Specified Rate-affecting Material Contains A Ketone Group -c-(co)n-c-, The (co)n Not Being Part Of A Ring Patents (Class 522/33)
  • Publication number: 20040091816
    Abstract: A photosensitive composition exhibiting enhanced sensitivity is disclosed, comprising an ethylenically unsaturated monomer, a photopolymerization initiator composition and a polymer binder, wherein the photopolymerization initiator composition contains a polyhalogen compound. There is also disclosed a photosensitive lithographic printing plate comprising the foregoing photosensitive composition on a support having a hydrophilic surface.
    Type: Application
    Filed: October 17, 2003
    Publication date: May 13, 2004
    Applicant: Konica Minolta Holdings, Inc.
    Inventors: Toshiyuki Matsumura, Kazuhiko Hirabayash
  • Publication number: 20040082678
    Abstract: The present invention relates to a biodegradable composition for the preparation of table-ware, mulching film and package, which comprises: 2-6% by weight of starch; 35-45% by weight of plant powders; 20-30% by weight of calcium carbonate; 2-7% by weight of sorbital; 7-13% by weight of polypropene; 2-5% by weight of polyethylene; 2-6% by weight of coupling agent; 1-2% by weight of defoamer; 2-5% by weight of stearic acid; 2-6% by weight of stearate; 3-6% by weight of glycerine or epoxidized soybean oil; and 60-100 ppm photosensitizer. The present invention also relates to a method for preparing the composition, which comprises: treating a plant wastes with a diluent acid, drying and pulverizing, then mixing it with starch, polypropene, and polyethylene, sorbital, defoamer, coupling agent, stearic acid, stearate, glycerine and photosensitizer homogeneously; blending the mixture obtained in a double-screw extruder at a temperature of 160-180 C to obtain the composition of the present invention.
    Type: Application
    Filed: December 29, 2003
    Publication date: April 29, 2004
    Inventor: Hao Xu
  • Patent number: 6716893
    Abstract: The present invention discloses an ultraviolet light curable ferromagnetic composition and method for making such a composition that may be used to produce a ferromagnetic coating on a suitable substrate. These coatings may be used to produce printed capacitors and inductors. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: April 6, 2004
    Assignee: UV Specialties, Inc.
    Inventor: Roy C. Krohn
  • Publication number: 20040034115
    Abstract: A process for the production of coatings with scratch-resistant durable surfaces that comprise as photoinitiator (B) in a photocurable formulation at least one surface-active photoinitiator, concentrated at the surface of the formulation, of formula (Ia) or (Ib), wherein Ra is a radical of formula (IIa), Rb is a radical of formula (IIb)), or Ra and Rb are naphthyl, anthracyl, phenanthryl or a heterocyclic radical each of which is unsubstituted or substituted; R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are, for example, each independently of the others hydrogen; A—Y; C1-C12alkyl, halogen or phenyl; R11 and R12 are, for example, C1 -C12 alkyl; X is —OR20 or —N(R21)(R22); R20 is, for example, hydrogen or C1-C4alkyl; R21 and R22 are, for example, hydrogen or C1-C12 alkyl; X1 is, for example, —O—; Y is, for example, a single bond or —O—; Y1 is, for example, a single bond; and A is, for example, C6-C30alkyl.
    Type: Application
    Filed: June 11, 2003
    Publication date: February 19, 2004
    Inventors: Gisele Baudin, Tunja Jung
  • Patent number: 6673850
    Abstract: Photoinitiators of formula (Ia) or (Ib) having chain transfer groups, wherein n is 1 or 2; PI is for example a group of formula (IIa); PI′ inter alia is a group of formula (IIIa); Ar is for example phenyl; Ar2 is inter alia phenylene; R1 and R2 are for example C1-C8alkyl, or R1 and R2 together C2-C9alkylene; M1 inter alia is —NR3R4 or —OH; M1′ is for example a group (c); R3′ is a direct bond, C1-C12alkylene, or phenylene; R3 is for example hydrogen, or C1-C12alkyl; R4 is e.g. C1-C12alkyl; A1 and A2 are for example a direct bond; CT is a chain transfer group; are useful for the preparation of macrophotoinitiators which can be employed for preparing block copolymers.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: January 6, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Hitoshi Yamato, Masaki Ohwa, Toshikage Asakura, Akira Matsumoto
  • Patent number: 6669994
    Abstract: A method of forming a polymer layer on a support surface by the use of a coating agent and polymerizable compounds. The coating agent provides photoreactive groups adapted to attach the agent to the surface, as well as photoreactive groups adapted to remain unattached to the surface, and thus serve as photoinitiators for the activation of polymerizable compounds in order to form a polymer layer thereon. Also provided are coating agents, per se, as well as a method of using such agents and the resultant surfaces and devices fabricated therefrom.
    Type: Grant
    Filed: April 23, 2001
    Date of Patent: December 30, 2003
    Assignee: SurModics, Inc.
