2010
    Date of Patent: October 30, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yasuo Kadokura, Yukiaki Nakamura, Noriyuki Mizutani, Atsushi Sugawara, Yusuke Ikeda
  • Patent number: 8298741
    Abstract: An image forming apparatus includes plural developing units separately containing a toner A and a toner B that satisfy relationships (1) and (2) and have similar colors. The toner A and the toner B each contain a binder resin containing a polyester about 90 mass % or more of the binder resin, and about 90 mass % of the binder resin of the toner A and about 90 mass % of the binder resin of the toner B are the same resin. The polyester contains an amorphous polyester having an alkyl side chain and a crystalline polyester. The relationship (1) is Ta (toner A)>Tb (toner B) in terms of flow tester ½ effluent temperature. The relationship (2) is Aa (toner A)>Ab (toner B) in terms of an amount of an aluminum (with reference to net intensity) measured with fluorescent X-ray.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: October 30, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Satoshi Yoshida, Eisuke Iwazaki, Shintaro Anno
  • Patent number: 8298736
    Abstract: Provided is a toner comprising toner particles containing a binder resin and coloring matters, wherein the coloring matters comprise a dye represented by Formula (X-1), a metal compound represented by Formula (1) and a quinacridone pigment represented by Formula (2):
    Type: Grant
    Filed: May 15, 2009
    Date of Patent: October 30, 2012
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Naohiro Hirose, Hiroyuki Yasukawa, Natsuko Kusaka, Miyuki Murakami, Yohei Ohno
  • Patent number: 8293444
    Abstract: A toner that includes at least one polyester resin wherein the amount of free polyvalent acid monomer in the polyester resin is less than 4 mg/gram, and wherein the percentage of the at least one polyester resin with a MW less than 1500 is less than about 10%.
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: October 23, 2012
    Assignee: Xerox Corporation
    Inventors: John L. Pawlak, Timothy L. Lincoln, William H. Hollenbaugh, Jr., Yuhua Tong, Brendan H. Williamson
  • Patent number: 8293440
    Abstract: The present invention provides a white toner for electrostatic image development, including a binder resin, a first white pigment and a second white pigment, the specific gravity D1 of the first white pigment satisfies the relationship of about 3.5<D1<about 6.0, and the specific gravity D2 of the second white pigment satisfies the relationship of about 0.3<D2<about 1.2.
    Type: Grant
    Filed: May 14, 2010
    Date of Patent: October 23, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yukiaki Nakamura, Yasuo Kadokura, Noriyuki Mizutani, Atsushi Sugawara, Yusuke Ikeda
  • Patent number: 8293442
    Abstract: Disclosed is a resin particle having a volume average particle diameter of 10 nm to 500 nm, obtained by polymerizing an addition polymerizable monomer containing a silsesquioxane (a) represented by Formula (I) or by copolymerizing the silsesquioxane (a) with an addition polymerizable monomer (b), where R1 to R7 each independently represent a group selected from the group consisting of hydrogen, alkyl having 1 to 40 carbon atoms, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl; any hydrogen in the alkyl group is optionally substituted by fluorine and any —CH2— is optionally substituted by —O—, —CH?CH—, cycloalkylene or cycloalkenylene; any hydrogen in alkylene in the arylalkyl group is optionally substituted by fluorine and any —CH2— is optionally substituted by —O— or —CH?CH—; and A1 represents an addition polymerizable functional group.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: October 23, 2012
    Assignees: Ricoh Company, Ltd., JNC Corporation
    Inventors: Masaki Watanabe, Naohito Shimota, Hiroshi Yamashita, Naohiro Watanabe, Tsuneyasu Nagatomo, Tsuyoshi Sugimoto, Shinichi Wakamatsu, Kenya Itoh, Mikio Yamahiro
  • Patent number: 8293443
    Abstract: A toner formulation is disclosed comprising a binder and an IR absorbing black pigment at a concentration of 0.25-2.0% by weight, including one or more infrared transmissive pigments, wherein the infrared transmissive pigments are configured to provide a black color. Such toner formulation may provide a response to a toner patch sensor to indicate a mass per unit area of 0.1-1.5 mg/cm2 or a reflectance relative to a substrate to define a reflectance ratio that varies relative to L* values for the toner over the range L*=0-50 or a bulk reflectivity of greater than 6.0% for a portion of the wavelength range of 850-2000 nanometers.
