Less Than 40 Percent By Weight Silica Patents (Class 501/73)
  • Patent number: 6551720
    Abstract: Materials for making a plasma display having a transparent front panel spaced from a back panel which is a metal core having layers of a dielectric material extending over and bonded to the core. The materials of which the back panel is made are chosen to form a back panel having a thermal coefficient of expansion compatible with that of the front panel. The dielectric material is made from a green ceramic tape which is bonded to the core and cofired with the core to form the back panel. The materials for the dielectric can be chosen such that the composite TCE of the cofired assembly matches the TCE of the front panel.
    Type: Grant
    Filed: May 2, 2001
    Date of Patent: April 22, 2003
    Assignee: Sarnoff Corporation
    Inventors: Attiganal Narayanaswamy Sreeram, Kalipada Palit, Leszek Hozer, Ellen Schwartz Tormey, Michael James Liberatore
  • Publication number: 20030064878
    Abstract: An optical amplifying glass having Er doped in an amount of from 0.01 to 10% as represented by mass percentage to a matrix glass comprising, by mol %, BiO2: 20 to 80, B2O3+SiO2: 5 to 75, Ga2O3+WO3+TeO2: 0.1 to 35, Al2O3≦10, GeO2≦30, TiO2≦30, and SnO2≦30, and containing no CeO2.
    Type: Application
    Filed: July 18, 2002
    Publication date: April 3, 2003
    Applicant: ASAHI GLASS COMPANY LIMITED
    Inventors: Naoki Sugimoto, Setsuro Ito
  • Patent number: 6528442
    Abstract: To provide an optically transparent film containing 0.01 to 20% by weight glass forming oxide consisting of Nb2O5, V2O5, B2O3, SiO2, and P2O6; 0.01 to 20% by weight Al2O3 or Ga2O3; and 0.01 to 5% by weight hard oxide of ZrO2 and TiO2 as required; balance being ZnO, and a sputtering target for forming such a film. This sputtering target reduces occurrence of particles during sputtering, decreases the number of interruption or discontinuance of sputtering to improve production efficiency, and forms a protective film for optical disks with large transmittance and low reflectance.
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: March 4, 2003
    Assignee: Nikko Materials Company, Limited
    Inventors: Katsuo Kuwano, Hideo Takami
  • Patent number: 6511931
    Abstract: The present invention provides a ground coat composition for use in forming an enamel layer on sheet steel that exhibits good spot acid resistance, a satin finish, good bond, and is easy-to-clean. The composition according to the invention includes a glass component that includes a blend of from about 40% to about 70% by weight of a first glass portion including one or more alkali aluminophosphate frits, up to about 30% by weight of a second glass portion including one or more zirconia-phosphate frits, and up to about 30% by weight of a third glass portion including one or more alkali borosilicate frits.
    Type: Grant
    Filed: July 16, 2001
    Date of Patent: January 28, 2003
    Assignee: Ferro Corporation
    Inventor: Charles A. Baldwin
  • Patent number: 6503860
    Abstract: According to one aspect of the present invention an optically active glass contains Sb2O3, up to about 4 mole % of an oxide of a rare earth element, and 0-20 mole % of a metal halide selected from the group consisting of a metal fluoride, a metal bromide, a metal chloride, and mixtures thereof, wherein this metal is a trivalent metal, a divalent metal, a monovalent metal, and mixtures thereof. In addition, any of the glass compositions described herein may contain up to 15 mole % B2O3 substituted for an equivalent amount of Sb2O3.
    Type: Grant
    Filed: February 4, 2000
    Date of Patent: January 7, 2003
    Assignee: Corning Incorporated
    Inventors: James E. Dickinson, Adam J. G. Ellison, Alexandre M. Mayolet, Michel Prassas
  • Patent number: 6485622
    Abstract: Lithium ion conductive glass-ceramics comprise in mol %: P2O5 30-45% SiO2 0-15% GeO2 + TiO2 25-50% in which GeO2 0-50% TiO2 0-50% ZrO2 0-8% M2O3 0<-10% where M is an element or elements selected from the group consisting of In, Fe, Cr, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb and Lu Al2O3 0-12% Ga2O3 0-12% Li2O 10-25% and contain Li1+X(M, Al, Ga)X(Ge1−YTiY)2−X(PO4)3 (where 0<X≦0.8 and 0≦Y≦1.0) as a predominant crystal phase. A solid electrolyte, an electric cell and a gas sensor utilizing these glass-ceramics are also provided.
    Type: Grant
    Filed: September 27, 1999
    Date of Patent: November 26, 2002
    Assignee: Kabushiki Kaisha Ohara
    Inventor: Jie Fu
  • Patent number: 6482758
    Abstract: A bulk single phase glass comprising 23 molar % to 50 molar % rare earth oxides, RE203, and 50 molar % to 77 molar % aluminum oxide, A12O3 is provided. The glass contains at least 50 molar % of Al2O3+RE2O3 and smaller amounts of oxide glass forming agents and other oxides than are found in prior art glasses. The addition of small amounts of lanthanum oxide, La2O3, prevents phase separation. The single phase glass is useful for optical applications such as lasers and optical amplifiers.
