Less Than 40 Percent By Weight Silica Patents (Class 501/73)
  • Patent number: 4650923
    Abstract: In an article comprising a ceramic body fired at a comparatively low temperature and a circuit pattern attached to the body, the ceramic body is produced from a preselected composition comprising first powder of alumina and second powder of a vitreous material which comprises any one of MgO-Al.sub.2 O.sub.3 -SiO.sub.2, CaO-MgO-Al.sub.2 O.sub.3 -SiO.sub.2, CaO-Al.sub.2 O.sub.3 -SiO.sub.2 glass, CaO-Al.sub.2 O.sub.3 -SiO.sub.2 -B.sub.2 O.sub.3 glass, MgO-Al.sub.2 O.sub.3 -SiO.sub.2 -B.sub.2 O.sub.3 glass, and CaO-MgO-Al.sub.2 O.sub.3 SiO.sub.2 -B.sub.2 O.sub.3 glass. The ceramic body comprises coexistence of an alumina part, a noncrystallized part, and a crystallized part and exhibits an excellent moisture proof. The circuit pattern comprises an internal conductive pattern of Ag and an external conductive pattern of an alloy of Ag-Pd. A chromium component may be included in the internal and the external conductive patterns.
    Type: Grant
    Filed: May 31, 1985
    Date of Patent: March 17, 1987
    Assignee: Narumi China Corporation
    Inventors: Susumu Nishigaki, Junzo Fukuda, Masashi Fukaya, Shinsuke Yano
  • Patent number: 4626514
    Abstract: Dental materials using calcium phosphate glass-ceramics and having the color tone with high approximation to that of natural teeth. In those dental materials, calcium phosphate composite, nickel oxide and one or more other type of compounds selected from oxides of iron, manganese, cerium, titanium and tungsten, are contained as coloring component. Also, if necessary, Al.sub.2 O.sub.3 and/or SiO.sub.2 is contained as a color assisting agent in that composite. The calcium phosphate glass-ceramic according to this invention consists of the same components as that of natural teeth. Besides, it is possible to adjust the color tone delicately to match with the color tone of each individual`s teeth. Moreover, the coloring components are incorporated in crystals of calcium phosphate. Consequently, they cause no elution during use and are therefore ideal as dental material.
    Type: Grant
    Filed: March 27, 1986
    Date of Patent: December 2, 1986
    Assignee: Kyushu Refractories Co., Ltd.
    Inventors: Akira Watanabe, Yoshimitsu Takeuchi, Hiroyasu Tokuda, Seiji Kihara, Yasuhiro Makino, Keiji Kamegawa
  • Patent number: 4618590
    Abstract: The invention relates to the formulation of a starting mixture for an insulating composition, comprising a vitreous phase and several ceramic phases in the respective ratios by volume for the vitreous phase between 85 and 60% and for the ceramic phases between 15 and 40%, the vitreous phase being a silicate of zinc and alkaline earth.According to an embodiment of the invention the starting mixture is remarkable in that the vitreous phase is constituted by the molar ratios of the following oxides:30 to 55% of silicon (SiO.sub.2), 15 to 30% of zinc oxide (ZnO), 0 to 20% of boric anhydride (B.sub.2 O.sub.3), 0 to 10% of alumina (Al.sub.2 O.sub.3), 15 to 40% of barium oxide (BaO), and in that the ceramic phases are constituted by the ratios by volume of the following oxides: 0 to 10% of cobalt oxide (Co.sub.3 O.sub.4), 5 to 20% of zinc oxide (ZnO), and 10 to 25% of lead oxide (PbO.sub.2).Application: Manufacture of microcircuits on colaminated metallic substrates.
    Type: Grant
    Filed: May 3, 1985
    Date of Patent: October 21, 1986
    Assignee: U.S. Philips Corporation
    Inventor: Hugues Baudry
  • Patent number: 4617045
    Abstract: A process for making a homogeneous melt for producing mineral wool insulation. This insulating material is made from waste products namely, bottom ash, cement kiln dust, slag, and waste from mineral wool production. These materials, along with a binder, are homogenized into a mixture. Thereafter, the process includes briquetting the mixture into agglomerated pieces. The agglomerates are then melted in a cupola furnace and the molten agglomerate is discharged into a receiver. Hot combustion gases are then passed into the melt or molten agglomerate to chemically homogenize the melt and heat the melt to a preselected temperature. Thereafter, the melt is converted into fibers using conventional practices.
