Contacting Two Or More Solid Polymers Derived From Ethylenic Reactants Only With A Poly 1,2-epoxy-containing Reactant; Or Contacting A Solid Polymer Derived From Ethylenic Reactants Only With A Poly 1,2-epoxy-containing Reactant And Subsequently Contacting With An Additional Polymer Derived From Ethylenic Reactants Only Patents (Class 525/108)
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Patent number: 5135969Abstract: A composition suitable for use as a coating composition depositable by cationic electrodeposition which has improved edge protection capability containing, in addition to the conventional ingredients used in compositions for cationic electrocoat, such as an aqueous cationic resin, micro-resin particles of a size sufficient to be water dispersible which particles comprise an internally crosslinked polymer of (A) an active hydrogen containing monomer and (B) a monomer containing at least two active double bonds, which polymer further contains a cationic group in sufficient proportion to allow the micro-resin particle to be water dispersed.Type: GrantFiled: January 23, 1990Date of Patent: August 4, 1992Assignee: Shinto Paint Co., Ltd.Inventors: Minoru Tooyama, Akitoshi Shirasaka
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Patent number: 5130201Abstract: A vinylidene fluoride resin composition which comprises (A) 10 to 95 parts by weight of a vinylidene fluoride resin, (B) 1 to 80 parts by weight of a resin having a poor compatibility with said vinylidene fluoride resin (A), and (C) 1 to 30 parts by weight of a resin having an excellent compatibility with both said vinylidene fluoride resin (A) and said resin (B), total amount of said resins (A), (B) and (C) being 100 parts by weight. The film obtained by baking the composition of the present invention has the structure that the surface side is rich in the VdF resin, and the excellent adhesion to the substrate. Consequently, the film has the excellent chemical resistance, adhesion to a substrate, and the like.Type: GrantFiled: April 23, 1990Date of Patent: July 14, 1992Assignee: Daikin Industries, Ltd.Inventors: Tatsushiro Yoshimura, Nobuyuki Tomihashi, Akira Chida
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Patent number: 5128412Abstract: A removable adhesive composition comprising (i) 100 parts by weight of a copolymer (A) which is tacky at ordinary temperature, synthesized of 90 to 99.9% by weight of a nonfunctional vinyl type monomer (a) mainly composed of an acrylate or methacrylate ester having an alkyl group having 2 to 12 carbon atoms and 0.1 to 10% by weight of a functional vinyl type monomer (b) having one or more of a carboxyl group, a hydroxyl group, an amino group or an epoxy group in its molecule; (ii) 20 to 1,000 parts by weight of a copolymer (B) whose glass transition point is 10.degree. C. or less and also having a mean particle diameter of 0.5 to 300 .mu.m, synthesized of 90 to 99.9% by weight of a nonfunctional vinyl type monomer (a) mainly composed of acrylate or methacrylate ester having an alkyl group having 2 to 12 carbon atoms and 0.1 to 10% by weight of an .alpha.-monoolefinic carboxylic acid (c); and (iii) 0.Type: GrantFiled: May 14, 1990Date of Patent: July 7, 1992Assignee: Nichiban Company LimitedInventors: Hiroyasu Miyasaka, Yasuaki Kitazaki, Tetsuaki Matsuda, Junichi Kobayashi
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Patent number: 5098822Abstract: Disclosed is an antistatic layer for a plastic film having an antistatic layer comprising a reaction product of a water-soluble conductive polymer, a hydrophobic latex and an epoxy type hardener, characterized in that said hydrophobic latex comprises a hydrophobic polymer having at least one of an alkylene oxide chain and an amide group.Type: GrantFiled: December 6, 1990Date of Patent: March 24, 1992Assignee: Konica CorporationInventors: Noriki Tachibana, Yoichi Saito
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Patent number: 5098955Abstract: A thermosetting powder coating composition which has good stability, pigment dispersion and impact characteristics is disclosed. The composition comprises a co-reactable particle mixture of an acid group-containing acrylic polymer having a Tg in the range of -20.degree. C. to 30.degree. C., an acid group-containing acrylic polymer having a Tg in the range of 40.degree. C. to 100.degree. C. and a curing agent, therefor.Type: GrantFiled: October 1, 1990Date of Patent: March 24, 1992Assignee: PPG Industries, Inc.Inventor: Paul H. Pettit, Jr.