    Inventors: Dale G. Swan, Richard A. Amos, Terrence P. Everson, Stephen J. Chudzik, Ralph A. Chappa, Sean M. Stucke, Peter H. Duquette
  • Patent number: 6652970
    Abstract: The present invention is directed toward compositions that are chemically different after application to a substrate as compared to the composition prior to its application. A method of the invention comprises a method of transitioning a crosslinked polymer composition from a first chemical state to a second chemical state. Advantageously, compositions of the invention are relatively stable after transformation to their altered, or second, chemical state.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: November 25, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Albert I. Everaerts, Charles M. Leir, Roger A. Mader, Peter A. Stark
  • Patent number: 6649669
    Abstract: A single solution bonding formulation for dental applications comprising a plurality of at least one self-polymerizable polyvinyl acidic monomer or at least two different polymerizable polyvinyl acidic monomers, a calcium phosphate filler, at least one photoinitiator, optionally an accelerator, optionally a solvent, and optionally a fluoride additive is provided. Additionally, a method for treating enamel, dentin, and/or pulp with the same single solution bonding formulation is provided. The single solution bonding formulation provides for the release of calcium, phosphate and/or fluoride ions which are sufficient in situ to form hydroxyapatite and/or fluorapatite.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: November 18, 2003
    Assignee: American Dental Association Health Foundation
    Inventor: Sabine Dickens
  • Publication number: 20030203986
    Abstract: By means of a curing process combining thermal and UV curing it is possible, using compositions comprising (A) a coating system based on a polyacrylate polyol or polyester polyol with melamine, or a polyacrylate polyol and/or polyester polyol with a blocked or unblocked polyisocyanate, or a carboxyl-, anhydride- or amino-functional polyester and/or polyacrylate with an epoxy-functional polyester or polyacrylate, (B) an OH—, NH2—, COOH—, epoxy- or NCO-functional resin containing, in addition, at least one ethylenically unsaturated double bond, which is separated from the functional group by a spacer group, and (C) at least one photoinitiator, to obtain coatings having good surface properties.
    Type: Application
    Filed: March 27, 2003
    Publication date: October 30, 2003
    Inventor: Andreas Valet
  • Publication number: 20030139489
    Abstract: Radically post-crosslinked polymers are made by a process comprising the steps of: (1) forming a polyurethane (a*) by reacting a compound (a) with an aliphatic and/or an aromatic isocyanate and a compound (c) wherein compound (a) is the product of the reaction of an epoxidized fatty acid ester and/or an epoxidized triglyceride with acrylic acid and/or methacrylic acid and wherein compound (c) is selected from the group consisting of acrolein, acrylamide, vinyl acetate and styrene; (2) forming a crosslinked polyurethane by reacting the polyurethane (a*) with a radical initiator (b). The polymers are useful as components in composites comprised of natural and/or synthetic fibers.
    Type: Application
    Filed: December 6, 2002
    Publication date: July 24, 2003
    Inventors: Horst Sulzbach, Ralf Bemmann, Rainer Hoefer, Michael Skwiercz
  • Publication number: 20030134928
    Abstract: Radically post-crosslinked polymers are made by a process comprising the steps of: (1) forming a polyurethane (a*) by reacting a compound (a) with an aliphatic and/or an aromatic isocyanate and a compound (c) wherein compound (a) is the product of the reaction of an epoxidized fatty acid ester and/or an epoxidized triglyceride with acrylic acid and/or methacrylic acid and wherein compound (c) is a polyol ester having two or more C═C double bonds per molecule; (2) forming a crosslinked polyurethane by reacting the polyurethane (a*) with a radical initiator (b). The polymers are useful as components in composites comprised of natural and/or synthetic fibers.
    Type: Application
    Filed: November 22, 2002
    Publication date: July 17, 2003
    Inventors: Horst Sulzbach, Ralf Bemmann, Rainer Hoefer, Michael Skwiercz
  • Patent number: 6559223
    Abstract: Forming graft copolymers in water using labeling of water soluble polymers with photoinitiators. Water soluble polymers can form environmentally responsive hydrophobically stimulated cages. The cages, which contain initiating radicals after irradiation, may be “opened” or “closed” by changes in environmental conditions. When the cage is closed, the radicals are trapped inside and thus do not cause substantial polymerization of water soluble monomers in the same solution. When the cage is closed, the radicals escape and cause polymerization. In another variation, hydrogels and graft copolymers are formed by covalently linking phototoinitiator groups to water soluble polymers that do not form cages. Thus, monomers may form grafts to the polymer, allowing formation of physical hydrogels.
    Type: Grant
    Filed: February 22, 2001
    Date of Patent: May 6, 2003
    Assignee: Polytechnic University
    Inventors: Mark M. Green, Sung Yun Yang
  • Publication number: 20030082355
    Abstract: A photocurable and thermosetting composition which is useful in forming a matte film and can be developed with an aqueous alkaline solution is provided. The composition comprises (A) a photosensitive prepolymer obtained by causing a saturated or unsaturated polybasic acid anhydride to react with a hydroxyl group of an esterification product of a novolak type epoxy compound and an unsaturated monocarboxylic acid, (B) a carboxyl group-containing copolymer resin, (C) a photopolymerization initiator, (D) a diluent, (E) a polyfunctional epoxy compound having at least two epoxy groups in its molecule, and, when necessary, (F) an inorganic filler. The composition may further comprise (G) an epoxy resin curing agent. This composition can be advantageously used for the formation of a solder resist on a printed circuit board.
