With Polycarboxylic Acid Or Derivative As Reactant Patents (Class 528/176)
  • Patent number: 8765012
    Abstract: A thermosetting composition including an organic solvent, a liquid crystalline thermoset oligomer, and either a crosslinking agent or an epoxy resin or both is disclosed. A printed circuit board which includes the thermosetting composition is also disclosed. The printed circuit board is produced by impregnating the thermosetting composition into a reinforcing material.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: July 1, 2014
    Assignees: Samsung Electronics Co., Ltd., Samsung Electro-Mechanics Co., Ltd., Samsung Fine Chemicals Co., Ltd.
    Inventors: Myung Sup Jung, Chung Kun Cho, Kwang Hee Kim, Kalinina Fedosya, Man Jong Kim, Tae Jun Ok
  • Patent number: 8765161
    Abstract: The invention relates to novel monomers of Formula (I) useful for preparation of phase-separated biocompatible polymers or polymer compositions. These polymers or polymer compositions may be bioresorbable and/or biodegradable and have desirable mechanical properties, such as fracture and/or fatigue toughness, which have not been a primary design criteria for such polymers previously. The polymers or polymer compositions are useful in a variety of medical applications, such as in the fabrication of medical devices. Therefore, methods for preparing these polymers or polymer compositions and medical devices are also encompassed by this disclosure.
    Type: Grant
    Filed: July 31, 2010
    Date of Patent: July 1, 2014
    Assignee: Rutgers, The State University of New Jersey
    Inventors: Joachim B. Kohn, Durgadas Bolikal, Ramiro Rojas
  • Patent number: 8741399
    Abstract: The birefringent film of the present invention contains an aromatic polyester having a repeating unit represented by the following general formula (1). In the general formula (1), A(s), B(s), C(s), and D(s) are each independently represent a group selected from a halogeno group, an alkyl group which has 1 to 6 carbon atoms, and an aryl group. Also, a and b each represent an integer of 0 to 4, and c and d each represent an integer of 0 to 3. R1 represents a hydrogen atom, or an alkyl group which has 1 to 10 carbon atoms. R2 represents an alkyl group which has 2 to 10 carbon atoms. R3 to R6 each independently represent a group or atom selected from a hydrogen atom, a halogeno group, an alkyl group which has 1 to 6 carbon atoms, and an aryl group. Furthermore, l and m each represent an integer of 2 or more.
    Type: Grant
    Filed: March 25, 2009
    Date of Patent: June 3, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Tomoyuki Hirayama, Toshiyuki Iida, Yutaka Ohmori, Satoru Suzuki, Miyuki Kurogi, Hisae Shimizu
  • Patent number: 8722813
    Abstract: A resin composition containing: an ester compound including a carboxylic acid ester obtained by using (1) a monohydric alcohol having an alkyl group having 1 to 4 carbon atoms; (2) a dicarboxylic acid having an alkylene group having 2 to 4 carbon atoms; and (3) a dihydric alcohol having an alkylene group having 2 to 6 carbon atoms, the ester compound having an acid value of 1.00 mgKOH/g or less, a hydroxyl value of 5.0 mgKOH/g or less, and a number-average molecular weight of from 300 to 700; and an aliphatic polyester. Since the resin composition of the present invention inhibits the generation of volatile compounds, the resin composition can be suitably used in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.
    Type: Grant
    Filed: August 18, 2011
    Date of Patent: May 13, 2014
    Assignee: Kao Corporation
    Inventors: Hiroki Sawada, Masahiro Mori
  • Patent number: 8722843
    Abstract: Disclosed is a material for fiber manufacturing comprising a liquid crystal polyester satisfying the following requirements (a) and (b): (a) the weight-average molecular weight is equal to or less than 30000 and the polydispersity is equal to or less than 2.5; and (b) the melt viscosity measured at 360° C. with conditions of a nozzle pore diameter of 0.5 mm and a shear velocity of 1000 s?1 using a flow feature testing machine is equal to or less than 70 Pa·s.
    Type: Grant
    Filed: November 19, 2012
    Date of Patent: May 13, 2014
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tomoya Hosoda, Mitsuo Maeda, Satoshi Okamoto
  • Patent number: 8716428
    Abstract: An fluorinated polyester compound is disclosed. The fluorinated polyester compound can be made by combining ingredients comprising a hydroxyl terminated polyphenyl ether; a carboxylic acid terminated perfluoropolyether; an acid catalyst; and a solvent. A coating solution comprising the fluorinated polyester compound and a method of coating a substrate therewith are also disclosed.
