Gelatin Or Derivative Containing Patents (Class 430/642)
  • Patent number: 5374498
    Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support having thereon a silver halide emulsion layer, wherein the silver halide emulsion layer contains a hydrazine derivative, and at least one of the silver halide emulsion layer and another hydrophilic colloid layer provided on the emulsion layer-coated side of the support contains a latex comprising polymer particles stabilized with gelatin.
    Type: Grant
    Filed: May 13, 1993
    Date of Patent: December 20, 1994
    Assignee: Konica Corporation
    Inventors: Akio Fujita, Takeo Arai
  • Patent number: 5368984
    Abstract: A silver halide photographic light-sensitive material is disclosed. The material comprises a light-sensitive silver halide emulsion layer and containing both of a latex stabilized by gelatin and a redox compound from which a development inhibitor is released when the redox is oxidized in the emulsion layer or other non-light-sensitive hydrophilic colloidal layer. The silver halide photographic light-sensitive material is suitable for graphic arts plate-making use and is excellent in Ming-Gothic type reproduction, screen-image enlarging and screen-image reduction aptitudes, white-on-color letter quality, paste-up trace prevention, easy handling and stability.
    Type: Grant
    Filed: November 10, 1993
    Date of Patent: November 29, 1994
    Assignee: Konica Corporation
    Inventor: Kazuhiro Yoshida
  • Patent number: 5366857
    Abstract: A coating composition suitable for use in the preparation of a photographic material comprises an aqueous solution of a hydrophilic colloid and a surface active coating aid having the formulaCF.sub.3 (CF.sub.2).sub.n CH.sub.2 O(glycidyl).sub.m Hwhereinn is an integer from 4 to 7; and,m is an integer from 6 to 45.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: November 22, 1994
    Assignee: Eastman Kodak Company
    Inventors: Alan R. Pitt, Bernard A. Clark, John F. Padday
  • Patent number: 5362626
    Abstract: Disclosed is a silver halide photographic light-sensitive material comprising a support and having thereon at least one silver halide emulsion layer, wherein the silver halide emulsion layer contains a gelatin comprising an iron ion of 0.5 ppm to 5 ppm and .alpha.-constituent having weight-average molecular weight of 80,000 to 120,000 in an amount of not less than 40% by weight of the gelatin.
    Type: Grant
    Filed: September 29, 1993
    Date of Patent: November 8, 1994
    Assignee: Konica Corporation
    Inventors: Takaaki Kojima, Mitsuhiro Okumura, Takahiko Nojima
  • Patent number: 5336592
    Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support having thereon a photographic layer including a silver halide emulsion layer wherein the outermost surface of said photographic layer has a pH value of from 5.4 to 5.9 and said silver emulsion layer contains a compound represented by the following formula I; ##STR1## wherein R.sub.1 is an alkyl group, a cycloalkyl group or an aryl group; R.sub.2 is an alkyl group, a cycloalkyl group, an acyl group or an aryl group; R.sub.3 is a substituent, n is 0 or 1; X.sub.1 is a substituent capable of splitting off upon coupling reaction with the oxidation product of a color developing agent; and Y.sub.1 is an organic group. The light-sensitive material is excellent in stability during storage and gives stable photographic characteristics even when pH value of developer is varied.
    Type: Grant
    Filed: November 3, 1992
    Date of Patent: August 9, 1994
    Assignee: Konica Corporation
    Inventors: Shigeo Chino, Takashi Kadowaki, Toyoki Nishijima
  • Patent number: 5326684
    Abstract: In a heat-developable color photosensitive material comprising a photosensitive silver halide, a dye providing compound, and a binder on a support, the content of calcium is controlled to 500 ppm or more based on the total weight of the binder, allowing the use of inexpensive binders. The photosensitive material is cost effective and forms an image with a low fog density (Dmin) and a high image density (Dmax).
    Type: Grant
    Filed: January 12, 1993
    Date of Patent: July 5, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuo Aotsuka
  • Patent number: 5318889
    Abstract: This invention describes the advantages associated with the use of chain-extended acid processed ossein gelatin as the makeup gelatin, with emulsion precipitated in lime-processed ossein gelatin. Such photographic elements show a definite speed-fog advantage, compared to systems where standard lime-processed ossein gelatin is used solely.