    Type: Grant
    Filed: April 5, 1985
    Date of Patent: October 14, 1986
    Inventor: Boris Bronshtein
  • Patent number: 4615989
    Abstract: An optical CuO-bearing, alkali- and alkaline-earth rich phosphate glass with relatively high elongation (at 20.degree.-300.degree. C. from 110.times.10.sup.-7 grd.sup.-1 to 138.times.10.sup.-7 grd.sup.-1) and a transformation range .ltoreq.380.degree. C., with substantially improved transmission in the UV to blue range of the spectrum (UV-transmission at .lambda.=350 nm between .gtoreq.69% and .gtoreq.83%) and a very strong absorption in the red region of the spectrum (IR-absorption at .lambda.=700 nm between .ltoreq.2% and .ltoreq.12%), consisting essentially of the following synthesis/composition, in wt. %: P.sub.2 O.sub.5 65-70%; SiO.sub.2 0-0.75%; B.sub.2 O.sub.3 0-2%; A.sub.2 O.sub.3 2.5-6%; R.sub.2 O (alkali metal oxides) 11-17%; BaO 3-9.5%; CeO.sub.2 0.45-2.0%; CuO 2.55-6.55%; Cl.sup.- 0.15-0.75%; F.sup.- 0.25-1.50%; refining agent 0.10-2.00% with .SIGMA.CeO.sub.2 +Al.sub.2 O.sub.3 +BaO+CuO.gtoreq.8.5 and .SIGMA.R.sub.2 O=F.sup.- +Cl.sup.- .gtoreq.21.
    Type: Grant
    Filed: April 17, 1985
    Date of Patent: October 7, 1986
    Assignee: Schott Glaswerke
    Inventor: Willy Ritze
  • Patent number: 4608352
    Abstract: The present invention relates to neutron-absorbent oxide or oxynitride glasses containing gadolinium and a process for their preparation.The glasses according to the invention, which incorporate silicon, aluminum, oxygen or oxygen and nitrogen, additionally contain gadolinium in a proportion of approximately 5 to 15 atom %.
    Type: Grant
    Filed: September 30, 1985
    Date of Patent: August 26, 1986
    Assignee: Centre National de la Recherche Scientifique (CNRS)
    Inventors: Yves Laurent, Patrick Verdier
  • Patent number: 4605443
    Abstract: This invention relates to the preparation of hydraulic cements consisting essentially of glasses having compositions within area ABCDEA of FIG. 1 which, when contacted with water, hydrate to form strong, low porosity cements having crystals composed predominantly of hydrogarnet solid solution and/or hydrogehlenite.
    Type: Grant
    Filed: January 28, 1985
    Date of Patent: August 12, 1986
    Assignee: Corning Glass Works
    Inventor: John F. MacDowell
  • Patent number: 4605415
    Abstract: Bioreactive materials, for use in forming implants or prostheses, obtained by fusion of a mixture of 20 to 50% by weight of SiO.sub.2, 15 to 25% by weight of CaO, 5 to 10% by weight of P.sub.2 O.sub.5, 15 to 25% by weight of Na.sub.2 O and 3 to 15% by weight of Al.sub.2 O.sub.3, or their metallic precursors yielding equivalent quantities of oxides by fusion.
    Type: Grant
    Filed: December 2, 1983
    Date of Patent: August 12, 1986
    Assignee: Region Wallonne, representee par l'Executif Regional Wallon
    Inventor: Raymond M. Richez
  • Patent number: 4575493
    Abstract: Compositions of metal oxides which may be melted and cooled to produce glasses are disclosed. The glasses may be heat treated to produce glass-ceramics. The glasses have good transmittances for electromagnetic radiation in the ultraviolet, infrared and visible spectra, while the glass-ceramics have good transmittances of infrared radiation. Other physical properties make these materials desirable for purposes such as radomes.
    Type: Grant
    Filed: March 16, 1982
    Date of Patent: March 11, 1986
    Assignee: General Electric Co.
    Inventor: Harry W. Rauch, Sr.
  • Patent number: 4567151
    Abstract: A thick film conductor composition comprising an admixture of finely divided particles of noble metal and inorganic binder dispersed in organic medium in which the inorganic binder consists essentially of a bismuth silicate glass and/or bismuth germanate glass, ZnO and optionally Bi.sub.2 O.sub.3.
    Type: Grant
    Filed: January 14, 1985
    Date of Patent: January 28, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Barry E. Taylor
  • Patent number: 4560666
    Abstract: A high strength glass-ceramic containing apatite and alkaline earth metal silicate (diopside/forsterite/akermanite) crystals having an excellent affinity for a living body and a process for producing the same are disclosed. The glass-ceramic is useful as an implant material such as an artificial dental root and an artificial bone.
    Type: Grant
    Filed: December 6, 1984
    Date of Patent: December 24, 1985
    Assignee: Hoya Corporation
    Inventors: Masahiro Yoshida, Kenji Nakagawa
  • Patent number: 4547467
    Abstract: A composition for a dielectric ink used in a screening process including a lead-free glass frit binder, silica, and a vehicle. The dielectric composition is particularly suited for use in gas plasma display panels.
    Type: Grant
    Filed: June 22, 1983
    Date of Patent: October 15, 1985
    Assignee: Burroughs Corporation
    Inventors: Edward G. Barth, Ruvim Braude, Nicholas W. Kay
  • Patent number: 4544974
    Abstract: There are described a glass composition and a magnetic head containing the same, wherein the glass composition comprises an oxide of an alkali metal or alkaline earth, and at least one non-alkali metal oxide in an amount sufficient to provide a coefficient of thermal expansion of 80-170.times.10.sup.-7 .degree. C..sup.-1, the composition featuring from 5-15 mole % Al.sub.2 O.sub.3 and an amount of a compatible glass former sufficient to insure the Al.sub.2 O.sub.3 is soluble in the composition.
