Less Than 40 Percent By Weight Silica Patents (Class 501/73)
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Patent number: 4650923Abstract: In an article comprising a ceramic body fired at a comparatively low temperature and a circuit pattern attached to the body, the ceramic body is produced from a preselected composition comprising first powder of alumina and second powder of a vitreous material which comprises any one of MgO-Al.sub.2 O.sub.3 -SiO.sub.2, CaO-MgO-Al.sub.2 O.sub.3 -SiO.sub.2, CaO-Al.sub.2 O.sub.3 -SiO.sub.2 glass, CaO-Al.sub.2 O.sub.3 -SiO.sub.2 -B.sub.2 O.sub.3 glass, MgO-Al.sub.2 O.sub.3 -SiO.sub.2 -B.sub.2 O.sub.3 glass, and CaO-MgO-Al.sub.2 O.sub.3 SiO.sub.2 -B.sub.2 O.sub.3 glass. The ceramic body comprises coexistence of an alumina part, a noncrystallized part, and a crystallized part and exhibits an excellent moisture proof. The circuit pattern comprises an internal conductive pattern of Ag and an external conductive pattern of an alloy of Ag-Pd. A chromium component may be included in the internal and the external conductive patterns.Type: GrantFiled: May 31, 1985Date of Patent: March 17, 1987Assignee: Narumi China CorporationInventors: Susumu Nishigaki, Junzo Fukuda, Masashi Fukaya, Shinsuke Yano
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Patent number: 4626514Abstract: Dental materials using calcium phosphate glass-ceramics and having the color tone with high approximation to that of natural teeth. In those dental materials, calcium phosphate composite, nickel oxide and one or more other type of compounds selected from oxides of iron, manganese, cerium, titanium and tungsten, are contained as coloring component. Also, if necessary, Al.sub.2 O.sub.3 and/or SiO.sub.2 is contained as a color assisting agent in that composite. The calcium phosphate glass-ceramic according to this invention consists of the same components as that of natural teeth. Besides, it is possible to adjust the color tone delicately to match with the color tone of each individual`s teeth. Moreover, the coloring components are incorporated in crystals of calcium phosphate. Consequently, they cause no elution during use and are therefore ideal as dental material.Type: GrantFiled: March 27, 1986Date of Patent: December 2, 1986Assignee: Kyushu Refractories Co., Ltd.Inventors: Akira Watanabe, Yoshimitsu Takeuchi, Hiroyasu Tokuda, Seiji Kihara, Yasuhiro Makino, Keiji Kamegawa
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Patent number: 4618590Abstract: The invention relates to the formulation of a starting mixture for an insulating composition, comprising a vitreous phase and several ceramic phases in the respective ratios by volume for the vitreous phase between 85 and 60% and for the ceramic phases between 15 and 40%, the vitreous phase being a silicate of zinc and alkaline earth.According to an embodiment of the invention the starting mixture is remarkable in that the vitreous phase is constituted by the molar ratios of the following oxides:30 to 55% of silicon (SiO.sub.2), 15 to 30% of zinc oxide (ZnO), 0 to 20% of boric anhydride (B.sub.2 O.sub.3), 0 to 10% of alumina (Al.sub.2 O.sub.3), 15 to 40% of barium oxide (BaO), and in that the ceramic phases are constituted by the ratios by volume of the following oxides: 0 to 10% of cobalt oxide (Co.sub.3 O.sub.4), 5 to 20% of zinc oxide (ZnO), and 10 to 25% of lead oxide (PbO.sub.2).Application: Manufacture of microcircuits on colaminated metallic substrates.Type: GrantFiled: May 3, 1985Date of Patent: October 21, 1986Assignee: U.S. Philips CorporationInventor: Hugues Baudry
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Patent number: 4617045Abstract: A process for making a homogeneous melt for producing mineral wool insulation. This insulating material is made from waste products namely, bottom ash, cement kiln dust, slag, and waste from mineral wool production. These materials, along with a binder, are homogenized into a mixture. Thereafter, the process includes briquetting the mixture into agglomerated pieces. The agglomerates are then melted in a cupola furnace and the molten agglomerate is discharged into a receiver. Hot combustion gases are then passed into the melt or molten agglomerate to chemically homogenize the melt and heat the melt to a preselected temperature. Thereafter, the melt is converted into fibers using conventional practices.Type: GrantFiled: April 5, 1985Date of Patent: October 14, 1986Inventor: Boris Bronshtein
