Fixer Patents (Class 430/455)
  • Patent number: 4458010
    Abstract: A process for bleaching color photographic sensitive materials and color photographic sensitive materials are disclosed. The process comprises bleaching the silver halide color photographic sensitive materials which are comprised of a support base, a silver halide emulsion layer, and a compound represented by the general formula (I) or strong acid salts thereof in a layer which does not substantially form silver salts of said compounds with a treating solution containing persulfate after being exposed to the light and carrying out color development: ##STR1## wherein M represents a hydrogen atom, an alkali metal atom, an alkaline earth metal, a quaternary ammonium group, a quaternary phosphonium group, an amidino group or ##STR2## R.sup.1 and R.sup.2 each represents a hydrogen atom or an aliphatic group, and m represents an integer of 2 to 4. The bleaching process effectively bleaches color sensitive materials having a high silver content and/or a colloidal silver layer without creating a bad odor.
    Type: Grant
    Filed: November 12, 1982
    Date of Patent: July 3, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyohiko Yamamuro, Shigeo Hirano, Yasuo Iwasa
  • Patent number: 4444873
    Abstract: A process for processing a silver halide color photographic material is disclosed. The process particularly relates to bleaching and fixing of a color developed silver halide color photographic material. The color developed material is processed with an acid bleaching solution containing a ferric salt, inorganic salt and a halide. Immediately after the bleaching step, the photographic material is processed with the fixing solution containing 5 g/l to 50 g/l of polycarboxylic acids. By utilizing the bleaching and fixing steps disclosed it is possible to process a silver halide color photographic material rapidly utilizing a reduced number of baths, obtain an excellent bleaching rate and produce an image having excellent stability.
    Type: Grant
    Filed: December 29, 1982
    Date of Patent: April 24, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Kiyoshi Imai, Mamoru Tashiro, Junya Nakajima
  • Patent number: 4388398
    Abstract: This invention relates to photographic products and processes employing silver halide solvent precursors of the formula ##STR1## wherein R.sup.1 is a monovalent organic radical; R.sup.2 is hydrogen or a monovalent organic radical; Z is a moiety that undergoes .beta.-elimination in aqueous alkaline solution and preferably is a moiety that undergoes .beta.-elimination in aqueous alkaline solution to release a photographically useful reagent; and n is an integer 3, 4 or 5.
    Type: Grant
    Filed: March 23, 1982
    Date of Patent: June 14, 1983
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Ernest W. Ellis
  • Patent number: 4387154
    Abstract: Photographic elements, multicolor filters and receivers are disclosed having supports providing microvessels for materials such as radiation-sensitive materials, imaging materials, mordants, silver precipitating agents and materials which are useful in conjunction with these materials. Processes of forming microvessels and introducing materials therein are also disclosed. Processes of forming images are disclosed employing microvessel containing elements. Image transfer processes are disclosed for producing one or a combination of silver and multicolor subtractive primary images alone or in combination with multicolor additive primary images.
    Type: Grant
    Filed: June 1, 1982
    Date of Patent: June 7, 1983
    Assignee: Eastman Kodak Company
    Inventor: Keith E. Whitmore
  • Patent number: 4382119
    Abstract: This invention relates to photographic products and processes employing silver halide solvent precursors of the formulae ##STR1## wherein R.sup.1 and R.sup.2, the same or different, each are hydrogen, alkyl, phenalkyl, phenyl or phenyl substituted with an electron-donating or electron-withdrawing group; R.sup.3 is alkyl, phenalkyl, phenyl or substituted phenyl; Z is --CN or --SO.sub.2 R.sup.4 wherein R.sup.4 is branched-chain alkyl, phenalkyl, phenyl or substituted phenyl; and n is an integer 3, 4 or 5.
    Type: Grant
    Filed: May 27, 1982
    Date of Patent: May 3, 1983
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Ernest W. Ellis
  • Patent number: 4378424
    Abstract: Mesoionic 1,2,4-triazolium-3-thiolates are silver halide stabilizers and fixing agents. They are useful in heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic materials, developed and stabilized silver images are produced by heating the materials. The mesoionic 1,2,4-triazolium-3-thiolates are also silver halide stabilizers and fixing agents in photographic silver halide processing compositions.