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Patent number: 5093391Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-90% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups;(c) 5-50% by weight, based on the weight of the binder of an acid functional monomeric, oligomeric or polymeric compound which may or may not contain hydroxyl functionality; andthe composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.Type: GrantFiled: June 15, 1990Date of Patent: March 3, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventors: Robert J. Barsotti, Lee R. Harper
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Patent number: 5091469Abstract: Disclosed are epoxy/polyamide adhesive compositions having improved flexibility containing a polyolefin and a maleated polypropylene. A typical epoxy/polyamide adhesive is bisphenol A/epichlorohydrin.Type: GrantFiled: June 28, 1990Date of Patent: February 25, 1992Assignee: Eastman Kodak CompanyInventors: Richard A. Miller, David J. Olsen
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Patent number: 5068153Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-90% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups; and(c) 0.1-7% by weight, based on the weight of the binder, of a phosphonium catalyst or a blend of a phosphonium catalyst and a tertiary amine catalyst which may or may not contain hydroxyl groups.Type: GrantFiled: October 11, 1989Date of Patent: November 26, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventors: Robert Barsotti, Lester S. Cohen
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Patent number: 5066750Abstract: Thermosettable vinyl ester resin compositions are prepared from polyepoxide compounds, optionally monoepoxide compounds, at least one of which contains a mesogenic or rigid rodlike moiety and a monounsaturated monocarboxylic acid. These vinyl ester resins can be mixed with polymerizable ethylenically unsaturated monomers which can, if desired, contain a mesogenic or rigid rodlike moiety.Type: GrantFiled: June 4, 1990Date of Patent: November 19, 1991Assignee: The Dow Chemical CompanyInventors: Robert E. Hefner, Jr., Paul M. Puckett, Jimmy D. Earls
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Patent number: 5057555Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-90% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups;5-50% by weight, based on weight of the binder, of a polymeric component containing multiple hydroxy groups; andthe composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.Type: GrantFiled: February 8, 1990Date of Patent: October 15, 1991Inventors: Donald A. White, Robert J. Barsotti, Patrick H. Corcoran, Lili W. Altschuler
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Patent number: 5043220Abstract: A substrate coated with a basecoat of a pigmented film-forming polymer and a clearcoat applied to the basecoat of a film-forming polymer wherein the clearcoat and/or the basecoat is a curable composition comprising(i) an acid-functional compound having an average of at least two carboxylic acid groups per molecule; and(ii) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhydride groups per molecule; and(iii) an epoxy-functional compound having an average of at least one epoxy group per molecule; and(iv) a hydroxy-functional compound having an average of at least two hydroxyl groups per molecule;wherein at least one of the compounds (i), (ii), (iii) or (iv) comprises a film forming polymer.Type: GrantFiled: September 25, 1989Date of Patent: August 27, 1991Assignee: The Sherwin-Williams CompanyInventors: Mohamad D. Shalati, James A. Marquart, Sandra H. Angelo, Rodney M. Harris
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Patent number: 5043366Abstract: A self-curing aqueous resin dispersion obtained by neutralizing a resin having at least one alicyclic epoxy group and at least two carboxyl groups in the molecule, with a base and dispersing the neutralized resin in water.Type: GrantFiled: February 16, 1990Date of Patent: August 27, 1991Assignee: Kansai Paint Co., Ltd.Inventor: Osamu Isozaki