    Type: Grant
    Filed: October 4, 2000
    Date of Patent: November 19, 2002
    Assignee: Containerless Research, Inc.
    Inventors: J. K. Richard Weber, Johan G. Abadie, April D. Hixson, Paul C. Nordine
  • Patent number: 6458436
    Abstract: Mineral fiber products, in particular rigid bonded mineral fiber products, are provided which comprise composite mineral fibers having a coating-core configuration wherein the core provides at least 90% by weight of the fibers and is formed of mineral melt and the coating is coated onto the core. The mineral melt is chosen so that the fibers without coating have adequate biological solubility and the coating comprises a phosphate or hydrogen phosphate of alkali metal, quaternary ammonium or ammonium in an amount of at least 0.3% or by weight of the core. The coated fibers retain their biological solubility while improving resistance to ageing in use.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: October 1, 2002
    Assignee: Rockwool International A/S
    Inventors: Erling Hansen, Povl Nissen, Soren Lund Jensen
  • Patent number: 6451720
    Abstract: A glass composition is disclosed which has a high modulus of elasticity and a low density, i.e., has a high specific modulus. Also disclosed is an inexpensive glass composition which is suitable for use as an information recording medium substrate, for example, because it can be formed easily, is less apt to suffer devitrification, is suitable for mass production, and can be easily made to have high surface smoothness by polishing. The glass compositions comprise, in terms of mol %, 35 to 45% silicon dioxide (SiO2), 15 to 20% aluminum oxide (Al2O3), 3 to 10% lithium oxide (Li2O), 0.1 to 5% sodium oxide (Na2O), 15 to 30% magnesium oxide (MgO), 0 to 10% calcium oxide (CaO), 0 to 4% strontium oxide (SrO), 25 to 35% RO (MgO+CaO+SrO), 2 to 10% titanium dioxide (TiO2), 0.5 to 4% zirconium oxide (ZrO2), 4 to 12% TiO2+ZrO2, and 0 to 4% yttrium oxide (Y2O3).
    Type: Grant
    Filed: October 18, 2000
    Date of Patent: September 17, 2002
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Shoichi Kishimoto, Akihiro Koyama, Hiroyuki Tanaka
  • Patent number: 6444598
    Abstract: An insulator composition which can be sintered at a relatively low temperature and which exhibits a low dielectric constant and a thermal expansion coefficient suitable for forming an insulator layer of a laminated electronic part contains a crystallized glass composition containing SiO2, MgO and CaO as main components, and Al2O3, an amorphous silicate glass composition, and a ceramic composition. The composition ratio by weight % (SiO2, MgO, CaO) of the main components of the crystallized glass composition lies in a region surrounded by point A (30, 25, 45), point B (30, 5, 65), point C (45, 5, 50) and point D (45, 25, 30) shown in a ternary composition diagram thereof. The thermal expansion coefficient of the insulator composition after sintering can easily be changed by changing the content ratio of the crystallized glass composition, the amorphous silicate glass composition and the ceramic composition.
    Type: Grant
    Filed: September 6, 2000
    Date of Patent: September 3, 2002
    Assignee: Murata Manufacturing Co. Ltd
    Inventors: Hiromichi Kawakami, Toshiki Tanaka
  • Patent number: 6410467
    Abstract: A glass consisting essentially of antimony oxide. An optically active glass consisting essentially of antimony oxide and up to about 4 mole % of an oxide of a rare earth element. A rare earth-doped, antimony oxide-containing glass including 0-99 mole % SiO2, 0-99 mole % GeO2, 0-75 mole % (Al, Ga)2O3, 0.5-99 mole % Sb2O3, and up to about 4 mole % of an oxide of a rare earth element. The oxide of the rare earth element may comprise Er2O3. The glass of the invention further includes fluorine, expressed as a metal fluoride. An optical energy-producing or light-amplifying device, in particular, an optical amplifier, comprising the above-described glass. The optical amplifier can be either a fiber amplifier or a planar amplifier, either of which may have a hybrid composition. Embodiments of the glass of the invention can be formed by conventional glass making techniques, while some of the high content antimony oxide embodiments are formed by splat or roller quenching.