    Type: Grant
    Filed: December 21, 1992
    Date of Patent: June 7, 1994
    Assignee: Eastman Kodak Company
    Inventors: Pranab Bagchi, Melvin Sterman, Jacob Cohen
  • Patent number: 5316902
    Abstract: Hydrophilic organic colloids such as collagen or gelatin are modified for use in photographic elements such as film or paper, or for use as reagents in automated dry chemical analyzers. The modification comprises reaction of some of the carboxy groups attached to the polypeptide with (i) a amide bond forming agent, e.g. 1-pyrrolidinylcarbonylpyridinium chloride, and (ii) a di- or triamine, such as piperazine, diethylenetriamine or ethylenediamine. Such modification enables that colloid to react faster with a gelatin hardener such as bis(vinylsulfonyl)methane (BVSM). When coated over an equal amount of unmodified gelatin, and both layers imbibed with BVSM, a modified gelatin layer showed an enzyme resistance greater than that of the unmodified gelatin. This demonstrates that the modified gelatin hardened preferentially.
    Type: Grant
    Filed: January 4, 1993
    Date of Patent: May 31, 1994
    Assignee: Eastman Kodak Company
    Inventors: Donald P. Specht, Kenneth G. Harbison
  • Patent number: 5310637
    Abstract: A method of reducing the tendency toward formation of ripple imperfections in the coating of multilayer photographic elements is disclosed. Coating compositions are prepared for upper, middle, and lower gelatin-containing layers of a layered mass. The middle layer has a gelatin concentration within three weight percent of each of the upper and lower layers and the upper, middle, and lower layers each have a viscosity that differs from a norm by no more than 15%. A laminar flow of a layered mass including the coating compositions is formed and then received as a layered coating on a moving support. A multilayer photographic element is also disclosed.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: May 10, 1994
    Assignee: Eastman Kodak Company
    Inventors: Mark R. Kurz, Steven J. Weinstein, Kenneth J. Ruschak
  • Patent number: 5302505
    Abstract: Light-sensitive silver halide photographic elements are disclosed comprising a support and silver halide emulsion layer or layers, wherein at least one of said silver halide emulsion layers contains tabular silver halide grains having an average diameter:thickness ratio of at least 3:1 and highly deionized gelatin and wherein said photographic elements show a swelling index lower than 140% and a melting time of from 45 to 120 minutes.The light-sensitive materials can be advantageously developed in hardener free developer and used in high temperature super rapid processing in automatic processors which include transporting rollers and have good physical and photographic characteristics.
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: April 12, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gerolamo Delfino, Milena Debenedetti, Marco Bucci, Dino Ferrari
  • Patent number: 5300409
    Abstract: A method of processing a light-sensitive silver halide photographic material is disclosed. The method comprises a processing steps of developing, fixing and a washing or stabilizing, wherein a replenishing solution for the washing or the stabilizing step is an amount of not more than 3 liters per square meter of the light-sensitive material. The photographic material comprises a support, and a hydrophilic colloidal layer on each of the both side of the support, wherein either one of the hydrophilic colloidal layers contains a dye represented by a specific chemical formula.
    Type: Grant
    Filed: November 9, 1990
    Date of Patent: April 5, 1994
    Assignee: Konica Corporation
    Inventors: Hiroyuki Ushiroyama, Kazuhiro Yoshida
  • Patent number: 5298382
    Abstract: Photographic silver halide photosensitive material is processed, after exposure, by treating it with a working fixer solution. The photosensitive material comprises at least one layer of silver halide emulsion on a support and contains at least 10% by weight, based on gelatins, of a gelatin having an isoelectric point of at least 5.0 on the emulsion layer side. The working fixer solution is prepared by furnishing a fixer concentrate of at least pH 5 containing a thiosulfate as a fixing agent, 0.05-0.8 mol/liter of a sulfite and up to 0.01 mol/liter of a water-soluble aluminum salt, and diluting the fixer concentrate with water, thereby forming the working fixer solution containing a minimized amount of ammonium thiosulfate and 0.5-2.5 mol/liter of sodium thiosulfate. The method provides improved rapid processing with increased degrees of fixation and drying while preventing the generation of sulfurous acid and ammonia gases.
    Type: Grant
    Filed: February 25, 1993
    Date of Patent: March 29, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Toyoda, Itsuo Fujiwara
  • Patent number: 5298389
    Abstract: The present invention is a method to add dry gelatin to a photographic emulsion in either a liquid or a solid form. The dry gelatin is added by entraining the dry gelatin in air to form a gaseous mixture of dry gelatin in air and directing this mixture into the solid or liquid photographic emulsion. An air eductor is used to deliver the dry gelatin. When adding dry gelatin to a solution, the rate is determined by the solution viscosity and volume. When adding the dry gelatin to a solid emulsion, the dry gelatin rate is not as critical but uniform addition is still needed to interdisperse the dry gel with the emulsion pellets.