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Patent number: 5037888Abstract: Thermoplastic elastomeric compositions of improved properties are prepared by cross-linking an ethylene/.alpha.,.beta.-unsaturated carboxylic acid, ester, or anhydride copolymer in the presence of a polyolefin using an epoxy compound catalyzed with a tertiary amine.Type: GrantFiled: November 9, 1989Date of Patent: August 6, 1991Assignee: Eastman Kodak CompanyInventor: Jeffrey J. Vanderbilt
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Patent number: 5017650Abstract: A resin composition comprising 100 parts by weight of a polyester composition comprised of(A) 5-95% by weight of an aromatic polyester, and(B) 95-5% by weight of a polyphenylene ether having a repeating unit of ##STR1## and/or a modified polyphenylene ether obtained by reacting 0.05-20% by weight of an active functional group containing monomer to said polyphenylene ether,(C) 0.05-30 parts by weight of an epoxy compound represented by the formula ##STR2## and (D) 1-60 parts by weight of an impact modifier.Type: GrantFiled: May 11, 1989Date of Patent: May 21, 1991Assignee: Toray Industries, Inc.Inventors: Kiyokazu Nakamura, Kiichi Kometani, Akihiko Koshino, Kenjiro Horiuchi
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Patent number: 4997720Abstract: Thermoplastic compositions and articles made therefrom which have a high receptivity toward automotive paints comprises the following components:2%-25% of a copolymer of an ethylenically unsaturated carboxylic acid and ethylene,3%-50% of an elastomer comprising an ethylene-alpha-olefin copolymer,1%-50% of a crystalline homopolymer or copolymer of propylene,5%-40% of polyethylene or a copolymer of ethylene and an alpha-olefin,2%-20% of an epoxy or phenoxy resin; andoptionally, up to 50% of an inorganic filler. Such articles, when injection molded, exhibit flexural moduli in the range of 100,000 to 200,000 psi and have excellent paintability, a broad range of stiffness values and high impact and tensile strengths suitable for automotive applications such as bumpers, facias and wheel covers.Type: GrantFiled: July 19, 1990Date of Patent: March 5, 1991Assignee: Dexter CorporationInventors: Edward Bourbonais, Davei Yu, Khemchand Nangrani
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Patent number: 4988548Abstract: A vulcanizable rubber composition comprising (1) 100 parts by weight of a polymer composition comprising(I) a vinylidene fluoride resin,(II) at least one rubber selected from the group consisting of acrylic rubbers, .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers and hydrides of .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers, said acrylic rubber consisting of (A) 30 to 99.9% by weight of an alkyl acrylate and/or an alkoxy-substituted alkyl acrylate, (B) 0.1 to 10% by weight of a crosslinkable monomer and (C) 0 to 70% by weight of another ethylenically unsaturated compound copolymerizable with (A) and (B) (the sum of (A), (B) and (C) is 100% by weight) and said .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubber consisting of (D) 10 to 60% by weight of an .alpha.,.beta.Type: GrantFiled: November 22, 1988Date of Patent: January 29, 1991Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Yasuhiko Takemura, Shinichiro Zen, Yoshiaki Zama, Hiroji Enyo
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Patent number: 4988767Abstract: A thermosetting powder coating composition which has good stability, pigment dispersion and impact characteristics is disclosed. The composition comprises a co-reactable particle mixture of an acid group-containing acrylic polymer having a Tg in the range of -20.degree. C. to 30.degree. C., an acid group-containing acrylic polymer having a Tg in the range of 40.degree. C. to 100.degree. C. and a curing agent, therefor.Type: GrantFiled: September 18, 1989Date of Patent: January 29, 1991Assignee: PPG Industries, Inc.Inventor: Paul H. Pettit, Jr.