    Type: Grant
    Filed: April 8, 1999
    Date of Patent: June 25, 2002
    Assignee: Corning Incorporated
    Inventors: James E. Dickinson, Adam J G Ellison, Alexandre M. Mayolet, Michel Prassas
  • Patent number: 6403507
    Abstract: The lead-free bismuth-containing silicate glasses, which are particularly suitable for use as funnel glass or neck glass for cathode ray tubes and as soldering glass, have the following respective compositions (in % by weight, based on oxide): SiO2 40-60; Bi2O3, 10-30; ZrO2, 0-3; Al2O3, 0.5-5; MgO, 0-6; CaO, 0.5-5; SrO, 1-15; BaO, 0-15; sum of the alkaline earth metal oxides, 2-20; ZnO, 0-2; Li2O, 0-10; Na2O, 1-10; K2O, 2-10; Cs2O, 0-3, sum of the alkali metal oxides, 5-20; CeO2, 0-8; WO3, 0.5-5; MoO3, 0-5 and Sb2O3, 0-0.6; and SiO2 30-50; Bi2O3, 20-40; ZrO2, 0-3; Al2O3, 0.5-5; MgO, 0-4; CaO, 0.5-4; SrO, 1-15; BaO, 0-15; sum of the alkaline earth metal oxides, 2-20; ZnO, 0-2; Li2O, 0-5; Na2O, 1-12; K2O, 2-15; Cs2O, 0-3, sum of the alkali metal oxides, 5-20; CeO2, 0-8; WO3, 0.5-5; MoO3, 0-5 and Sb2O3, 0-0.6.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: June 11, 2002
    Assignee: Schott Glas
    Inventors: Karin Naumann, Magdalena Winkler-Trudewig, Ute Woelfel, Christian Kunert
  • Patent number: 6376084
    Abstract: A glass-ceramics having a high elastic modulus, processes for producing the same, and an information recording medium substrate effectively inhibited from bending or vibrating are disclosed. The glass-ceramics has a major crystalline phase which has a Mohs' hardness of 6 or higher and is constituted of crystals containing manganese (Mn).
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: April 23, 2002
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Shoichi Kishimoto, Akihiro Koyama, Hiroyuki Tanaka
  • Patent number: 6376403
    Abstract: A glass composition is disclosed which has a high modulus of elasticity (Young's modulus) and a high rigidity (modulus of elasticity/specific gravity) and is capable of being effectively inhibited from bending or vibrating. Also disclosed is process for producing the glass composition. The glass composition comprises, in terms of mol %, 40 to 65% SiO2, 5 to 25% Al2O3, 2 to 20% Li2O, 0 to 9% Na2O, 0 to 10% TiO2, 0 to 10% ZrO2, 0 to 25% MgO, 0 to 25% CaO, and 0 to 10% SrO, provided that the content of RO (RO=MgO+CaO+SrO) is from 2 to 40% and the sum of (Li2O)/2 and Na2O is from 1 to 10 mol %, said glass composition further containing, as clarifiers, from 0.01 to 5 mol % SnO2 and up to 0.1 mol % sulfur (S) in terms of the amount of SO3.
    Type: Grant
    Filed: August 21, 2001
    Date of Patent: April 23, 2002
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Akihiro Koyama, Shoichi Kishimoto, Junji Kurachi, Nobuyuki Yamamoto
  • Patent number: 6372155
    Abstract: The object of the present invention is to provide an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by &ggr;-rays, X-rays, UV-rays, etc. and light emission can be continued for a long time even after stopping the excitation. That is, the present invention relates to an oxide glass capable of exhibiting a long lasting afterglow and photostimulated luminescence, characterized by a constitutional composition comprising, at least, terbium oxide (Tb2O3) or manganese oxide (MnO), gallium oxide (Ga2O3) or aluminum oxide (Al2O3), alkali metal oxide or alkaline earth metal oxide and boron oxide (B2O3) or silicon oxide (SiO2) or zinc oxide (ZnO).
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: April 16, 2002
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Yamazaki, Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 6348427
    Abstract: A glass ceramic sintered product obtained by sintering a mixture powder containing a BaO-containing glass, metal oxide particles having a coefficient of linear thermal expansion at 40 to 400° C. of not smaller than 6 ppm/°C., and a Zr compound and, particularly, containing the Zr compound in an amount of from 0.1 to 30% by weight calculated as Zr02, and exhibiting a coefficient of linear thermal expansion at 40 to 400° C. of from 8.5 to 18 ppm/°C. The glass ceramic sintered product exhibits excellent resistance against chemicals and does not discolor even when subjected to treatment with an acidic or alkaline solution in the step of plating. A wiring board using the glass ceramic sintered product as an insulating substrate exhibits a coefficient of linear thermal expansion substantially similar to that of an external circuit board, effectively suppressing the occurrence of thermal stress and cracking.