    Type: Grant
    Filed: April 10, 2012
    Date of Patent: May 6, 2014
    Assignee: Xerox Corporation
    Inventors: Jin Wu, Lanhui Zhang, Lin Ma, David W. Martin
  • Patent number: 8709693
    Abstract: A polyester resin for a toner is a polycondensate of a dicarboxylic acid component and an alcohol component including rosin diol that is represented by the following formula (1), and has a weight average molecular weight (Mw) of from 40000 to 150000, and a molecular weight distribution (Mw/Mn) of from 12 to 25: wherein, R1 and R2 each independently represents hydrogen or a methyl group; L1, L2, and L3 each independently represents a divalent linking group selected from a group consisting of a carbonyl group, a carboxyl group, an ether group, a sulfonyl group, a chain-like alkylene group which may have a substituent, a cyclic alkylene group which may have a substituent, an arylene group which may have a substituent, and combinations thereof, and L1 and L2 or L1 and L3 may form a ring; and A1 and A2 represent a rosin ester group.
    Type: Grant
    Filed: September 11, 2012
    Date of Patent: April 29, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Sumiaki Yamasaki, Yuki Sasaki
  • Patent number: 8709692
    Abstract: A polyester resin for a toner is a polycondensate of a carboxylic acid component and an alcohol component including rosin diol that is represented by the following formula (1) and has an alicyclic structure (alicyclic alcohol), wherein R1 and R2 each independently represents hydrogen or a methyl group, L1 represents a divalent linking group having an alicyclic structure, L2 and L3 each independently represents a divalent linking group selected from a group consisting of a carbonyl group, a carboxyl group, an ether group, a sulfonyl group, a chain-like alkylene group which may have a substituent, a cyclic alkylene group, a phenylene group, and combinations thereof, and A1 and A2 represent a rosin ester group, provided that a divalent linking group having the alicyclic structure represented by L1 may be a divalent linking group having an alicyclic structure formed through linking with any of R1, R2, L2 or L3.
    Type: Grant
    Filed: September 5, 2012
    Date of Patent: April 29, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Emi Miyata, Sumiaki Yamasaki, Yuki Sasaki, Satoshi Hiraoka, Hirofumi Shiozaki
  • Patent number: 8703252
    Abstract: A multi-layer stretched film has 251 or more alternating layers which consist of first layers and second layers, wherein the first layers are made of a polyester which contains (i) 5 to 50 mol % of a naphthoic acid component as a dicarboxylic acid component and (ii) a diol having an alkylene group with 2 to 10 carbon atoms as a diol component; and the second layers are made of a thermoplastic resin having an average refractive index of 1.50 to 1.60 and differences in refractive index among a uniaxial stretching direction, a direction orthogonal to the uniaxial stretching direction and a film thickness direction of 0.05 or less before and after stretching, and the film has specific reflectance characteristics for a P polarization component and an S polarization component.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: April 22, 2014
    Assignee: Teijin Limited
    Inventors: Taro Oya, Mitsumasa Ono, Tetsuo Yoshida
  • Patent number: 8703899
    Abstract: The present invention relates to a method for producing a polyester, containing conducting a transesterification reaction of at least one compound selected from compounds represented by the following formulae (1) to (3) with a diol compound in the presence of a catalyst: wherein Ar is a divalent aromatic hydrocarbon group or the like; R1 is CX1Y1R4; R2 is a hydrogen atom or CX2Y2R5; R3 is a hydrogen atom or CX3Y3R6; R7 is a perfluoroalkylene group having 1 to 5 carbon atoms; X1 to X3 are a hydrogen atom, a fluorine atom or Rf; Y1 to Y3 are a fluorine atom or Rf; R4 to R6 are a fluorine atom, Rf, ORf or the like; and Rf is a fluoroalkyl group having 1 to 4 carbon atoms.
    Type: Grant
    Filed: August 30, 2013
    Date of Patent: April 22, 2014
    Assignee: Asashi Glass Company Limited
    Inventors: Jumpei Nomura, Hidekazu Okamoto, Atsushi Fujimori, Takashi Okazoe
  • Patent number: 8695752
    Abstract: Deep-drawn membranes formed of polyester or polycarbonate films, comprising units of Formula (I) and (II), useful for acoustic signal converters as microphones and speakers. The film can be produced by thermoplastic processes or solvent cast processes.