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Patent number: 4975474Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-94% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups;(c) 1-40% by weight, based on the weight of the binder, of a self-stabilized dispersed resin; andthe composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.Type: GrantFiled: October 11, 1989Date of Patent: December 4, 1990Assignee: E. I. du Pont de Nemours and CompanyInventors: Robert J. Barsotti, Patrick H. Corcoran
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Patent number: 4966928Abstract: An epoxy resin based powder coating composition is disclosed, comprising an epoxy resin, a reaction product of dicyclopentadiene and maleic anhydride, and a cure accelerator.The coating composition may further comprise an aromatic acid anhydride based curing agent, an impact modifier and a surface smoothing agent.The coating composition has stable powder characteristic and provides good heat resistance and electrical insulation.Type: GrantFiled: August 17, 1988Date of Patent: October 30, 1990Assignee: Somar CorporationInventors: Katugi Kitagawa, Ichiro Akutagawa, Kazuya Ono
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Patent number: 4943605Abstract: An end dam nosing material useful for expansion joints and having high levels of bonding strength, tensile strength, compressive strength, flexural capabilities, resiliency, and resistance to chemical action is disclosed. The end dam nosing material of the present invention does not require the addition of external heat for curing. The end dam nosing material of the present invention comprises a mixture of a dipolymerized elastomer, an epoxy resin, a filler material and an amount of a curing agent effective to cure the epoxy resin and generate sufficient heat to cure the dipolymerized elastomer.Type: GrantFiled: February 29, 1988Date of Patent: July 24, 1990Assignee: MM Systems CorporationInventor: John D. Nicholas
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Patent number: 4931505Abstract: A coating composition comprising:(A) a fluorine-containing copolymer having a fluorine content based on fluoroolefin of at least 10% by weight, and(B) a fluorine-containing copolymer of a polyfluorocarbon chain-containing monomer with a hydrophilic group-containing monomer.Type: GrantFiled: October 4, 1988Date of Patent: June 5, 1990Assignee: Asahi Glass Company Ltd.Inventors: Nobuyuki Miyazaki, Masao Unoki, Seiji Munekata
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Patent number: 4908397Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-94% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups;(c) 1-40% by weight, based on the weight of the binder, of a self-stabilized dispersed resin; andthe composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.Type: GrantFiled: June 27, 1988Date of Patent: March 13, 1990Assignee: E. I. Du Pont de Nemours and CompanyInventors: Robert J. Barsotti, Patrick H. Corcoran
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Patent number: 4906677Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-90% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups; and(c) 0.1-7% by weight, based on the weight of the binder, of a phosphonium catalyst or a blend of a phosphonium catalyst and a tertiary amine catalyst which may or may not contain hydroxyl groups.Type: GrantFiled: June 27, 1988Date of Patent: March 6, 1990Assignee: E. I. Du Pont de Nemours & CompanyInventors: Robert Barsotti, Lester S. Cohen
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Patent number: 4895900Abstract: This invention provides a coating composition comprising a basic nitrogen-containing acrylic resin, a polyepoxy compound and a carboxyl group-containing acrylic resin.Type: GrantFiled: December 7, 1987Date of Patent: January 23, 1990Assignee: Kansai Paint Company, LimitedInventors: Hajime Sukejima, Hiroshi Iwai, Kozi Matsumoto
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Patent number: 4879337Abstract: A higher solid coating composition comprises a solid resin mixture of polyol resin and alkyletherified melamine resin, 0.2.about.10 parts by weight of an aliphatic sulfonic acid compound and 1.about.100 parts by weight of a non-aqueous polymer dispersion based on 100 parts by weight of the resin mixture. The non-aqueous polymer dispersion consists of (a) organic solvent component, (b) particle component insoluble in the component (a), and (c) particular dispersion stabilizer component soluble in the component (a) and capable of stably dispersing the component (b) into the component (a).Type: GrantFiled: November 2, 1987Date of Patent: November 7, 1989Assignee: Nippon Oil and Fats Co., Ltd.Inventors: Kishio Shibato, Masataka Kawamura