    Type: Grant
    Filed: October 20, 1983
    Date of Patent: October 1, 1985
    Assignee: Eastman Kodak Company
    Inventors: Bradford D. West, Jr., Jean Berchtold
  • Patent number: 4544614
    Abstract: An ionically conductive glass is disclosed for use as electrolyte in a high temperature electrochemical cell, particularly a cell with sodium anode and sulfur cathode. The glass includes the constituents Na.sub.2 O, ZrO.sub.2, Al.sub.2 O.sub.3 and SiO.sub.2 in selected proportions to be a single phase solid solution substantially free of crystalline regions and undissolved constituents. Other advantageous properties are an ionic conductivity in excess of 2.times.10.sup.-3 (ohm-cm).sup.-1 at 300.degree. C. and a glass transition temperature in excess of 500.degree. C.
    Type: Grant
    Filed: January 8, 1985
    Date of Patent: October 1, 1985
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Gene H. Kucera, Michael F. Roche
  • Patent number: 4536452
    Abstract: This invention is related to the production of machinable glass-ceramic articles which are essentially free from crystals having a mica structure and consist essentially, in weight percent, ofSiO.sub.2 : 24-28Al.sub.2 O.sub.3 : 9-20MgO: 12-28SrO: 0-11BaO: 0-14CuO: 0-5Ag.sub.2 O: 0-3.5NiO: 0-1.5Cr.sub.2 O.sub.3 : 0.5-6.
    Type: Grant
    Filed: October 24, 1983
    Date of Patent: August 20, 1985
    Assignee: Corning Glass Works
    Inventors: John L. Stempin, Dale R. Wexell
  • Patent number: 4530909
    Abstract: A process for preparing aluminosilicate glass comprising from 30 to 60 molar % of SiO.sub.2, from 20 to 35 molar % of Al.sub.2 O.sub.3 and from 10 to 30 molar % of a total of rare earth oxides composed mainly of Y.sub.2 O.sub.3, wherein an yttrium concentrate is used as the rare earth oxides composed mainly of Y.sub.2 O.sub.3, and ZrO.sub.2 not in excess of 8 molar % to improve alkali resistance.
    Type: Grant
    Filed: October 19, 1984
    Date of Patent: July 23, 1985
    Assignee: National Institute for Researches in Inorganic Materials
    Inventors: Akio Makishima, Tatsuya Nagata, Takajiro Shimohira
  • Patent number: 4513070
    Abstract: Electrochemical devices use a vitreous material having a general formulaxAaR.sub.b --yNmRc--zN.sub.n Y.sub.pwherein A is Si, Ge, P, S, B, Nb, As, V, Cr or Mo; R is O, S or Se; N is Li, Na, K or Ag and Y is I, Br, Cl, F, ClO.sub.4, CF.sub.3, SO.sub.3, SCN or SO.sub.4 with the proviso that the material contain at least two salts NY. Such materials have increased cationic conductivity.
    Type: Grant
    Filed: February 8, 1983
    Date of Patent: April 23, 1985
    Assignee: Centre National de la Recherche Scientifique
    Inventors: Brigitte Carette, Ali Kone, Jean-Louis Souquet, Michel Ribes, Maurice Maurin
  • Patent number: 4511664
    Abstract: A mixture containing 35 to 65% by weight of Al.sub.2 O.sub.3, 30 to 60% by weight of SiO.sub.2, 1.5 to 4% by weight of Cr.sub.2 O.sub.3, and 0.01 to 0.1% by weight of carbon, the balance being unavoidable impurities, is melted, and amorphous fibers are formed from said molten material by blowing or spinning. The fibers are heated rapidly to a temperature of 950.degree. C. to 1,150.degree. C., held at that temperature for several to about a dozen minutes, and cooled rapidly to ordinary room temperature.
    Type: Grant
    Filed: June 4, 1984
    Date of Patent: April 16, 1985
    Assignee: Isolite Babcock Refractories Co., Ltd.
    Inventor: Masafumi Yamamoto
  • Patent number: 4508834
    Abstract: A spectacle glass which is colorless in the visible spectrum range, not transmissive in the ultraviolet spectrum range below 350 nm, has a refractive index n.sub.d higher than 1.56 and an Abbe number of more than 45, and which has an extremely low density, has the following composition (in % by weight):______________________________________ 12-40 P.sub.2 O.sub.5 13-34 Al.sub.2 O.sub.3 8-30 SiO.sub.2 0-16 B.sub.2 O.sub.3 4-12 TiO.sub.2 0-4 ZrO.sub.2 2-18 CaO 0-4 MgO 0-15 Na.sub.2 O 0-11 K.sub.2 O 0-6 Li.sub.2 O 0-12 Nb.sub.2 O.sub.5 0-8 ZnO.
