Less Than 40 Percent By Weight Silica Patents (Class 501/73)
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Patent number: 6136459Abstract: A nonmagnetic substrate includes NiO, TiO.sub.2, ZnO, and CaO as major constituents, and major ilmenite and spinel structures, in which the percentage of the total area of the ilmenite and spinel crystalline domains occupied in the area of a given cross section of the nonmagnetic substrate is 20% or more. Preferably, the remainder of the area of the cross section, other than the ilmenite and spinel crystalline domain, contains a CaTiO.sub.3 phase and a TiO.sub.2 phase.Type: GrantFiled: November 16, 1998Date of Patent: October 24, 2000Assignee: Sony CorporationInventors: Yukari Nihei, Takashi Tamura
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Patent number: 6132643Abstract: This invention relates to fluorescent photosensitive vitroceramics and the process for the production thereof. The fluorescent photosensitive vitroceramics according to the present invention employ fluorosilicate glass compositions including various photosensitizing metals and rare earths which impart photosensitive properties and fluorescent properties to the vitroceramic. After irradiation, the photosensitive agents control the precipitation of fine fluoride crystals which also contain rare earth ions. These rare earth ions can be made to fluoresce in a controlled manner. The inventive fluorescent photosensitive vitroceramics can be used in photographic applications, florescent displays and computer memories.Type: GrantFiled: July 27, 1998Date of Patent: October 17, 2000Inventor: Eugen Pavel
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Patent number: 6117804Abstract: A process of making a mineral powder usable for manufacturing functional fiber includes pulverizing mineral ingredients including germanium of 60 weight percent, biostrome of 20 weight percent, jade of 10 weight percent, anorthite of 5 weight percent and minerals of 5 weight percent to about 100 mesh and charging the mineral ingredients into an internal furnace of copper having a wall thickness of 2-5 mm; placing feldspar pulverized to about 325 mesh between an inner surface of an electric heating plate and an outer surface of the internal furnace; heating the mineral ingredients and feldspar for seven days at about 1000.degree. C. by means of the electric heating plate; pulverizing the mineral ingredients having had thermal deformation from the internal furnace again to more than about 325 mesh; placing the pulverized mineral ingredients into the internal furnace again; charging the internal furnace with the burnt feldspar; again heating the mineral ingredients for three days at 1000.degree. C.Type: GrantFiled: April 29, 1997Date of Patent: September 12, 2000Assignee: Han IL Mulsan Co., Ltd.Inventor: Eung-Hwa Cho
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Patent number: 6107229Abstract: The invention relates to an aluminofluorosilicate glass for use in a material for dental restoration, which has the following features:a) a ratio of Al (calculated as Al.sub.2 O.sub.3) to Si (calculated as SiO.sub.2) of 0.57-1.12 by mass;b) a total content of Mg (calculated as MgO) and Ba (calculated as BaO) of 29-36% by mass;c) a ratio of Mg (calculated as MgO) to Ba (calculated as BaO) of 0.028-0.32 by mass;d) a content of P (calculated as P.sub.2 O.sub.5) of 2-10% by mass.The glass according to the invention has a high radiopacity, and the refractive index n.sub.D for visible light can be adjusted by varying the phosphorus content.Type: GrantFiled: June 19, 1998Date of Patent: August 22, 2000Assignee: Ernst Muhlbauer KGInventors: Rainer Luck, Dieter Reif, Barbara Leuner
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Patent number: 6077799Abstract: These glasses incorporate a combination of F and Al.sub.2 O.sub.3 to achieve even wider fluorescence and improved gain flatness. In addition, SPCVD incorporates large amounts of N into low-loss fiber whose high charge has an impact on rare earth behavior. The Surface Plasma Chemical Vapor Deposition (SPCVD) produces fiber preforms with high levels of F, Al.sub.2 O.sub.3, and N. These heavily fluorinated glasses provide much broader Er.sup.3+ emission than Type I or Type II silica for enhanced multichannel amplifiers. SPCVD successfully fluorinates silica with losses below 5 dB/km and increased Er.sup.3+ emission width.Type: GrantFiled: March 12, 1999Date of Patent: June 20, 2000Assignee: Corning Inc.Inventors: Matthew J. Dejneka, Rostislav Khrapko
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Patent number: 6071839Abstract: These color television (CTV) panel tint glasses involve using base CTV panel glass compositions with enhanced levels of Ni and Co colorants. The approach uses non-lead CTV panel glass compositions with high levels of Ni and Co oxide as colorant glasses for tinting clear CTV non-lead panel glass. Nickel oxide was varied from 2 to 18%, while cobalt oxide was varied from 0.2 to 2%. A preferred range of compositions with cobalt oxide levels below 1% and nickel oxide levels below 10% was found to be very acceptable for CTV panel colorants.Type: GrantFiled: August 26, 1999Date of Patent: June 6, 2000Assignee: Corning Inc.Inventors: David C. Boyd, David A. Tammaro