    Type: Grant
    Filed: January 28, 2010
    Date of Patent: April 15, 2014
    Assignee: tesa SE
    Inventors: Kerstin Metzler, Bernhard Müssig, Frank Virus
  • Publication number: 20140100342
    Abstract: Disclosed in the present invention are a fluorine-containing polymerizable compound of the general formula (1) and a polymer compound obtained therefrom: where A represents a single bond, an oxygen atom, a sulfur atom, SO2, CH2, CO, C(CH3)2, C(CH3)(CH2CH3), C(CF3)2, C(CH3)(C6H5), CH2—C6H4—CH2 or a divalent organic group obtained by elimination of two hydrogen atoms from benzene, biphenyl, naphthalene, cyclohexene or fluorene; and a and b each independently represent an integer of 0 to 2 and satisfy a relationship of 1?a+b?4. The thus-obtained polymer compound combines adequate hydrophilicity and high transparency with low water adsorption of fluorine-containing compound.
    Type: Application
    Filed: May 29, 2012
    Publication date: April 10, 2014
    Applicant: Central Glass Company, Limited
    Inventors: Junya Nakatsuji, Makoto Matsuura, Kazuhiro Yamanaka
  • Publication number: 20140072912
    Abstract: Processes for preparing polyester resins as toner production components. The processes include reacting an organic diol and a cyclic alkylene carbonate to produce carbon dioxide (CO2) and a polyalkoxy diol. The carbon dioxide is reacted with an alkylene glycol or alkylene oxide to produce additional cyclic alkylene carbonate having the same chemical structure as the cyclic alkylene carbonate used to produce the polyalkoxy diol. The additional cyclic alkylene carbonate is added with the cyclic alkylene carbonate used to produce the polyalkoxy diol. The polyalkoxy diol can be reacted with an organic diacid or diester in preparing a polyester resin. To prepare a toner, the polyester resin can be contacted with at least one toner production component.
    Type: Application
    Filed: September 12, 2012
    Publication date: March 13, 2014
    Applicant: XEROX CORPORATION
    Inventor: Guerino G. Sacripante
  • Patent number: 8663889
    Abstract: A polyester resin for a toner containing: a repeating unit derived from a dicarboxylic acid component; and a repeating unit derived from a dial component represented by Formula (1): wherein each of R1 and R2 independently represents a hydrogen atom or a methyl group, each of L1, L2 and L3 independently represents a divalent linking group selected from the group consisting of carbonyl groups, ester groups, ether groups, sulfonyl groups, substituted or unsubstituted chained alkylene groups, substituted or unsubstituted cyclic alkylene groups, substituted or unsubstituted arylene groups, and combinations thereof, L1 and L2 or L1 and L3 optionally forms a ring, each of A1 and A2 independently represents a rosin ester group, and the acid value is from 3 mgKOH/g to 30 mgKOH/g.
    Type: Grant
    Filed: September 25, 2012
    Date of Patent: March 4, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Sumiaki Yamasaki, Satoshi Hiraoka, Yuki Sasaki, Susumu Yoshino, Hirotaka Matsuoka
  • Publication number: 20140051802
    Abstract: Methods for performing a condensation reaction are disclosed. Specifically, various methods for the production of highly-pure bisphenol-A are disclosed in which an attached promoter ion exchange resin catalyst system is combined with a solvent crystallization step.
    Type: Application
    Filed: May 2, 2012
    Publication date: February 20, 2014
    Applicant: SABIC INNOVATIVE PLASTICS IP B.V.
    Inventors: Johannes De Brouwer, Paulus Johannes Maria Eijsbouts
  • Patent number: 8652731
    Abstract: An electrostatic image developing toner includes (A) an amorphous polyester resin containing at least a repeating unit derived from a dicarboxylic acid component and a repeating unit derived from a dialcohol component represented by the specific formula, and (B) an amorphous polyester resin differing in the weight average molecular weight from the amorphous polyester resin (A), wherein the difference (absolute value) in the weight average molecular weight between the amorphous polyester resin (A) and the amorphous polyester resin (B) is from about 30,000 to about 100,000.
    Type: Grant
    Filed: September 25, 2012
    Date of Patent: February 18, 2014
    Assignee: Fuji Xerox Co., Ltd
    Inventors: Yuki Sasaki, Sumiaki Yamasaki, Satoshi Hiraoka, Susumu Yoshino, Hirotaka Matsuoka
  • Publication number: 20140030341
    Abstract: Polymers, microspheres, and associated methods are presented for the treatment of chronic and acute pain. An anhydride polymer comprising a biodegradable backbone that comprises one or more pendant residues of a non-steroidal anti-inflammatory (NSAID). NSAIDs may be incorporated in to the polymers as pendant groups that are not part of the polymer backbone. The polymer comprises repeating units that form the biodegradable backbone, wherein in each repeating unit comprises a pendant residue of the NSAID.