    Type: Grant
    Filed: October 12, 2007
    Date of Patent: October 23, 2012
    Assignee: Lexmark International, Inc.
    Inventors: Albert Mann Carter, Jr., Gary Allen Denton, Joseph Edward Johnson, John Melvin Olson, Trent Peter, Cary Patterson Ravitz, Tao Yu
  • Patent number: 8288067
    Abstract: The present disclosure provides toners and processes for making said toners. In embodiments, the toners are invisible when viewed under natural light, but possess a UV additive that renders them visible when exposed to UV light of a specific wavelength. By selecting the appropriate UV additive and ionic crosslinker, with optional chelating agent, the gloss of the toner may be tailored to match the gloss of any substrate, such as paper, to which the toner is to be applied, thereby further enhancing its invisibility under visible light.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: October 16, 2012
    Assignee: Xerox Corporation
    Inventors: Yi Xin Gong, Shigang Qiu, Daryl W. Vanbesien, Gabriel Iftime, Edward Graham Zwartz, Karen Ann Moffat, Richard P. N. Veregin
  • Publication number: 20120251938
    Abstract: A method for producing colored resin particles including: dissolving or dispersing at least binder resin and colorant in organic solvent to prepare oil phase; dissolving resin A and basic compound in aqueous medium to prepare aqueous phase, the resin A having solubility <2.0 g/100 g water having temperature 25° C. and pH 3.0 and solubility ?2.0 g/100 g water having temperature 25° C. and pH 10.0; dispersing the oil phase in the aqueous phase to prepare core particle dispersion liquid; dispersing resin particles in aqueous medium to prepare resin particle dispersion liquid, and adding the resin particle dispersion liquid to the core particle dispersion liquid so that the resin particles are attached onto the core particles, to prepare dispersion liquid containing particles each having the core particle and the resin particles attached thereonto; removing the organic solvent from the dispersion liquid; washing the particles; and drying the particles.
    Type: Application
    Filed: February 1, 2012
    Publication date: October 4, 2012
    Inventors: Atsushi Yamamoto, Takuya Kadota, Yoshihiro Mikuriya, Tsuyoshi Nozaki, Yoshimichi Ishikawa, Kazuoki Fuwa, Tomohiro Fukao, Tomoharu Miki
  • Publication number: 20120251935
    Abstract: There is provided a toner for electrophotography containing at least a binder resin, a colorant and a barium compound, and having a relaxation modulus G(t) of from about 2.0×102 Pa to about 3.0×103 Pa in a relaxation time of t=10×Dt (wherein Dt is the heating time taken during fixing) as determined by the measurement of dynamic viscoelasticity, and a barium content of from about 0.1% to about 0.5% with respect to the total amount of constituent atoms in the toner as determined by X-ray fluorescence.
    Type: Application
    Filed: August 16, 2011
    Publication date: October 4, 2012
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Yuka ISHIHARA, Emi TAKAHASHI, Masahiro OKITA
  • Patent number: 8273515
    Abstract: A toner containing a lignin resin, a carbon-neutral biomass polymer having a low environmental load and taking global environmental protection into account, as a constitutional component of a binder resin, and having a wide fixing non-offset range and an excellent fixing property, is provided. The toner contains at least a binder resin, a colorant, and a release agent. Furthermore, in the toner, the binder resin includes a resin A that is a lignin resin and a resin B that is another resin component, and the resin B has a peak top molecular weight of 103 to 104 and an acid number of 20 or less.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: September 25, 2012
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Satoru Ariyoshi, Katsuru Matsumoto
  • Publication number: 20120237865
    Abstract: A toner set includes a plurality of toners, at least one toner but less than all toners of the toner set including binder, colorant and fluorescence agent and remaining additional toners including binder, colorant and free of fluorescence agent. At least a first toner grouping and a second toner grouping of the toner set form a combination, the first and second groupings of the combination exhibiting a substantially same color under ambient light conditions upon image formation. The first toner grouping and the second toner grouping of the combination contain a different amount of the fluorescence agent, wherein upon exposure to activating energy, the fluorescence agent fluoresces to cause a visible change in the color of a pattern formed in an image by the first toner grouping as compared to the second toner grouping.