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Patent number: 4871807Abstract: Water-dilutable paint binders for the formulation of ecological stoving paints containing only minor quantities of organic solvents are described. The binders are partial condensation products of (A) a polycondensation, polymerization, or polyaddition resin as the film-forming polycarboxy compound (PC-component), and (B) an epoxy resin amine adduct (PH-component) carrying hydroxy groups and being water-insoluble under normal processing conditions. The products afford improved corrosion resistance and are particularly suited for the formulation of primers, intercoats (primer surfacers), and single coat paints.Type: GrantFiled: December 23, 1987Date of Patent: October 3, 1989Assignee: Vianova Kunstharz, A.G.Inventors: Werner Staritzbichler, Gert Dworak, Wolfgang Daimer
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Patent number: 4871803Abstract: The adhesive properties of a hot melt adhesive, comprising a base polymer and a tackifying resin, can be improved by introducing into the hot melt adhesive an epoxy adduct comprising the reaction product between a compound such as a polymer having at least one active hydrogen and an epoxy compound.Type: GrantFiled: February 3, 1988Date of Patent: October 3, 1989Assignee: H. B. FullerInventors: John M. Zimmel, Pamela M. Klinkenberg, William L. Bunnelle, Keith C. Knutson
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Patent number: 4871806Abstract: Curable compositions which comprise:(i) an acid-functional compound having an average of at least two carboxylic acid groups per molecule; and(ii) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhdyride groups per molecule; and(iii) an epoxy-functional compound having an average of at least one epoxy group per molecule; and(iv) a hydroxy-functional compound having an average of at least two hydroxyl groups per molecule;wherein at least one of the compounds (i), (ii), (iii) or (iv) comprises a film forming polymer.Type: GrantFiled: November 16, 1987Date of Patent: October 3, 1989Assignee: The Sherwin-Williams CompanyInventors: Mohamad D. Shalati, James A. Marquart
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Patent number: 4829124Abstract: A thermoplastic elastomer is described which comprises a blend of (a) a carboxylated butadieneacrylonitrile elastomer and (b) an ethylene/acrylic acid copolymer which has been at least partially neutralized with a metal ion, the blend of (a) and (b) having been dynamically crosslinked with an epoxy crosslinking agent having a minimum of 2 epoxy moieties per molecule.Type: GrantFiled: February 29, 1988Date of Patent: May 9, 1989Assignee: Armstrong World Industries, Inc.Inventor: Lawrence Clark
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Patent number: 4822654Abstract: A vulcanizable rubber composition comprising (1) 100 parts by weight of a polymer composition comprising(I) a vinylidene fluoride resin,(II) at least one rubber selected from the group consisting of acrylic rubbers, .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers and hydrides of .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers, said acrylic rubber consisting of (A) 30 to 99.9% by weight of an alkyl acrylate and/or an alkoxy-substituted alkyl acrylate, (B) 0.1 to 10% by weight of a crosslinkable monomer and (C) 0 to 70% by weight of another ethylenically unsaturated compound copolymerizable with (A) and (B) (the sum of (A), (B) and (C) is 100% by weight) and said .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubber consisting of (D) 10 to 60% by weight of an .alpha.,.beta.Type: GrantFiled: March 10, 1988Date of Patent: April 18, 1989Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Yasuhiko Takemura, Shinichiro Zen, Yoshiaki Zama, Hiroji Enyo
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Patent number: 4818601Abstract: A rubber-cord composite body used for cord reinforcing rubber articles is produced by embedding fiber cords treated with an epoxy compound and further with a particular resorcin-formaldehyde-rubber latex adhesive into a particular rubber composition containing 0.5.about.10 parts by weight of each of a bismaleimide compound and sulfur.Type: GrantFiled: February 9, 1988Date of Patent: April 4, 1989Assignee: Bridgestone CorporationInventors: Michio Itoh, Tadashi Saito, Nobuyuki Okamura, Hisao Yamamoto, Yutaka Iseda, Hirohiko Takagi
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Patent number: 4789697Abstract: Into a material based on a caoutchouc-type or caoutchouc-containing mixture for producing hard rubber, there is incorporated a pre-mix containing high-strength organic fibers and a liquid hardenable plastic material. The high-strength and temperature resistant material thus obtained is particularly suitable for the attenuation of noise in combustion engines when heavy-weight fillers are also added to such material. Engine components like, for example, valve covers, timing gear covers and oil pans can be manufactured from this material.Type: GrantFiled: September 9, 1985Date of Patent: December 6, 1988Assignee: Semperit AGInventors: Josef Affenzeller, Wolf-Dieter Jost