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Patent number: 4615989Abstract: An optical CuO-bearing, alkali- and alkaline-earth rich phosphate glass with relatively high elongation (at 20.degree.-300.degree. C. from 110.times.10.sup.-7 grd.sup.-1 to 138.times.10.sup.-7 grd.sup.-1) and a transformation range .ltoreq.380.degree. C., with substantially improved transmission in the UV to blue range of the spectrum (UV-transmission at .lambda.=350 nm between .gtoreq.69% and .gtoreq.83%) and a very strong absorption in the red region of the spectrum (IR-absorption at .lambda.=700 nm between .ltoreq.2% and .ltoreq.12%), consisting essentially of the following synthesis/composition, in wt. %: P.sub.2 O.sub.5 65-70%; SiO.sub.2 0-0.75%; B.sub.2 O.sub.3 0-2%; A.sub.2 O.sub.3 2.5-6%; R.sub.2 O (alkali metal oxides) 11-17%; BaO 3-9.5%; CeO.sub.2 0.45-2.0%; CuO 2.55-6.55%; Cl.sup.- 0.15-0.75%; F.sup.- 0.25-1.50%; refining agent 0.10-2.00% with .SIGMA.CeO.sub.2 +Al.sub.2 O.sub.3 +BaO+CuO.gtoreq.8.5 and .SIGMA.R.sub.2 O=F.sup.- +Cl.sup.- .gtoreq.21.Type: GrantFiled: April 17, 1985Date of Patent: October 7, 1986Assignee: Schott GlaswerkeInventor: Willy Ritze
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Patent number: 4608352Abstract: The present invention relates to neutron-absorbent oxide or oxynitride glasses containing gadolinium and a process for their preparation.The glasses according to the invention, which incorporate silicon, aluminum, oxygen or oxygen and nitrogen, additionally contain gadolinium in a proportion of approximately 5 to 15 atom %.Type: GrantFiled: September 30, 1985Date of Patent: August 26, 1986Assignee: Centre National de la Recherche Scientifique (CNRS)Inventors: Yves Laurent, Patrick Verdier
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Patent number: 4605443Abstract: This invention relates to the preparation of hydraulic cements consisting essentially of glasses having compositions within area ABCDEA of FIG. 1 which, when contacted with water, hydrate to form strong, low porosity cements having crystals composed predominantly of hydrogarnet solid solution and/or hydrogehlenite.Type: GrantFiled: January 28, 1985Date of Patent: August 12, 1986Assignee: Corning Glass WorksInventor: John F. MacDowell
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Patent number: 4605415Abstract: Bioreactive materials, for use in forming implants or prostheses, obtained by fusion of a mixture of 20 to 50% by weight of SiO.sub.2, 15 to 25% by weight of CaO, 5 to 10% by weight of P.sub.2 O.sub.5, 15 to 25% by weight of Na.sub.2 O and 3 to 15% by weight of Al.sub.2 O.sub.3, or their metallic precursors yielding equivalent quantities of oxides by fusion.Type: GrantFiled: December 2, 1983Date of Patent: August 12, 1986Assignee: Region Wallonne, representee par l'Executif Regional WallonInventor: Raymond M. Richez
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Patent number: 4575493Abstract: Compositions of metal oxides which may be melted and cooled to produce glasses are disclosed. The glasses may be heat treated to produce glass-ceramics. The glasses have good transmittances for electromagnetic radiation in the ultraviolet, infrared and visible spectra, while the glass-ceramics have good transmittances of infrared radiation. Other physical properties make these materials desirable for purposes such as radomes.Type: GrantFiled: March 16, 1982Date of Patent: March 11, 1986Assignee: General Electric Co.Inventor: Harry W. Rauch, Sr.
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Patent number: 4567151Abstract: A thick film conductor composition comprising an admixture of finely divided particles of noble metal and inorganic binder dispersed in organic medium in which the inorganic binder consists essentially of a bismuth silicate glass and/or bismuth germanate glass, ZnO and optionally Bi.sub.2 O.sub.3.Type: GrantFiled: January 14, 1985Date of Patent: January 28, 1986Assignee: E. I. Du Pont de Nemours and CompanyInventor: Barry E. Taylor