    Type: Application
    Filed: May 30, 2012
    Publication date: September 20, 2012
    Applicant: XEROX CORPORATION
    Inventors: Peter M. KAZMAIER, Gabriel IFTIME, Daryl W. VANBESIEN, Edward G. ZWARTZ, Shen-ge WANG, Reiner ESCHBACH
  • Publication number: 20120237267
    Abstract: An electrostatic image developing toner including: toner particles each containing binder resin and colorant; and an external additive supported on the toner particles, wherein the toner particles each have protrusions on surface thereof, average of lengths of long sides of the protrusions is 0.10 ?m or more but less than 0.50 ?m, standard deviation of the lengths of the long sides of the protrusions is 0.20 or less, coverage rate of the protrusions on the surface of each toner particle is 30% to 90%, the external additive includes at least two different particles including external additive (A) and one or more external additives (B), external additive (A) has longest average primary particle diameter among the external additives and charged to have the opposite polarity to the toner particles, and at least one of the external additives (B) is charged to have the same polarity as the toner particles.
    Type: Application
    Filed: March 16, 2012
    Publication date: September 20, 2012
    Inventors: Tomohiro FUKAO, Takuya Kadota, Yoshihiro Mikuriya, Tsuyoshi Nozaki, Yoshimichi Ishikawa, Kazuoki Fuwa, Tomoharu Miki
  • Publication number: 20120237868
    Abstract: A toner including a binder resin, a colorant, and a release agent is provided. The toner has a peak loss tangent (tan ?) value of 3 or more within a temperature range of 80 to 160° C. Here, the loss tangent (tan ?) is a ratio (G?/G?) of a loss elastic modulus (G?) to a storage elastic modulus (G?). The toner provides a good combination of low-temperature fixability, hot offset resistance, storage stability, coloring power and/or opacifying power, and gloss.
    Type: Application
    Filed: February 24, 2012
    Publication date: September 20, 2012
    Inventors: Saori Yamada, Mitsuo Aoki, Hisashi Nakajima, Masashi Nagayama, Shigenori Yaguchi
  • Publication number: 20120237253
    Abstract: An electrostatic image developing toner including: toner particles; wherein the toner particles each contain: a core particle including a first resin and a colorant; and fine resin particles each formed of a second resin and existing in a surface of the core particle, wherein part of each fine resin particle is embedded in the core particle to form an embedded region, and the remaining part of the fine resin particle is exposed on the surface of the core particle to form an exposed region, and wherein each toner particle satisfies an expression of R1>R1? where, in a cross-section of the toner particle, R1? denotes an average diameter of openings of the first resin in which the second resin is embedded and R1 denotes an average diameter of the exposed regions.
    Type: Application
    Filed: March 12, 2012
    Publication date: September 20, 2012
    Inventors: Tomohiro FUKAO, Takuya Kadota, Yoshihiro Mikuriya, Tsuyoshi Nozaki, Yoshimichi Ishikawa, Kazuoki Fuwa, Tomoharu Miki
  • Patent number: 8268524
    Abstract: A black toner includes: toner mother particles containing carbon black as a colorant and a binder resin, the toner mother particles being surface-modified with a polyalkyleneimine.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: September 18, 2012
    Assignee: Seiko Epson Corporation
    Inventors: Masahiro Oki, Yoshihiro Ueno
  • Patent number: 8269018
    Abstract: A compound represented by Formula (X-1) is disclosed. in the formula, Rx1 and Rx2 each independently represents an alkyl group, Lx is a hydrogen atom or an alkyl group, Gx1 is an alkyl group having 2 or more carbon atoms, Gx2 is an alkyl group or an aromatic hydrocarbon group, Gx3 is a hydrogen atom, a halogen atom, a Gx4-CO—NH— group or a Gx5-N(Gx6)-CO—group, Gx5 and Gx6 each independently represents a hydrogen atom or a substituent, and Qx1, Qx2, Qx3, Qx4 and Qx5 each independently represents a hydrogen atom or a substituent. An electrophotographic toner containing the compound is also disclosed.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: September 18, 2012
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Kimihiko Ookubo, Ryohei Iwamoto, Koji Daifuku, Keiko Ishidai, Kaori Ono, Issei Nakahara
  • Patent number: 8252496
    Abstract: A method for producing a developing agent including preparing a dispersion liquid containing first fine particles containing a binder resin and second fine particles containing a color developable compound, a color coupler, and a color eraser, and aggregating the first and second fine particles in the dispersion liquid to form aggregated particles.