    Type: Grant
    Filed: September 29, 1992
    Date of Patent: March 29, 1994
    Assignee: Eastman Kodak Company
    Inventors: Steven D. Possanza, Donald E. Eaton, Lawrence D. Meston, Edgar P. Lougheed
  • Patent number: 5284752
    Abstract: A polymeric latex composition having a hydrophobe incorporated therein can be prepared using a novel latex "loading" method. This method includes providing a loadable latex, providing a hydrophobe dissolved in a water-miscible organic solvent, heating the loadable latex to about 30.degree. to about 90.degree. C. and gradually adding the hydrophobe solution to the heated loadable latex under conditions to keep the hydrophobe in solution and to "load" it into the latex particles. In preferred embodiments, the latex is surfactant-free and has particles which have outer reactive groups which are capable of reacting with free amine or sulfhydryl groups of a biological compound. Such latices can be used to prepare water-insoluble biological reagents having a biological compound attached to the particles.
    Type: Grant
    Filed: May 3, 1993
    Date of Patent: February 8, 1994
    Assignee: Eastman Kodak Company
    Inventor: Richard C. Sutton
  • Patent number: 5275931
    Abstract: A silver halide light-sensitive material containing at least silver halide grains, a dispersion medium, an antifoggant, and a hardening agent, wherein said antifoggant is an antifoggant having a reactive substituent capable of reacting with a functional group of the dispersion medium to form a covalent bond after adsorption on the silver halide grains and/or an antifoggant previously covalently bonded to the dispersion medium. The antifoggant is immobilized in a light-sensitive material while exerting its antifogging activity and is not therefore dissolved into a developing solution.
    Type: Grant
    Filed: November 24, 1992
    Date of Patent: January 4, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsuo Saitou, Hisashi Okamura, Tadashi Ikeda
  • Patent number: 5272053
    Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support and a silver halide emulsion layer provided on the support, and the silver halide emulsion layer comprises a hydrogen peroxide-treated gelatin in a ratio of not lower than 20% by weight to the total amount of gelatin contained in the silver halide emulsion layer and silver halide grains composed of silver chlorobromide having a silver chloride content of not lower than 90 mol %. The light-sensitive material is improved in the stability of emulsion coating solutions.
    Type: Grant
    Filed: December 15, 1992
    Date of Patent: December 21, 1993
    Assignee: Konica Corporation
    Inventors: Mitsuhiro Okumura, Shigeo Tanaka, Hirokazu Sato
  • Patent number: 5264339
    Abstract: In a method for the manufacture of a recording material containing a coated and dried gelatin containing layer on a support, the improvement wherein such layer is coated from an aqueous coating composition containing:(1) hydrophilic colloid matter consisting of at least 90% by weight of gelatin,(2) not more than 5% by weight with respect to the total gelatin content of a thickening agent increasing the viscosity of said composition, and(3) a hardening agent for gelatin that reduces its water-solubility after coating, characterized in that said gelatin is a gelatin species which as a 10% by weight aqueous solution at 36.degree. C. and pH 6 has a viscosity of at least 35 Mpa.s at a shear rate of 1000 S.sup.-1 and shows a decrease in viscosity by at least 10 Mpa.s at a shear rate of 40,000 s.sup.-1, and as a 3% by weight aqueous solution at Ph 6 and after cooling for 30 seconds at a shearing rate of 208 s.sup.
    Type: Grant
    Filed: September 4, 1992
    Date of Patent: November 23, 1993
    Assignee: Agfa-Gevaert N.V.
    Inventors: Bernard H. Tavernier, Frank P. Michiels
  • Patent number: 5264338
    Abstract: A method of preparing a superfine grain emulsion with a grain size of 0.05 .mu.m or less is provided, which includes mixing aqueous solutions of a water-soluble silver salt and a water-soluble halide with vigorous stirring inside a closed mixing device furnished with an agitator, where the solutions are fed into the device simultaneously and continuously, in the presence of at least one of a high molecular compound and a substance capable of adsorbing to silver halide, each of which has a physical retardance value of at least 40 as determined by PAGI method, and immediately expelling the newly-formed grains from the mixing device. Another method includes mixing the aqueous solutions in a mixing device as described above, immediately expelling the newly-formed grains from the device, and mixing the expelled grains with at least one of the above-described high molecular compound and substance.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: November 23, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeharu Urabe, Shunichi Aida
  • Patent number: 5248558
    Abstract: It has been shown by Photon Correlation Spectroscopy than when additional hardener is added to below saturation gel-grafted polymer particles, the gel layer shrinks due to hardening, as there is no free gel left in solution. In films, such case-hardened gelatin-grafted soft polymer particles can act as highly elastic stress absorbing fillers. This is because the dry case-hardened shell is expected to form a thin hard shell around the soft polymer particles. It is shown that gelatin-grafted soft polymer particles and case-hardened gelatin-grafted soft polymer particles, incorporated in the emulsion layers of pressure sensitive photographic products, produce coatings with highly reduced pressure sensitivity without any developability or delamination concerns. In this invention the case-hardened gelatin-grafted polymer particles are preferred over the simple gelatin-grafted material. The core polymer particle can have diameters anywhere between 10 to 10.sup.