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Patent number: 6043170Abstract: Mineral fiber composition which is decomposable in the physiological medium, characterized by the following constituents in weight percent: SiO.sub.2 30 to less than 51; Al.sub.2 O.sub.3 higher than 11.5, in particular higher than 13,up to 25; CaO 2 to less than 23; MgO 0 to 15; Na.sub.2 O+K.sub.2 O higher than 10, up to 19; TiO.sub.2 +Fe.sub.2 O.sub.3 6 to 18; various 0 to 3.Type: GrantFiled: October 6, 1997Date of Patent: March 28, 2000Assignee: Isover Saint-GobainInventors: Bernd Steinkopf, Wolfgang Holstein, Axel Katzschmann, Peter Lohe
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Patent number: 5998036Abstract: The present invention relates to dielectric materials which may be used in the manufacture of, e.g., low profile heaters. Such dielectric materials comprise at least about 50% of a glass composition having about 35-50% SiO.sub.2, about 30-40% of an alkaline earth metal oxide selected from the group consisting of CaO, MgO, and SrO, about 13--22% Al.sub.2 O.sub.3, and about 0-10% B.sub.2 O.sub.3, the percentages being weight percentages based on the weight of the total glass composition. Certain dielectric compositions of the disclosure have a linear thermal expansion coefficient in the range of about 6.0 to 9.0 ppm/.degree. C.Type: GrantFiled: February 9, 1998Date of Patent: December 7, 1999Inventors: Sidney J. Stein, Richard L. Wahlers, Paul W. Bless, Charles Barclay, Richard B. Tait
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Patent number: 5969861Abstract: A polarizing optical system comprising: at least, polarizing characteristic imparting means for imparting a polarizing characteristic to light emitted from a light source; analyzer means for converting the polarizing characteristic into light intensity information; and output means for outputting the light intensity information; at least one element constituting the polarizing characteristic imparting means comprising an optical glass having a photoelastic constant C in the range of substantially zero with respect to a wavelength range of 0.4 .mu.m to 3.0 .mu.m. The optical glass has a photoelastic constant C in the range of -0.8 to +0.8 (10.sup.-8 cm.sup.2 /N) with respect to a wavelength range of 0.4 .mu.m to 3.0 .mu.m, and has the following composition when represented in terms of wt.% of oxides:SiO.sub.2 : 17.0-27.0% (35.5-57.0 mol %)Li.sub.2 O+Na.sub.2 O+K.sub.2 O: 0.5-5.0% (0.7-20.0 mol %)PbO: 72.0-75.0% (39.1-45.0 mol %)As.sub.2 O.sub.3 +Sb.sub.2 O.sub.3 : 0-3.0% (0.0-2.Type: GrantFiled: August 1, 1996Date of Patent: October 19, 1999Assignee: Nikon CorporationInventors: Motoi Ueda, Takeshi Hasegawa, Mikio Okamoto
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Patent number: 5961883Abstract: A glass material is provided which is capable of exhibiting fluorescence in the visible region by ultraviolet ray excitation. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %):______________________________________ SiO.sub.2 2 to 60%, B.sub.2 O.sub.3 5 to 70% (SiO.sub.2 + B.sub.2 O.sub.3 = 50 to 70%) RO 5 to 30% (R: at least one atom selected from Mg, Ca, Sr and Ba) ZnO 0 to 15% ZrO.sub.2 0 to 10%, Tb.sub.2 O.sub.3 or Eu.sub.2 O.sub.3 2 to 15% (containing either of Tb.sub.2 O.sub.3 or Eu.sub.2 O.sub.3) Ln.sub.2 O.sub.3 0 to 20% (Ln: at least one atom selected from Y, La, Gd, Yb, Lu, Sm, Dy and Tm) CeO.sub.2 0 to 1% Bi.sub.2 O.sub.3 0 to 2% Sb.sub.2 O.sub.3 0.01 to 0.5% and R'.sub.Type: GrantFiled: December 11, 1997Date of Patent: October 5, 1999Assignee: Sumita Optical Glass, Inc.Inventors: Masaaki Yamazaki, Masaaki Otsuka, Hideaki Takaku, Naruhito Sawanobori
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Patent number: 5958807Abstract: High magnesium-content magnesium aluminosilicate glasses are used to form green tape compositions that are fired stepwise, i.e., first to about 500.degree. C. to remove organic materials, then to a temperature 10-30.degree. C. above the glass transition temperature for a time sufficient to nucleate the glass, and finally to a higher temperature near but below the softening temperature to complete crystallization of the glass. The resultant glass-ceramic may include substantial amounts of the forsterite crystalline phase. Multilayer ceramic printed circuit boards are made that are useful for high frequency, microwave applications. The fired high magnesium oxide content glasses have low dielectric constant and low dissipation loss factors, and they have a thermal coefficient of expansion that is compatible with metal or ceramic support substrates that impart mechanical strength to the printed circuit boards and that are thermally conductive. The boards are compatible with gallium arsenide devices.Type: GrantFiled: July 1, 1997Date of Patent: September 28, 1999Assignee: Sarnoff CorporationInventors: Ananda Hosakere Kumar, Barry Jay Thaler, Ashok Narayan Prabhu, Ellen Schwartz Tormey