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Patent number: 4560666Abstract: A high strength glass-ceramic containing apatite and alkaline earth metal silicate (diopside/forsterite/akermanite) crystals having an excellent affinity for a living body and a process for producing the same are disclosed. The glass-ceramic is useful as an implant material such as an artificial dental root and an artificial bone.Type: GrantFiled: December 6, 1984Date of Patent: December 24, 1985Assignee: Hoya CorporationInventors: Masahiro Yoshida, Kenji Nakagawa
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Patent number: 4547467Abstract: A composition for a dielectric ink used in a screening process including a lead-free glass frit binder, silica, and a vehicle. The dielectric composition is particularly suited for use in gas plasma display panels.Type: GrantFiled: June 22, 1983Date of Patent: October 15, 1985Assignee: Burroughs CorporationInventors: Edward G. Barth, Ruvim Braude, Nicholas W. Kay
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Patent number: 4544974Abstract: There are described a glass composition and a magnetic head containing the same, wherein the glass composition comprises an oxide of an alkali metal or alkaline earth, and at least one non-alkali metal oxide in an amount sufficient to provide a coefficient of thermal expansion of 80-170.times.10.sup.-7 .degree. C..sup.-1, the composition featuring from 5-15 mole % Al.sub.2 O.sub.3 and an amount of a compatible glass former sufficient to insure the Al.sub.2 O.sub.3 is soluble in the composition.Type: GrantFiled: October 20, 1983Date of Patent: October 1, 1985Assignee: Eastman Kodak CompanyInventors: Bradford D. West, Jr., Jean Berchtold
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Patent number: 4544614Abstract: An ionically conductive glass is disclosed for use as electrolyte in a high temperature electrochemical cell, particularly a cell with sodium anode and sulfur cathode. The glass includes the constituents Na.sub.2 O, ZrO.sub.2, Al.sub.2 O.sub.3 and SiO.sub.2 in selected proportions to be a single phase solid solution substantially free of crystalline regions and undissolved constituents. Other advantageous properties are an ionic conductivity in excess of 2.times.10.sup.-3 (ohm-cm).sup.-1 at 300.degree. C. and a glass transition temperature in excess of 500.degree. C.Type: GrantFiled: January 8, 1985Date of Patent: October 1, 1985Assignee: The United States of America as represented by the United States Department of EnergyInventors: Gene H. Kucera, Michael F. Roche
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Patent number: 4536452Abstract: This invention is related to the production of machinable glass-ceramic articles which are essentially free from crystals having a mica structure and consist essentially, in weight percent, ofSiO.sub.2 : 24-28Al.sub.2 O.sub.3 : 9-20MgO: 12-28SrO: 0-11BaO: 0-14CuO: 0-5Ag.sub.2 O: 0-3.5NiO: 0-1.5Cr.sub.2 O.sub.3 : 0.5-6.Type: GrantFiled: October 24, 1983Date of Patent: August 20, 1985Assignee: Corning Glass WorksInventors: John L. Stempin, Dale R. Wexell
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Patent number: 4530909Abstract: A process for preparing aluminosilicate glass comprising from 30 to 60 molar % of SiO.sub.2, from 20 to 35 molar % of Al.sub.2 O.sub.3 and from 10 to 30 molar % of a total of rare earth oxides composed mainly of Y.sub.2 O.sub.3, wherein an yttrium concentrate is used as the rare earth oxides composed mainly of Y.sub.2 O.sub.3, and ZrO.sub.2 not in excess of 8 molar % to improve alkali resistance.Type: GrantFiled: October 19, 1984Date of Patent: July 23, 1985Assignee: National Institute for Researches in Inorganic MaterialsInventors: Akio Makishima, Tatsuya Nagata, Takajiro Shimohira
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Patent number: 4513070Abstract: Electrochemical devices use a vitreous material having a general formulaxAaR.sub.b --yNmRc--zN.sub.n Y.sub.pwherein A is Si, Ge, P, S, B, Nb, As, V, Cr or Mo; R is O, S or Se; N is Li, Na, K or Ag and Y is I, Br, Cl, F, ClO.sub.4, CF.sub.3, SO.sub.3, SCN or SO.sub.4 with the proviso that the material contain at least two salts NY. Such materials have increased cationic conductivity.Type: GrantFiled: February 8, 1983Date of Patent: April 23, 1985Assignee: Centre National de la Recherche ScientifiqueInventors: Brigitte Carette, Ali Kone, Jean-Louis Souquet, Michel Ribes, Maurice Maurin