    Type: Grant
    Filed: June 20, 1991
    Date of Patent: September 28, 1993
    Assignee: Eastman Kodak Company
    Inventors: Pranab Bagchi, William L. Gardner
  • Patent number: 5246824
    Abstract: Light-sensitive silver halide photographic elements are disclosed comprising a support and silver halide emulsion layer or layers, wherein at least one of said silver halide emulsion layers contains tabular silver halide grains having an average diameter:thickness ratio of at least 3:1 and highly deionized gelatin hardened with a compound of formula (CH.sub.2 .dbd.CH--SO.sub.2 --).sub.n --A, wherein A is an n-valent organic group containing at least one hydroxy group and n is 2,3 or 4.The light-sensitive materials can be advantageously used in high temperature processing in automatic processors which include transporting rollers and have good characteristics of resistance to pressure marking.
    Type: Grant
    Filed: January 22, 1992
    Date of Patent: September 21, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gerolamno Delfino, Riccardo Gallesio
  • Patent number: 5244784
    Abstract: An improved silver halide photographic materials comprising a support and a photographic layer unit thereon. The improvement is such that said photographic layer unit comprises a light sensitive layer having silver halide grains, of which a chloride content is not less than 30 mol %, and said photographic layer unit comprises not more than 2.8 g/m.sup.2 of gelatin, and a portion not less than 50 wt % of said gelatin has a jelly strength of not less than 240.
    Type: Grant
    Filed: February 28, 1991
    Date of Patent: September 14, 1993
    Assignee: Konica Corporation
    Inventors: Tomonobu Moriya, Kazuhiro Yoshida
  • Patent number: 5238795
    Abstract: A light-sensitive silver halide photographic material is disclosed. The light-sensitive material comprises a support and two photographic layers each being provided on both sides, side A and side B, of the support and comprising a silver halide emulsion layer and a hydrophilic colloid layer wherein the light-sensitive material satisfies the relationship between sensitivities sA, sB and sA' thereof represented by the following expressions I and II, and an organic substance remained in the photographic layers after processing is an amount of not more than 90% by weight of the organic substance contained in the photographic layers before processing of the light-sensitive material;I: sA/sA'>4.0II: sA/sB=1.
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: August 24, 1993
    Assignee: Konica Corporation
    Inventor: Iku Metoki
  • Patent number: 5236822
    Abstract: A method for hardening gelatin which comprises using as a hardening agent a compound represented by formula (I): ##STR1## wherein R.sub.1, when taken along, may be alkyl of 1 to 20 carbon atoms, aralkyl of from 7 to 20 carbon atoms, aryl of from 6 to 20 carbon atoms, and alkenyl of from 2 to 20 carbon atoms. R.sub.1 and R.sub.2 can also combine with each other to form a heterocyclic ring of 5 to 8 atoms. The R.sub.1 -R.sub.2 ring contains the nitrogen atoms to which R.sub.1 and R.sub.2 are attached, and may also contain an additional nitrogen atom. R.sub.2 and R.sub.3 can combine to form either a 5 or 6 membered ring. The R.sub.2 -R.sub.3 ring contains the nitrogen atom to which R.sub.2 is attached, and may also contain one or two additional nitrogen atoms. R.sub.4 may be hydrogen or alkyl of 1 to 4 carbon atoms. R.sub.
    Type: Grant
    Filed: October 3, 1991
    Date of Patent: August 17, 1993
    Assignee: Eastman Kodak Company
    Inventors: Edgar E. Riecke, Derek D. Chapman, Chung Y. Chen, Kenneth G. Harbison
  • Patent number: 5234841
    Abstract: A polymeric latex composition having a hydrophobe incorporated therein can be prepared using a novel latex "loading" method. This method includes providing a loadable latex, providing a hydrophobe dissolved in a water-miscible organic solvent, heating the loadable latex to about 30.degree. to about 90.degree. C. and gradually adding the hydrophobe solution to the heated loadable latex under conditions to keep the hydrophobe in solution and to "load" it into the latex particles. In preferred embodiments, the latex is surfactant-free and has particles which have outer reactive groups which are capable of reacting with free amine or sulfhydryl groups of a biological compound. Such latices can be used to prepare water-insoluble biological reagents having a biological compound attached to the particles.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: August 10, 1993
    Assignee: Eastman Kodak Company
    Inventor: Richard C. Sutton
  • Patent number: 5221603
    Abstract: A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the silver halide emulsion layer or another hydrophilic colloid layer contains a compound represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 30 carbon atoms, and at least one of R.sub.1 and R.sub.2 represents a substituted or unsubstituted hydrocarbon group, including an alkyl group having not less than 6 carbon atoms; L represents a divalent bonding group; and M represents a hydrogen atom or a cation.