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Patent number: 5955388Abstract: A transparent class ceramic composition includes an oxide component, a rare earth component, a halide component, and a substantially pure rare earth-halide (e.g., REF.sub.3) crystal component. A method for making a transparent oxyfluoride glass includes preparing an oxyfluoride glass containing rare earth ions by a conventional melting method and subjecting the glass to a heat treatment thereby precipitating fluoride fine crystals containing a large amount of rare earth ions.Type: GrantFiled: October 2, 1997Date of Patent: September 21, 1999Assignee: Corning IncorporatedInventor: Matthew John Dejneka
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Patent number: 5948536Abstract: A glass composition for a substrate with a built-in lead-dielectric material, containing up to 35 mol % calculated as Al.sub.2 O.sub.3 of aluminum oxide, 20 to 60 mol % calculated as CaO of calcium oxide, and 8 to 40 mol % calculated as SiO.sub.2 of silicon oxide.Type: GrantFiled: May 5, 1997Date of Patent: September 7, 1999Assignee: TDK CorporationInventors: Yasuyoshi Suzuki, Hiroshi Tsuyuki
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Patent number: 5935483Abstract: The present invention relates to multi-purpose mineral powder emitting the large quantities of far infrared rays, negative ion and oxygen heat having ingredients of germanium of 20 weight percent, clinochlore of 10 weight percent, jade of 10 weight percent, zeolite of 10 weight percent and halite of 50 weight percent, and its process, in which the above five ingredients are pulverized to about 300 mesh; are placed into an inner surface having silver leaf (Ag) of an internal furnace made of chondrodite; are heated through a heating plate for nine days at about 1000.degree. C. so as to have thermal deformation after placing chondrodite pulverized to about 200 mesh between the inner surface of the electric heating plate and the outer surface of the internal furnace; and are then pulverized to about 325 mesh.Type: GrantFiled: April 29, 1997Date of Patent: August 10, 1999Assignee: Yong-Mi KimInventor: Byung-Suk Kong
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Patent number: 5935886Abstract: Man-made vitreous fibres has a solubility at pH 4.5 of at least 20 nm per day and a melt viscosity of 10-70 poise at 1,400.degree. C. and are formed from a composition which includes 18 to 30% by weight Al.sub.2 O.sub.3.Type: GrantFiled: May 8, 1997Date of Patent: August 10, 1999Assignee: Rockwool International A/SInventors: Soren Lund Jensen, Vermund Rust Christensen, Marianne Guldberg
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Patent number: 5932500Abstract: Man-made vitreous fibres have a solubility at pH 4.5 of at least 20 nm per day and a melt viscosity of 10-70 poise at 1,400.degree. C. A composition which will provide these properties is selected for their manufacture and contains at least 10% by weight Al.sub.2 O.sub.3. Novel fibres contain at least 6% by weight Na.sub.2 O +K.sub.2 O.Type: GrantFiled: May 8, 1997Date of Patent: August 3, 1999Assignee: Rockwool International A/SInventors: Soren Lund Jensen, Vermund Rust Christensen, Marianne Guldberg
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Patent number: 5914356Abstract: Novel fillers comprising combeite glass-ceramic are provided, along with filled polymerizable resin composites. Further provided are methods for making the combeite crystallite-containing novel fillers for use in hardenable, biocompatible bone restorations. Hard, shaped bodies or orthopaedic, dental and other uses are also provided.Type: GrantFiled: June 5, 1998Date of Patent: June 22, 1999Assignee: Orthovita, Inc.Inventor: Erik M. Erbe
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Patent number: 5910459Abstract: The glass-ceramic material of the present invention has the hexagonal sheet structure of hexacelsian as its primary crystal phase and exhibits x-ray diffraction patterns indicative of hexacelsian, said glass-ceramic material has a stabilized thermal expansion and an overall weight percent composition comprising: 35-55% SiO.sub.2, 5-25% Al.sub.2 O.sub.3, 5-25% MgO, 5-35% BaO, 6-14% TiO.sub.2, 0-10% ZnO, and 0-8% ZrO.sub.2.Type: GrantFiled: October 28, 1996Date of Patent: June 8, 1999Assignee: Corning IncorporatedInventors: George H. Beall, Hans J. Holland, Jeffrey T. Kohli
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Patent number: 5880045Abstract: Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole %.iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.Type: GrantFiled: July 27, 1998Date of Patent: March 9, 1999Assignee: Brookhaven Science AssociatesInventors: Hui Cao, Jay W. Adams, Paul D. Kalb