    Type: Grant
    Filed: February 11, 2010
    Date of Patent: August 28, 2012
    Assignee: Toshiba Tec Kabushiki Kaisha
    Inventors: Takahito Kabai, Tsuyoshi Itou
  • Patent number: 8252493
    Abstract: Single component toners are provided with at least one surface additive including a large polymeric spacer, and processes for producing the same. In embodiments, the toner is a non-magnetic single component toner produced by emulsion aggregation methods. The large polymeric spacer additives provide excellent flow characteristics to the resulting toners, and reduce the incidence of clogging failure and print defects such as ghosting, white bands, and low toner density compared with conventionally produced toners.
    Type: Grant
    Filed: October 15, 2008
    Date of Patent: August 28, 2012
    Assignee: Xerox Corporation
    Inventors: Samir Kumar, Grazyna L. Kmiecik-Lawrynowicz, Maura A. Sweeney, Michael L. Grande, Julie C. Pickering, Timothy L. Lincoln
  • Patent number: 8252497
    Abstract: A toner, has a number mode diameter of 3 ?m or more and 6 ?m or lower and a particle size distribution of a toner including an externally-applied agent in the range of 0.6 ?m to 400 ?m in which the number frequency of a toner smaller than the number mode diameter is smaller than the number frequency of a toner equal to or larger than the number mode diameter.
    Type: Grant
    Filed: April 12, 2010
    Date of Patent: August 28, 2012
    Assignee: Seiko Epson Corporation
    Inventors: Soichi Yamazaki, Takatomo Fukumoto, Hideki Okada, Toshikazu Ono
  • Patent number: 8252494
    Abstract: A fluorescent particle includes a fluorescent pigment, such as a trans-dicarboxylic-indenofluorenone, and at least one stabilizing wax chemically attached to the fluorescent pigment. The stabilizing wax includes an amine group at its terminal end and the fluorescent pigment includes at least one carboxylic acid group, where the amine group reacts with the carboxylic acid group to form an amide bond. A method for making fluorescent particles for use in toners by chemically attaching at least one stabilizing wax to a fluorescent pigment where the at least one stabilizing wax includes an amine group at its terminal end and the fluorescent pigment includes at least one carboxylic acid group. A toner may include a resin and the fluorescent particle.
    Type: Grant
    Filed: May 3, 2010
    Date of Patent: August 28, 2012
    Assignee: Xerox Corporation
    Inventors: Daryl W. Vanbesien, Maria M. Birau, C. Geoffrey Allen, Carol A. Jennings, Peter G. Odell
  • Patent number: 8252492
    Abstract: An embodiment of toner for electrostatic development may include toner base particles, and resin fine particles. Further, some embodiments may include external additives, such as hydrophobic silica. In some embodiments, the resin fine particles may include a polymer having an isobornyl group-containing acrylate monomer.
    Type: Grant
    Filed: May 21, 2009
    Date of Patent: August 28, 2012
    Assignee: KYOCERA Document Solutions Inc.
    Inventor: Koji Kuramashi
  • Publication number: 20120214095
    Abstract: An image forming apparatus including an image forming device forming a toner image on a recording material, and a fixing device including an endless fixing belt feeding the recording material at a speed of 400 to 1,700 mm/sec while heating to fix the toner image thereon. The fixing belt has a rubber layer located on a substrate and having thickness of 400 ?m to 700 ?m, and a fluorine-containing resin layer located on the rubber layer and having thickness of 2 ?m to 20 ?m. The toner includes a release agent including a microcrystalline wax and/or a synthetic ester wax, and a binder resin including a crystalline polyester and an amorphous polyester. The ratio (W/R) of the height (W) of the third falling peak of the crystalline polyester to the height (R) of the maximum rising peak of the amorphous polyester in the FT-IR spectrum of the toner is 0.045 to 0.850.
    Type: Application
    Filed: February 9, 2012
    Publication date: August 23, 2012
    Applicant: RICOH COMPANY, LTD.
    Inventors: Hyo Shu, Hiroki Ishii, Wakana Itoh
  • Publication number: 20120206548
    Abstract: A method of dynamically controlling a perceived ink color printed on a substrate can include mixing selected amounts of each of a polystyrene nano-sphere dopant component and a nano-particle dopant component with a clear fluid carrier component, the mixed components configured in real time to define an ink structure having a predetermined wavelength. The method can further include imaging the substrate by ejecting the mixed components onto the substrate, the perceived color of the imaged substrate corresponding to a reflected wavelength of the ink structure. In embodiments, each of the carrier and dopant components can be in a powder form suitable for fuser type imaging devices.