    Type: Grant
    Filed: September 4, 1991
    Date of Patent: June 22, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masakazu Yoneyama, Tomokazu Yasuda, Yasushi Suga
  • Patent number: 5213959
    Abstract: A silver halide light-sensitive material containing at least silver halide grains, a dispersion medium, an antifoggant, and a hardening agent, wherein said antifoggant is an antifoggant having a reactive substituent capable of reacting with a functional group of the dispersion medium to form a covalent bond after adsorption on the silver halide grains and/or an antifoggant previously covalently bonded to the dispersion medium. The antifoggant is immobilized in a light-sensitive material while exerting its antifogging activity and is not therefore dissolved into a developing solution.
    Type: Grant
    Filed: June 20, 1991
    Date of Patent: May 25, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsuo Saitou, Hisashi Okamura, Tadashi Ikeda
  • Patent number: 5202218
    Abstract: The present invention provides a lithographic printing plate material for silver complex diffusion transfer process by scanning type exposure which comprises a film support and, provided thereon, at least a silver halide emulsion layer and a surface physical development nuclei layer, wherein water content in the whole lithographic printing plate material including the support is 1.5% or less. Preferably, the silver halide emulsion comprises about 95 mol % or more of silver chloride, 90% by weight or more of the silver halide grains have a size within .+-.40% of average grain size, the silver halide grains have an average grain size of about 0.3.mu.-about 1.0.mu., and the surface of the grains is replaced with about 0.1 mol %-about 3.0 mol % of an iodide per 1 mol of the silver halide.
    Type: Grant
    Filed: March 19, 1991
    Date of Patent: April 13, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Akio Yoshida, Keisuke Iguchi, Hiroyuki Ishikura, Hiroshi Nishinoiri
  • Patent number: 5196300
    Abstract: A method of preparing a superfine grain emulsion with a grain size of 0.05 .mu.m or less is provided, which includes mixing aqueous solutions of a water-soluble silver salt and a water-soluble halide with vigorous stirring inside a closed mixing device furnished with an agitator, where the solutions are fed into the device simultaneously and continuously, in the presence of at least one of a high molecular compound and a substance capable of adsorbing to silver halide, each of which has a physical retardance value of at least 40 as determined by PAGI method, and immediately expelling the newly-formed grains from the mixing device. Another method includes mixing the aqueous solutions in a mixing device as described above, immediately expelling the newly-formed grains from the device, and mixing the expelled grains with at least one of the above-described high molecular compound and substance.
    Type: Grant
    Filed: December 5, 1990
    Date of Patent: March 23, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeharu Urabe, Shunichi Aida
  • Patent number: 5187259
    Abstract: A soluble, chain extended gelatin having a high molecular weight and significantly higher viscosity at equivalent gelatin concentration compared to standard gelatin and significantly faster setting time is produced by preparing an aqueous gelatin composition containing from about 6% to about 18% dry weight of gelatin and from about 0.25 to about 5 millimoles of a bis-(vinyl sulfonyl) compound per 100 grams of gelatin, heating the composition at a temperature of from about 40 to about 60.degree.C. and at a pH of from about 4.5 to about 7 for from about one to about eight hours.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: February 16, 1993
    Assignee: Eastman Kodak Company
    Inventors: Melvin D. Sterman, James L. Bello
  • Patent number: 5185230
    Abstract: The invention creates a selective oxygen barrier around individual coupler or other photographically active particles by surrounding each particle with a layer of water applicable oxygen barrier polymer such as polyvinyl alcohol (PVA), which will also act as a steric barrier to coalescence of the particles. Photographic products formed with such materials are more dye stable.
    Type: Grant
    Filed: September 3, 1991
    Date of Patent: February 9, 1993
    Assignee: Eastman Kodak Company
    Inventors: Pranab Bagchi, James L. Edwards, Wendell F. Smith, Jr., Brian Thomas
  • Patent number: 5182190
    Abstract: The present invention relates to a method for obtaining a silver halide photographic composition for a coating layer. The method consists in individually preparing the various components of the desired layer, comprising at least one silver halide emulsion, and solutions or dispersions containing one or more finishing addenda and/or gelatin, chilling these components to solidify each of them, cutting them into chunks, cold-blending, in a solid state, the components selected according to the formulation of the desired layer, and liquefying the resulting solid composition just before its introduction into the coating station. The method can be applied to all types of silver halide photographic products, for black and white or color photography.