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Patent number: 4511664Abstract: A mixture containing 35 to 65% by weight of Al.sub.2 O.sub.3, 30 to 60% by weight of SiO.sub.2, 1.5 to 4% by weight of Cr.sub.2 O.sub.3, and 0.01 to 0.1% by weight of carbon, the balance being unavoidable impurities, is melted, and amorphous fibers are formed from said molten material by blowing or spinning. The fibers are heated rapidly to a temperature of 950.degree. C. to 1,150.degree. C., held at that temperature for several to about a dozen minutes, and cooled rapidly to ordinary room temperature.Type: GrantFiled: June 4, 1984Date of Patent: April 16, 1985Assignee: Isolite Babcock Refractories Co., Ltd.Inventor: Masafumi Yamamoto
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Patent number: 4508834Abstract: A spectacle glass which is colorless in the visible spectrum range, not transmissive in the ultraviolet spectrum range below 350 nm, has a refractive index n.sub.d higher than 1.56 and an Abbe number of more than 45, and which has an extremely low density, has the following composition (in % by weight):______________________________________ 12-40 P.sub.2 O.sub.5 13-34 Al.sub.2 O.sub.3 8-30 SiO.sub.2 0-16 B.sub.2 O.sub.3 4-12 TiO.sub.2 0-4 ZrO.sub.2 2-18 CaO 0-4 MgO 0-15 Na.sub.2 O 0-11 K.sub.2 O 0-6 Li.sub.2 O 0-12 Nb.sub.2 O.sub.5 0-8 ZnO.Type: GrantFiled: February 10, 1983Date of Patent: April 2, 1985Assignee: Schott GlaswerkeInventors: Georg Gliemeroth, Ludwig Ross, Burkhard Speit, Volkmar Geiler, Hans-Georg Krolla, Lothar Meckel
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Patent number: 4495298Abstract: A thallium-containing optical glass composition which comprises the following oxides in the indicated proportions in mole %: SiO.sub.2 35-80, Tl.sub.2 O 1-30, Tl.sub.2 O+R.sub.2 O (R being an alkali metal) 1-35, ZnO 0-35, GeO.sub.2 0-30, BaO 0-25, TiO.sub.2 0-20, MgO 0-20, B.sub.2 O.sub.3 0-less than 10, ZrO.sub.2 0-2, Al.sub.2 O.sub.3 0-8, SnO 0-5, CaO 0-10, SrO 0-10, PbO 0-10, La.sub.2 O.sub.3 0-5, Bi.sub.2 O.sub.3 0-8, and Ta.sub.2 O.sub.5 0-2, and satisfies the following relations:5.ltoreq.ZnO+GeO.sub.2 +BaO+TiO.sub.2 +MgO+B.sub.2 O.sub.3 .ltoreq.40,0.1.ltoreq.ZrO.sub.2 +Al.sub.2 O.sub.3 +SnO.ltoreq.8,and0.ltoreq.CaO+SrO+PbO+La.sub.2 O.sub.3 +Bi.sub.2 O.sub.3 +Ta.sub.2 O.sub.5 .ltoreq.10.Type: GrantFiled: May 11, 1982Date of Patent: January 22, 1985Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Takasi Yamagishi, Yukio Noguchi
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Patent number: 4484949Abstract: A water hardenable cement composition comprising a fluorine-free calcium alumino silicate glass in particulate form in which the individual particulates have a particle size of less than 100 microns consisting essentially of 25-35% silica, 27-35% calcium oxide, 25-40% alumina, up to 4% of an alkali metal oxide, up to 5% of titania, the total amount of alkali metal oxide and titania being 0.5-9%, wherein the ratio of calcium oxide to silica is 0.7:1 to 1:0-7, together with a polycarboxylic acid.Type: GrantFiled: June 28, 1982Date of Patent: November 27, 1984Assignee: Smith & Nephew Research LimitedInventors: William D. Potter, Andrew C. Barclay, Reginald Dunning, Richard J. Parry
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Patent number: 4481299Abstract: An optical glass comprising, in % by weight21.0 to 35.0% SiO.sub.2 ;0 to 10.0% B.sub.2 O.sub.3 ;0 to 4.0% Al.sub.2 O.sub.3 ;0.5 to 4.0% Li.sub.2 O;33.0 to 55.0% BaO+SrO+CaO+MgO+ZnO, with the proviso of19.0 to 45.0% BaO,0 to 15.0% SrO,0 to 20.0% CaO,0 to 5.0% MgO, and1.5 to 20.0% ZnO;8.0 to 23.0% La.sub.2 O.sub.3 ;2.0 to 8.0% ZrO.sub.2 ;0 to 10.0% TiO.sub.2 ;0 to 4.5% Nb.sub.2 O.sub.5 +Ta.sub.2 O.sub.5 ;0 to 5.0% WO.sub.3 ; and0 to 5.0% PbO.Type: GrantFiled: April 23, 1984Date of Patent: November 6, 1984Assignee: Hoya CorporationInventor: Hidemi Tajima
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Patent number: 4477580Abstract: Optical components using a germania-silica glass are made by a gel technique. Tetra pentyloxygermane and a silicon alkoxide are hydrolyzed to form a gel, which is subsequently dried. Optical components, including optical fibers and devices, can be made using glass prepared by this technique.Type: GrantFiled: September 28, 1982Date of Patent: October 16, 1984Assignee: AT&T Bell LaboratoriesInventor: James W. Fleming, Jr.