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Patent number: 5854152Abstract: Glasses for use as substrates for flat panel displays, having a composition consisting essentially of, as calculated in weight percent on an oxide basis, 38-56 SiO.sub.2, 10-28 Al.sub.2 O.sub.3, 0-4 Li.sub.2 O, 0-6 Na.sub.2 O, 0-15 K.sub.2 O, 4-18 CaO, 0-5 MgO, more than 8 and less than or equal to about 24 SrO, 0-2 ZrO.sub.2, said glass further consisting essentially of Na.sub.2 O+K.sub.2 O in total between about 6 and 18 weight percent.Type: GrantFiled: December 10, 1997Date of Patent: December 29, 1998Assignee: Corning IncorporatedInventors: Jeffrey T. Kohli, Pascale Laborde
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Patent number: 5837628Abstract: This patent discloses the composition of germanate glass and a new method for its fabrication. The composition comprises germanate, the oxide of an alkali earth group, Al.sub.2 O.sub.3, ZnO, a halides compound eg. CaF.sub.2, CaCl.sub.2 and so on,, and can combine with a series of oxygenous compounds such as silicate, borate, phosphate, arsenate, tellurate and so on, if required. The addition of an alkali oxide could increase the glass formation rate and homogeneity, and the defects of devitrification, cord, knot, and blister are reduced. Its fabricated methods which consist of the reduction pressure melting with the addition of a halide and the drying procedure. The germanate glass body that is made is colorless and transparent and it can increase the transmittance of infrared from 20% to greater than 60% in the wave length 2.75-3.0 .mu.m. The price of producing the germanate glass is decreased and the transmittance of this composition system increased from 5% to 80%.Type: GrantFiled: February 20, 1996Date of Patent: November 17, 1998Assignee: National Science CouncilInventors: Jenn-Shing Wang, Moo Chin Wang, Min-Hsiung Hon
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Patent number: 5815625Abstract: The object of the present invention is to provide an absorber glass for FOP having a broad absorption band which extends from ultraviolet region through visible region to near infrared region. The absorber glass of the present invention contains 18 to 40% by weight of SiO.sub.2 and not smaller than 20% by weight of FeO and Fe.sub.2 O.sub.3 in total.Type: GrantFiled: May 23, 1997Date of Patent: September 29, 1998Assignee: Hamamatsu Photonics K.K.Inventor: Takeo Sugawara
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Patent number: 5702995Abstract: There are provided glass-ceramics having a high lithium ion conductivity which include in mol %______________________________________ P.sub.2 O.sub.5 38-40% TiO.sub.2 25-45% M.sub.2 O.sub.3 (where M is Al or Ga) 5-15% Li.sub.2 O 10-20% ______________________________________and contain Li.sub.1+X (Al, Ga).sub.X Ti.sub.2-X (PO.sub.4).sub.3 (where X is 0 to 0.8) as a main crystal phases. There are also provided glass-ceramics having a high lithium ion conductivity which include in mol % ______________________________________ P.sub.2 O.sub.5 26-40% SiO.sub.2 0.5-12% TiO.sub.2 30-45% M.sub.2 O.sub.3 (where M is Al or Ga) 5-10% Li.sub.2 O 10-18% ______________________________________and contain Li.sub.1+X+Y M.sub.X Ti.sub.2-X Si.sub.Y P.sub.3-Y O.sub.12 (where 0<X.ltoreq.0.4 and 0<Y.ltoreq.0.6) as a main crystal phase.Type: GrantFiled: October 31, 1996Date of Patent: December 30, 1997Assignee: Kabushiki Kaisha OharaInventor: Jie Fu
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Patent number: 5696039Abstract: The object of the present invention is to provide an absorber glass for FOP having a broad absorption band which extends from ultraviolet region through visible region to near infrared region. The absorber glass of the present invention contains FeO, 18 to 40% by weight of SiO.sub.2 and not less than 20% by weight of FeO and Fe.sub.2 O.sub.3 in total.Type: GrantFiled: July 3, 1996Date of Patent: December 9, 1997Assignee: Hamamatsu Photonics K.K.Inventor: Takeo Sugawara
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Patent number: 5668066Abstract: A near infrared absorption filter glass containing______________________________________ P.sub.2 O.sub.5 35.about.50% Li.sub.2 O 0.about.5% Na.sub.2 O 0.about.12% K.sub.2 O 0.about.20% Cs.sub.2 O 0.about.20% R.sub.2 O (in which R is an alkali metal) 1.5.about.20% ZnO 17.about.48% MgO 0.about.7% CaO 0.about.7% SrO 0.about.7% BaO 0.about.12% R'O (in which R' is an alkaline earth metal) 0.about.15% CuO 0.2.about.12% ______________________________________ in which % stands for % by weighthas excellent transmittance characteristics in the ultraviolet region over conventional phosphate-based glass, has glass stability and processability which enable the mass production, and further has sufficient weatherability.Type: GrantFiled: July 24, 1996Date of Patent: September 16, 1997Assignee: Hoya CorporationInventors: Hironori Oguma, Kazuo Tachiwana