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Patent number: 4777213Abstract: Promoters for a crosslinking reaction involved in the curing of a system comprising crosslinkable polymers are bound to polymeric microparticles having a diameter of about 0.01 to 6 microns prepared by polymerizing a mixture of ethylenically unsaturated monomers. The microparticles carrying the crosslinking reaction promoter may be incorporated to coating compositions, printing inks, sealants, adhesives and other polymeric products in place of conventional crosslinking reaction promoters.Type: GrantFiled: March 2, 1987Date of Patent: October 11, 1988Assignee: Nippon Paint Co., Ltd.Inventors: Kazunori Kanda, Shinichi Ishikura, Keizou Ishii, Akio Kashihara
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Patent number: 4773624Abstract: Into a material based on a caoutchouc-type or caoutchouc-containing mixture for producing hard rubber, there is incorporated a pre-mix containing high-strength organic fibers and a liquid hardenable plastic material. The high-strength and temperature resistant material thus obtained is particularly suitable for the attenuation of noise in combustion engines when heavy-weight fillers are also added to such material. Engine components like, for example, valve covers, timing gear covers and oil pans can be manufactured from this material.Type: GrantFiled: April 28, 1986Date of Patent: September 27, 1988Assignee: Semperit AktiengesellschaftInventors: Josef Affenzeller, Wolf-Dieter Jost
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Patent number: 4772645Abstract: Storage-stable, thermally-curable, one-part epoxy resin compositions comprising a curable opoxide resin; a curative amount of an aliphatic or non-aromatic cyclic polyol having about 2 to 18 carbon atoms, at least two hydroxy groups of said polyol being primary or secondary, and said polyol being free of strong acid groups, and free of electron-withdrawing substituents and large groups which cause steric hindrance in the .alpha.-position in relation to the carbon atoms attached to the methylol groups of the polyol; and a catalytic amount of an imidazole compound.Type: GrantFiled: December 11, 1987Date of Patent: September 20, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kent S. Tarbutton, Janis Robins, John C. Tangen
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Patent number: 4771106Abstract: An adhesive resin composition is described, comprising: (A) a thermoplastic copolyester resin prepared from (1) a dicarboxylic acid component comprising from 40 to 100 mol % of terephthalic acid and from 0 to 60 mol % of other aromatic dicarboxylic acid and (2) a low molecular weight glycol component comprising from 40 to 100 mol % of 1,4-butanediol and from 0 to 60 mol % of diethylene glycol or 1,6-hexanediol and further from 0 to 10 mol %, based on the total carboxylic acid, of polytetramethylene glycol having a molecular weight of from 600 to 6,000, which has a melting point of from 90.degree. to 160.degree. C. and a reduced viscosity of at least 0.5; and (B) an ethylene copolymer having at least one functional group selected from an epoxy group, a carboxylic acid group, and a dicarboxylic anhydride group; and if desired, (C) a thermoplastic resin other than the resin (A), and if further desired, (D) a polyfunctional epoxy compound.Type: GrantFiled: September 21, 1987Date of Patent: September 13, 1988Assignees: Sumitomo Chemical Co., Ltd., Toyobo Co., Ltd.Inventors: Tadayuki Ohmae, Mitsuyuki Okada, Hiroshi Nagai, Yutaka Mizumura
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Patent number: 4771085Abstract: A printable dielectric composition comprising finely divided particles of talc and/or mica dispersed in a curable liquid composition containing acrylated rubber modified epoxy resin oligomer, acrylated polydiene oligomer and alkyl acrylate.Type: GrantFiled: December 3, 1987Date of Patent: September 13, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Christina N. Lazaridis
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Patent number: 4751267Abstract: A high solids coating composition comprises a low molecular weight polymeric blend of acrylic polymer, polyester polymer, and amine cross-linking resin. The acrylic and polyester polymers contain primary hydroxyl groups adapted to coreact and cross-link with active amine cross-linking resin such as aminoplast resins. All of the polymers have a number average molecular weight below about 3000.Type: GrantFiled: May 1, 1987Date of Patent: June 14, 1988Assignee: The Glidden CompanyInventor: Wellington F. Berghoff