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Patent number: 4472510Abstract: What is disclosed is a method of preparing carbon-containing monolithic glassy ceramics from organosilsesquioxanes, metal oxides and metal alkoxides through pyrolysis of their gels. Also disclosed are certain gel compositions used in the method and the glassy ceramics.Type: GrantFiled: December 23, 1982Date of Patent: September 18, 1984Assignee: Dow Corning CorporationInventor: James R. January
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Patent number: 4472030Abstract: A cesium-containing optical glass comprising, by weight, 32-56% of SiO.sub.2, 6-25% of K.sub.2 O, 6-32% of Cs.sub.2 O, 0-30% of BaO, 0-2.5% of MgO, 5-34% of ZnO, 0-3% of ZrO.sub.2 and 0-5% of SnO.sub.2, provided that the total proportion of BaO, MgO and ZnO is 8-40% and the total proportion of ZrO.sub.2 and SnO.sub.2 is 0.2-6%. When this cesium-containing optical glass is treated in a molten bath containing potassium nitrate, the cesium ion in the glass is easily exchanged with a potassium ion and therefore, the cesium ion concentration gradually decreases radially outwardly from the central axis and the potassium ion concentration gradually increases in that direction. Thus, there is obtained a light converge-type lens in which the refractive index gradually decreases in the same direction.Type: GrantFiled: November 4, 1983Date of Patent: September 18, 1984Assignee: Nippon Sheet Glass Company, LimitedInventors: Masakiyo Tachibana, Yukio Noguchi, Noboru Akazawa
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Patent number: 4465744Abstract: An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.Type: GrantFiled: November 30, 1982Date of Patent: August 14, 1984Assignee: The United States of America as represented by the United States Department of EnergyInventors: Sherman Susman, Kenneth J. Volin
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Patent number: 4461840Abstract: The present invention concerns glass compositions capable of being attenuated in the form of fibers.These glass fibers comprise the following oxides in the percentages by weight: SiO.sub.2 :37 to 48%; Al.sub.2 O.sub.3 :17 to 25%; CaO:23 to 33%; MgO:0.1 to 7%; Fe.sub.2 O.sub.3 :0.1 to 3%; Na.sub.2 O:2 to 8%; K.sub.2 O:0.1 to 7%, the sum of the percentages of earthalkaline oxides (CaO and MgO) being less than or equal to 34%, and the sum of the alkaline oxides (Na.sub.2 O and K.sub.2 O) being greater than 5%.The invention is applicable to the manufacture of products subjected to elevated temperatures, for instance, products used for insulation purposes, even when such products may be subjected to a temperature as high as 700.degree. C.Type: GrantFiled: July 19, 1982Date of Patent: July 24, 1984Inventors: Jean-Jacques Massol, Daniel Sainte-Foi
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Patent number: 4459510Abstract: The invention relates to lamps having a glass lamp vessel (1) and to a glass suitable therefor. The relevant glass is adequately resistant to attack by electrons, is resistant to atmospheric influences and is properly workable in a gas flame. This glass contains 44-60 mole % silicon oxide; 0-7.5 mole % boron oxide; 0-6 mole % zirconium oxide; 0-7.5 mole % aluminium oxide; 5-20 mole % calcium oxide; 12.5-25 mole % barium oxide; 0-15 mole % magnesium oxide; 0-10 mole % strontium oxide; 2-8 mole % sodium oxide. The sum of the alkaline earth metals is 25-42.5 mole %.No discoloration occurs in sodium vapor discharge lamps when the lamp vessel has been made of this glass.Type: GrantFiled: September 6, 1983Date of Patent: July 10, 1984Assignee: U.S. Philips CorporationInventor: Hendrik J. M. Joormann
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Patent number: 4455384Abstract: The chemical durability of alkali phosphate glasses is improved by incorporation of up to 23 weight percent of nitrogen. A typical phosphate glass contains: 10 to 60 mole % of Li.sub.2 O, Na.sub.2 O or K.sub.2 O; 5-40 mole % of BaO or CAO; 0-1 to 10 mole % of Al.sub.2 O.sub.3 ; and 40-70 mole % of P.sub.2 O.sub.5. Nitrides, such as AlN, are the favored additives.Type: GrantFiled: December 8, 1982Date of Patent: June 19, 1984Assignee: The United States of America as represented by the United States Department of EnergyInventors: Delbert E. Day, James A. Wilder, Jr.
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Patent number: 4438212Abstract: The invention relates to calciumaluminosilicate glasses. The glasses contain, in weight percent, 25 to 35% silica, 27 to 35% calcium oxide, 25 to 40% alumina, 0 to 4% of alkali metal oxide selected from lithium oxide, sodium oxide and potassium oxide, and 0 to 5% of titanium oxide and a total content of lithium, sodium, potassium and titanium oxides of 0.5 to 9%. The glasses, in finely divided form, react with aqueous polycarboxylic acids and set to a solid mass; cements made from the glass and polycarboxylic acids are useful in splinting compositions.Type: GrantFiled: June 28, 1982Date of Patent: March 20, 1984Assignee: Pilkington Brothers P.L.C.Inventors: William D. Potter, Andrew C. Barclay, Reginald Dunning, Richard J. Parry