    Type: Grant
    Filed: February 1, 2000
    Date of Patent: February 19, 2002
    Assignee: Kyocera Corporation
    Inventors: Noriaki Hamada, Hideto Yonekura, Kenichi Nagae, Youji Furukubo, Yoshihiro Nakao, Masahiko Higashi
  • Patent number: 6348424
    Abstract: A glass having an oxide-converted composition of 35 to 65 wt % of SiO2, 5 to 35 wt % of B2O3, 2 to 20 wt % of CaO, 5 to 25 wt % of Al2O3 where the ratio of CaO to Al2O3 is 1/1 to 1/2.5, 0.5 to 5 wt % of TiO2, 0.5 to 5 wt % of ZrO2, 0.5 to 5 wt % of ZnO, 0 to 5 wt % of MgO, 0 to 5 wt % of SrO, 0 to 5 wt % of BaO and 0 to 1 wt % of the total of group 1A element oxides such as Na2O, K2O and Li2O, or a glass having an oxide-converted composition of 10 to 45 wt % of SiO2, 20 to 50 wt % of CaO, 20 to 45 wt % of Al2O3, 0.1 to 5 wt % of MgO, 0.1 to 5 wt % of SrO, 0.1 to 5 wt % of BaO, 0.1 to 5 wt % of TiO2, 0.1 to 5 wt % of ZnO, 0.1 to 5 wt % of ZrO2 and 0 to 3 wt % of a group 1A element oxide has a low glass softening point, can be calcined as a composite with a variety of ceramics at a temperature below 1000° C., precipitates crystals during the calcination process, and can provide a glass ceramic exhibiting a low dielectric constant and a low dielectric loss.
    Type: Grant
    Filed: November 12, 1999
    Date of Patent: February 19, 2002
    Assignee: NEC Corporation
    Inventors: Ichiro Hazeyama, Kazuhiro Ikuina
  • Publication number: 20020019303
    Abstract: A sealing material for electric parts containing a lead-free tin silicate-phosphate glass of 50-100 volume percents and refractory fillers of the balance. The lead free tin silicate-phosphate glass consists essentially of, by molecular percent, 30-80% SnO, 5.5-20% SiO2, and 10-50% P2O5. The glass may contain at least one of glass stabilizing elements, said glass stabilizing elements including 3-25% ZnO, 0-4.9% B2O3, 0-5% Al2O3, 0-10% WO3, 0-10% MoO3, 0-10% Nb2O5, 0-10% TiO2, 0-10% ZrO2, 0-15% R2O (R is Li, Na, K, and/or Cs), 0-5% CuO, 0-5% MnO, 0-10% R′O (R′ is Mg, Ca, Sr and/or Ba), a total content of at least one of the glass stabilizing elements being up to 40%.
    Type: Application
    Filed: May 22, 2001
    Publication date: February 14, 2002
    Applicant: NIPPON ELECTRIC GALSS CO., LTD.
    Inventor: Toshio Yamanaka
  • Patent number: 6342460
    Abstract: The invention relates to a glass excellent in infrared absorption capability and corrosion resistance, and its fabrication process. A compound of divalent copper and a compound of a metal species for a network modifier oxide are introduced in a wet gel. Then, the wet gel is dipped in a dipping solution having a low solubility with respect to the compound of divalent copper and the compound of a metal species for a network modifier oxide for the precipitation in the wet gel of the divalent-t copper compound and the compound of a metal species for a network modifier oxide, followed by drying and firing. Thus, an infrared absorbing glass comprising 70 to 98 mol % of SiO2, 1 to 12 mol % of CuO and 1 to 18 mol % of a network modifier oxide other than CuO is fabricated.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: January 29, 2002
    Assignee: Olympus Optical Co., Ltd.
    Inventors: Yoshinobu Akimoto, Hiroaki Kinoshita
  • Patent number: 6340647
    Abstract: A glass composition is disclosed which has a high modulus of elasticity (Young's modulus) and a high rigidity (modulus of elasticity/specific gravity) and is capable of being effectively inhibited from bending or vibrating. Also disclosed is a substrate for information recording media, which comprises the glass composition. The glass composition comprises the following components in terms of mol %: 40 to 60% SiO2, 8 to 25% Al2O3, 2 to 20% Li2O, 0 to 5% Na2O; provided that the content of R2O (R2O=Li2O+Na2O) is from 2 to 20%, 0 to 10% TiO2, 0 to 10% ZrO2, 5 to 25% MgO, 0 to 25% CaO and 0 to 6% SrO, provided that the content of RO (RO=MgO+CaO+SrO) is from more than 15 to 40%.
    Type: Grant
    Filed: April 19, 1999
    Date of Patent: January 22, 2002
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Akihiro Koyama, Shoichi Kishimoto, Junji Kurachi, Nobuyuki Yamamoto
  • Publication number: 20020004443
    Abstract: Low temperature melting lead-free glass and enamel compositions are provided which have low boron content and possess high durability properties. Enamel pastes containing frits of the glass compositions are particularly useful in forming colored borders in automotive glass.