    Type: Grant
    Filed: February 10, 1983
    Date of Patent: April 2, 1985
    Assignee: Schott Glaswerke
    Inventors: Georg Gliemeroth, Ludwig Ross, Burkhard Speit, Volkmar Geiler, Hans-Georg Krolla, Lothar Meckel
  • Patent number: 4495298
    Abstract: A thallium-containing optical glass composition which comprises the following oxides in the indicated proportions in mole %: SiO.sub.2 35-80, Tl.sub.2 O 1-30, Tl.sub.2 O+R.sub.2 O (R being an alkali metal) 1-35, ZnO 0-35, GeO.sub.2 0-30, BaO 0-25, TiO.sub.2 0-20, MgO 0-20, B.sub.2 O.sub.3 0-less than 10, ZrO.sub.2 0-2, Al.sub.2 O.sub.3 0-8, SnO 0-5, CaO 0-10, SrO 0-10, PbO 0-10, La.sub.2 O.sub.3 0-5, Bi.sub.2 O.sub.3 0-8, and Ta.sub.2 O.sub.5 0-2, and satisfies the following relations:5.ltoreq.ZnO+GeO.sub.2 +BaO+TiO.sub.2 +MgO+B.sub.2 O.sub.3 .ltoreq.40,0.1.ltoreq.ZrO.sub.2 +Al.sub.2 O.sub.3 +SnO.ltoreq.8,and0.ltoreq.CaO+SrO+PbO+La.sub.2 O.sub.3 +Bi.sub.2 O.sub.3 +Ta.sub.2 O.sub.5 .ltoreq.10.
    Type: Grant
    Filed: May 11, 1982
    Date of Patent: January 22, 1985
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Takasi Yamagishi, Yukio Noguchi
  • Patent number: 4484949
    Abstract: A water hardenable cement composition comprising a fluorine-free calcium alumino silicate glass in particulate form in which the individual particulates have a particle size of less than 100 microns consisting essentially of 25-35% silica, 27-35% calcium oxide, 25-40% alumina, up to 4% of an alkali metal oxide, up to 5% of titania, the total amount of alkali metal oxide and titania being 0.5-9%, wherein the ratio of calcium oxide to silica is 0.7:1 to 1:0-7, together with a polycarboxylic acid.
    Type: Grant
    Filed: June 28, 1982
    Date of Patent: November 27, 1984
    Assignee: Smith & Nephew Research Limited
    Inventors: William D. Potter, Andrew C. Barclay, Reginald Dunning, Richard J. Parry
  • Patent number: 4481299
    Abstract: An optical glass comprising, in % by weight21.0 to 35.0% SiO.sub.2 ;0 to 10.0% B.sub.2 O.sub.3 ;0 to 4.0% Al.sub.2 O.sub.3 ;0.5 to 4.0% Li.sub.2 O;33.0 to 55.0% BaO+SrO+CaO+MgO+ZnO, with the proviso of19.0 to 45.0% BaO,0 to 15.0% SrO,0 to 20.0% CaO,0 to 5.0% MgO, and1.5 to 20.0% ZnO;8.0 to 23.0% La.sub.2 O.sub.3 ;2.0 to 8.0% ZrO.sub.2 ;0 to 10.0% TiO.sub.2 ;0 to 4.5% Nb.sub.2 O.sub.5 +Ta.sub.2 O.sub.5 ;0 to 5.0% WO.sub.3 ; and0 to 5.0% PbO.
    Type: Grant
    Filed: April 23, 1984
    Date of Patent: November 6, 1984
    Assignee: Hoya Corporation
    Inventor: Hidemi Tajima
  • Patent number: 4477580
    Abstract: Optical components using a germania-silica glass are made by a gel technique. Tetra pentyloxygermane and a silicon alkoxide are hydrolyzed to form a gel, which is subsequently dried. Optical components, including optical fibers and devices, can be made using glass prepared by this technique.
    Type: Grant
    Filed: September 28, 1982
    Date of Patent: October 16, 1984
    Assignee: AT&T Bell Laboratories
    Inventor: James W. Fleming, Jr.
  • Patent number: 4472510
    Abstract: What is disclosed is a method of preparing carbon-containing monolithic glassy ceramics from organosilsesquioxanes, metal oxides and metal alkoxides through pyrolysis of their gels. Also disclosed are certain gel compositions used in the method and the glassy ceramics.
    Type: Grant
    Filed: December 23, 1982
    Date of Patent: September 18, 1984
    Assignee: Dow Corning Corporation
    Inventor: James R. January
  • Patent number: 4472030
    Abstract: A cesium-containing optical glass comprising, by weight, 32-56% of SiO.sub.2, 6-25% of K.sub.2 O, 6-32% of Cs.sub.2 O, 0-30% of BaO, 0-2.5% of MgO, 5-34% of ZnO, 0-3% of ZrO.sub.2 and 0-5% of SnO.sub.2, provided that the total proportion of BaO, MgO and ZnO is 8-40% and the total proportion of ZrO.sub.2 and SnO.sub.2 is 0.2-6%. When this cesium-containing optical glass is treated in a molten bath containing potassium nitrate, the cesium ion in the glass is easily exchanged with a potassium ion and therefore, the cesium ion concentration gradually decreases radially outwardly from the central axis and the potassium ion concentration gradually increases in that direction. Thus, there is obtained a light converge-type lens in which the refractive index gradually decreases in the same direction.