    Type: Grant
    Filed: September 14, 1990
    Date of Patent: January 26, 1993
    Assignee: Eastman Kodak Company
    Inventors: Jacques Le Faou, Jean-Claude Hervieux
  • Patent number: 5180651
    Abstract: A process for improving the method by which a powder such as a dye is added to a gelatino silver halide element is described. This process involves encapsulating the powder within a gelatin capsule. This process avoids cross-contamination and dusting when powder is added to solvent and also reduces the use of extra solvent in the manufacture of the element.
    Type: Grant
    Filed: May 1, 1991
    Date of Patent: January 19, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Eileen Mason
  • Patent number: 5176990
    Abstract: A method for forming a photographic element includes steps of heating an emulsion containing grains of a radiation sensitive silver haloiodide to form a first melt, heating an emulsion containing grains of a silver salt effective to enhance the photographic properties of the silver haloiodide emulsion to form a second melt, and coating the first and second melts onto a photographic support to form an image recording layer. The silver salt grains are substantially insensitive to radiation at wavelengths at which said silver haloiodide grains are sensitive. The coating step is preferably carried out by blending the first and second melts together, then immediately coating the silver haloiodide emulsion onto the support. In a preferred embodiment, the silver salt is essentially silver chloride in the form of relatively fine cubic grains, and the silver haloiodide is in the form of tabular grains larger than the cubic grains.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: January 5, 1993
    Assignee: Eastman Kodak Company
    Inventor: Sang H. Kim
  • Patent number: 5112728
    Abstract: A silver halide photographic light-sensitive material comprising a support having thereon a photographic silver halide emulsion layer containing a magenta coupler, a photographic silver halide emulsion layer containing a yellow coupler, a photographic silver halide emulsion layer containing a cyan coupler and an non-light-sensitive layer containing a binder and a UV absorbent, wherein said silver halide photographic light-sensitive material has not more than 7.6 g/m.sup.2 of gelatin, said UV absorbent is liquid at an ordinary temperature, and said magenta coupler is a compound represented by Formula I; ##STR1## wherein Z represents a non-metallic group necessary to form a nitrogen-containing heterocyclic ring, X represents a hydrogen atom or a group capable of being split upon reaction with an oxidation product of a color developing agent, and R represents a hydrogen atom or a substituent.
    Type: Grant
    Filed: September 25, 1990
    Date of Patent: May 12, 1992
    Assignee: Konica Corporation
    Inventors: Masaki Tanji, Toyoki Nishijima, Takahiro Ogawa, Shun Takada, Kazuhiro Murai
  • Patent number: 5102770
    Abstract: The present invention provides a method for producing a photosensitive material for silver complex diffusion transfer process containing a hydroxybenzene developing agent which comprises coating at least one gelatin-containing coating solution on a support to form photographic layers including a photosensitive layer and drying the coat, said drying being carried out by raising surface wet-bulb temperature of the coat to 14.degree. C. or higher before gelatin concentration in the coat reaches at most about 30% by weight.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: April 7, 1992
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Susumu Baba, Akio Yoshida, Yasuo Tsubai
  • Patent number: 5087554
    Abstract: The invention provides stable dispersions of couplers and methods of their formation. The stable dispersions are formed by the use of a nonionic water soluble polymer in combination with an anionic surfactant having a sulfate or sulfonate head group and a hydrophobic group of 8 to 20 carbons. The preferred nonionic water soluble polymers are polyethyleneoxide and polyvinylpyrrolidene. It is preferred that the dispersions have a pH of between about 5 and 5.5.
    Type: Grant
    Filed: June 27, 1990
    Date of Patent: February 11, 1992
    Assignee: Eastman Kodak Company
    Inventors: Krishnan Chari, James T. Beck
  • Patent number: 5063139
    Abstract: A color photographic light-sensitive material capable of being processed at an ultrahigh speed, which comprises at least two light-sensitive layers on at least one side of a support wherein each layer contains a light-sensitive silver halide emulsion and a nondiffusive oil-soluble coupler capable of coupling with an oxidation proudct of an aromatic primary amine color developing agent to produce a dye, said light-sensitive layers having different sensitive wavelength ranges, said silver halide is silver chloride or silver chlorobromide containing at least 90 mol % of silver chloride, and the alkali-consuming amount of said light-sensitive material is not more than 2.6 mmol/m.sup.2.A process for the formation of color images using the light-sensitive material, which comprises imagewise exposing light-sensitive material, and then subjecting the material to color development for not more than 20 seconds.