    Type: Application
    Filed: February 15, 2011
    Publication date: August 16, 2012
    Applicant: XEROX CORPORATION
    Inventor: Aillil Ian Halsema
  • Publication number: 20120202148
    Abstract: Disclosed is a toner which comprises particles comprising: (a) a core comprising: (1) a first resin; and (2) a first conductive colorant; and (b) a shell comprising: (1) a second resin; and (2) a second conductive colorant.
    Type: Application
    Filed: February 4, 2011
    Publication date: August 9, 2012
    Applicant: XEROX CORPORATION
    Inventors: Richard P. N. Veregin, Kimberly D. Nosella, Cuong Vong, Abdisamed Sheik-Qasim, Melanie Davis, Suxia Yang, Majid Kamel-Kasmaei, Paul J. Gerroir
  • Patent number: 8236471
    Abstract: A toner for developing an electrostatic charge image, the toner including a binder resin containing a crystalline polyester resin and a noncrystalline polyester resin, a colorant, a releasing agent, a ketone solvent, and an alcoholic solvent, the total concentration of the ketone solvent and the alcoholic solvent in the toner dispersion liquid being less than about 10 ppm when 0.5 g of the toner is dispersed in 2 g of deionized water to form a toner dispersion liquid, and the total concentration of the ketone solvent and the alcoholic solvent in the toner dispersion liquid being from about 2 ppm to about 50 ppm when 0.5 g of the toner is dispersed in 2 g of N,N-dimethylformamide to form a toner dispersion liquid.
    Type: Grant
    Filed: April 27, 2009
    Date of Patent: August 7, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Shinpei Takagi, Satoshi Yoshida
  • Publication number: 20120196221
    Abstract: A black toner composition comprising toner particles prepared by a chemical process of manufacture comprising carbon black pigment, a first addition polymer comprising carboxylic acid groups along the polymer backbone, and a thermoplastic second polymer binder distinct from the first polymer, wherein the first polymer has an Acid Value of from 30 to 220 and is present at a weight ratio of greater than 1:2 relative to the amount of carbon, and at a relatively lower weight percent than the second polymer.
    Type: Application
    Filed: January 31, 2011
    Publication date: August 2, 2012
    Inventors: Dinesh Tyagi, Louise Granica
  • Patent number: 8232035
    Abstract: According to embodiments illustrated herein, there is provided a black toner having a resin, an optional additive, and at least two or more colored pigments, and the at least two or more colored pigments are selected from the group consisting of a blue pigment, a green pigment, a red pigment, a magenta pigment, a cyan pigment, a yellow pigment, a white pigment, and mixtures thereof, and the black toner has a colorimetric value L* of about less than 30.
    Type: Grant
    Filed: August 26, 2010
    Date of Patent: July 31, 2012
    Assignee: Xerox Corporation
    Inventors: Mark Scheuer, Mark Petrush, James Winters, John Ianni, Julia Kohlmeier, William Hollenbaugh, Jr., Kip Jugle, Jeffrey McEwen
  • Patent number: 8232033
    Abstract: A toner, a developer, a two-component developer, a developing device and an image forming apparatus are provided. In the image forming apparatus, images are formed with a developer that fills a developing tank of the developing device. The developer includes the toner containing at least a binder resin, a colorant, and a release agent, the release agent having an acid value of less than 4 mgKOH/g and in which an amount of the release agent exposed on a surface of toner is 0.5% by weight or more and 2.5% by weight or less of a total amount of the toner.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: July 31, 2012
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yoritaka Tsubaki, Hiroshi Onda, Yasuo Imura
  • Patent number: 8232036
    Abstract: A toner for electrophotography includes toner particles containing at least a binder resin and a colorant, to which strontium titanate and hydrophobic silica as external additives are admixed, wherein the strontium titanate has a BET specific surface area of 20-50 m2/g and contains particles in a rectangular parallelepiped shape and wherein the hydrophobic silica contains hydrophobic silica A that has at least a BET specific surface area of 150-300 m2/g and the surface of which has been treated with an aminosilane and hexamethyldisilazane and hydrophobic silica B that has at least a BET specific surface area of 90-150 m2/g and the surface of which has been treated with hexamethyldisilazane.