    Type: Grant
    Filed: November 4, 1983
    Date of Patent: September 18, 1984
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Masakiyo Tachibana, Yukio Noguchi, Noboru Akazawa
  • Patent number: 4465744
    Abstract: An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.
    Type: Grant
    Filed: November 30, 1982
    Date of Patent: August 14, 1984
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Sherman Susman, Kenneth J. Volin
  • Patent number: 4461840
    Abstract: The present invention concerns glass compositions capable of being attenuated in the form of fibers.These glass fibers comprise the following oxides in the percentages by weight: SiO.sub.2 :37 to 48%; Al.sub.2 O.sub.3 :17 to 25%; CaO:23 to 33%; MgO:0.1 to 7%; Fe.sub.2 O.sub.3 :0.1 to 3%; Na.sub.2 O:2 to 8%; K.sub.2 O:0.1 to 7%, the sum of the percentages of earthalkaline oxides (CaO and MgO) being less than or equal to 34%, and the sum of the alkaline oxides (Na.sub.2 O and K.sub.2 O) being greater than 5%.The invention is applicable to the manufacture of products subjected to elevated temperatures, for instance, products used for insulation purposes, even when such products may be subjected to a temperature as high as 700.degree. C.
    Type: Grant
    Filed: July 19, 1982
    Date of Patent: July 24, 1984
    Inventors: Jean-Jacques Massol, Daniel Sainte-Foi
  • Patent number: 4459510
    Abstract: The invention relates to lamps having a glass lamp vessel (1) and to a glass suitable therefor. The relevant glass is adequately resistant to attack by electrons, is resistant to atmospheric influences and is properly workable in a gas flame. This glass contains 44-60 mole % silicon oxide; 0-7.5 mole % boron oxide; 0-6 mole % zirconium oxide; 0-7.5 mole % aluminium oxide; 5-20 mole % calcium oxide; 12.5-25 mole % barium oxide; 0-15 mole % magnesium oxide; 0-10 mole % strontium oxide; 2-8 mole % sodium oxide. The sum of the alkaline earth metals is 25-42.5 mole %.No discoloration occurs in sodium vapor discharge lamps when the lamp vessel has been made of this glass.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: July 10, 1984
    Assignee: U.S. Philips Corporation
    Inventor: Hendrik J. M. Joormann
  • Patent number: 4455384
    Abstract: The chemical durability of alkali phosphate glasses is improved by incorporation of up to 23 weight percent of nitrogen. A typical phosphate glass contains: 10 to 60 mole % of Li.sub.2 O, Na.sub.2 O or K.sub.2 O; 5-40 mole % of BaO or CAO; 0-1 to 10 mole % of Al.sub.2 O.sub.3 ; and 40-70 mole % of P.sub.2 O.sub.5. Nitrides, such as AlN, are the favored additives.
    Type: Grant
    Filed: December 8, 1982
    Date of Patent: June 19, 1984
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Delbert E. Day, James A. Wilder, Jr.
  • Patent number: 4438212
    Abstract: The invention relates to calciumaluminosilicate glasses. The glasses contain, in weight percent, 25 to 35% silica, 27 to 35% calcium oxide, 25 to 40% alumina, 0 to 4% of alkali metal oxide selected from lithium oxide, sodium oxide and potassium oxide, and 0 to 5% of titanium oxide and a total content of lithium, sodium, potassium and titanium oxides of 0.5 to 9%. The glasses, in finely divided form, react with aqueous polycarboxylic acids and set to a solid mass; cements made from the glass and polycarboxylic acids are useful in splinting compositions.
    Type: Grant
    Filed: June 28, 1982
    Date of Patent: March 20, 1984
    Assignee: Pilkington Brothers P.L.C.
    Inventors: William D. Potter, Andrew C. Barclay, Reginald Dunning, Richard J. Parry
  • Patent number: 4427784
    Abstract: This specification discloses fluophosphate optical glass of low dispersion containing no beryllium and arsenic and having an optical constant nd=1.43-1.48 and .nu.d=85-97 and which can be produced stably and easily.
    Type: Grant
    Filed: July 6, 1981
    Date of Patent: January 24, 1984
    Assignee: Nippon Kogaku K.K.
    Inventors: Hiroshi Nakamura, Takeo Ichimura
  • Patent number: 4407786
    Abstract: A copper phosphate water soluble glass composition. The composition of the glass may be adjusted so as to release copper at a uniform preselected rate and to produce a desired pH in the resultant solution. In one application of the glass copper may be supplied to an animal from an implant formed from a cupric oxide/phosphorus pentoxide glass which also incorporates one or more glass modifying oxides such as alkali metal oxides and alumina, to control the glass solubility. Suitable glasses comprise 5-55 mole % cupric oxide + alkali metal oxides. 45-75 mole % phosphorus pentoxide, and not more than 15 mole % alumina, where the copper oxide concentration is not less than 5 mole %.