    Type: Application
    Filed: April 6, 2012
    Publication date: January 30, 2014
    Applicant: RUTGERS, THE STATE UNIVERSITY OF NEW JERSEY
    Inventors: Kathryn E. Uhrich, Roselin Rosario-Melendez
  • Patent number: 8628902
    Abstract: A polyester resin for a toner containing: a repeating unit derived from a dicarboxylic acid component; and a repeating unit derived from a diol component represented by Formula (1): wherein each of R1 and R2 independently represents a hydrogen atom or a methyl group, each of L1, L2 and L3 independently represents a divalent linking group selected from the group consisting of carbonyl groups, ester groups, ether groups, sulfonyl groups, substituted or unsubstituted chained alkylene groups, substituted or unsubstituted cyclic alkylene groups, substituted or unsubstituted arylene groups, and combinations thereof, L1 and L2 or L1 and L3 optionally forms a ring, and each of A1 and A2 independently represents a rosin ester group.
    Type: Grant
    Filed: November 15, 2011
    Date of Patent: January 14, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Sumiaki Yamasaki, Satoshi Hiraoka, Yuki Sasaki, Susumu Yoshino, Hirotaka Matsuoka
  • Patent number: 8609802
    Abstract: Disclosed are a production method for a wholly aromatic liquid crystalline polyester resin, a wholly aromatic liquid crystalline polyester resin produced using the method, and a compound of the wholly aromatic liquid crystalline polyester resin. The disclosed production method for a wholly aromatic liquid crystalline polyester resin comprises the steps of synthesizing a wholly aromatic liquid crystalline polyester resin by synthesizing a wholly aromatic liquid crystalline polyester prepolymer by a condensation polymerization of a monomer and then reducing the pressure inside a reaction vessel containing the synthesized prepolymer at a predetermined internal pressure reduction rate of the reaction vessel.
    Type: Grant
    Filed: January 12, 2011
    Date of Patent: December 17, 2013
    Assignee: Samsung Fine Chemicals Co., Ltd.
    Inventors: Hyun Min Kim, Jong Hwa Yun, Mahn Jong Kim
  • Patent number: 8598300
    Abstract: The invention provides an amorphous polyester resin that can sufficiently achieve the reciprocal performance properties of hot offset resistance and cold offset resistance, which is a major issue for a toner for electrostatic image development, while allowing adequate blocking resistance to be obtained, as well as a binder resin for toner for electrostatic image development, and an amorphous polyester resin production method, the amorphous polyester resin being obtained by reaction between a polybasic carboxylic acid compound and a polyhydric alcohol, wherein the polybasic carboxylic acid compound comprises (a) the reaction product between an aromatic polybasic carboxylic acid compound and a C2-4 glycol at 60 mol % or greater based on the total amount of the polybasic carboxylic acid compound, and the amorphous polyester resin has a glass transition point of 55° C. to 75° C. and a weight-average molecular weight of 10,000 to 50,000.
    Type: Grant
    Filed: April 23, 2010
    Date of Patent: December 3, 2013
    Assignee: Nicca Chemical Co., Ltd.
    Inventors: Tatsuhiro Hishida, Koji Ogawa, Yasumichi Moriyama, Masaaki Hosoda, Kazuo Tanabe
  • Patent number: 8586183
    Abstract: A laser composition comprises a combination of: (a) from more than 45 to less than 94 weight percent of a crystalline or semi-crystalline thermoplastic polyester component selected from poly(butylene terephthalate), poly(ethylene terephthalate), poly(butylene terephthalate) copolymers poly(ethylene terephthalate) copolymers, and combinations thereof; (b) from greater than 6 to less than 25 weight percent of an amorphous thermoplastic poly(ester) copolymer, poly(ester-carbonate), or combination thereof; (c) optionally, from 1 to 30 weight percent of a filler; and (d) optionally, from 0.01 to 5 weight percent of an antioxidant, mold release agent, colorant, stabilizer, or a combination thereof; wherein an article having a 2 mm thickness and molded from the composition has (i) a near infrared transmission at 960 nanometers of greater than 30 percent and (ii) a Vicat softening temperature of at least 170° C.
    Type: Grant
    Filed: January 13, 2011
    Date of Patent: November 19, 2013
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Tony Farrell, Johannes Hubertus G. M. Lohmeijer
  • Patent number: 8580908
    Abstract: Reclaiming cured elastomer material by mixing the cured elastomer as crumbs or chips with a devulcanization-aiding chemical composition, and devulcanizing the cured material by applying a shear-stress deformation to the mixture of the crumbs or chips with a devulcanization-aiding chemical while performing a mechanical disintegration of the cured elastomer into fine-ground crumbs under controllable temperature not exceeding about 90 degrees C.