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Patent number: 5607886Abstract: An optical glass having optical constants of a refractive index (Nd) from 1.50 to 1.60 and an Abbe number (.nu.d) ranging from 62 to 73, a transformation temperature (Tg) of 550.degree. C. or below, and barely cracks or sticks to metal molds when the glass is subjected to mold pressing, maintains excellent chemical durability, and having softening capability at a low temperature which can be obtained by restricting the composition of the glass in weight percents within a specific range of a SiO.sub.2 --Al.sub.2 O.sub.3 --P.sub.2 O.sub.5 --R.sub.2 O system.Type: GrantFiled: October 6, 1995Date of Patent: March 4, 1997Assignee: Kabushiki Kaisya OharaInventor: Masahiro Onozawa
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Patent number: 5525554Abstract: This invention is directed to the production of glasses essentially free of Nb.sub.2 O.sub.5, and having refractive index close to 1.7, an Abbe number of about 35 and a density close to 3.2. The glasses consist essentially in weight percent on the oxide basis, of______________________________________ SiO.sub.2 38-45 TiO.sub.2 15-<20 ZrO.sub.2 6-10 La.sub.2 O.sub.3 0.5-4 BaO 12-19 CaO 3-8 BaO + CaO + SrO 17-25 Na.sub.2 O 2-6 K.sub.2 O 4-8 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 6-10.Type: GrantFiled: June 7, 1995Date of Patent: June 11, 1996Assignee: Corning France, S.A.Inventor: Marie J. M. Comte
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Patent number: 5491118Abstract: The invention is directed to a lead-free and cadmium-free thick film paste composition suitable for forming resistor or thermistor patterns on a substrate.Type: GrantFiled: December 20, 1994Date of Patent: February 13, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: Jacob Hormadaly
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Patent number: 5476821Abstract: This invention is directed at glass-ceramic articles, and methods for producing such articles, exhibiting Young's modulus between about 14 to 24.times.10.sup.6 psi and a fracture toughness in excess of 1.0 MPa.sqroot. in. The crystal phase assemblage is comprised predominately of generally uniformly-sized spinel-type crystals which are uniformly dispersed within a highly siliceous residual glass matrix phase. The composition of these glass-ceramic articles is consists essentially, expressed in terms of weight percent on the oxide basis, of 35-60% SiO.sub.2, 20-35% Al.sub.2 O.sub.3, 0-25% MgO, 0-25% ZnO, at least about 10% MgO+ZnO, 0-20% TiO.sub.2, 0-10% ZrO.sub.2, 0-2% Li.sub.2 O and 0-8% NiO. However, if the Al.sub.2 O.sub.3 constituent is present in an amount less than about 25%, the TiO.sub.2 +ZrO.sub.2 +NiO amount should be at least 5%. The composition may also contain up to 5% of optional constituents selected from the group consisting of BaO, CaO, PbO, SrO, P.sub.2 O.sub.5, B.sub.2 O.sub.3, Ga.sub.2 O.Type: GrantFiled: November 1, 1994Date of Patent: December 19, 1995Assignee: Corning IncorporatedInventors: George H. Beall, Linda R. Pinckney
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Patent number: 5439852Abstract: The invention is directed to a thick film paste composition comprising electrically conductive particles and finely divided particles of a glass composition comprising by mole % 5-70% Bi.sub.2 O.sub.3, 18-35% SiO.sub.2, 0.1-40% CuO, 0.5-25% ZnO, 0.5-40% CoO, 0.5-40% Fe.sub.2 O.sub.3, and 0.5-40% MnO, which the glass composition is free of lead and cadmium, all dispersed in an organic medium.Type: GrantFiled: August 1, 1994Date of Patent: August 8, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Jacob Hormadaly
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Patent number: 5422319Abstract: Novel oxide coatings which can be conveniently applied to reinforcing fibers such as silicon carbide fibers, and which when introduced as a fiber coating into fiber reinforced ceramic matrix composites provide composites exhibiting improved resistance to embrittlement at high temperatures, are described. Oxides effective to provide the improved composites in accordance with the invention include CeO.sub.2 and ZrO.sub.2.Type: GrantFiled: September 9, 1988Date of Patent: June 6, 1995Assignee: Corning IncorporatedInventors: John L. Stempin, Dale R. Wexell
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Patent number: 5397750Abstract: An aluminum article having a mirror-like surface and an improved working tool and method for fabricating the article from an aluminum blank, the tool comprising a mechanically strong, abrasion-resistant body against which the aluminum blank is forced under pressure, the tool body comprising a whisker-reinforced, crystalline body consisting essentially of about 5-35 weight % of SiC whiskers and 65-95 weight % of a crystalline matrix. The predominant crystal phase in the crystalline matrix may be a CaO--Al.sub.2 O.sub.3 --SiO.sub.2 crystal phase.Type: GrantFiled: April 29, 1994Date of Patent: March 14, 1995Assignee: Corning IncorporatedInventor: Kishor P. Gadkaree