    Type: Application
    Filed: July 30, 2001
    Publication date: January 10, 2002
    Inventors: George E. Sakoske, Gerhard Tunker
  • Publication number: 20010056024
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Application
    Filed: April 2, 2001
    Publication date: December 27, 2001
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Publication number: 20010056022
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Application
    Filed: April 2, 2001
    Publication date: December 27, 2001
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Publication number: 20010056025
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Application
    Filed: April 2, 2001
    Publication date: December 27, 2001
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Publication number: 20010056016
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Application
    Filed: April 2, 2001
    Publication date: December 27, 2001
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Publication number: 20010056015
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Application
    Filed: April 2, 2001
    Publication date: December 27, 2001
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Patent number: 6333116
    Abstract: A lead silicate glass frit composition particularly useful for the formation of dielectric layers and barrier ribs in plasma display panels.
    Type: Grant
    Filed: May 17, 1999
    Date of Patent: December 25, 2001
    Assignee: Corning Incorporated
    Inventor: Pascale Laborde
  • Publication number: 20010051583
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Application
    Filed: April 2, 2001
    Publication date: December 13, 2001
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Publication number: 20010051580
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Application
    Filed: April 2, 2001
    Publication date: December 13, 2001
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Publication number: 20010051581
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Application
    Filed: April 2, 2001
    Publication date: December 13, 2001
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Publication number: 20010051578
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Application
    Filed: April 2, 2001
    Publication date: December 13, 2001
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Publication number: 20010051579
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Application
    Filed: April 2, 2001
    Publication date: December 13, 2001
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Publication number: 20010046934
    Abstract: The lead-free bismuth-containing silicate glasses, which are particularly suitable for use as funnel glass or neck glass for cathode ray tubes and as soldering glass, have the following respective compositions (in % by weight, based on oxide): SiO2 40-60; Bi2O3, 10-30; ZrO2, 0-3; Al2O3, 0.5-5; MgO, 0-6; CaO, 0.5-5; SrO, 1-15; BaO, 0-15; sum of the alkaline earth metal oxides, 2-20; ZnO, 0-2; Li2O, 0-10; Na2O, 1-10; K2O, 2-10; Cs2O, 0-3, sum of the alkali metal oxides, 5-20; CeO2, 0-8; WO3, 0.5-5; MoO3, 0-5 and Sb2O3, 0-0.6; and SiO2 30-50; Bi2O3, 20-40; ZrO2, 0-3; Al2O3, 0.5-5; MgO, 0-4; CaO, 0.5-4; SrO, 1-15; BaO, 0-15; sum of the alkaline earth metal oxides, 2-20; ZnO, 0-2; Li2O, 0-5; Na2O, 1-12; K2O, 2-15; Cs2O, 0-3, sum of the alkali metal oxides, 5-20; CeO2, 0-8; WO3, 0.5-5; MoO3, 0-5 and Sb2O3, 0-0.6.
    Type: Application
    Filed: March 28, 2001
    Publication date: November 29, 2001
    Inventors: Karin Naumann, Magdalena Winkler-Trudewig, Ute Woelfel, Christian Kunert
  • Publication number: 20010044369
    Abstract: An optical amplifier glass comprising a matrix glass containing Bi2O3 and at least one of Al2O3 and Ga2O3, and Er doped to the matrix glass, wherein from 0.01 to 10% by mass percentage of Er is doped to the matrix glass which has a total content of Al2O3 and Ga2O3 of at least 0.1 mol %, a content of Bi2O3 of at least 20 mol %, a refractive index of at least 1.8 at a wavelength of 1.55 &mgr;m, a glass transition temperature of at least 360° C. and an optical basicity of at most 0.49.
    Type: Application
    Filed: January 23, 2001
    Publication date: November 22, 2001
    Inventors: Naoki Sugimoto, Setsuro Ito, Setsuhisa Tanabe
  • Patent number: 6315881
    Abstract: A solid electric cell includes a case, a negative electrode, a positive electrode and a solid electrolyte. The negative electrode, positive electrode and solid electrolyte are disposed in the case in such a manner that the negative electrode opposes the positive electrode through the solid electrolyte. The solid electrolyte is made of an alkali ion conductive glass-ceramic having ion conductivity no less than 10−3S/cm at room temperature. A gas sensor includes a case, a negative electrode, a positive electrode, a solid electrolyte and a layer for which an electromotive force corresponding to the concentration of the gas is produced between the two electrodes. In the case, the negative electrode opposes the positive electrode through the solid electrolyte. The solid electrolyte is made of an alkali ion conductive glass-ceramic having ion conductivity no less than 10−3S/cm at room temperature.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: November 13, 2001
    Assignee: Kabushiki Kaisha Ohara
    Inventor: Jie Fu
  • Patent number: 6309992
    Abstract: A dielectric forming material for use as a transparent dielectric layer formed on an inside surface of a front glass substrate in a plasma display panel comprises powder of colored glass. The powder of colored glass comprises a base glass and coloring ingredients added thereto. The coloring ingredients comprise CoO and NiO. The powder of colored glass provides a glass film having a spectral transmittance T%(460 nm) of 50-75% at the wavelength of 460 nm or a glass film having a spectral transmittance T%(460 nm) higher than a spectral transmittance T%(550 nm) at the wavelength of 550 nm and a spectral transmittance T%(620 nm) at the wavelength of 620 nm. The glass film is formed by applying the colored glass powder onto a soda lime glass plate having a thickness of 1.7 mm and by baking the colored glass powder to form a baked film having a thickness of 20-40 &mgr;m as the glass film.