    Type: Grant
    Filed: November 5, 2012
    Date of Patent: November 12, 2013
    Inventor: Lev Beirakh
  • Patent number: 8568950
    Abstract: There is provided a polyester resin for a toner, including: a polycondensate of a polyvalent carboxylic acid component and a polyhydric alcoholic component, wherein the polyhydric alcoholic component contains a rosin diol represented by the following Formula (1) and a content of the rosin diol is 80 mole % to 100 mole % based on the total polyhydric alcoholic component. wherein, each of R1 and R2 independently represents a hydrogen atom or a methyl group; L1 represents a divalent linking group having the following Formula (I); each of L2 and L3 independently represents a divalent linking group selected from the group consisting of carbonyl groups, carboxyl groups, ether groups, sulfonyl groups, substituted or unsubstituted chained alkylene groups, substituted or unsubstituted cyclic alkylene groups, substituted or unsubstituted arylene groups, and combinations thereof; and each of A1 and A2 independently represents a rosin ester group.
    Type: Grant
    Filed: September 25, 2012
    Date of Patent: October 29, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hirofumi Shiozaki, Sumiaki Yamasaki, Satoshi Hiraoka, Yuki Sasaki, Susumu Yoshino, Hirotaka Matsuoka, Emi Miyata
  • Publication number: 20130281652
    Abstract: The present invention relates to compounds of formula I, which are functionalized phenolic compounds, and polymers formed from the same. Ar—[O—(X)p—R?]q??I Polymers formed from the functionalized phenolics are expected to have controllable degradation profiles, enabling them to release an active component over a desired time range. The polymers are also expected to be useful in a variety of medical applications.
    Type: Application
    Filed: October 17, 2012
    Publication date: October 24, 2013
    Inventor: Rao S. Bezwada
  • Patent number: 8524855
    Abstract: Environmentally-friendly, biodegradable polyol:carboxylic acid polyester solid-phase products may be produced utilizing microwave heating. In this process, a di- or tricarboxylic acid is reacted with a polyol such as a glycerol or a sugar alcohol, or an ester thereof with the application of heating by microwave energy. Sufficient microwave heating is provided to esterify the polyol with the carboxylic acids, while removing as steam the water by-product which is generated during the reaction. The polyesters so-produced are resistant to high temperatures and solvents, and may by cured and/or molded.
    Type: Grant
    Filed: May 16, 2012
    Date of Patent: September 3, 2013
    Assignee: The United States of America, as represented by the Secretary of Agriculture
    Inventors: Brent Tisserat, Ronald A. Holser, Rogers E. Harry-O'Kuru
  • Patent number: 8487068
    Abstract: The present invention provides a method for producing a polybenzoxazole precursor having reduced contents of residual aprotic polar solvent and residual halogen without discharging a large amount of waste water during purification. The present invention specifically relates to a method for producing a polybenzoxazole precursor, which comprises synthesizing a polybenzoxazole precursor in an aprotic polar solvent, adding and mixing water and a water-insoluble solvent with the resulting polybenzoxazole precursor solution to still stand the solution, and then separating a water layer from the solution to reduce a content of impurities remaining in the polybenzoxazole precursor.
    Type: Grant
    Filed: August 30, 2012
    Date of Patent: July 16, 2013
    Assignee: Toho Chemical Industry Co., Ltd.
    Inventor: Naoya Kutsuzawa
  • Patent number: 8450446
    Abstract: Rosin modified phenolic resins are prepared by reacting together resin acid, fatty acid, tri- or higher-functional phenolic compound and aldehyde. The fatty acid may be Monomer (derived from the fatty acid dimerization process). The reaction mixture may optionally include a,l3-olefinically unsaturated carbonyl compounds and/or polyol. The resin may be dissolved in a solvent to form a varnish. The resin may be used as a component of printing inks, e.g., inks for lithographic or gravure printing.
    Type: Grant
    Filed: August 27, 2007
    Date of Patent: May 28, 2013
    Assignee: Arizona Chemical Company, LLC
    Inventor: Thomas Fontana
  • Patent number: 8445627
    Abstract: The invention provides new aliphatic diester-di-acid-containing PEA polymer compositions with significant improvement in hydrolytic degradation rates as compared to aliphatic di-acid-containing PEA polymers. The di-acids used in the invention PEA compositions include non-toxic fatty aliphatic homologs. These molecules inherently contain two-ester groups, which easily can be cleaved by biotic (enzymatic) and abiotic hydrolysis. Additional di-acid-type compounds useful for active polycondensation are ?,?-alkylene dicarboxylates composed of short aliphatic non toxic diols and di-acids. In addition, the invention PEA polymer compositions optionally can include a second monomer, such as a C-protected L-lysine-based monomer, to introduce additional chain flexibility into the polymer. The invention PEA polymer compositions are useful for delivery of bioactive agents when administered internally.