    Type: Application
    Filed: August 13, 2002
    Publication date: May 1, 2003
    Inventors: Satoru Iwaida, Yoshihiro Ohno, Masayuki Isono, Akio Sekimoto
  • Patent number: 6555593
    Abstract: Photopolymerization compositions which include maleimides and processes using the same are disclosed. Polymerization of compositions which include maleimides in combination with a benzophenone compound/hydrogen atom donor sensitizer system may be activated by irradiating the composition with radiation.
    Type: Grant
    Filed: January 29, 1999
    Date of Patent: April 29, 2003
    Assignee: Albemarle Corporation
    Inventors: Charles E. Hoyle, Rajamani Nagarajan, Christopher W. Miller, Shan Christopher Clark, E. Sonny Jönsson, Liying Shao
  • Publication number: 20030065049
    Abstract: Novel benzophenone derivatives and methods of making and using the same are disclosed. The novel compounds can display highly active photoinitiation and photopolymerization properties.
    Type: Application
    Filed: October 1, 2002
    Publication date: April 3, 2003
    Applicant: Albemarle Corporation
    Inventors: John Gabriel Santobianco, Rajamani Nagarajan, August John Muller, Joseph Stanton Bowers
  • Patent number: 6506814
    Abstract: A UV-curable acrylate-thiol-ene insulating coating composition for electrical conductors, a method of manufacturing a UV-curable acrylate-thiol-ene insulating coating composition for electrical conductors. The insulating coating being of about 2.5 &mgr;m to about 500 &mgr;m thickness, which cured coating has a dielectric dissipation factor (60 Hz, 24° C.) of lower than about 0.05.
    Type: Grant
    Filed: May 7, 1998
    Date of Patent: January 14, 2003
    Assignee: DSM N.V.
    Inventors: Vadim V. Krongauz, Chau T. M. Ha, Sangeeta Rampuria
  • Publication number: 20020177632
    Abstract: A non-woven sheet of polyolefin fibers having opposed major surfaces is disclosed. Some areas of one or both of the major surfaces are hydrophilic as a consequence of an acrylic graft polymerized with the surfaces of the fibers in those areas while the fibers in other areas of that major surface are free of the graft and, as a consequence, remain hydrophobic. A battery separator composed of at least two such non-woven sheets is also disclosed, as well as batteries having a separator composed of at least one such non-woven sheet. Also disclosed is a non-woven sheet of polyolefin fibers where opposed major surfaces of the sheet are hydrophilic as a consequence of such an acrylic acid graft, but the ion exchange coefficients of the two major surfaces are different.
    Type: Application
    Filed: May 6, 2002
    Publication date: November 28, 2002
    Applicant: Hollingsworth & Vose Company
    Inventor: Wai Ming Choi
  • Patent number: 6485886
    Abstract: New oxime derivatives of formula (I) or. (II), wherein m is 0 or 1; R1 inter alia is phenyl, naphthyl, anthracyl, phenanthryl or a heteroaryl radical; R′1 is for example C2-C12alkylene, phenylene, naphthylene; R2 is CN; R3 is C2-C6haloalkanoyl, halobenzoyl, a phosphoryl or an organosilyl group; R4, R5, R10 and R11 inter alia are hydrogen, C1-C6alkyl, C1-C6alkoxy; R6 inter alia is hydrogen phenyl, C1-C12alkyl; R7 and R8 inter alia are hydrogen, C1-C12alkyl; or R7 and R8, together with the nitrogen atom to which they are bonded, form a 5-, 6 or 7-membered ring; R9 is for example C1-C12alkyl; and A inter alia is S, O, NR7a; are useful as latent acids, especially in photoresist applications.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: November 26, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Hitoshi Yamato, Toshikage Asakura, Jean-Luc Birbaum, Kurt Dietliker
  • Publication number: 20020156143
    Abstract: The invention comprises a composition and method for controlling the gloss of surface covering products through curing of the composition to create a wearlayer surface, and preferably on a floor covering product. The surface covering product preferably is prepared by application of an aromatic polyester acrylate composition including a flatting agent and/or hard particles, and at least one free-radical generating compound to a substrate, and then the coating is partially cured by exposure to low peak irradiance UV light in either ambient or inert air, followed by fully curing the coating with high peak irradiance UV light in preferably an inert atmosphere to form a low gloss abrasion resistant wearlayer surface. Alternatively, a high gloss wearlayer surface is obtained by solely exposing the preferred composition to high peak irradiance UV light in ambient atmosphere. Furthermore, a differential gloss flooring product is obtained by using the present inventive method described herein.