    Type: Grant
    Filed: November 24, 1981
    Date of Patent: March 29, 1983
    Assignee: Eastman Kodak Company
    Inventors: Henry W. Altland, Edward L. Dedio, Gary J. McSweeney
  • Patent number: 4370402
    Abstract: There is disclosed an aqueous composition for removing or reducing the intensity of dyes in dye transfers and the intensity of dyes used by photo retouchers on transparencies and color prints. The composition comprises, per 100 parts by weight of water, from about 1 to about 10 parts by weight of a thiourea and from about 5 to about 20 parts by weight of an ammonium nitrate compound. Application of this composition to dye transfers and/or to dyes used by photo retouchers on transparencies and color prints proportionally removes magenta, cyan and yellow dyes therefrom.
    Type: Grant
    Filed: September 24, 1980
    Date of Patent: January 25, 1983
    Inventor: Harry Anderson
  • Patent number: 4367279
    Abstract: Certain organic, carbon acid silver halide complexing agents in a photographic diffusion transfer system provide suitable replacement for conventional silver halide complexing agents. Such organic, silver halide complexing agents include certain sulfones, nitriles and onium salts. These are especially useful in a silver salt diffusion transfer system. They can be employed with silver halide developing agents, such as in a monobath, and are especially suitable with a hydroxylamine silver halide developing agent. Other addenda commonly employed in photographic diffusion transfer systems can be employed in combination with these silver halide complexing agents.
    Type: Grant
    Filed: September 6, 1974
    Date of Patent: January 4, 1983
    Assignee: Eastman Kodak Company
    Inventors: Arthur H. Herz, Daniel S. Daniel
  • Patent number: 4362811
    Abstract: A processing solution composition for treating an image receiving layer in silver complex diffusion transfer process, which contains 1.7.times.10.sup.-3 to 1.7.times.10.sup.-2 mole/liter of a bromide and 2.0 to 12.0 mole-% of potassium ion based on total cations of the salts contained in the composition accelerates the transfer speed and gives a silver image high in maximum density, contrast and sharpness to the image.
    Type: Grant
    Filed: July 10, 1981
    Date of Patent: December 7, 1982
    Assignee: Mitsubishi Paper Mills Ltd.
    Inventors: Shigeru Iguchi, Shozi Oka
  • Patent number: 4355090
    Abstract: Method for making lithographic printing plates by silver salt diffusion transfer process is disclosed. That is, lithographic printing plates having excellent printing endurance are obtained by carrying out the diffusion transfer processing in the presence of a compound having the ring structure ##STR1## which may be present in at least one constitutive layer of the printing plate materials (photographic materials) used for making the printing plates or in the diffusion transfer processing solution.
    Type: Grant
    Filed: July 1, 1980
    Date of Patent: October 19, 1982
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Shoji Yamada, Eiji Kanada, Kozo Haino
  • Patent number: 4353976
    Abstract: There are described photographic products, processes and compositions wherein cyclic crown ether ligands are utilized as silver halide solvents. Also disclosed are novel cyclic crown ether ligands.
    Type: Grant
    Filed: October 30, 1980
    Date of Patent: October 12, 1982
    Assignee: Polaroid Corporation
    Inventors: Stanley M. Bloom, deceased, Krishna G. Sachdev
  • Patent number: 4345018
    Abstract: Alkanes containing an intralinear sulfonyl group and a cyano group separated by a single carbon substituted with at least one hydrogen atom are employed as silver halide solvents in photographic processes and compositions.
    Type: Grant
    Filed: November 1, 1976
    Date of Patent: August 17, 1982
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Richard B. Greenwald
  • Patent number: 4310613
    Abstract: A liquid processing composition for silver complex diffusion transfer process which contains the specific quaternary ammonium salts as defined in the specification prevents formation of colored sludge for a long time without damaging characteristics of silver complex diffusion transfer development and improves color tone of silver images obtained.
    Type: Grant
    Filed: May 14, 1980
    Date of Patent: January 12, 1982
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Shigeru Iguchi, Kazuhiro Emoto
  • Patent number: 4304847
    Abstract: A color image forming process which comprises processing a photographic light-sensitive element comprising a support having thereon a layer containing imagewise distributed silver therein with an aqueous alkaline solution containing a stannous ion and in the presence of a dye and a bispyridinium compound represented by the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 each represents a lower aliphatic hydrocarbon group or R.sub.1 and R.sub.2 are bonded each other to form a ring; n represents 0 or 1; and X.sup.- represents an anion; to bleach the dye in an imagewise manner. By the process of the present invention, color images which are stable to light, heat and moisture are formed using light-sensitive elements containing a reduced amount of silver salt and without using chemicals causing environmental pollution problems for the processing.