    Type: Grant
    Filed: June 15, 1990
    Date of Patent: November 5, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroshi Hayashi
  • Patent number: 5053443
    Abstract: A polymeric latex composition having a hydrophobe incorporated therein can be prepared using a novel latex "loading" method. This method includes providing a loadable latex, providing a hydrophobe dissolved in a water-miscible organic solvent, heating the loadable latex to about 30.degree. to about 90.degree. C. and gradually adding the hydrophobe solution to the heated loadable latex under conditions to keep the hydrophobe in solution and to "load" it into the latex particles. In preferred embodiments, the latex is surfactant-free and has particles which have outer reactive groups which are capable of reacting with free amine or sulfhydryl groups of a biological compound. Such latices can be used to prepare water-insoluble biological reagents having a biological compound attached to the particles.
    Type: Grant
    Filed: May 4, 1989
    Date of Patent: October 1, 1991
    Assignee: Eastman Kodak Company
    Inventor: Richard C. Sutton
  • Patent number: 5045445
    Abstract: A process for the in-line preparation of gelatin solutions comprising(a) mixing gelatin particles with an aqueous solution to wet the gelatin forming a gelatin-aqueous solution mixture,(b) heating rapidly said mixture to a temperature capable of digesting gelatin in said mixture, and(c) maintaining the digested gelatin at said temperature for a period to dissolve the gelatin particles into the aqueous solution.The process provides gelatin solutions for photographic uses in an improved manner without the general dissolution problems. The process is quick and is accomplished in-line, preferably continuously.
    Type: Grant
    Filed: June 29, 1990
    Date of Patent: September 3, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert R. Schultz
  • Patent number: 5024932
    Abstract: A light-sensitive silver halide photographic material having a support and, provided thereon, photographic component layers including at least one light-sensitive silver halide emulsion layer containing silver halide grains having a silver chloride content of not less tha 90 mole % and having been subjected to gold sensitization, said photographic component layer containing a gelatin of which isoelectric point being 4.0 to 5.0 and the film pH of said photographic component layer being not more than 6.0.
    Type: Grant
    Filed: February 26, 1990
    Date of Patent: June 18, 1991
    Assignee: Konica Corporation
    Inventors: Masaki Tanji, Toyoki Nishijima
  • Patent number: 5001046
    Abstract: A sheet of silver halide photographic light-sensitive material is disclosed, which is suitable for an ultra-rapid processing and improved on decreased fog due to corner cutting the sheet. The sheet of photographic material is comprised of a light-sensitive layer, provided on a support, containing a silver halide grain composed of at least two phases and the silver iodide content of outermost phase is at least 1 mol % lower than that of inside phase contiguous to said outermost phase, and 10% to 100% of surface area of said silver halide grain is occupied with (111) face, and the total gelatin amount of component layers on the same side of the support including said light-sensitive layer is within the range of from 2.0 g/m.sup.2 to 3.5 g/m.sup.2.
    Type: Grant
    Filed: January 18, 1990
    Date of Patent: March 19, 1991
    Assignee: Konica Corporation
    Inventors: Chika Honda, Haruhiko Sakuma
  • Patent number: 4999282
    Abstract: An improved silver halide photographic material having at least one layer of a light-sensitive silver halide emulsion that is spectrally sensitized with a sensitizing dye of the following general formula (1) to light having a wavelength of 750 nm and above. Said silver halide emulsion is prepared by a process which comprises generating silver halide grains by adding a solution of a water-soluble silver salt and a solution of a water-soluble halide to a solution containing a protective colloid, aggregating the generated silver halide grains with a polymeric flocculating together with the protective colloid, and removing the dissolved matter; ##STR1## where Z.sub.1 and Z.sub.3 each represents the non-metallic atomic group necessary to form an optionally substituted benzothiazole, benzoxazole, naphthothiazole or naphthoxazole nucleus; R.sub.1 and R.sub.2 each represents a saturated or unsaturated aliphatic group; Z.sub.2 represents a 5- or 6-membered ring of carbon atoms; A represents a hydrogen atom when Z.sub.
    Type: Grant
    Filed: May 17, 1989
    Date of Patent: March 12, 1991
    Assignee: Konica Corporation
    Inventors: Kiyoshi Sato, Kouji Ono
  • Patent number: 4990440
    Abstract: The sensitivity/fog ratio can be improved by using photographic silver halide emulsions containing gelatine which has a cysteine content of less than 10 ppm and a gold number of .gtoreq.23 .mu.mol/g.