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Patent number: 5393558Abstract: The present invention provides a method of adherently depositing a thick film composition on an aluminum nitride substrate comprising the steps of providing an aluminum nitride substrate, providing a thick film composition, and applying the thick film composition on the aluminum nitride substrate. The thick film composition includes a glass frit binder, a conductive metallic material and a lithium-containing adhesion promoting compound.Type: GrantFiled: June 7, 1993Date of Patent: February 28, 1995Assignee: Ferro CorporationInventors: Kevin W. Allison, Dana L. Hankey, Edward Stadnicar, Jr., Gordon J. Roberts
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Patent number: 5391320Abstract: This invention relates to terbium activated silicate luminescent glasses exhibiting reduced afterglow and enhanced luminescence due to incorporation therein of selected rare earth oxides of cerium, europium and gadolinium.Type: GrantFiled: June 24, 1991Date of Patent: February 21, 1995Assignee: Lockheed Missiles & Space Company, Inc.Inventors: Robert A. Buchanan, Clifford Bueno
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Patent number: 5378662Abstract: A glass comprising 10-40 mol % as Ln.sub.2 O.sub.3 of a lanthanide oxide wherein Ln is a lanthanide element, 30-60 mol % as SiO.sub.2, B.sub.2 O.sub.3 and GeO.sub.2 in total of silicon dioxide, boron oxide and/or germanium oxide, and 16-40 mol % as Al.sub.2 O.sub.3 of aluminum oxide has high Tg, a low average coefficient of linear expansion and a high dielectric constant. A dielectric composition containing the glass and a dielectric material is useful in the fabrication of multilayer wiring substrates and multilayer ceramic capacitors.Type: GrantFiled: June 30, 1993Date of Patent: January 3, 1995Assignee: TDK CorporationInventor: Hiroshi Tsuyuki
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Patent number: 5378408Abstract: A screen-printable thick film paste composition suitable for forming conductive patterns on a rigid substrate comprising:(a) finely divided particles of a lead-free glass composition having a softening point log (eta)=7.6 poise from 400.degree. C.-650.degree. C., a log (eta.) specific viscosity in a range from 2 at 500.degree. C. to 5 at 700.degree. C. and consisting essentially of, by weight 65-95% Bi.sub.2 O.sub.3, 2-15% SiO.sub.2, 0.1-9% B.sub.2 O.sub.3, 0-5% Al.sub.2 O.sub.3, 0-5% CaO, and 0-20% ZnO; and(b) electrically conductive particles; andall of (a) and (b) being dispersed in (c) an organic medium.Type: GrantFiled: July 29, 1993Date of Patent: January 3, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Alan F. Carroll, Kenneth W. Hang
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Patent number: 5346870Abstract: An aluminum titanate ceramic has as main crystalline phases, a crystalline phase of aluminum titanate and a solid solution thereof, a crystalline phase of mullite and a crystalline phase of rare earth titanate represented by RE.sub.2 Ti.sub.2 O.sub.7 (RE represents Y, Yb, Er, Dy, Ho, Tm or Lu). The aluminum titanate ceramic is superior in casting property and has high heat cycle durability.Type: GrantFiled: August 21, 1992Date of Patent: September 13, 1994Assignee: NGK Insulators, Ltd.Inventors: Yasushi Noguchi, Shinichi Miwa, Kaname Fukao
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Patent number: 5336644Abstract: A sealing glass composition suitable for bonding ceramic surfaces at low temperatures and which includes in weight percent 5-50% thallium oxide, 10-40% vanadium oxide, 5-30% tellurium oxide, 1.5-15% arsenic oxide and 1-5% phosphorous oxide. Other additives may be included, such as bismuth oxide. A paste formulated from said glass and a filler for the purpose of adjusting the fluidity and/or dielectric constant of the paste.Type: GrantFiled: July 9, 1993Date of Patent: August 9, 1994Assignee: Johnson Matthey Inc.Inventors: Masyood Akhtar, Kim C. Le, Jess Pedigo, Charles H. Smith
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Patent number: 5324691Abstract: The invention provides: a glass composition comprising about 20 to about 85% of SiO.sub.2, about 2 to about 75% of B.sub.2 O.sub.3, about 15% or less of Al.sub.2 O.sub.3, about 30% or less of at least one of Li.sub.2 O, Na.sub.2 O, K.sub.2 O, Rb.sub.2 O and Cs.sub.2 O, about 0.1 to about 10% of ZnO, about 10% or less, calculated as total amount in combination with ZnO, of at least one of MgO, CaO, BaO, SrO and PbO, about 10% or less of at least one of ZrO.sub.2, La.sub.2 O.sub.3, Y.sub.2 O.sub.3, Ta.sub.2 O.sub.3 and Gd.sub.2 O.sub.3, and about 0.05 to about 15% of at least one copper halide.Type: GrantFiled: July 27, 1992Date of Patent: June 28, 1994Assignee: Isuzu Glass Co., Ltd.Inventors: Takashi Tarumi, Toshihiko Einishi