    Type: Grant
    Filed: March 22, 2007
    Date of Patent: May 21, 2013
    Assignee: Medivas, LLC
    Inventors: Ramaz Katsarava, Natia Mazanashvili, Zaza D. Gomurashvili, Turner Daniel Jenkins, Nino Mchedlishvili
  • Patent number: 8378055
    Abstract: This invention is to provide a polyester carbonate copolymer suitable for an optical lens that has high refractivity and transparency and low birefringence and little optical strain, and optical lenses formed therefrom. This invention is a polyester carbonate copolymer for an optical lens, which comprises 67 to 95 mol % of a unit of the following formula (I) and 33 to 5 mol % of a unit of the following formula (II) and has a specific viscosity of 0.12 to 0.30, wherein Y in the formula (II) is a phenylene group or a naphthalenediyl group.
    Type: Grant
    Filed: July 16, 2010
    Date of Patent: February 19, 2013
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Kazunori Nunome, Manabu Matsui, Kazushi Tando, Teruyuki Shigematsu, Tetsuya Motoyoshi, Tomokiyo Doi
  • Patent number: 8354494
    Abstract: A cholesteric polymerizable liquid crystal composition excellent in UV curing property and alignment property is provided. The polymerizable liquid crystal composition contains at least one liquid crystal compound selected from compounds represented by Formula (1-1) and Formula (1-2), at least one liquid crystal compound selected from compounds represented by Formula (2), and 5 to 15% by weight of at least one optically active compound selected from compounds represented by Formula (4) and may contain at least one liquid crystal compound selected from compounds represented by Formula (3). The meanings of the symbols in the Formulae are described in the specification.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: January 15, 2013
    Assignees: JNC Petrochemical Corporation, JNC Corporation
    Inventors: Kazumi Hagihara, Ryushi Shundo
  • Publication number: 20120321861
    Abstract: The present invention relates to a resin composition for protective layer transfer sheets which includes a polyester resin produced by polycondensing a polyhydric alcohol component containing a hydrogenated bisphenol A in an amount of 30 mol % or more and a polycarboxylic acid component containing a benzenedicarboxylic acid in an amount of 50 mol % or more.
    Type: Application
    Filed: November 9, 2010
    Publication date: December 20, 2012
    Applicants: DAI NIPPON PRINTING CO., LTD., KAO CORPORATION
    Inventors: Nobumichi Kamiyoshi, Takashi Mukai, Toshifusa Hirano, Masahiro Yuki
  • Patent number: 8318634
    Abstract: The present invention relates to a resin for use in a thermal transfer image-receiving sheet which is excellent in dyeability with dyes and releasability of the sheet, a resin dispersion using the resin, and a thermal transfer image-receiving sheet. The resin for a thermal transfer image-receiving sheet is obtained by addition polymerizing and condensation polymerizing (a) raw monomers of a polyester, (b) a raw monomer of an addition polymer-based resin containing at least one compound selected from the group consisting of styrene and styrene derivatives and (c) at least one dually reactive monomer selected from the group consisting of acrylic acid, methacrylic acid and derivatives of these acids, wherein the raw monomers (a) of a polyester include an alcohol component containing 80 mol % or more of an alkyleneoxide adduct of 2,2-bis(4-hydroxyphenyl)propane.
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: November 27, 2012
    Assignee: Kao Corporation
    Inventors: Yoshiaki Ban, Eiji Shirai, Nobumichi Kamiyoshi, Yuuta Matsumoto, Takashi Mukai
  • Patent number: 8313849
    Abstract: A biaxially oriented laminated polyester film which has dimensional stability against environmental changes such as temperature and humidity variations and rarely elongates when a load is applied thereto at a high temperature. The biaxially oriented laminated film comprises a film layer (A) made of an aromatic polyester (A) and a film layer (B) made of an aromatic polyester (B), wherein the content of a 6,6?-(alkylenedioxy)di-2-naphthoic acid component represented by the following formula (I) based on the total of all the acid components is less than 5 mol % in the aromatic polyester (A) and not less than 5 mol % and less than 80 mol % in the aromatic polyester (B); and the peak temperature of tan ? on a high temperature side is 135° C. or higher when viscoelasticity is measured in the machine direction. (in the formula (I), R is an alkylene group having 1 to 10 carbon atoms.
