Silver Salt Transfer Process Patents (Class 430/244)
  • Patent number: 4568634
    Abstract: The present invention relates to a composition for processing, by the silver salt diffusion transfer technique, a photographic material which contains a developing agent and at least one each of a silver halide photographic emulsion layer and an image receiving layer containing nuclei for physical development. The composition contains about 0.03 mol/l to about 0.10 mol/l of a phosphate salt and about 0.3 mol/l to about 1.0 mol/l of a compound of the following formula (I): ##STR1## wherein R is a hydrogen atom or a lower alkyl group having 1 to 4 carbon atoms; R.sup.1 is a hydrogen atom or a lower alkyl group having 1 to 4 carbon atoms; R.sup.2 and R.sup.3 are each a hydrogen atom or a hydroxyl group, respectively; m and n are each 0 or 1, provided that m and n are not 0 at the same time. The processing composition allows for obtaining a high contrast image by the silver salt diffusion transfer technique.
    Type: Grant
    Filed: November 14, 1984
    Date of Patent: February 4, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Katsumi Hayashi
  • Patent number: 4562140
    Abstract: Disclosed is a photosensitive material which comprises a support and at least an undercoating layer and a silver halide emulsion layer, said undercoating layer containing a matting agent having an average particle size larger than the thickness of the undercoating layer. Use of this photosensitive material for diffusion transfer process causes neither slipping between the photosensitive material and the image receptive layer nor pinholes in silver images.
    Type: Grant
    Filed: October 11, 1984
    Date of Patent: December 31, 1985
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Isao Kohmura, Jun Miura, Norio Kajima
  • Patent number: 4546062
    Abstract: Polymeric optical filter agents and products and processes using same are disclosed. The polymeric optical filter agents are pH-sensitive materials comprising a polymeric backbone having a plurality of pendant moieties of the formula (I). ##STR1## wherein X is ##STR2## and R is alkyl, aryl, alkaryl or aralkyl; A is hydrogen, alkyl or the radical ##STR3## where each of Y.sup.1, Y.sup.2 and Y.sup.3 is hydrogen or an electron-withdrawing group; and each Z.sup.1, Z.sup.2 and Z.sup.3 is hydrogen or an electron-withdrawing group; with the proviso that, when each of Z.sup.1, Z.sup.2 and Z.sup.3 is hydrogen, said A is a radical ##STR4## wherein at least one of said Y.sup.1, Y.sup.2 and Y.sup.3 groups comprises an electron-withdrawing group. These agents upon contact with alkali are converted from a substantially non-light absorbing form to a highly colored light-absorbing form useful in photographic products.
    Type: Grant
    Filed: July 30, 1984
    Date of Patent: October 8, 1985
    Assignee: Polaroid Corporation
    Inventors: Irena Y. Bronstein-Bonte, Edward P. Lindholm
  • Patent number: 4456674
    Abstract: This invention relates to diffusion transfer processes and products wherein the transmission density of the pigmented processing composition layer is increased by employing an alkali earth metal salt to increase the light-absorbing ability of a carboxynaphthol phthalein optical filter agent within said processing composition layer. In another embodiment, a carboxyindole phthalein optical filter agent also is included in said processing composition layer, and a zinc or cadmium salt is employed to shift the spectral absorption of the carboxyindole phthalein into the green region of the visible spectrum. In a further embodiment, a calcium salt is employed in a viscous pigmented processing compositon comprising a light-reflecting pigment, colloidal silica and a metal chelating agent, e.g., an alkylene polyamine polyacetic acid to stabilize the spreading characteristics of the compositions.
    Type: Grant
    Filed: July 25, 1983
    Date of Patent: June 26, 1984
    Assignee: Polaroid Corporation
    Inventors: Leon D. Cerankowski, Gary S. LaPointe, Neil C. Mattucci
  • Patent number: 4416971
    Abstract: In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein each R.sup.1 is the same and is selected from ##STR2## R.sup.2 is alkyl, R.sup.3 is an electron-withdrawing group positioned ortho, meta or para to said N atom, R.sup.4 is hydrogen, alkyl or an electron-withdrawing group positioned ortho, meta or para to said N atom; R.sup.5 is alkyl; X is hydrogen, an electron-withdrawing group or an electron-donating group; and A is an anion. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds, e.g., as photographic light-screening dyes.
    Type: Grant
    Filed: December 28, 1982
    Date of Patent: November 22, 1983
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Louis Cincotta, John W. Lee, Jr.