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Patent number: 4727097Abstract: A highly reactive, water-absorptive resin is prepared by (1) impregnating a highly water-absorptive resin having carboxyl or carboxylate groups and a water content of 50 percent by weight or lower with a hydrophilic polymer or monomer having a reactive group and (2) polymerizing said monomer or crosslinking said polymer with a crosslinking agent.Type: GrantFiled: March 4, 1986Date of Patent: February 23, 1988Assignee: Kao CorporationInventors: Takatoshi Kobayashi, Harumasa Yamasaki, Yuzo Sumida
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Patent number: 4720524Abstract: An adhesive resin composition is described, comprising: (A) a thermoplastic copolyester resin prepared from (1) a dicarboxylic acid component comprising from 40 to 100 mol % of terephthalic acid and from 0 to 60 mol % of other aromatic dicarboxylic acid and (2) a low molecular weight glycol component comprising from 40 to 100 mol % of 1,4-butanediol and from 0 to 60 mol % of diethylene glycol or 1,6-hexanediol and further from 0 to 10 mol %, based on the total carboxylic acid, of polytetramethylene glycol having a molecular weight of from 600 to 6,000, which has a melting point of from 90.degree. to 160.degree. C. and a reduced viscosity of at least 0.5; and (B) an ethylene copolymer having at least one functional group selected from an epoxy group, a carboxylic acid group, and a dicarboxylic anhydride gruop; and if desired, (C) a thermoplastic resin other than the resin (A), and if further desired, (D) a polyfunctional epoxy compound.Type: GrantFiled: August 27, 1986Date of Patent: January 19, 1988Assignees: Sumitomo Chemical Company, Ltd., Toyobo Co., LtdInventors: Tadayuki Ohmae, Mitsuyuki Okada, Hiroshi Nagai, Yutaka Mizumura
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Patent number: 4716200Abstract: A high solids coating composition comprises a low molecular weight polymeric blend of acrylic polymer, polyester polymer, and amine cross-linking resin. The acrylic and polyester polymers contain primary hydroxyl groups adapted to coreact and cross-link with active amine cross-linking resin such as aminoplast resins. All of the polymers have a number average molecular weight below about 3000.Type: GrantFiled: March 6, 1986Date of Patent: December 29, 1987Assignee: The Glidden CompanyInventor: Wellington F. Berghoff
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Patent number: 4684677Abstract: Rapid air drying thermosetting solvent solution primer compositions are disclosed which comprise volatile polar organic solvent having dissolved therein a fluorocarbon polymer in an amount of from 20% to 45% of total resin solids, a solvent-soluble, hydroxy-functional copolymer of monoethylenically unsaturated monomers containing from 5% to 30% of hydroxy-functional monoethylenic monomer in an amount of from 0.7 to 1.5 parts of hydroxy-functional copolymer per part of fluorocarbon resin, a resinous polyepoxide in an amount providing from 0.1 to 0.6 part of polyepoxide per part of hydroxy-functional copolymer, and a curing agent reactive with hydroxy functionality, preferably an aminoplast resin, for curing the hydroxy-functional acrylic copolymer and the polyepoxide. The primer is pigmented with inorganic pigment in a weight ratio with respect to the resin solids of from 0.2:1 to 0.8:1.Type: GrantFiled: February 13, 1986Date of Patent: August 4, 1987Assignee: DeSoto, Inc.Inventors: Clark A. Higginbotham, James W. Wichmann
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Patent number: 4683263Abstract: Disclosed is a metal vessel comprising an upper member and a lower member, each consisting of a coated cup-shaped formed metal body and a circumferential side seam being formed by lap-bonding the open ends of the upper and lower members to each other through an adhesive, wherein said coated cup-shaped formed metal body is composed of a metal blank having a coating of a vinyl chloride resin having a vinyl chloride unit content of 30 to 97% by weight and a glass transition temperature of at least 40.degree. C.Type: GrantFiled: May 7, 1985Date of Patent: July 28, 1987Assignee: Toyo Seikan Kaisha Ltd.Inventors: Kazuo Taira, Akihiko Morofuji, Seishichi Kobayashi, Hiroshi Ueno