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Patent number: 4427784Abstract: This specification discloses fluophosphate optical glass of low dispersion containing no beryllium and arsenic and having an optical constant nd=1.43-1.48 and .nu.d=85-97 and which can be produced stably and easily.Type: GrantFiled: July 6, 1981Date of Patent: January 24, 1984Assignee: Nippon Kogaku K.K.Inventors: Hiroshi Nakamura, Takeo Ichimura
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Patent number: 4407786Abstract: A copper phosphate water soluble glass composition. The composition of the glass may be adjusted so as to release copper at a uniform preselected rate and to produce a desired pH in the resultant solution. In one application of the glass copper may be supplied to an animal from an implant formed from a cupric oxide/phosphorus pentoxide glass which also incorporates one or more glass modifying oxides such as alkali metal oxides and alumina, to control the glass solubility. Suitable glasses comprise 5-55 mole % cupric oxide + alkali metal oxides. 45-75 mole % phosphorus pentoxide, and not more than 15 mole % alumina, where the copper oxide concentration is not less than 5 mole %.Type: GrantFiled: April 9, 1981Date of Patent: October 4, 1983Assignee: International Standard Electric CorporationInventors: Cyril F. Drake, Mary Tripp
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Patent number: 4399232Abstract: Continuous inorganic fibers consisting substantially of Si, Ti and C and optionally of O, said fibers being composed of (1) an amorphous material consisting substantially of Si, Ti and C and optionally of O, or (2) an aggregate consisting substantially of ultrafine crystalline particles of .beta.-SiC, TiC, a solid solution of .beta.-SiC and TiC and TiC.sub.1-x wherein 0<x<1 and having a particle diameter of not more than 500 A, in which amorphous SiO.sub.2 and TiO.sub.2 sometimes exist in the neighborhood of these ultrafine crystalline particles, or (3) a mixture of said amorphous material (1) and said aggregate (2) of ultrafine crystalline particles. The aforesaid continuous inorganic fibers can be produced by the following steps: a first step of preparing a semi-inorganic block copolymer comprising polycarbosilane blocks having a main chain skeleton composed mainly of carbosilane units of the formula --Si-CH.sub.Type: GrantFiled: May 26, 1982Date of Patent: August 16, 1983Assignee: UBE Industries, Ltd.Inventors: Seishi Yajima, Kiyohito Okamura, Yoshio Hasegawa, Takemi Yamamura
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Patent number: 4396721Abstract: Glass ceramic materials having controllable temperature coefficients of dielectric constant or capacitance (TCC) are provided. The ceramic component of the composition possesses paraelectric properties at least over the temperature range of -55.degree. C. to 125.degree. C. and can be controllably crystallized from the glassy matrix initially formed. Heat treatment of the glass produces crystallization of the ceramic component and results in glass ceramic materials with controlled TCC values which are useful as capacitors, resonators, microwave substrates, and the like because of their low dielectric loss characteristics and temperature stability.Type: GrantFiled: August 5, 1981Date of Patent: August 2, 1983Inventor: William N. Lawless
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Patent number: 4391915Abstract: Optical components can be pressed with such a precision that grinding and polishing of the formed components is not necessary, from glasses containing 45-55 wt. % P.sub.2 O.sub.5, 3.5-9 wt. % Al.sub.2 O.sub.3, 5-20 wt. % K.sub.2 O, 0-3 wt. % Li.sub.2 O, 8-15% BaO, 4.5-9 wt. % ZnO, 0-6 wt. % MgO, 0-18 wt. % PbO, 0-1 wt. % SiO.sub.2, 0-3 wt. % B.sub.2 O.sub.3, 0-2 wt. % TiO.sub.2.Type: GrantFiled: December 7, 1981Date of Patent: July 5, 1983Assignee: U.S. Philips CorporationInventors: Gertraud A. A. Meden-Piesslinger, Johannes H. P. Van de Heuvel
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Patent number: 4376835Abstract: A calcium aluminum fluorosilicate glass powder is disclosed which has average particle size of at least 0.5 microns, and is characterized in that the calcium in the surface of the powder's particles is depleted so that the quotient of the atomic ratio Si/Ca at the surface of the particles and the atomic ratio Si/Ca in the core region of the particles is at least 2.0, more preferably at least 3.0 and most preferably at least 4.0. The glass powder may be prepared by surface treating calcium aluminum fluorosilicate glass powder particles with an acid which forms calcium salts, washing the calcium salts off the treated particles and drying the washed particles.The glass powder has utility in self-hardening glass ionomer cements, such as dental or bone cements. Cements formed from the glass powder exhibit reduced periods of water sensitivity, while permitting sufficient time for processing.Type: GrantFiled: January 4, 1982Date of Patent: March 15, 1983Assignee: ESPE Fabrik Pharmazeutischer Praparate GmbHInventors: Werner Schmitt, Robert Purrmann, Peter Jochum, Oswald Gasser