  • Patent number: 4386151
    Abstract: A silver diffusion transfer film unit which comprises, in order, a support, a silver precipitating layer, a protective layer comprising chitosan having a copper salt and a polyol selected from the group consisting of glycerol, sorbitol, polyvinyl alcohol, inositol, ethylene glycol, propylene glycol and hydroxyethyl cellulose disposed therein, a release layer, and a photosensitive silver halide layer. In a particularly preferred embodiment, the film unit is an additive color diffusion transfer film unit.
    Type: Grant
    Filed: July 22, 1982
    Date of Patent: May 31, 1983
    Assignee: Polaroid Corporation
    Inventors: Michael Berger, Charles H. Byers, John J. Magenheimer
  • Patent number: 4383022
    Abstract: A silver diffusion transfer film unit which comprises, in order, a support carrying a silver precipitating layer, a protective layer comprising chitosan having a copper salt and gelatin disposed therein, a release layer and a photosensitive silver halide layer. In a particularly preferred embodiment, the film unit is an additive color diffusion transfer film unit.
    Type: Grant
    Filed: June 28, 1982
    Date of Patent: May 10, 1983
    Assignee: Polaroid Corporation
    Inventor: Michael Berger
  • Patent number: 4367277
    Abstract: Diffusion transfer films and processes are disclosed wherein the processing composition includes a light-reflecting pigment and an optical filter agent, and the image-receiving layer carries over it a layer of unhardened gelatin adapted to decolorize optical filter agent immediately adjacent the interface between said processing composition and said decolorizing layer.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: January 4, 1983
    Assignee: Polaroid Corporation
    Inventors: Charles K. Chiklis, Neil C. Mattucci
  • Patent number: 4366227
    Abstract: A diffusion transfer film unit comprising a support, a photosensitive silver halide emulsion layer, an image-receiving layer and, intermediate said silver halide emulsion layer and said image-receiving layer, a release layer which comprises a water-soluble polymer and a styrenated acid functional acrylic resin. In a preferred embodiment, the film unit is a silver diffusion transfer film unit.
    Type: Grant
    Filed: June 26, 1981
    Date of Patent: December 28, 1982
    Assignee: Polaroid Corporation
    Inventors: Michael Berger, John J. Magenheimer
  • Patent number: 4362806
    Abstract: Photographic elements, multicolor filters and receivers are disclosed having supports providing microvessels for materials such as radiation-sensitive materials, imaging materials, mordants, silver precipitating agents and materials which are useful in conjunction with these materials. Processes of forming microvessels and introducing materials therein are also disclosed. Processes of forming images are disclosed employing microvessel containing elements. Image transfer processes are disclosed for producing one or a combination of silver and multicolor subtractive primary images alone or in combination with multicolor additive primary images.
    Type: Grant
    Filed: September 8, 1980
    Date of Patent: December 7, 1982
    Assignee: Eastman Kodak Company
    Inventor: Keith E. Whitmore
  • Patent number: 4362811
    Abstract: A processing solution composition for treating an image receiving layer in silver complex diffusion transfer process, which contains 1.7.times.10.sup.-3 to 1.7.times.10.sup.-2 mole/liter of a bromide and 2.0 to 12.0 mole-% of potassium ion based on total cations of the salts contained in the composition accelerates the transfer speed and gives a silver image high in maximum density, contrast and sharpness to the image.
    Type: Grant
    Filed: July 10, 1981
    Date of Patent: December 7, 1982
    Assignee: Mitsubishi Paper Mills Ltd.
    Inventors: Shigeru Iguchi, Shozi Oka
  • Patent number: 4359518
    Abstract: A stripping sheet adapted for use with a diffusion transfer film unit to remove at least the photosensitive layer from said film unit subsequent to processing is disclosed, as well as methods for using said stripping sheet, wherein said stripping sheet comprises a support, carrying in order, a water-absorbing layer, and a layer capable of conversion from substantial liquid processing composition impermeability to a condition of substantial liquid processing composition permeability.
    Type: Grant
    Filed: June 26, 1981
    Date of Patent: November 16, 1982
    Assignee: Polaroid Corporation
    Inventors: Raymond B. Hanselman, Karl J. Schreiber
  • Patent number: 4357407
    Abstract: Process for the production of a reverse reading positive line and/or halftone image suited for use in the production of a lithographic offset printing plate, said process comprising the steps of:(1) photo-exposing a photographic negative working silver halide emulsion material comprising a negative working silver halide emulsion layer on a transparent film support and an anti-halation layer either between the emulsion layer and the film support or at the side of said support opposite the emulsion layer, the exposure of the emulsion layer occurring through the support and the anti-halation layer in a camera without a reversing optical system,(2) bringing the emulsion layer side of the photographic material into contact with an image-receiving material to form by diffusion transfer processing a visible silver image upon the latter, and(3) separating the photographic material from the image-receiving material.