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Patent number: 5318929Abstract: The invention relates to an apatite glass ceramic which can be used as a material in medicine and as an inorganic component of a glass ionomer cement. The apatite glass ceramic comprises in wt-%) 15-40% SiO.sub.2, 15-35% Al.sub.2 O.sub.3, 12-30% CaO, 6-25% P.sub.2 O.sub.5, 2.5-15% F.sup.-, 0-18% R.sub.2 O, wherein R.sub.2 O is an alkali oxide. The apatite glass ceramic comprises a crystal phase which contains apatite.Type: GrantFiled: October 10, 1991Date of Patent: June 7, 1994Assignee: Thera Patent GmbH & Co. KG Gesellschaft fur Industrielle SchutzrechteInventors: Carsten Jana, Wolfram Holand, Werner Vogel
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Patent number: 5302557Abstract: Thick film paste composition for applying conductive patterns to automotive window glass comprising finely divided particles of metallic silver, glass frit having transition metal oxide, contained in the glass, all of the particulate solids being dispersed in an organic medium.Type: GrantFiled: December 3, 1991Date of Patent: April 12, 1994Assignee: E. I. du Pont de Nemours and CompanyInventors: Alan F. Carroll, Hideaki Kuno
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Patent number: 5283212Abstract: This invention relates to thallium tellurite glasses possessing a high Verdet constant and high optical nonlinearity, as well as good visible and infrared transmission, making them suitable materials for the fabrication of active optical devices. The glasses consist essentially, expressed in terms of cation percent, of 5-74.5% TeO.sub.2, 0.5-20% SiO.sub.2, 4-50% TlO.sub.0.5, and 0-71% PbO, wherein PbO+T10.sub.0.5.gtoreq.25 %, TeO.sub.2 +SiO.sub.2 .gtoreq.25%, and TeO.sub.2 +SiO.sub.2 +TlO.sub.0.5 +PbO constitutes at least 65% of the total composition.Type: GrantFiled: December 17, 1992Date of Patent: February 1, 1994Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Douglas W. Hall, Mark A. Newhouse
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Patent number: 5234871Abstract: The invention relates to a glass consisting essentially of______________________________________ P.sub.2 O.sub.5 43-59 SiO.sub.2 0-9 Al.sub.2 O.sub.3 7-11 Li.sub.2 O 0-15 Na.sub.2 O 0-15 K.sub.2 O 0-15 MgO 0-15 CaO 0-0.5 BaO 0-7 ZnO 0-7 CeO.sub.2 0-0.5 CuO 7-21 V.sub.2 O.sub.5 0.07-0.7 Pr.sub.6 O.sub.11 0-1.5 Nd.sub.2 O.sub.3 0-1.5 Nb.sub.2 O.sub.5 0-3 B.sub.2 O.sub.3 0-3 Y.sub.2 O.sub.3 0-3 Cr.sub.2 O.sub.3 0-1 ______________________________________having a photopic transmission of at least 10% at full rated voltage and a color space of NVIS Green A or B. The glass is useful in the production of optical filters for use with light sources in order to render said sources compatible with night vision imaging systems.Type: GrantFiled: November 27, 1991Date of Patent: August 10, 1993Assignee: Schott Glass Technologies, Inc.Inventor: David G. Krashkevich
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Patent number: 5196381Abstract: A low-K crystallizable glass composition having a softening point of 550.degree.-800.degree. C., consisting essentially of mole % of:41-70% P.sub.2 O.sub.5 ;10-48% MgO, ZnO or mixtures thereof;2-20% Al.sub.2 O.sub.3, Cr.sub.2 O.sub.3 or mixtures thereof;0-10% alkali metal oxide(s);0-10% CaO, SrO, BaO or mixtures thereof;0-10% SiO.sub.2 ;0-20% B.sub.2 O.sub.3 ;0-10% ZrO.sub.2, TiO.sub.2 or mixtures thereof; and0-10% Fe.sub.2 O.sub.3, with the provisos that:(i) a=n(b+3c+d+e+2f+3g), wherein n=0.8-1.0, anda=mole % P.sub.2 O.sub.5 ;b=mole % MgO, ZnO or mixtures thereof;c=mole % Al.sub.2 O.sub.3, Cr.sub.2 O.sub.3 or mixtures thereof;d=mole % M.sub.2 O, where M=Na, K, Rb, Cse=mole % M'O, where M'=Ca, Sr, Baf=mole % ZrO.sub.2, TiO.sub.2 or mixtures thereof;g=mole % Fe.sub.2 O.sub.3, (where Ln is any of the rare earth elements), or mixtures thereof;(ii) the total amount of alkali oxides, CaO, SrO, and BaO does not exceed 10 mole %;(iii) the total amount of ZrO.sub.2, TiO.sub.2, and Fe.sub.2 O.sub.Type: GrantFiled: January 16, 1990Date of Patent: March 23, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Yung-Haw Hu, Michael A. Saltzberg, Robert D. Shannon
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Patent number: 5173456Abstract: A low-or no-silica, low- or no-alkali phosphate glass useful as a laser amplifier in a multiple pass, high energy laser system having a high thermal conductivity, K.sub.90.degree. C. >0.85 W/mK, a low coefficient of thermal expansion, .alpha..sub.20.degree.-300.degree. C. <80.times.10.sup.-7 /.degree.C., low emission cross section, .sigma.<2.5.times.10.sup.-20 cm.sup.2, and a high fluorescence lifetime, .tau.>325 .mu.secs at 3 wt. % Nd doping, consisting essentially of (on an oxide composition basis):______________________________________ Mole % ______________________________________ P.sub.2 O.sub.5 52-72 Al.sub.2 O.sub.3 0-<20 B.sub.2 O.sub.3 >0-25 ZnO 0-31 Li.sub.2 O 0-5 K.sub.2 O 0-5 Na.sub.2 O 0-5 Cs.sub.2 O 0-5 Rb.sub.2 O 0-5 MgO >0-<30 CaO 0-20 BaO 0-20 SrO 0-<20 Sb.sub.2 O.sub.3 0-<1 As.sub.2 O.sub.3 0-<1 Nb.sub.2 O.sub.5 0-<1 Ln.sub.2 O.sub.3 up to 6.5 PbO 0-<5 SiO.sub.2 0-3 ______________________________________whereinLn.sub.2 O.sub.Type: GrantFiled: December 20, 1990Date of Patent: December 22, 1992Assignee: Schott Glass Technologies, Inc.Inventors: Yuiko T. Hayden, Donna Guesto-Barnak