    Type: Grant
    Filed: August 4, 1989
    Date of Patent: February 5, 1991
    Assignee: Agfa-Gevaert Aktiengessellschaft
    Inventors: Franz Moll, Bruno Mucke, Walter Patzold, Klaus Wagner
  • Patent number: 4990439
    Abstract: A silver halide light-sensitive photographic material having a support and provided thereon, hydrophlic colloidal layers including at least one silver halide light-sensitive emulsion layer is disclosed. The silver halide emulsion layer comprises a silver halide emulsion (I) prepared by adding a high-molecular flocculant under at least one of Conditions (1) through (3) to a silver halaide emulsion (II) prepared by a water-soluble silver salt solution and a water-soluble halide solution to a protevtive colloid solution so as to flocculate and settle a silver halide grain together with a protective colloid for desalting of dissolved substances, and by dispersing again the desalted silver halide emulsion in a protective colloid solution;Condition (1): a temperature of the silver halide emulsion (II) is not lower than 30.degree. C.
    Type: Grant
    Filed: August 1, 1989
    Date of Patent: February 5, 1991
    Assignee: Konica Corporation
    Inventors: Kazuyoshi Goan, Takuji Hasegawa
  • Patent number: 4978607
    Abstract: A photographic recording material which comprises at least one gelatin-containing silver halide emulsion layer and at least one protective layer containing a gelatin derivative, the protective layer being further away from the layer support than each silver halide emulsion layer and 30 to 90% of the amino groups of the gelatin in the gelatin derivative being reacted with a monofunctional acid derivative, and which is hardened with an instant hardener can be produced at high speed and, hence, at high drying temperatures without any reticulation grain occurring during processing.
    Type: Grant
    Filed: September 1, 1988
    Date of Patent: December 18, 1990
    Assignee: AGFA-Gevaert Aktiengessellschaft
    Inventors: Edouard Roche, Wolfgang Himmelmann, Hans-Theo Buschmann, Heinz Quambusch
  • Patent number: 4957857
    Abstract: The invention provides stable dispersions of couplers and methods of their formation. The stable dispersions are formed by the use of a nonionic water soluble polymer in combination with an anionic surfactant having a sulfate or sulfonate head group and a hydrophobic group of 8 to 20 carbons. The preferred nonionic water soluble polymers are polyethyleneoxide and polyvinylpyrrolidene.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: September 18, 1990
    Assignee: Eastman Kodak Company
    Inventor: Krishnan Chari
  • Patent number: 4944966
    Abstract: A novel hardening agent for photographic gelatin coatings comprising a composite solution of a substituted 1,3,5 triazine and formaldehyde, in which the ratio of triazine to formaldehyde ranges from 1:0.1 to 1:0.7. The hardening agent may be added to the gelatin coating in the amount of 0.5 to 4 weight % based upon the gelatin content.
    Type: Grant
    Filed: August 16, 1988
    Date of Patent: July 31, 1990
    Assignee: Felix Schoeller Jr. GmbH & Co. KG
    Inventor: Hans Jerenz
  • Patent number: 4942121
    Abstract: A silver halide photographic light-sensitive material comprising a support having at least one hydrophilic colloidal layer having spectrally sensitized silver halide grains. There are particular sensitizers which are used and the colloidal layer contains gelatin which has a saturated solubility of not more than ten in an amount of at least 35% by weight.
    Type: Grant
    Filed: December 19, 1985
    Date of Patent: July 17, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Makoto Kajiwara, Kaoru Onodera, Toshio Kimura, Kazuo Komorita
  • Patent number: 4942120
    Abstract: The present invention is directed to a process of precipitating for use in photography a silver halide emulsion employing a gelatino-peptizer containing alkylated methionine and to an emulsion produced by this process. A variety of advantages can be realized, including an increase in the population of twinned grains and a higher yield of thin tabular grains.
    Type: Grant
    Filed: April 28, 1989
    Date of Patent: July 17, 1990
    Assignee: Eastman Kodak Company
    Inventors: Scott A. King, Philip I. Rose, Joe E. Maskasky
  • Patent number: H1063
    Abstract: Disclosed is a negative type light-sensitive silver halide photographic material comprising at least one light-sensitive silver halide emulsion provided on a support, wherein the ratio of silver amount to gelatin amount (Ag/Gel) (wherein the silver amount is the total silver amount in one or more layers provided in the same side as the light-sensitive silver halide emulsion layer with respect to the support, and the gelatin amount is the total gelatin amount in one or more gelatin layers provided in the same side as the light-sensitive silver halide emulsion layer with respect to the support) is 1.0 or more, and a hydrophilic colloid layer in the light-sensitive silver halide emulsion contains a hydrazine compound.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: June 2, 1992
    Inventor: Yuji Hosoi