    Type: Grant
    Filed: April 6, 1981
    Date of Patent: November 2, 1982
    Assignee: AGFA-Gevaert N.V.
    Inventors: Leon L. Vermeulen, Albert L. Poot, Jozef W. Van den Houte
  • Patent number: 4324853
    Abstract: A processing composition adapted for use in a silver diffusion transfer process which includes a saturated polyol containing at least 3 hydroxyl groups wherein each hydroxyl group is no more than 3 carbon atoms away from another hydroxyl group.
    Type: Grant
    Filed: July 18, 1979
    Date of Patent: April 13, 1982
    Assignee: Polaroid Corporation
    Inventor: Michael Berger
  • Patent number: 4316950
    Abstract: In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein each R.sup.1 the same or different is hydrogen or alkyl, each R.sup.2 the same or different is alkyl or phenyl, R.sup.3 is phenyl or alkyl, Y is an electron-withdrawing group and A is an anion. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: February 23, 1982
    Assignee: Polaroid Corporation
    Inventors: Louis Cincotta, James W. Foley
  • Patent number: 4309499
    Abstract: A black-and-white negative image forming process is disclosed using a diffusion transfer type film unit. An exposed silver halide emulsion comprising internal latent image type silver halide grains which have substantially no fogging centers at their surface is processed with a composition comprising a silver halide solvent, a developing agent, a foggant, alkali and a fog promoting agent. The solvent for the silver halide characteristically possesses a solubilizing power for AgBr of from about 2.times.10.sup.-5 to 5.times.10.sup.-3 mol/l in a 0.002 molar aqueous solution.
    Type: Grant
    Filed: November 14, 1979
    Date of Patent: January 5, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Takagi, Katsumi Hayashi
  • Patent number: 4304834
    Abstract: In one embodiment, the present invention is concerned with novel xanthene compounds selected from those of the formulae ##STR1## wherein each R.sup.1 the same or different is alkyl, each R.sup.2 the same or different is an electron-withdrawing group having a positive sigma value greater than 0.6, X is ##STR2## wherein R.sup.3 is alkyl, Y is an electron-withdrawing group, n is 0 or 1 and A is an anion. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds, e.g., as photographic light-screening dyes.
    Type: Grant
    Filed: July 17, 1980
    Date of Patent: December 8, 1981
    Assignee: Polaroid Corporation
    Inventors: Richard L. Cournoyer, James W. Foley
  • Patent number: 4304833
    Abstract: The present invention is concerned with photographic products and processes, particularly diffusion transfer products and processes employing certain colored triarylmethane compounds possessing in their triaryl structure a 4'-oxo-1'-naphthylidene (or a 4'-oxo-1'-phenylidene) moiety, a naphthyl (or phenyl moiety) and a phenyl moiety substituted in the ortho-position to the central carbon atom with a non-nucleophilic group that cannot add to the central carbon atom but in alkaline solution undergoes an irreversible cleavage reaction with base that is complete within a predetermined time at a predetermined alkaline pH to provide a nucleophilic moiety that adds to the central carbon atom to form a ring-closed compound which is colorless.
    Type: Grant
    Filed: May 22, 1980
    Date of Patent: December 8, 1981
    Assignee: Polaroid Corporation
    Inventor: James W. Foley
  • Patent number: 4299908
    Abstract: A method for forming a negative image comprising imagewise exposing a photographic material to provide exposed areas and unexposed areas, said material comprising, on a support, (1) an emulsion layer containing a light-sensitive silver halide, (2) unsensitized silver halide metallic salt grains which are more soluble in a developer than the light sensitive silver halide, and (3) nuclei for physical development, processing said material in the presence of a reducing agent and a solvent for said grains with said developer containing a substance which renders said grains less soluble by adsorbing thereto, said developer rendering said grains in said exposed areas and not in said unexposed areas soluble in said solvent, whereby metal ions are released and deposited on said nuclei.
    Type: Grant
    Filed: April 10, 1980
    Date of Patent: November 10, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Noboru Ito, Eiichi Sakamoto, Mikio Kawasaki, Takashi Uchida
  • Patent number: 4298677
    Abstract: A silver diffusion transfer photographic process using a silver halide photosensitive emulsion layer comprising silver iodochlorobromide or silver iodobromide wherein the iodide comprises from about 6 to 25 mole % of the halide content.