    Type: Application
    Filed: January 31, 2002
    Publication date: October 24, 2002
    Applicant: Armstrong World Industries, Inc.
    Inventors: Gary A. Sigel, Jeffrey S. Ross, Elizabeth A. Malkowski, Richard E. Herr, Larry W. Leininger
  • Patent number: 6451870
    Abstract: The present invention relates to dual curing silicone compositions which are capable of cross-linking when subjected to ultraviolet (“UV”) or visible (“VIS”) light and/or by a moisture condensation method. When cured, these compositions have excellent adhesion to a variety of substrates. These are particularly useful in potting and coating applications.
    Type: Grant
    Filed: December 14, 2000
    Date of Patent: September 17, 2002
    Assignee: Henkel Loctite Corporation
    Inventors: Alfred A. DeCato, Hsien-Kun Chu
  • Publication number: 20020107297
    Abstract: The invention relates to the use of surface-active photoinitiators of formula I 1
    Type: Application
    Filed: December 21, 2001
    Publication date: August 8, 2002
    Inventors: Gisele Baudin, Tunja Jung
  • Publication number: 20020091229
    Abstract: Hydrogels of polymerized and crosslinked macromers comprising hydrophilic oligomers having biodegradable monomeric or oligomeric extensions, which biodegradable extensions are terminated on free ends with end cap monomers or oligomers capable of polymerization and cross linking are described. The hydrophilic core itself may be degradable, thus combining the core and extension functions. Macromers are polymerized using free radical initiators under the influence of long wavelength ultraviolet light, visible light excitation or thermal energy. Biodegradation occurs at the linkages within the extension oligomers and results in fragments which are non-toxic and easily removed from the body. Preferred applications for the hydrogels include prevention of adhesion formation after surgical procedures, controlled release of drugs and other bioactive species, temporary protection or separation of tissue surfaces, adhering of sealing tissues together, and preventing the attachment of cells to tissue surfaces.
    Type: Application
    Filed: October 22, 2001
    Publication date: July 11, 2002
    Applicant: Board of Regents, The University of Texas System Texas
    Inventors: Jeffrey A. Hubbell, Chandrashekhar P. Pathak, Amarpreet S. Sawhney, Neil P. Desai, Jennifer L. Hill
  • Patent number: 6384100
    Abstract: A method for producing an acrylic graft polymer on the surface of a polyolefin article is disclosed. The method comprises the steps of immersing the polyolefin article in a solution of a photoinitiator in a volatile solvent, allowing the volatile solvent in the photoinitiator solution to vaporize, immersing the polyolefin article in a solution of an acrylic monomer, and subjecting the polyolefin article, while in a suitable atmosphere, which can be air or can be inert, to ultraviolet irradiation to cause the acrylic monomer to graft to the polyolefin surface. A method which involves subjecting a polyolefin article to corona discharge, immersing the article, after corona discharge treatment, in a solution of a photoinitiator and an acrylic monomer in a volatile solvent, and subjecting the article to ultra violet irradiation to cause the acrylic monomer to graft to the polyolefin surface is also disclosed. The latter method improves the ammonia trapping capacity of the grafted article.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: May 7, 2002
    Assignee: Hollingsworth + Vose Company
    Inventor: Wai Ming Choi
  • Publication number: 20020052428
    Abstract: When dust or contaminants invade into a hard disk drive and adhere to the surface of a magnetic head, there arise operation errors in recording and reading out signals. Accordingly, it has been required to develop compositions containing little outgas components as ultraviolet-curing resins to be used in assembling hard disk drives.
    Type: Application
    Filed: January 2, 2002
    Publication date: May 2, 2002
    Applicant: THREE BOND CO., LTD.