    Type: Grant
    Filed: April 9, 1981
    Date of Patent: October 4, 1983
    Assignee: International Standard Electric Corporation
    Inventors: Cyril F. Drake, Mary Tripp
  • Patent number: 4399232
    Abstract: Continuous inorganic fibers consisting substantially of Si, Ti and C and optionally of O, said fibers being composed of (1) an amorphous material consisting substantially of Si, Ti and C and optionally of O, or (2) an aggregate consisting substantially of ultrafine crystalline particles of .beta.-SiC, TiC, a solid solution of .beta.-SiC and TiC and TiC.sub.1-x wherein 0<x<1 and having a particle diameter of not more than 500 A, in which amorphous SiO.sub.2 and TiO.sub.2 sometimes exist in the neighborhood of these ultrafine crystalline particles, or (3) a mixture of said amorphous material (1) and said aggregate (2) of ultrafine crystalline particles. The aforesaid continuous inorganic fibers can be produced by the following steps: a first step of preparing a semi-inorganic block copolymer comprising polycarbosilane blocks having a main chain skeleton composed mainly of carbosilane units of the formula --Si-CH.sub.
    Type: Grant
    Filed: May 26, 1982
    Date of Patent: August 16, 1983
    Assignee: UBE Industries, Ltd.
    Inventors: Seishi Yajima, Kiyohito Okamura, Yoshio Hasegawa, Takemi Yamamura
  • Patent number: 4396721
    Abstract: Glass ceramic materials having controllable temperature coefficients of dielectric constant or capacitance (TCC) are provided. The ceramic component of the composition possesses paraelectric properties at least over the temperature range of -55.degree. C. to 125.degree. C. and can be controllably crystallized from the glassy matrix initially formed. Heat treatment of the glass produces crystallization of the ceramic component and results in glass ceramic materials with controlled TCC values which are useful as capacitors, resonators, microwave substrates, and the like because of their low dielectric loss characteristics and temperature stability.
    Type: Grant
    Filed: August 5, 1981
    Date of Patent: August 2, 1983
    Inventor: William N. Lawless
  • Patent number: 4391915
    Abstract: Optical components can be pressed with such a precision that grinding and polishing of the formed components is not necessary, from glasses containing 45-55 wt. % P.sub.2 O.sub.5, 3.5-9 wt. % Al.sub.2 O.sub.3, 5-20 wt. % K.sub.2 O, 0-3 wt. % Li.sub.2 O, 8-15% BaO, 4.5-9 wt. % ZnO, 0-6 wt. % MgO, 0-18 wt. % PbO, 0-1 wt. % SiO.sub.2, 0-3 wt. % B.sub.2 O.sub.3, 0-2 wt. % TiO.sub.2.
    Type: Grant
    Filed: December 7, 1981
    Date of Patent: July 5, 1983
    Assignee: U.S. Philips Corporation
    Inventors: Gertraud A. A. Meden-Piesslinger, Johannes H. P. Van de Heuvel
  • Patent number: 4376835
    Abstract: A calcium aluminum fluorosilicate glass powder is disclosed which has average particle size of at least 0.5 microns, and is characterized in that the calcium in the surface of the powder's particles is depleted so that the quotient of the atomic ratio Si/Ca at the surface of the particles and the atomic ratio Si/Ca in the core region of the particles is at least 2.0, more preferably at least 3.0 and most preferably at least 4.0. The glass powder may be prepared by surface treating calcium aluminum fluorosilicate glass powder particles with an acid which forms calcium salts, washing the calcium salts off the treated particles and drying the washed particles.The glass powder has utility in self-hardening glass ionomer cements, such as dental or bone cements. Cements formed from the glass powder exhibit reduced periods of water sensitivity, while permitting sufficient time for processing.
    Type: Grant
    Filed: January 4, 1982
    Date of Patent: March 15, 1983
    Assignee: ESPE Fabrik Pharmazeutischer Praparate GmbH
    Inventors: Werner Schmitt, Robert Purrmann, Peter Jochum, Oswald Gasser
  • Patent number: 4376168
    Abstract: A strong and biocompatible sintered phosphate of calcium ceramics are obtained by sintering a powdery material substantially consisting of phosphate of calcium having a Ca/P ratio of 1.4-1.75, e.g. apatite group and/or tricalcium phosphate, and not exceeding 15% by weight of CaO-P.sub.2 O.sub.5 frit having a Ca/P ratio of 0.2-0.75. Y.sub.2 O.sub.3 incorporation therein improves the bending strength of the ceramics. Furthermore, a P.sub.2 O.sub.5 -metal oxide frit wherein metal oxide being one or more selected from BaO, CaO, MgO, ZnO, NaO and K.sub.2 O provides a more improved bending strength. The Y.sub.2 O.sub.3 incorporation herein still improves the strength of the sintered product.