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Patent number: 4376168Abstract: A strong and biocompatible sintered phosphate of calcium ceramics are obtained by sintering a powdery material substantially consisting of phosphate of calcium having a Ca/P ratio of 1.4-1.75, e.g. apatite group and/or tricalcium phosphate, and not exceeding 15% by weight of CaO-P.sub.2 O.sub.5 frit having a Ca/P ratio of 0.2-0.75. Y.sub.2 O.sub.3 incorporation therein improves the bending strength of the ceramics. Furthermore, a P.sub.2 O.sub.5 -metal oxide frit wherein metal oxide being one or more selected from BaO, CaO, MgO, ZnO, NaO and K.sub.2 O provides a more improved bending strength. The Y.sub.2 O.sub.3 incorporation herein still improves the strength of the sintered product.Type: GrantFiled: April 21, 1981Date of Patent: March 8, 1983Assignee: NGK Spark Plugs Co., Ltd.Inventors: Akio Takami, Kazuo Kondo
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Patent number: 4366251Abstract: Fiberizable glass compositions are disclosed. The fibers may be produced from sand, clay, limestone, dolomite or other suitable raw materials. The fibers can be used to make low density composites for ceiling tile or boards.Type: GrantFiled: June 15, 1981Date of Patent: December 28, 1982Assignee: Owens-Corning Fiberglas CorporationInventor: Charles F. Rapp
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Patent number: 4358543Abstract: A fluoride glass basically containing ingredients of a P-Si-Al-alkaline-earth metals-alkali metals-F system within specific content ranges has extremely high anomalous partial dispersion and low dispersion properties and is stable without tendency to devitrification.Type: GrantFiled: September 18, 1980Date of Patent: November 9, 1982Assignee: Kabushika Kaisha Ohara Kogaku Garasu SeizoshoInventor: Nobuhiro Nozawa
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Patent number: 4358541Abstract: The present invention is directed to the production of glass-ceramic coatings capable of being fired repeatedly to temperatures in excess of 950.degree. C. without thermal deformation and being especially suitable for application to titanium-stabilized stainless steels. The coatings are highly crystalline, substantially free from alkali metal oxides, and consist essentially, by weight, of:______________________________________ MgO 5-35 CaO 0-35 ZnO 0-25 CaO + ZnO 10-35 Al.sub.2 O.sub.3 0-10 B.sub.2 O.sub.3 0-25 P.sub.2 O.sub.5 0-10 B.sub.2 O.sub.3 + P.sub.2 O.sub.5 4-25 SiO.sub.Type: GrantFiled: November 23, 1981Date of Patent: November 9, 1982Assignee: Corning Glass WorksInventors: Ronald L. Andrus, Kenneth Chyung, Richard F. Reade, deceased, by Clara M. Reade, administratrix
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Patent number: 4337316Abstract: A process for producing feldspathic sanitary ware and the end product are disclosed in which a fluxing amount of a glass frit is used in the ceramic slip used to cast the sanitary ware. The frit contains both deflocculent oxides and flocculent alkaline earths which are leachable from the frit when it is placed in the ceramic slip. The deflocculent oxides counterbalance the effect of the flocculent alkaline earths to the extent they are respectively leached from the frit upon dispersal in a ceramic slip and maintain the slip at a workable viscosity. Upon casting and firing the slip, the present frit precipitates fine crystals of diopside having an average particle size of less than one micron which are particularly useful in lowering the firing temperature of feldspathic bodies by promoting the required degree of vitrification at lower temperatures than heretofore possible.Type: GrantFiled: September 19, 1980Date of Patent: June 29, 1982Assignee: Ferro CorporationInventor: Werner F. Votava
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Patent number: 4334908Abstract: A composition of matter for use as a vitreous fertilizer comprising a soluble vitreous constituent comprising the following ingredients: 35 to 55 moles %, P.sub.2 O.sub.5 ; less than 10 moles %, K.sub.2 O; and the balance to 100 moles %, CaO and/or MgO. The balance of the composition, if any, is constituted by optional additions of nutrient proportions of one or more micro-nutrients in plant assimilable form, and/or optional additions of one or more plant-inert filler materials. Such compositions have favorable nutrient release rates. The invention also encompasses compositions of matter adapted for use as a plant fertilizer which comprises soluble vitreous plant nutrient release material in expanded or cellular form, and to methods of plant cultivation using such compositions.Type: GrantFiled: September 28, 1979Date of Patent: June 15, 1982Assignee: BFG GlassgroupInventors: Jacques Duchateau, Christien Van den Bossche
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Patent number: 4333848Abstract: A phosphate laser glass in which the optical path length is substantially independent of temperature, or "athermal", particularly under rapid pulsing, and chemically stable, while providing high gain. The base glass composition comprises, in mole percent, 55 to 70% P.sub.2 O.sub.5, 3 to 15% of an alkali metal oxide, preferably Li.sub.2 O plus K.sub.2 O, 20 to 30% BaO and 0.5 to 5% Al.sub.2 O.sub.3. Up to 15% of the BaO may be replaced by CaO, SrO or MgO and part of the Al.sub.2 O.sub.3 may be replaced by Nd.sub.2 O.sub.3. The total Al.sub.2 O.sub.3 plus Nd.sub.2 O.sub.3 is 4 mole percent .+-.1.5%. The laser glass composition also includes a laseable component, preferably Nd.sub.2 O.sub.3 and preferably includes a solarization inhibitor.Type: GrantFiled: December 3, 1980Date of Patent: June 8, 1982Assignee: Kigre, Inc.Inventors: John D. Myers, Charles S. Vollers