    Inventor: Yoshihide Arai
  • Patent number: 6376568
    Abstract: The invention relates to the use of surface-active photoinitiators of formula I the units being arranged randomly or in blocks, and wherein n is a number from 1 to 1000; m is a number from 0 to 100; p is a number from 0 to 10 000; x is the number 1, or, when n is 1, x may also be the number 2; A1 and A2 are, for example, C1-C18alkyl; or A1 and A2 together are a single bond; R1, R2 and R3 are, for example, each independently of the others C1-C18alkyl, phenyl or C5-C8cycloalkyl; R4 is, for example, unsubstituted or substituted C1-C18alkyl, unsubstituted or substituted phenyl or C5-C8cycloalkyl; IN, when x is 1, is a radical of formula or IN, when x is 2, is a radical of formula R13 and R14 are, for example, each independently of the other C1-C12alkyl; Y is, for example, —(CH2)a—O—; X is OR15 or N(R16)(R17); R15 is, for example, hydrogen or C1-C4alkyl; R16 and R17 are, for example, hydrogen or C1-C12alkyl; X1 has, for example, one of the mea
    Type: Grant
    Filed: July 18, 2000
    Date of Patent: April 23, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Giséle Baudin, Tunja Jung
  • Patent number: 6369123
    Abstract: Radiation-crosslinkable elastomeric compositions containing: (a) an elastomeric polymer containing abstractable hydrogen atoms in an amount sufficient to enable the elastomeric polymer to undergo crosslinking in the presence of a suitable radiation-activatable crosslinking agent; and (b) a radiation-activatable crosslinking agent of the formula: wherein: X represents CH3—; phenyl; or substituted-phenyl; or substituted-phenyl with the proviso that any substituents on the substituted-phenyl do not interfere with the light-absorbing capacity of the radiation-activatable crosslinking agent and do not promote intramolecular hydrogen abstraction of the radiation activatable crosslinking agent; W represents —O—, —NH—, or —S—; Z represents an organic spacer selected from the group consisting of aliphatic, aromatic, aralkyl, heteroaromatic, and cycloaliphatic groups free of esters, amides, ketones, urethanes, and also free of ethers, thiols, allylic grou
    Type: Grant
    Filed: August 14, 1995
    Date of Patent: April 9, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Peter A. Stark, Edward G. Stewart, Albert I. Everaerts
  • Patent number: 6350792
    Abstract: A radiation-curable composition in a liquid or solid form comprises at least one solid, non-crystalline radiation-transmissible material, dispersed in at least one cationic-curable or free-radical curable composition or mixture thereof. The solid, non-crystalline radiation-transmissible materials comprise glasses and other suitable materials that transmit (i.e., are transparent to) at least about 40% of radiation having a wavelength from about 180 to about 600 nanometers. The solid forms of the radiation-curable compositions of the invention are useful as powder coatings for coating decorative and functional objects and that would be cured by a thermal heating flow process followed by radiation exposure. The cured compositions of the invention are useful as coatings and inks for metal, paper, plastics, glass, ceramics, and wood, as adhesives, as sealants, and as composite materials and other articles and in biomedical and dental applications.
    Type: Grant
    Filed: July 13, 2000
    Date of Patent: February 26, 2002
    Assignee: Suncolor Corporation
    Inventors: David A. Smetana, Joseph V. Koleske
  • Patent number: 6335382
    Abstract: An ultraviolet-curable adhesive having an excellent moisture resistance and suitable for bonding optical disks having an information recording layer (vapor deposition layer), particularly optical disks having a thick vapor deposition layer, which contains, as essential components, (A) N-vinylpyrrolidone, (B) a urethane (meth)acrylate oligomer derived from a caprolactone-based polyol, an alicyclic diisocyanate and (meth)acrylic acid, and (C) a photopolymerization initiator containing (C-1) a photopolymerization initiator composed of only a carbon atom, a hydrogen atom and an oxygen atom without containing a nitrogen atom, a sulfur atom and a phosphorus atom and (C-2) a photopolymerization initiator containing a nitrogen atom and/or a sulfur atom in a (C-1)/(C-2) ratio of 70/30 to 100/0 by weight.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: January 1, 2002
    Assignee: Nagase-Ciba Ltd.
    Inventor: Takafumi Iida
  • Publication number: 20010044480
    Abstract: Ethylene copolymer elastomer compositions, acrylate rubber compositions, nitrile rubber compositions, fluoroelastomer compositions, and chlorinated elastomer compositions are provided which are curable by exposure to UV radiation. The compositions are particularly suited for production of elastomeric seals using hot melt equipment and a gasketing in place technique.
    Type: Application
    Filed: April 26, 2001
    Publication date: November 22, 2001
    Inventors: Patrick L. Paglia, Christian Ruepping
  • Publication number: 20010036977
    Abstract: Ethylene copolymer elastomer compositions, acrylate rubber compositions, nitrile rubber compositions, fluoroelastomer compositions, and chlorinated elastomer compositions are provided which are curable by exposure to UV radiation. The compositions are particularly suited for production of elastomeric seals using hot melt equipment and a gasketing in place technique.
    Type: Application
    Filed: April 26, 2001
    Publication date: November 1, 2001
    Inventor: Christian Ruepping
  • Publication number: 20010034379
    Abstract: By means of a curing process combining thermal and UV curing it is possible, using compositions comprising (A) a coating system based on a polyacrylate polyol or polyester polyol with melamine, or a polyacrylate polyol and/or polyester polyol with a blocked or unblocked polyisocyanate, or a carboxyl-, anhydride- or amino-functional polyester and/or polyacrylate with an epoxy-functional polyester or polyacrylate, (B) an OH—, NH2—, COOH—, epoxy- or NCO-functional resin containing, in addition, at least one ethylenically unsaturated double bond, which is separated from the functional group by a spacer group, and (C) at least one photoinitiator, to obtain coatings having good surface properties.
    Type: Application
    Filed: May 3, 2001
    Publication date: October 25, 2001
    Inventor: Andreas Valet
  • Patent number: 6306932
    Abstract: Disclosed herein is an anti-fogging coating material comprising at least one selected from the group consisting of an inorganic alkoxide, a hydrolysate of the inorganic alkoxide and a polycondensate of the hydrolysate of the inorganic alkoxide, a polyacrylic, and polyvinyl alcohol.