    Type: Grant
    Filed: February 3, 2000
    Date of Patent: October 30, 2001
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Yoshiro Morita, Hiroyuki Oshita, Masahiko Ohji, Kazuo Hadano
  • Patent number: 6306786
    Abstract: A glass composition is disclosed which has a high modulus elasticity (Young's modulus) and a high rigidity (modulus of elasticity/specific gravity) and is capable of being effectively inhibited from bending or vibrating. Also disclosed is a process for producing the glass composition. The glass composition comprises, in terms of mol %, 40 to 65% SiO2, 5 to 25% Al2O3, 2 to 20% Li2O, 0 to 9% Na2O, 0 to 10% TiO2, 0 to 10% ZrO2, 0 to 25% MgO, 0 to 25% CaO, and 0 to 10% SrO, provided that the content of RO (RO=MgO+CaO+SrO) is from 2 to 40% and the sum of (Li2O)/2 and Na2O is from 1 to 10 mol %, said glass composition further containing, as clarifiers, from 0.01 to 5 mol % SnO2 and up to 0.1 mol % sulfur (S) in terms of the amount of SO3.
    Type: Grant
    Filed: April 19, 1999
    Date of Patent: October 23, 2001
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Akihiro Koyama, Shoichi Kishimoto, Junji Kurachi, Nobuyuki Yamamoto
  • Patent number: 6300262
    Abstract: A glass-ceramic which is substantially and desirably totally transparent, and which contains a predominant crystal phase of forsterite. The glass-ceramic is formed from precursor glasses having the following compositions, in weight percent on an oxide basis: SiO2 30-60; Al2O3 10-25; MgO 13-30; K2O 8-20; TiO2 0-10; and GeO2 0-25. The glass-ceramic may be doped with up to 1 wt. % chromium oxide to impart optical activity thereto.
    Type: Grant
    Filed: October 11, 2000
    Date of Patent: October 9, 2001
    Assignee: Corning Incorporated
    Inventor: George H. Beall
  • Patent number: 6297181
    Abstract: The invention relates to a barium-free, X-ray-opaque dental glass, to a dental glass/polymer composite comprising the glass, and to the use thereof as dental filling, where the dental glass has the following composition (in % by weight): SiO2 20-45, Al2O3 5-35, B2O3 1-10, Na2O 1-10, K2O 0-8, Cs2O 0-8, sum all alkali metal oxides 1-15, CaO 0-8, SrO 0-27, ZnO 2-20, ZrO2 2-10, P2O5 0-10, La2O3 0-10, F 2-20, the total content of B2O3, ZnO, ZrO2 and La2O3 is >20% by weight, and the refractive index nd of the dental glass is in the range from 1.47 to 1.70.
    Type: Grant
    Filed: October 27, 1999
    Date of Patent: October 2, 2001
    Assignee: Schott Glas
    Inventors: Christian Kunert, Susanne Kessler, Hartmut Paschke, Alwin Weitzel, Ute Wolfel
  • Patent number: 6271160
    Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, can be used not only as a material for confirming an infrared laser or controlling an optical axis, but also as a material for recording or reproducing of &ggr;-rays, X-rays or UV-rays images and further can be used as an optical recording material of such a type that can be read. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %): GeO2 21 to 80% ZnO 0 to 50% Ga2O2 0 to 55% (ZnO + Ga2O3 = 3 to 55%) Tb2O3 0 to 10% MnO 0 to 2% (Tb2O3 + MnO = 0.01 to 10%) R2O 0 to 45% (R: at least one atom selected from Li, Na, K and Cs) R′O 0 to 40% (R′: at least one atom selected from Mg, Ca, Sr and Ba) R2O + R′O 0.
    Type: Grant
    Filed: May 12, 1999
    Date of Patent: August 7, 2001
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Yoshinori Yamamoto, Masaaki Yamazaki, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 6268303
    Abstract: The present invention relates to a glass matrix which includes 4-70 wt. % SiO2, 0.5-20 wt. % Al2O3, 0-20 wt. % R2O, 0-30 wt. % R′O, 8-85 wt. % Ta2O5, 0-40 wt. % Nb2O5, and 0.01-1.0 wt. % R″2O3, where R2O+R″O is between about 2-35 wt. %, Ta2O5+Nb2O5 is between about 8-85 wt. %, R is selected from a group consisting of Li, Na, K, and combinations thereof, R′ is selected from a group consisting of Ba, Sr, Ca, Mg, Zn, Pb, and combinations thereof, and R″ is a rare earth element. The present invention also relates to use of the glass matrix in forming optic waveguides such as optic amplifiers. The present invention further relates to a transparent glass ceramic that contains pyrochlore, perovskite, or a combination thereof as its major crystal phase, and includes 4-40 wt. % SiO2, 1-15 wt. % Al2O3, 0-20 wt. % K2O, 0-12 wt. % Na2O, 0-5 wt. % Li2O, 8-85 wt. % Ta2O5, and 0-45 wt. % Nb2O5, wherein Ta2O5+Nb2O5 is at least about 20 wt.