    Type: Grant
    Filed: April 21, 2009
    Date of Patent: November 20, 2012
    Assignee: Teijin Limited
    Inventors: Eiji Kinoshita, Mitsuo Tojo, Makoto Handa, Takeshi Ishida
  • Patent number: 8293861
    Abstract: An optical film comprising a copolycarbonate composed of 25 to 90 mol % of unit (A) of the following formula, and 10 to 75 mol % of unit (B) of the following formula, wherein the substituents are defined herein, and the optical film satisfies the following expression (1), R(450)<R(550)<R(650) (1), wherein R(450), R(550) and R(650) are in-plane retardation values of the film at wavelengths of 450 nm, 550 nm and 650 nm. The optical film exhibits a desired chromatic dispersion, low photoelasticity and excellent melt processability.
    Type: Grant
    Filed: June 3, 2011
    Date of Patent: October 23, 2012
    Assignee: Teijin Chemicals Ltd.
    Inventors: Tetsuya Motoyoshi, Masatoshi Ando, Akiko Washizu
  • Patent number: 8288499
    Abstract: A polyester for a toner having a softening point of from 70° to 110° C. and a glass transition temperature of from 38° to 60° C., obtained by polycondensing an alcohol component containing a propylene oxide adduct of bisphenol A and an ethylene oxide adduct of bisphenol A in a total amount of 80% by mole or more, with a carboxylic acid component, wherein the propylene oxide adduct has an average number of moles of from 2.0 to 2.4, and the ethylene oxide adduct has an average number of moles of from 2.5 to 4.2. The polyester for a toner of the present invention is suitably used as a resin binder of a toner, or the like, used for, for example, developing a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method, or the like.
    Type: Grant
    Filed: December 31, 2007
    Date of Patent: October 16, 2012
    Assignee: Kao Corporation
    Inventors: Eiji Shirai, Yoshitomo Kimura, Yasunori Inagaki
  • Patent number: 8277875
    Abstract: The present invention relates to a polyester for thermal transfer image-receiving sheets which includes a polyester A produced from an alcohol component containing 50 mol % or more of an alkyleneoxide adduct of 2,2-bis(4-hydroxyphenyl)propane and an acid component containing 80 mol % or more of an aliphatic carboxylic acid and/or an alicyclic carboxylic acid as a total amount thereof, and a polyester B produced from an alcohol component containing 80 mol % or more of the alkyleneoxide adduct of 2,2-bis(4-hydroxyphenyl)propane and an acid component containing 10 to 35 mol % of a trivalent or higher valent aromatic polycarboxylic acid; a resin dispersion containing the polyester; a process for producing the resin dispersion; a thermal transfer image-receiving sheet using the polyester; and a process for producing the thermal transfer image-receiving sheet. The thermal transfer image-receiving sheet is capable of satisfying all of a dyeability, a light resistance and a releasability at the same time.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: October 2, 2012
    Assignee: Kao Corporation
    Inventors: Nobumichi Kamiyoshi, Takashi Mukai, Yuuta Matsumoto, Shinichi Sata, Yoshiaki Ban
  • Publication number: 20120237471
    Abstract: The present invention relates to a protective agent suitable to protect the human skin against toxic materials, particularly against chemicals with nucleophilic sites. The active moiety is a polyanhydride derivative. The active transdermal retardant offers a barrier property and chemically and/or physically reacts with harmful chemicals to decrease percutaneous absorption. In the preferred embodiments, polyanhydride in its low molecular weight form reduced flux of nicotine and nitrofurazone significantly. Additionally, polyanhydride in its high molecular weight form prevented nicotine absorption and decreased nitrofurazone permeation dramatically. Moreover, the polyanhydride in its high molecular weight form reduced nitroglycerin flux to a lesser extent.
    Type: Application
    Filed: March 16, 2012
    Publication date: September 20, 2012
    Inventors: Mohammad ERFAN, Hamid Reza Moghimi, Azadeh Haeri, Tahereh Sadat Jafarzadeh Kashi, Farhad Jafarzade
  • Patent number: 8263728
    Abstract: A method for producing polyester resin includes: esterifying an alcoholic component, and an acid component containing polyvalent carboxylic acid and/or an ester-forming derivative thereof in a reaction solution. A condition of reaction pressure is changed from a pressurized state to a normal pressure state, or to a depressurized state under a condition (I) that an acid-based extent of reaction of the esterification is 76-94%, and a condition (II) that an undissolved acid component is present in the reaction solution.