    Type: Grant
    Filed: September 3, 2008
    Date of Patent: July 31, 2012
    Assignee: Tomoegawa Co., Ltd.
    Inventors: Tohru Moriya, Hitoshi Onoda, Kazuyoshi Hattori, Yoshihito Suwa
  • Patent number: 8232034
    Abstract: The disclosure provides an electrophotographic toner and methods for preparing the electrographic toner. The electrographic toner includes a binder, a colorant and a releasing agent, wherein the electrophotographic toner includes strontium (Sr), iron (Fe), titanium (Ti), and silicon (Si) containing particles; wherein, if [Sr], [Fe], [Ti] and [Si] denote the intensities of Sr, Fe, Ti, and Si in the electrophotographic toner, respectively, as measured by X-ray fluorescence spectrometry, then the [Sr]/[Fe] ratio is in the range of about 5.0×10?1 to about 4.5, the [Ti]/[Fe] ratio is in the range of about 5.0×10?1 to about 8.1×10?1, and the [Si]/[Fe] ratio is in the range of about 2.0×10?3 to about 4.0×10?3.
    Type: Grant
    Filed: August 10, 2010
    Date of Patent: July 31, 2012
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Kyung-yeon Kang, Sang-yup Kim, Hong-chul Shin, Sung-jin Park
  • Publication number: 20120189951
    Abstract: A toner including: a binder resin component; crystal nucleating agent; releasing agent; and colorant, wherein the binder resin component contains a crystalline polyester resin and a non-crystalline polyester resin, the crystal nucleating agent is at least one of an aliphatic ester compound and an aliphatic amide compound each having a melting point of 60° C. or higher but lower than 150° C., and wherein the toner satisfies Expressions (I) and (II): Tc>Tp+10??Expression (I) Tm>Tp+2??Expression (II) where Tp denotes lowest exothermic peak temperature [° C.] in 0° C. to 200° C. in DSC curve obtained DSC of the crystalline polyester resin, Tc denotes lowest exothermic peak temperature [° C.] in 0° C. to 200° C. in DSC curve obtained DSC of the crystal nucleating agent, and Tm denotes lowest exothermic peak temperature [° C.] in 0° C. to 200° C. in DSC curve through DSC of the mixture of the crystalline polyester resin and the crystal nucleating agent.
    Type: Application
    Filed: December 23, 2011
    Publication date: July 26, 2012
    Inventors: Tsuyoshi SUGIMOTO, Hiroshi Yamashita, Daisuke Asahina, Masaki Watanabe, Satoyuki Sekiguchi, Rintaro Takahashi
  • Publication number: 20120189952
    Abstract: An electrophotographic toner and a process for preparing the same. The electrophotographic toner includes a binder, a coloring agent, and a release agent. The binder includes two resins having different weight average molecular weights.
    Type: Application
    Filed: January 20, 2012
    Publication date: July 26, 2012
    Applicant: Samsung Electronics Co.,
    Inventors: Jy-yeon Lee, Jun-Young Lee, Kyeong Pang, Tae-Hoe Koo, Su-bum Park
  • Patent number: 8227159
    Abstract: The present disclosure provides toner particles having excellent charge characteristics. In embodiments, a toner particle of the present disclosure includes a cation binding material possessing cation binding groups. Processes for producing toners with these cation binding materials are also provided. The resulting toners exhibit excellent stability with respect to relative humidity and excellent charging characteristics.
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: July 24, 2012
    Assignee: Xerox Corporation
    Inventors: Richard P. N. Veregin, Daryl W. Vanbesien, Cuong Vong
  • Patent number: 8221537
    Abstract: The invention relates to aqueous pigment preparations containing (A) at least one organic and/or inorganic pigment, (B) a dispersant of formula (I) or (II), or mixtures of the dispersants of formula (I) and (II), (C) optionally wetting agents, (D) optionally other surfactants and/or dispersants, (E) optionally one or more organic solvents or one or more hydrotropic substances, (F) optionally other additives used conventionally for the production of aqueous pigment dispersions and (G) water.
    Type: Grant
    Filed: April 29, 2008
    Date of Patent: July 17, 2012
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bjoern Fechner, Carsten Schaefer, Alexander Woerndle