    Type: Grant
    Filed: May 27, 1999
    Date of Patent: July 31, 2001
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, George H. Beall, Nicholas F. Borrelli, Matthew J. Dejneka
  • Patent number: 6255598
    Abstract: A primarily polycrystalline but partially amorphous electrical insulator can hermetically seal first and second spaced electrical terminals, one made from an anodized aluminum and the second made from a beryllium copper or Kovar or an alloy of beryllium, copper, nickel and gold. Nickel may be diffused into the beryllium copper and a noble metal may be deposited on the nickel. The insulator provides a flat meniscus to abut a corresponding electrical insulator in a cable. The insulator may provide an electrical impedance of approximately 50 ohms, an electrical resistivity greater than approximately 1018 ohms and a dielectric constant of approximately 6.3. The insulator operates satisfactorily in a frequency range to approximately 40 gigahertz.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: July 3, 2001
    Inventor: James C. Kyle
  • Patent number: 6250108
    Abstract: In a method of making a high-quality silica glass, a rare earth element that is a substance making a great contribution to the index of refraction is introduced therein together with aluminum for stabilizing the glass. An alkoxide of aluminum or its derivative is used as the starting material for preparing a boehmite sol. A salt of at least one element selected from rare earth elements or a solution in which the salt is dissolved and the boehmite sol are mixed with a silica sol, whereupon the sols are vitrified.
    Type: Grant
    Filed: July 1, 1998
    Date of Patent: June 26, 2001
    Assignee: Olympus Optical Co., LTD
    Inventors: Hiroaki Kinoshita, Morinao Fukuoka
  • Patent number: 6228787
    Abstract: This invention relates to fluorescent photosensitive glasses and a process for the production thereof. The fluorescent photosensitive glasses according to the present invention employ silicate or phosphate glass compositions including minor amounts of one or more fluorescent agents (e.g., ytterbium (Yb), samarium (Sm), europium (Eu)) and one or more photosensitive agents (e.g., erbium (Er), thulium (Tm), praseodymium (Pr), ytterbium (Yb), holmium (Ho), samarium (Sm), cerium (Ce), dysprosium (Dy), terbium (Tb), neodymium (Nd)). The inventive fluorescent photosensitive glass can be used in photographic applications, florescent displays and computer memories.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: May 8, 2001
    Inventor: Eugen Pavel
  • Patent number: 6225244
    Abstract: A glass for a near infrared absorption filter, which has spectral characteristics that it efficiently transmits light in a wavelength region of from ultraviolet region to 600 nm and selectively absorbs light in a near infrared region of a wavelength of larger than about 600 nm, a near infrared absorption filter formed of the above glass, and a solid-state image sensing device to which the above filter is applied, the glass comprising, by cationic %, 35 to 54% of P, 20 to 47% of Zn, 0 to 8% of the total, R, of Li, Na, K and Cs which are monovalent metal elements, 0 to 17% of the total, M, of Mg, Ca, Ba, Sr and Pb which are divalent metal elements, the total of R and M being 1 to 22%, 0.1 to 7% of As, 0.2 to 9% of Cu and 0 to 6% of Al.
    Type: Grant
    Filed: January 20, 1999
    Date of Patent: May 1, 2001
    Assignee: Hoya Corporation
    Inventor: Hironori Oguma
  • Patent number: 6174829
    Abstract: A low-fire, low-dielectric ceramic composition is disclosed. The ceramic composition comprises a mixture of finely divided particles consisting of 30-90% by volume of Ca—Ba—Al—Zn—Si glass and 70-10% by volume of oxides, which can be densified up to 95% at temperatures of 800-1000° C. The sintered body produced thereby exhibits a dielectric constant in the range of 6-10 and a dielectric loss in the range of 0.01%-0.5% at 1 MHz. The ceramic composition can be processed with organic solvent, polymeric binder and plasticizer to produce a green sheet which is co-firable with high electrical conductivity metal such as gold, silver, silver-palladium and copper.
    Type: Grant
    Filed: January 7, 1999
    Date of Patent: January 16, 2001
    Assignee: Advanced Ceramic X Corp.