    Type: Grant
    Filed: August 26, 1998
    Date of Patent: October 23, 2001
    Assignees: Canon Kabushiki Kaisha, Nakato Laboratory, Inc.
    Inventors: Tohru Yamamoto, Shigeo Yoshida, Hatsumi Ikari, Keiji Ikemori, Keiji Ohtaka, Hideo Ukuda
  • Patent number: 6296986
    Abstract: A multifunctional photoinitiator is obtainable as the reaction product of a multifunctional core material containing two or more reactive groups and a photoinitiator or a derivative thereof. The photoinitiator or its derivative has a reactive group capable of reacting with the reactive groups of the multifunctional core.
    Type: Grant
    Filed: November 10, 1998
    Date of Patent: October 2, 2001
    Assignee: Coates Brothers PLC
    Inventors: Derek Ronald Illsley, Aylvin Angelo Dias, Robert Stephen Davidson, Roger Edward Burrows
  • Publication number: 20010025061
    Abstract: A photopolymerizable composition for use in forming a photopolymer composition for use in forming the light transmissive regions of light transmissive devices, and such devices.
    Type: Application
    Filed: March 27, 2001
    Publication date: September 27, 2001
    Inventors: Chengjiu Wu, Michael J. McFarland, Karl W. Beeson
  • Patent number: 6291543
    Abstract: A surfacially ultraviolet radiation-crosslinked article formed of a homogeneous composition including an elastoplastic material, a cross-linker component that is cross-linkable by free-radical polymerization, and a free-radical source material generating free radicals in exposure to ultraviolet radiation, wherein the elastoplastic material is surfacially cross-linked by exposure to ultraviolet radiation, wherein the sub-surface bulk volume of the article is non-cross-linked, and the article is resiliently deformable from and resiliently recoverable to a shape of the article when it was exposed to ultraviolet radiation for surfacial cross-linking thereof. The article is particularly amenable to embodiment as a catheter, or other similar medical device for cardiovascular or other medical procedures.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: September 18, 2001
    Assignee: Polyzen, Inc.
    Inventor: Tilak M. Shah
  • Publication number: 20010020047
    Abstract: The invention relates to thermoplastic polyolefin compositions having enhanced surface durability and products thereof which include a thermoplastic polyolefin base component at least one radiation-crosslinkable component present in an amount sufficient to enhance the surface durability of the thermoplastic polyolefin component when radiation-cured and at least one photoinitiator present in an amount sufficient to initiate crosslinking of the radiation-crosslinkable component upon exposure of the thermoplastic polyolefin composition to radiation.
    Type: Application
    Filed: December 11, 2000
    Publication date: September 6, 2001
    Inventors: Edmund K. Lau, Satchit Srinivasan, Peter J. Perron, Peter S. Solera, Anthony DeBellis, Chia-Hu Chang, Gerald Capocci, Joseph Puglisi, Douglas Horsey
  • Publication number: 20010007880
    Abstract: This invention pertains to a process for the manufacture of a hydrophilic polymeric product, consisting in causing a material comprising a crosslinked silicone polymer matrix and photoinitiator groups dispersed and immobilized within the polymer matrix to swell in a swelling solution comprising a solvent for swelling the crosslinked silicone polymer of the matrix of the material, a photopolymerizable hydrophilic monomer and optionally a crosslinking agent and a proton- or electron-donating coinitiator compound, when the material comprises photoactivable photoinitiator groups and does not comprise proton- or electron-donating coinitiator groups causing the photopolymerizable hydrophilic monomer to diffuse into the swollen material, and polymerizing, by irradiation, the photopolymerizable hydrophilic monomer.
    Type: Application
    Filed: December 28, 2000
    Publication date: July 12, 2001
    Applicant: Essilor International Compagnie Generale D'Optique
    Inventors: Brigitte Marchin, Dominique Baude, Jean-Pierre Vairon, Marine-Anne Dourges, Philippe Chaumont, Joel Steiner
  • Patent number: 6232360
    Abstract: UV-curable coating compositions containing urethane acrylates prepared from hydroxyalkyl acrylates and low-viscosity polyisocyanates having isocyanurate groups, low-viscosity acrylic ester components as reactive diluents, initiators, and optionally solvents and/or other known additives, and their use for coating molded articles of thermoplastic polycarbonates.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: May 15, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jürgen Meixner, Wolfgang Fischer, Josef Pedain
  • Patent number: 6204302
    Abstract: A photoinitiator composition that includes (a) 1-aryl-2-alkyl-1,2-ethanedione and (b) a rigid 1,2-dione in a weight ratio of (a):(b) in a range of about 1:20 to about 20:1 is disclosed. The photoinitiator composition can be used in a photocurable dental composition in an amount sufficient to achieve a degree of double-bond conversion of at least 50%. Methods for making the photocurable dental composition are also disclosed.
    Type: Grant
    Filed: November 19, 1999
    Date of Patent: March 20, 2001
    Assignee: Bisco, Inc.