    Type: Grant
    Filed: April 21, 1981
    Date of Patent: March 8, 1983
    Assignee: NGK Spark Plugs Co., Ltd.
    Inventors: Akio Takami, Kazuo Kondo
  • Patent number: 4366251
    Abstract: Fiberizable glass compositions are disclosed. The fibers may be produced from sand, clay, limestone, dolomite or other suitable raw materials. The fibers can be used to make low density composites for ceiling tile or boards.
    Type: Grant
    Filed: June 15, 1981
    Date of Patent: December 28, 1982
    Assignee: Owens-Corning Fiberglas Corporation
    Inventor: Charles F. Rapp
  • Patent number: 4358543
    Abstract: A fluoride glass basically containing ingredients of a P-Si-Al-alkaline-earth metals-alkali metals-F system within specific content ranges has extremely high anomalous partial dispersion and low dispersion properties and is stable without tendency to devitrification.
    Type: Grant
    Filed: September 18, 1980
    Date of Patent: November 9, 1982
    Assignee: Kabushika Kaisha Ohara Kogaku Garasu Seizosho
    Inventor: Nobuhiro Nozawa
  • Patent number: 4358541
    Abstract: The present invention is directed to the production of glass-ceramic coatings capable of being fired repeatedly to temperatures in excess of 950.degree. C. without thermal deformation and being especially suitable for application to titanium-stabilized stainless steels. The coatings are highly crystalline, substantially free from alkali metal oxides, and consist essentially, by weight, of:______________________________________ MgO 5-35 CaO 0-35 ZnO 0-25 CaO + ZnO 10-35 Al.sub.2 O.sub.3 0-10 B.sub.2 O.sub.3 0-25 P.sub.2 O.sub.5 0-10 B.sub.2 O.sub.3 + P.sub.2 O.sub.5 4-25 SiO.sub.
    Type: Grant
    Filed: November 23, 1981
    Date of Patent: November 9, 1982
    Assignee: Corning Glass Works
    Inventors: Ronald L. Andrus, Kenneth Chyung, Richard F. Reade, deceased, by Clara M. Reade, administratrix
  • Patent number: 4337316
    Abstract: A process for producing feldspathic sanitary ware and the end product are disclosed in which a fluxing amount of a glass frit is used in the ceramic slip used to cast the sanitary ware. The frit contains both deflocculent oxides and flocculent alkaline earths which are leachable from the frit when it is placed in the ceramic slip. The deflocculent oxides counterbalance the effect of the flocculent alkaline earths to the extent they are respectively leached from the frit upon dispersal in a ceramic slip and maintain the slip at a workable viscosity. Upon casting and firing the slip, the present frit precipitates fine crystals of diopside having an average particle size of less than one micron which are particularly useful in lowering the firing temperature of feldspathic bodies by promoting the required degree of vitrification at lower temperatures than heretofore possible.
    Type: Grant
    Filed: September 19, 1980
    Date of Patent: June 29, 1982
    Assignee: Ferro Corporation
    Inventor: Werner F. Votava
  • Patent number: 4334908
    Abstract: A composition of matter for use as a vitreous fertilizer comprising a soluble vitreous constituent comprising the following ingredients: 35 to 55 moles %, P.sub.2 O.sub.5 ; less than 10 moles %, K.sub.2 O; and the balance to 100 moles %, CaO and/or MgO. The balance of the composition, if any, is constituted by optional additions of nutrient proportions of one or more micro-nutrients in plant assimilable form, and/or optional additions of one or more plant-inert filler materials. Such compositions have favorable nutrient release rates. The invention also encompasses compositions of matter adapted for use as a plant fertilizer which comprises soluble vitreous plant nutrient release material in expanded or cellular form, and to methods of plant cultivation using such compositions.
    Type: Grant
    Filed: September 28, 1979
    Date of Patent: June 15, 1982
    Assignee: BFG Glassgroup
    Inventors: Jacques Duchateau, Christien Van den Bossche
  • Patent number: 4333848
    Abstract: A phosphate laser glass in which the optical path length is substantially independent of temperature, or "athermal", particularly under rapid pulsing, and chemically stable, while providing high gain. The base glass composition comprises, in mole percent, 55 to 70% P.sub.2 O.sub.5, 3 to 15% of an alkali metal oxide, preferably Li.sub.2 O plus K.sub.2 O, 20 to 30% BaO and 0.5 to 5% Al.sub.2 O.sub.3. Up to 15% of the BaO may be replaced by CaO, SrO or MgO and part of the Al.sub.2 O.sub.3 may be replaced by Nd.sub.2 O.sub.3. The total Al.sub.2 O.sub.3 plus Nd.sub.2 O.sub.3 is 4 mole percent .+-.1.5%. The laser glass composition also includes a laseable component, preferably Nd.sub.2 O.sub.3 and preferably includes a solarization inhibitor.
    Type: Grant
    Filed: December 3, 1980
    Date of Patent: June 8, 1982
    Assignee: Kigre, Inc.