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Patent number: 4672092Abstract: Curable epoxide resin compositions having improved mechanical and fire-resistant properties comprise an epoxide resin adducted with an elastomer polymer including a chlorinated monomer such as a chlorinated butadiene, vinyl chloride or vinylidene chloride and an unsaturated carboxylic acid monomer such as acrylic acid or methacrylic acid. The composition may be produced by stirring an aqueous latex of the polymer into the liquid resin, with heating if necessary. The compositions can be cured with conventional curing agents and can replace ordinary epoxide resins in most applications without any change in procedure.Type: GrantFiled: November 20, 1984Date of Patent: June 9, 1987Assignee: Scott Bader Company LimitedInventor: Robert S. Whitehouse
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Patent number: 4659778Abstract: A polyester composition having an average molecular weight of greater than 500 comprising a most prevalent compound having a main polyester chain containing at least 17 and fewer than 52 carbon atoms and at least 6 and fewer than 18 oxygen atoms, at least 52 weight percent of the molecules of said composition having a molecular weight within 50% of the average molecular weight of the composition. The polyester composition desirably contains at least 1.6 equivalents of unreacted hydroxy groups or at least 1.6 equivalents of unreacted carboxy groups per mole. The composition contains at least four equivalents of ester links in the main chains of the molecules per mole.The composition of the present invention is obtained by the method of the invention wherein alternating series of reactions are each driven essentially to completion where the final molecule of each reaction provides the only available reaction site for the next alternate monomer reaction.Type: GrantFiled: April 21, 1986Date of Patent: April 21, 1987Assignee: NL Chemicals, Inc.Inventor: Roy C. Williams
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Patent number: 4588778Abstract: Cured polyfunctional epoxy resins including tris(hydroxyphenyl)methane triglycidyl ether are toughened by addition of polybrominated polymeric additives having an EE below 1500 to the pre-cure composition. Carboxy-terminated butadiene-acrylonitrile rubber is optionally present in the pre-cure mixture as such or as a pre-formed copolymer with other reactants. Reinforced composites, particularly carbon-reinforced composites, of these resins are disclosed and shown to have improved toughness.Type: GrantFiled: August 15, 1985Date of Patent: May 13, 1986Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Zohar Nir, William J. Gilwee, Jr.
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Reinforcing agents for elastomers, the production of reinforced elastomers and reinforced elastomers
Patent number: 4585811Abstract: Elastomers reinforced with fibrous composite materials and having improved properties are obtained if the strengthening means used are composite materials based on reinforcing fibres and reactive resins which are coated with adhesion promoters based on polyisocyanates.Type: GrantFiled: July 31, 1984Date of Patent: April 29, 1986Assignee: Bayer AktiengesellschaftInventors: Lothar Preis, Rudolf Schmidt, Josef Esser, Hans Magg -
Patent number: 4578425Abstract: An adhesive is disclosed for use in flexible circuitry, laminates and electrical products. The adhesive has improved flexibility and adhesive properties. It may be applied in solution form or may be cast as a free-standing film which is later heated and compressed to give adhesive properties. The adhesive comprises a phenolaldehyde resin or other phenolic resin, an epoxy resin and an elastomer.Type: GrantFiled: February 13, 1985Date of Patent: March 25, 1986Assignee: Schenectady Chemicals, Inc.Inventor: Michael Santorelli
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Patent number: 4578315Abstract: An adhesive is disclosed for use in flexible circuitry, laminates and electrical products. The adhesive has improved flexibility and adhesive properties. It may be applied in solution form or may be cast as a free-standing film which is later heated and compressed to give adhesive properties. The adhesive comprises a phenol-aldehyde resin or other phenolic resin, an epoxy resin and an elastomer.Type: GrantFiled: August 15, 1985Date of Patent: March 25, 1986Assignee: Schenectady Chemicals Inc.Inventor: Michael Santorelli
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Patent number: 4576721Abstract: Miscible blends of poly-2-oxazolines and thermoplastic polymers are disclosed herein. These blends exhibit a single glass transition point indicative of a miscible blend. The blends of this invention are useful as membranes, particularly separation membranes for mixtures of organic compounds or organic compounds and water and a perevaporation process.Type: GrantFiled: May 21, 1985Date of Patent: March 18, 1986Assignee: The Dow Chemical CompanyInventors: Kathleen M. McCreedy, Henno Keskkula, James C. Pawloski, Edward H. Yonkers