    Inventors: H. Ralph Rawls, Yeong-Joon Park, Kyu-Ho Chae
  • Patent number: 6197173
    Abstract: Polymerization of gels for electrophoresis with improved photoinitiators results in gels which are suitable for electrophoresis. The new initiator systems are much faster than current systems for making such gels. Moreover, the polymerization reaction can be conducted in the presence of oxygen, which greatly simplifies gel casting. In particular, it is possible with the invention to cast and use gels of acrylic monomers in a “submarine” mode, which was not previously possible with acrylamide gels. Continuous casting of gels is facilitated.
    Type: Grant
    Filed: June 26, 1999
    Date of Patent: March 6, 2001
    Inventor: Francis H. Kirkpatrick
  • Patent number: 6176906
    Abstract: Disclosed is a photo-curable antifogging composition which may be applied to substrates such as glass, various plastic materials and the like to give antifogging property on the surface of these substrates. The main ingredient of the composition is a quaternary ammonium salt of the following formula (1): wherein: R1 is CH3(CH2)nCH2 or CH3(CH2)nCH2C6H4 wherein n is an integer from 1 to 16 inclusive; R2 and R3 are the same or different from each other, and represent CH2═C(CH3)COOCH2CH(OH)CH2,CH2═CHCOOCH2CH(OH)CH2 or H, with the proviso that R2 and R3 may not be H at the same time; R4 is H, CH3, CH3CH2 or CH3CH2CH2; and X is CH3OSO3, CH3CH2OSO3, CH3COO, CF3COO, CH3(CH2)nCOO wherein n is an integer from 1 to 16 inclusive, CH3(CH2)7CH═CH(CH2)7COO, C6H5COO, C6H5CH(OH)COO, HOOCCH2CH(OH)COO, Cl or Br.
    Type: Grant
    Filed: January 7, 2000
    Date of Patent: January 23, 2001
    Assignee: Ventree Co., Ltd.
    Inventors: Haeng-Woo Lee, Young-Hoon Park, Sang-Keun Kim, Eun-A Shin
  • Patent number: 6156816
    Abstract: A substantially water-free, water-washable, energy-curable composition includes an epoxy oligomer and/or urethane oligomer having at least two ethylenically unsaturated moieties, at least one alkoxylated polyol monomer having at least two ethylenically unsaturated moieties and capable of being copolymerized with the oligomer, and a surface active agent capable of being integrated into the molecular structure of the cured polymer and further capable of rendering the uncured composition dispersible in water. Optionally, the composition can contain a photoinitiator. The composition is self-dispersible in water and is especially suitable for use as a coating material for a printing screen.
    Type: Grant
    Filed: August 20, 1998
    Date of Patent: December 5, 2000
    Assignee: Henkel Corporation
    Inventor: Marie-Esther Saint Victor
  • Patent number: 6130270
    Abstract: A radiation curable composition comprising,(A) at least one compound containing a (meth)acrylate group represented by the following formula (1), ##STR1## wherein R.sup.1 is a hydrogen atom or a methyl group, R.sup.2 is an alkylene group or a hydroxyalkylene group having 2 to 6 carbon atoms, R.sup.3 is a divalent organic group, n is a number of 1 to 10, m is an integer of 0 or 1, and Ar.sup.1 and Ar.sup.2 are independently a group comprising an aromatic ring(B) at least one compound derived from trishydroxyethyl isocyanurate, and containing at least one (meth)acrylate group, and(C) at least one radiation polymerization initiator.The radiation curable resin composition affords a high productivity, exhibits high transparency, and produces molded articles exhibiting minimal coloration upon exposure to light, superior dimensional precision, high heat resistance, only slight adhesion to substrates under high temperature conditions. The composition is very useful for manufacturing molding articles.
    Type: Grant
    Filed: January 6, 1999
    Date of Patent: October 10, 2000
    Assignees: DSM N.V., JSR Corporation, Japan Fine Coatings Co., Ltd.
    Inventors: Masakatsu Ukon, Toshihiko Takahashi, Takashi Ukachi
  • Patent number: 6117919
    Abstract: Disclosed herein is an anti-fogging coating film comprising a hydrophilic polymer and a benzophenone compound represented by a general formula (I): ##STR1## wherein X.sub.1 to X.sub.10 are the same or different from one another and are individually a radical selected from the group consisting of hydrogen, hydroxyl group, sulfonic group, carboxyl group, acyl group, ester group, ether group, hydrocarbon groups, alkoxyl groups having 1 to 6 carbon atoms, amino group, hydroxyalkyl groups and hydroxyalkoxyl groups, with the proviso that at least one of X.sub.1 to X.sub.10 is a radical selected from among the hydroxyl and sulfonic groups. Anti-fogging articles comprising a base material such as glass, plastic, metal or mirror and the anti-fogging coating film provided thereon, and a composition for forming the anti-fogging coating film are also disclosed.