    Type: Grant
    Filed: November 13, 1979
    Date of Patent: December 8, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Nakamura, Isao Shimamura, Yukio Maekawa, Koichi Koyama, Shigeki Yokoyama
  • Patent number: 4272632
    Abstract: There are described novel acyclic silver complexing agents which are useful as silver halide solvents in photographic products, processes and compositions. Also disclosed are photographic compositions, products and processes in which the complexing agents are utilized.
    Type: Grant
    Filed: June 16, 1980
    Date of Patent: June 9, 1981
    Assignee: Polaroid Corporation
    Inventors: Krishna G. Sachdev, Stanley M. Bloom, deceased
  • Patent number: 4267256
    Abstract: There are described photographic products, processes and compositions wherein cyclic crown ether ligands are utilized as silver halide solvents. Also disclosed are novel cyclic crown ether ligands.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: May 12, 1981
    Assignee: Polaroid Corporation
    Inventors: Stanley M. Bloom, deceased, Krishna G. Sachdev
  • Patent number: 4267254
    Abstract: There is described a photograhic method employing a positive-negative diffusion transfer film unit wherein there is formed a positive silver transfer image which may be viewed as a positive transparency without being separated from the developed negative silver image, including an embodiment wherein additive color projection positive images are formed. According to the method, the exposed film unit is developed by contacting the silver halide emulsion layer with a photographic processing composition which comprises an aqueous alkaline solution containing a silver halide developing agent and a silver complexing agent. The silver complexing agent is stable in an alkaline environment, has a melting point less than about 50.degree. C. preferably about 25.degree. C. or less, and the log of the stability constant (.beta.) for a 1:1 complex of the complexing agent with silver is at least about 10.5. The film unit is not washed during the method.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: May 12, 1981
    Assignee: Polaroid Corporation
    Inventors: Stanley M. Bloom, deceased, Krishna G. Sachdev
  • Patent number: 4251617
    Abstract: There are described novel acyclic silver complexing agents which are useful as silver halide solvents in photographic products, processes and compositions. Also disclosed are photographic compositions, products and processes in which the complexing agents are utilized.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: February 17, 1981
    Assignee: Polaroid Corporation
    Inventors: Stanley M. Bloom, deceased, Krishna G. Sachdev
  • Patent number: 4230792
    Abstract: The present invention provides a lithographic printing plate, which is made by exposing a photographic material having a silver halide photosensitive emulsion layer, developing the exposed material and treating the developed material with a conversion liquid comprising a solvent for a silver halide and an organic compound capable of forming a compound which is more stable and has a lower solubility than a soluble silver complex formed by said solvent.
    Type: Grant
    Filed: January 4, 1979
    Date of Patent: October 28, 1980
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Yasuo Tsubai, Akio Yoshida, Shigeyoshi Suzuki
  • Patent number: 4192764
    Abstract: A method for depositing a metal on a surface is disclosed. The method comprises treating the surface with a sensitizing solution comprising at least a reducible salt of a non-noble metal and a radiation-sensitive reducing agent for the salt to form a sensitized surface. The sensitized surface is exposed to a source of light radiation to reduce the metal salt to a reduced metal salt species. Either or both of the preceding sensitizing or radiation exposing steps is restricted to a selected pattern on the surface to form a catalytic real image capable of directly catalyzing the deposition of a metal thereon from an electroless metal deposition solution. The catalytic real image is treated with a stabilizer comprising (a) a reducing agent for the non-noble metal ions of said reducible salt, (b) a complexing agent and (c) an accelerator to at least stabilize the catalytic real image.
    Type: Grant
    Filed: October 16, 1978
    Date of Patent: March 11, 1980
    Assignee: Western Electric Company, Inc.
    Inventor: Bruce S. Madsen
  • Patent number: 4187105
    Abstract: A non-silver photosensitive image forming composition containing at least one substituted bis-diaryl vinylidene compound and/or at least one substituted bis-diaryl imine compound and tetraiodoethylene in a dried photosensitive layer thickness not exceeding 3 microns in layer thickness, the nature of the substitution being such that substantially any high extinction absorption peak or combination of high extinction absorption peaks is available from a family of compositions covering the range of 350 to 900 nm in wavelength, said composition being placed on a transparent or reflective substrate fitted with a compatible adhesive for the photosensitive layer not more than 0.
    Type: Grant
    Filed: May 23, 1978
    Date of Patent: February 5, 1980
    Assignee: Horizons Research Incorporated
    Inventors: Eugene Wainer, James M. Lewis