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Patent number: 5173212Abstract: An aluminophosphate glass containing copper(II) oxide having a low transmission in the near infrared range with a steep absorption edge as well as a very uniform high transparency in the visible range is particularly suitable as filter glass for color video cameras or as filter glass, e.g., for goggles and color displays, said glass comprising, in % by weight on the oxide basis, 67-77 of P.sub.2 O.sub.5 ; 8-13 of Al.sub.2 O.sub.3 ; 0-5.5 of B.sub.2 O.sub.3 ; 0-2.1 of SiO.sub.2 ; 0-2.5 of Li.sub.2 O; 0-6 of Na.sub.2 O; 0-14 of K.sub.2 O; 0-2.5 of Rb.sub.2 O; 0-2.5 of Cs.sub.2 O; .SIGMA. alkali metal oxide 3-14; 2.5-4.9 of MgO; 0-2.5 of CaO; 0-2.5 of SrO; 0-2.5 of BaO; 0-2.5 of ZnO; .SIGMA. alkaline-earth metal oxides+ZnO less than 5; 2-7.5 of CuO; 0.001-0.5 of V.sub.2 O.sub.5 ; CuO+V.sub.2 O.sub.5 of 2-7.5.Type: GrantFiled: October 4, 1991Date of Patent: December 22, 1992Assignee: Schott GlaswerkeInventors: Burkhard Speit, Ansgar Karnehm, Magdalena Winkler-Trudewig
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Patent number: 5168079Abstract: This invention relates to glasses exhibiting very high optical non-linearity, very high Verdet constants, very high electro-optic constants, and excellent transmissions of infrared radiation. The glasses consist essentially, in cation percent, of:______________________________________ T10.sub.0.5 20-55 GeO.sub.2 0-17 BiO.sub.1.5 0-67 PbO 0-40 GaO.sub.1.5 13-30 T10.sub.0.5 + BiO.sub.1.5 + PbO 70-87 SiO.sub.2 0-5 TeO.sub.Type: GrantFiled: October 31, 1991Date of Patent: December 1, 1992Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Nicholas F. Borrelli
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Patent number: 5168082Abstract: The invention provides a ceramic composition including as an additive a functionalized colloidal silica sol. The ceramic composition of the invention having an increased green strength.Type: GrantFiled: August 12, 1991Date of Patent: December 1, 1992Assignee: Nalco Chemical CompanyInventors: Stephen A. Matchett, Kevin J. Moeggenborg
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Patent number: 5162268Abstract: Vanadium garnet materials and a method for their preparation. The vanadium garnet material has a trivalent vanadium cation and a composition that falls within a specific prismatic-shaped volume in a quaternary composition diagram of MnO, CaO, V.sub.2 O.sub.3, and SiO.sub.2. In the process, specific amounts of separately pre-heated V.sub.2 O.sub.3, MnO, CaO and SiO.sub.2 powders are ground and mixed together, pelletized, heated at a temperature in the range of about 1100.degree. C. to 1400.degree. C. for 12 to 48 hours in an atmosphere of carefully selected oxygen pressure comprising a gas mixture of high purity CO.sub.2 and H.sub.2 to produce a liquid melt, and cooling, crystallizing out and separating said vanadium garnet material. A typical vanadium garnet material has the formula Mn.sub.1.3 Ca.sub.1.7 V.sub.2 Si.sub.3 O.sub.12. The vanadium garnet materials may be used in laser applications.Type: GrantFiled: August 12, 1991Date of Patent: November 10, 1992Assignee: Texaco Inc.Inventors: Arnulf Muan, Mitri S. Najjar
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Patent number: 5153150Abstract: The present invention provides a new and useful composition and method of using the same for producing an enamel finish on a formed section of glass. The composition partially crystallizes upon heating, thereby helping to prevent the forming and handling equipment from sticking and/or adhering to the composition during the forming operation. The composition includes a crystallizable glass frit and seed powder. The crystallized glass frit includes precursors from which Zn.sub.2 SiO.sub.4 can be crystallized upon firing of the composition. The seed powder causes at least a portion of the precursors to crystallize upon firing such that during firing at least a portion of the crystallizable glass frit yields crystallized Zn.sub.2 SiO.sub.4 formed by the precursors. Preferably, the precursors contain 30-75 wt %/5-20 wt % SiO.sub.2, and the seed powder contains crystalline Zn.sub.2 SiO.sub.4.Type: GrantFiled: September 7, 1990Date of Patent: October 6, 1992Assignee: Ferro CorporationInventors: Clifford G. Ruderer, Gordon J. Roberts, Robert C. Stroup