    Inventors: John D. Myers, Charles S. Vollers
  • Patent number: 4323323
    Abstract: A cutting tool tip is formed at least at a cutting edge of the tip from a ceramic product consisting essentially of at least 75% by volume of a single phase compound having an expanded .beta.-phase silicon nitride lattice and having the general formula Si.sub.6-z Al.sub.z N.sub.8-z O.sub.z, where O<z.ltoreq.5, together with a second phase containing a metal from the list yttrium, lanthanum, cerium and scandium, or other rare earth metal.
    Type: Grant
    Filed: November 5, 1979
    Date of Patent: April 6, 1982
    Assignee: Lucas Industries Limited
    Inventors: Roland J. Lumby, Bernard North, Alfred J. Taylor, Roland M. Thomas
  • Patent number: 4323652
    Abstract: Dielectric composition, screen printing paste having such a composition and products obtained.The invention describes a dielectric composition which may be used in particular as an insulating screen-printing paste, which is compatible with a copper-containing conductive screen-printed layer, the paste containing, dispersed in an organic vehicle, a mixture of ceramic phases, consisting essentially of zinc oxide and cobalt oxide, and a vitreous phase containing at least a glass which can be devitrified by dissolving the zinc oxide.
    Type: Grant
    Filed: March 14, 1980
    Date of Patent: April 6, 1982
    Assignee: U.S. Philips Corporation
    Inventors: Hugues Baudry, Claude Morhaim, Dominique Bricout
  • Patent number: 4315778
    Abstract: A flux composition for ceramic color, containing no harmful heavy metal such as lead, cadmium, chromium, etc. is provided.The flux composition consists mainly of 30 to 45% of SiO.sub.2, 0 to 5% of TiO.sub.2, 4 to 10% of ZrO.sub.2, 13 to 18% of B.sub.2 O.sub.3, 18 to 23% of ZnO, 0 to 3% of CaO, 12 to 15% of the total of two or three kinds of R.sub.2 O selected from Na.sub.2 O, K.sub.2 O and Li.sub.2 O, 4 to 10% of fluorine and 0 to 5% of tin oxide (% being all by weight).The composition uses no lead which has been indispensable for lower melting glasses, and exhibits superior performances difficult to afford according to conventional lower melting lead-free fluxes.
    Type: Grant
    Filed: April 7, 1980
    Date of Patent: February 16, 1982
    Inventors: Kimitoshi Ueno, Toshio Yoshida
  • Patent number: 4314909
    Abstract: This invention is concerned with the production of glass-ceramics especially suitable for incorporating radioactive wastes. The inventive glass-ceramics contain at least two crystal phases selected from the group of pollucite, mullite, monazite, and, optionally, tetragonal or cubic zirconia as the predominant crystal phases and consist essentially, expressed in weight percent on the oxide basis, of 5-40% Cs.sub.2 O, 15-50% Al.sub.2 O.sub.3, 0-30% La.sub.2 O.sub.3 +CeO.sub.2, 0-20% P.sub.2 O.sub.5, 0-30% ZrO.sub.2, 12-65% La.sub.2 O.sub.3 +CeO.sub.2 +P.sub.2 O.sub.5, and 15-50% SiO.sub.2.
    Type: Grant
    Filed: June 30, 1980
    Date of Patent: February 9, 1982
    Assignee: Corning Glass Works
    Inventors: George H. Beall, Hermann L. Rittler
  • Patent number: 4314031
    Abstract: Glass compositions in the tin-phosphorus-oxyfluoride composition system exhibiting very low glass transition temperatures and capable of being modified by the addition of selected constituents to exhibit excellent stability in a humid environment, are described.
    Type: Grant
    Filed: June 17, 1980
    Date of Patent: February 2, 1982
    Assignee: Corning Glass Works
    Inventors: Leon M. Sanford, Paul A. Tick
  • Patent number: 4313900
    Abstract: A process for forming a glazed ceramic substrate, more particularly for forming a particular surface finish and/or surface pattern in the glass. The process consists of preparing a ceramic mixture which includes a basic oxide, such as Al.sub.2 O.sub.3, and a glass, forming the substrate as by molding, pressing, or doctor blading and lamination, and sintering in a non-reactive atmosphere on a setter tile that is non-wettable by the glass. During the sintering operation the glass becomes molten and flows downwardly under the influence of gravity through the ceramic particles. The glass flows to the setter plate to conform to its surface configuration, forming a glazed surface on the substrate.
    Type: Grant
    Filed: June 26, 1980
    Date of Patent: February 2, 1982
    Assignee: International Business Machines Corp.
    Inventors: Frank Gonzales, Jr., Joseph Sobon
  • Patent number: RE32107
    Abstract: What is disclosed is a method of preparing carbon-containing monolithic glassy ceramics from organosilsesquioxanes, metal oxides and metal alkoxides through pyrolysis of their gels. Also disclosed are certain gel compositions used in the method and the glassy ceramics.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: April 8, 1986
    Assignee: Dow Corning Corporation
    Inventor: James R. January