    Type: Grant
    Filed: July 21, 1998
    Date of Patent: September 12, 2000
    Assignees: Canon Kasei Kabushiki Kaisha, Canon Kabushiki Kaisha
    Inventors: Mihoko Oda, Teigo Sakakibara, Shunichiro Nishida, Hideo Ukuda
  • Patent number: 6114404
    Abstract: The present invention relates to a radiation curable ink formulation which has a tan .delta. of from about 0.5 to about 1.5. The radiation curable ink formulation includes a pigment, a radiation cross-linkable monomer or oligomer, and a rheology modifier. Flat panel color filters which contain a black radiation curable ink formulation and one or more colored radiation curable ink formulations are also disclosed. At least one of the black and colored radiation curable ink formulations has a tan .delta. of from about 0.5 to about 1.5 and includes a pigment, a radiation cross-linkable monomer or oligomer, and a rheology modifier. Methods for manufacturing these flat panel color filters are also disclosed. The radiation curable ink formulations of the present invention have the advantage of permitting clean doctoring.
    Type: Grant
    Filed: March 22, 1999
    Date of Patent: September 5, 2000
    Assignee: Corning Incorporated
    Inventors: John S. Deeken, Ronald E. Johnson, Lung-Ming Wu, Khalil M. Moussa
  • Patent number: 6096794
    Abstract: Dye compounds of the formula ##STR1## wherein X is for example CH, C--CH.sub.3 or .sup.+ NOR L.sup.- ; R is inter alia C.sub.1 -C.sub.6 alkyl; R.sub.1 is for example C.sub.1 -C.sub.8 alkoxy or C.sub.1 -C.sub.12 alkyl; s is 0 to 4; R.sub.2 is for example hydrogen; Ar is for example a group ##STR2## Y inter alia is C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxy; r in the formula (A) is 0 to 5, in the formulae (B) and (E) is 0 to 9 and in the formula (D) is 0 to 7; and L is an anion;in combination with an electron donor compound, especially a borate compound, are suitable as photoinitiators for the photopolymerization of radically polymerizable compositions.
    Type: Grant
    Filed: October 26, 1998
    Date of Patent: August 1, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Allan Francis Cunningham, Martin Kunz
  • Patent number: 6096795
    Abstract: This invention relates fluorinated polymers having high structural regularity, characterized by a high maximum operating temperature and by improved mechanical and processability properties, prepared by a (co)polymerization process of fluorinated olefinic monomers, optionally in association with non-fluorinated olefins, in aqueous emulsion, in the presence of radical photoinitiators and of ultraviolet-visible radiation.
    Type: Grant
    Filed: December 26, 1996
    Date of Patent: August 1, 2000
    Assignee: Auismont S.p.A.
    Inventors: Julio A. Abusleme, Pier Antonio Guarda, Ralph J. De Pasquale
  • Patent number: 6090236
    Abstract: A method of generating reactive species which includes exposing a polymolecular photoreactor to radiation, in which the polymolecular photoreactor comprises a wavelength-specific sensitizer associated with a reactive species-generating photoinitiator. The sensitizer absorbs energy and transfers the absorbed energy to the photoinitiator which in turn, generates reactive species. The wavelength-specific sensitizer is adapted to have an absorption wavelength band generally corresponding to an emission peak of the radiation. The radiation to which the polymolecular photoreactor is exposed generally will have a wavelength of from about 4 to about 1,000 nanometers. Thus, the radiation may be ultraviolet radiation, including near ultraviolet and far or vacuum ultraviolet radiation: visible radiation: and near infrared radiation. Desirably, the radiation will have a wavelength of from about 100 to about 900 nanometers.
    Type: Grant
    Filed: December 31, 1997
    Date of Patent: July 18, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
  • Patent number: 6071979
    Abstract: A method of generating reactive species which includes exposing a wavelength specific photoreactor to radiation, in which the wavelength specific photoreactor comprises a wavelength-specific sensitizer associated with one or more reactive species-generating photoinitiators. Also described are methods of polymerizing unsaturated monomers and curing an unsaturated oligomer/monomer mixture.
    Type: Grant
    Filed: December 26, 1997
    Date of Patent: June 6, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: John Gavin MacDonald, Ronald Sinclair Nohr
  • Patent number: 6057380
    Abstract: Compounds of formula I, II or III ##STR1## X is a divalent radical; Y is C.sub.1 -C.sub.6 aklylene, cyclohexylene or a direct bond;Ar.sub.1 is an aromatic radical as defined in claim 1,R.sub.1 and R.sub.2 are each independently the other, inter alia, a radical of formula ##STR2## in which p is zero or 1, or a radical of formula ##STR3## R.sub.3 is, inter alia, hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-C.sub.1 -C.sub.3 alkyl;R.sub.4 is, inter alia, C.sub.1 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.3 alkyl or phenyl;or an acid addition salt of a compound of formula I, II or III;are useful as photosensitive base catalysts in base crosslinking compositions.
    Type: Grant
    Filed: December 5, 1997
    Date of Patent: May 2, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jean-Luc Birbaum, Martin Kunz, Akira Kimura, Hisatoshi Kura, Hidetaka Oka, Hiroko Nakashima