    Inventors: Jau-Ho Jean, Shih-Chun Lin
  • Patent number: 6165923
    Abstract: The present invention provides a coating layer of the coke oven having a high strength, high impact resistance and excellent smoothness to enable long term protection of the fire brick of the coke oven. Carbon adhered to the brick can be removed by spraying a coating agent with a glaze layer mainly composed of 18 to 70% by weight of SiO.sub.2 and 10 to 60% by weight of Na.sub.2 O and/or K.sub.2 O and containing one or a plurality of 2 to 14% by weight of P.sub.2 O.sub.5, 0.5 to 25% by weight of BaO, 0.5 to 25% by weight of SrO and 0.5 to 20% by weight of Fe.sub.2 O.sub.3 onto the surface of a high temperature firebrick, thereby obtaining an excellent coating layer.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: December 26, 2000
    Assignees: Kawasaki Steel Corporation, Taiho Industries Co., Ltd.
    Inventors: Takeshi Ando, Shizuki Kasaoka, Teruo Onozawa, Shigeru Nakai
  • Patent number: 6162751
    Abstract: The glasses used for making rigid disk substrates have the following composition (based on the % by weight of the oxides): SiO.sub.2, 40 to 60; Al.sub.2 O.sub.3, 5 to 20; B.sub.2 O.sub.3, 0 to 5; Li.sub.2 O, 0 to 10; Na.sub.2 O, 0 to 12, with the proviso that Li.sub.2 O+Na.sub.2 O 5 to 12; K.sub.2 O, 0 to 5; MgO, 0 to 20; CaO, 0 to 6, with the proviso that MgO+CaO, 4 to 20,SrO+BaO, 0 to 10; Zr.sub.2 O, 0 to 5; TiO.sub.2, 0 to 5; CeO.sub.2, 0 to 1; La.sub.2 O.sub.3, 0 to 10; Fe.sub.2 O.sub.3, 0 to 10; Nb.sub.2 O.sub.5, 0 to 10; V.sub.2 O.sub.5, 0 to 15, with the proviso that TiO.sub.2 +ZrO.sub.2 +La.sub.2 O.sub.3 +Fe.sub.2 O.sub.3 +Nb.sub.2 O.sub.3 +V.sub.2 O.sub.5 .gtoreq.8, As.sub.2 O.sub.3 +Sb.sub.2 O.sub.3 +F, 0.1 to 1; or, SiO.sub.2, 10 to 30; Al.sub.2 O.sub.3, 0 to 5; B.sub.2 O.sub.3, 0 to 8; Li.sub.2 O, 0 to 8; Na.sub.2 O, 1 to 10, with the proviso that Li.sub.2 O+Na.sub.2 O, 5 to 10; K.sub.2 O, 0 to 3; MgO, 0 to 12; CaO, 0 to 15, with the proviso that MgO+CaO,10 to 15, SrO+BaO, 0 to 8; Zr.sub.
    Type: Grant
    Filed: January 26, 1999
    Date of Patent: December 19, 2000
    Assignee: Schott Glas
    Inventors: Burkhard Speit, Gerhard Westenberger
  • Patent number: 6153127
    Abstract: The present invention relates to an optical thin film containing titanium oxide, cerium oxide and bismuth oxide, wherein the content ratio of the titanium oxide, cerium oxide, and bismuth oxide is within the area expressed by four-cornered shape ABCD consisting of A (4,1,95), B (98,1,1), C (20,79,1), and D (3,14,83) in term of coordinate points (TiO.sub.2 mol percent, CeO.sub.2 mol percent, and Bi.sub.2 O.sub.3 mol percent) of the mol ratio when being converted to oxides of TiO.sub.2, CeO.sub.2, and Bi.sub.2 O.sub.3. Furthermore, with the invention, a comparatively high refractive index film layer and a comparatively low refractive index film layer are alternately laminated at least three layers on a transparent glass substrate, at least two layers of said three layers are high refractive index films, and at least one layer of said high refractive index films is said optical thin film.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: November 28, 2000
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Koichiro Nakamura, Koichi Maeda
  • Patent number: 6136737
    Abstract: A glass powder for dental glass ionomer cement is disclosed, comprising a fluoroaluminosilicate glass powder for dental glass ionomer cement having a specific gravity of 2.4.about.4.0, a mean particle size of 0.02.about.4 .mu.m, and a BET specific surface area of 2.5.about.6.0 m.sup.2 /g. Further, it preferably has a maximum particle size of less than 4 .mu.m and contains 10.about.21% by weight of Al.sup.3+, 9.about.21% by weight of Si.sup.4+, 1.about.20% by weight of F.sup.-, and 10.about.34% by weight in total of Sr.sup.2+ and/or Ca.sup.2+ in its components. The glass powder for dental glass ionomer cement of the invention can impart superior surface smoothness and film thickness, while utilizing superior characteristics inherent to the conventional dental glass ionomer cement, such as superior biocompatibility and adhesive strength.
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: October 24, 2000
    Assignee: GC Corporation
    Inventors: Atsuhiro Todo, Michiko Hirasawa, Shinichi Kato