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Patent number: 4323323Abstract: A cutting tool tip is formed at least at a cutting edge of the tip from a ceramic product consisting essentially of at least 75% by volume of a single phase compound having an expanded .beta.-phase silicon nitride lattice and having the general formula Si.sub.6-z Al.sub.z N.sub.8-z O.sub.z, where O<z.ltoreq.5, together with a second phase containing a metal from the list yttrium, lanthanum, cerium and scandium, or other rare earth metal.Type: GrantFiled: November 5, 1979Date of Patent: April 6, 1982Assignee: Lucas Industries LimitedInventors: Roland J. Lumby, Bernard North, Alfred J. Taylor, Roland M. Thomas
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Patent number: 4323652Abstract: Dielectric composition, screen printing paste having such a composition and products obtained.The invention describes a dielectric composition which may be used in particular as an insulating screen-printing paste, which is compatible with a copper-containing conductive screen-printed layer, the paste containing, dispersed in an organic vehicle, a mixture of ceramic phases, consisting essentially of zinc oxide and cobalt oxide, and a vitreous phase containing at least a glass which can be devitrified by dissolving the zinc oxide.Type: GrantFiled: March 14, 1980Date of Patent: April 6, 1982Assignee: U.S. Philips CorporationInventors: Hugues Baudry, Claude Morhaim, Dominique Bricout
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Patent number: 4315778Abstract: A flux composition for ceramic color, containing no harmful heavy metal such as lead, cadmium, chromium, etc. is provided.The flux composition consists mainly of 30 to 45% of SiO.sub.2, 0 to 5% of TiO.sub.2, 4 to 10% of ZrO.sub.2, 13 to 18% of B.sub.2 O.sub.3, 18 to 23% of ZnO, 0 to 3% of CaO, 12 to 15% of the total of two or three kinds of R.sub.2 O selected from Na.sub.2 O, K.sub.2 O and Li.sub.2 O, 4 to 10% of fluorine and 0 to 5% of tin oxide (% being all by weight).The composition uses no lead which has been indispensable for lower melting glasses, and exhibits superior performances difficult to afford according to conventional lower melting lead-free fluxes.Type: GrantFiled: April 7, 1980Date of Patent: February 16, 1982Inventors: Kimitoshi Ueno, Toshio Yoshida
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Patent number: 4314909Abstract: This invention is concerned with the production of glass-ceramics especially suitable for incorporating radioactive wastes. The inventive glass-ceramics contain at least two crystal phases selected from the group of pollucite, mullite, monazite, and, optionally, tetragonal or cubic zirconia as the predominant crystal phases and consist essentially, expressed in weight percent on the oxide basis, of 5-40% Cs.sub.2 O, 15-50% Al.sub.2 O.sub.3, 0-30% La.sub.2 O.sub.3 +CeO.sub.2, 0-20% P.sub.2 O.sub.5, 0-30% ZrO.sub.2, 12-65% La.sub.2 O.sub.3 +CeO.sub.2 +P.sub.2 O.sub.5, and 15-50% SiO.sub.2.Type: GrantFiled: June 30, 1980Date of Patent: February 9, 1982Assignee: Corning Glass WorksInventors: George H. Beall, Hermann L. Rittler
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Patent number: 4314031Abstract: Glass compositions in the tin-phosphorus-oxyfluoride composition system exhibiting very low glass transition temperatures and capable of being modified by the addition of selected constituents to exhibit excellent stability in a humid environment, are described.Type: GrantFiled: June 17, 1980Date of Patent: February 2, 1982Assignee: Corning Glass WorksInventors: Leon M. Sanford, Paul A. Tick
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Patent number: 4313900Abstract: A process for forming a glazed ceramic substrate, more particularly for forming a particular surface finish and/or surface pattern in the glass. The process consists of preparing a ceramic mixture which includes a basic oxide, such as Al.sub.2 O.sub.3, and a glass, forming the substrate as by molding, pressing, or doctor blading and lamination, and sintering in a non-reactive atmosphere on a setter tile that is non-wettable by the glass. During the sintering operation the glass becomes molten and flows downwardly under the influence of gravity through the ceramic particles. The glass flows to the setter plate to conform to its surface configuration, forming a glazed surface on the substrate.Type: GrantFiled: June 26, 1980Date of Patent: February 2, 1982Assignee: International Business Machines Corp.Inventors: Frank Gonzales, Jr., Joseph Sobon
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Patent number: RE32107Abstract: What is disclosed is a method of preparing carbon-containing monolithic glassy ceramics from organosilsesquioxanes, metal oxides and metal alkoxides through pyrolysis of their gels. Also disclosed are certain gel compositions used in the method and the glassy ceramics.Type: GrantFiled: December 17, 1984Date of Patent: April 8, 1986Assignee: Dow Corning CorporationInventor: James R. January