    Type: Grant
    Filed: June 9, 1980
    Date of Patent: November 3, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Takagi, Masakado Sakai
  • Patent number: 4298676
    Abstract: Optical filter agents and photographic products and processes using same are disclosed. The optical filter agents are pH-sensitive hydrazone compounds conforming to the following structural formula: ##STR1## where R is any group which can provide a double bond for conjugation with the ##STR2## portion of the compound to provide light-absorbing capability or color for the agent at a pH above its pKa, X is a substituent of R providing at least one electron-withdrawing group and each R' can be defined as any substituent that does not impair the light-absorbing capacity of the compound at a pH above the pKa thereof. The pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The pH-sensitive optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosensitive elements against the occurence of fogging during in-light development.
    Type: Grant
    Filed: October 29, 1979
    Date of Patent: November 3, 1981
    Assignee: Polaroid Corporation
    Inventors: Derek H. R. Barton, Irena Y. Bronstein-Bonte, Lloyd D. Taylor
  • Patent number: 4269925
    Abstract: Polymeric optical filter agents and photographic products and processes using same are disclosed. The polymeric optical filter agents are pH-sensitive optical filter agents comprising polymeric backbone units having the following hydrazone moiety: ##STR1## where R is a group which can provide a double bond for conjugation with the ##STR2## portion of the moiety to provide light-absorbing capability for the agent at a pH above its pKa, and X represents a substituent of R providing at least one electron-withdrawing group. The polymeric pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The polymeric optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosensitive elements against the occurence of fogging during in-light development.
    Type: Grant
    Filed: October 29, 1979
    Date of Patent: May 26, 1981
    Assignee: Polaroid Corporation
    Inventors: Derek H. R. Barton, Irena Y. Bronstein-Bonte, Lloyd D. Taylor
  • Patent number: 4267255
    Abstract: A processing composition adapted for use in a silver diffusion transfer film unit which comprises an aqueous alkaline solution, a silver halide developing agent and a surfactant comprising a hydrophobe and a polyethylene oxide portion containing an average of about 5-25 repeating units of ethylene oxide per hydrophobe.
    Type: Grant
    Filed: December 12, 1979
    Date of Patent: May 12, 1981
    Assignee: Polaroid Corporation
    Inventor: Karl J. Schreiber
  • Patent number: 4258119
    Abstract: In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein X is ##STR2## wherein R' is alkyl, Y is an electron-withdrawing group and n is 0 or 1. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: March 24, 1981
    Assignee: Polaroid Corporation
    Inventors: Richard L. Cournoyer, James W. Foley
  • Patent number: 4258118
    Abstract: In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein R' is alkyl; Y is an electron-withdrawing group and A is an anion. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: March 24, 1981
    Assignee: Polaroid Corporation
    Inventors: James W. Foley, Louis Locatell, Jr., Charles M. Zepp
  • Patent number: 4232107
    Abstract: Said material contains a quinone-type compound which corresponds to one of the formulae (A) or (B) and which is capable in reduced state and under alkaline conditions of releasing a photographically useful group e.g. a dye: ##STR1## wherein: each of (Nuox).sup.1 and (Nuox).sup.2 represents an oxidized nucleophilic group,Z represents a bivalent atomic group which is electronegative,Q together with the Z group represents a releasable photographically useful group,each of R.sup.1, R.sup.2 and R.sup.3 is hydrogen, halogen, alkyl, alkoxy, or an acylamino group or R.sup.1 and R.sup.2 in adjacent positions on the ring form a ring fused with the remainder of the molecule, or R.sup.2 and R.sup.3 together are fused with the remainder of the molecule.each of R.sup.4 and R.sup.5 represents hydrogen or a hydrocarbon group.At least one of the substituents R.sup.1, R.sup.2, R.sup.3, R.sup.4 or R.sup.5 is a ballasting group X.
    Type: Grant
    Filed: March 15, 1979
    Date of Patent: November 4, 1980
    Assignee: AGFA-GEVAERT N.V.
    Inventor: Wilhelmus Janssens
  • Patent number: 4192640
    Abstract: A photographic process and article resulting therefrom which utilizes multiple images that are transferred to a single image receiving surface. In the preferred embodiment the images are formed on the receiving surface by diffusion transfer development and each image on the receiving surface is electrically conductive. In the areas in which the images overlap, the electrical resistivity is lower than in the nonoverlapped areas. Electrical resistivity in a given area can be controlled by the number of images transferred to the receiving surface. One application of the process is the formation of electrical components such as, printed circuit boards, by photographic diffusion transfer development.
    Type: Grant
    Filed: August 17, 1977
    Date of Patent: March 11, 1980
    Assignee: Winter Park Associates
    Inventor: Glenn W. Merry