    Type: Grant
    Filed: November 26, 2009
    Date of Patent: September 11, 2012
    Assignee: Kao Corporation
    Inventors: Yuichi Kono, Kazuma Yoshida, Hidekazu Yawata, Seiki Yoshioka, Shinpei Oota
  • Patent number: 8247518
    Abstract: A multi-layer polymer film for printing and copying of the present invention comprising a two-layer polymer base film composed of layer A and layer B laminated on one side of the layer A, the layer B containing a filler in an amount of 50 to 3000 ppm and the layer A containing no filler or a filler in an amount of at least 1000 ppm and less than the B layer; an image receiving layer coated on the exposed surface of the layer A; and an antistatic layer coated on the exposed surface of the layer B, wherein the layer A having the image receiving coating layer and the layer B having the antistatic coating layer have average degrees of surface roughness (Ra) ranging from 10 to 60 nm and 50 to 150 nm, respectively, exhibits improved properties in terms of runnability, printing, optical (haze), antistatic, friction coefficient and anti-blocking properties, which can be advantageously used as an OHP film.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: August 21, 2012
    Assignee: SKC Inc.
    Inventors: Taehoung Jeong, Kwang Soo Choi, Mary Elizabeth Klima
  • Patent number: 8216704
    Abstract: A biaxially oriented laminated polyester film which has excellent dimensional stability to environmental changes such as temperature and humidity variations and excellent flatness and windability. A biaxially oriented laminated polyester film comprising a film layer B on one side of a film layer A and having a surface roughness (RaB) on the film layer B side which is 1.0 nm or more larger than the surface roughness (RaA) on the film layer A side, wherein at least one of the film layers comprises an aromatic polyester (I) composed of a glycol component and a dicarboxylic acid component containing 5 mol % or more and less than 80 mol % of a recurring unit represented by the following formula (A): wherein RA is an alkylene group having 1 to 10 carbon atoms.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: July 10, 2012
    Assignee: Teijin Limited
    Inventors: Eiji Kinoshita, Ieyasu Kobayashi, Mitsuo Tojo, Tomoyuki Kishino, Kazuteru Kohno
  • Publication number: 20120172570
    Abstract: The present invention provides an aromatic polyester which is substantially free from the occurrence of coloration and retains significantly high transparency even after being thermally processed at high temperature and which has high flowability. The aromatic polyester contains a polyhydric phenol residue and a residue of any one of aromatic polycarboxylic acid, halide thereof, and anhydride thereof, and terminals of the aromatic polyester have a structure represented by the formula —C(O)—R. The aromatic polyester has an end-capping rate of 90% or higher and a weight average molecular weight (Mw) ranging from 3,000 to 1,000,000.
    Type: Application
    Filed: September 9, 2010
    Publication date: July 5, 2012
    Applicants: NITTA CORPORATION, MURORAN INSTITUTE OF TECHNOLOGY
    Inventors: Masayoshi Tabata, Yasuteru Mawatari, Takayoshi Yamazaki
  • Patent number: 8211827
    Abstract: The present invention relates to a dye receptor layer composition for thermal transfer image-receiving sheets which includes (a) a resin dispersion containing a polyester-containing resin, (b) a glycol ether having a boiling point of from 160° C. to 280° C. and a vapor pressure at 20° C. of from 20 to 1,000 Pa and (c) an oxazoline group-containing compound, and is excellent in film-forming property; and a thermal transfer image-receiving sheet obtained from the composition which can be dried at a low temperature for a short period of time, exhibits a low heat fusibility, is excellent in releasability, printing sensitivity and imaging performance, and can produce images with a high density.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: July 3, 2012
    Assignee: KAO Corporation
    Inventors: Nobumichi Kamiyoshi, Takashi Mukai, Shinichi Sata
  • Patent number: 8207287
    Abstract: Disclosed are polymers derived from units of bisphenol compounds, such as tetramethylcyclobutane diol-bisphenol, and processes for making and using them.
    Type: Grant
    Filed: June 7, 2011
    Date of Patent: June 26, 2012
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventor: Jean-Francois Morizur
  • Patent number: 8202962
    Abstract: Processes for making polyesters in a polyester production facility are disclosed, that include the steps of: forming a reaction medium comprising at least one monomer that includes terephthalic acid (TPA) and/or an ester derivative of TPA; subjecting at least a portion of the reaction medium to one or more chemical reactions in the polyester production facility to thereby produce the polyester; heating at least a portion of the reaction medium via indirect heat exchange with high-pressure steam, wherein the heating causes at least a portion of the high-pressure steam to condense and thereby provide pressurized condensed water; flashing at least a portion of the pressurized condensed water to thereby produce lower-pressure steam; and heating one or more process fluid streams of the polyester production facility via indirect heat exchange with at least a portion of the lower-pressure steam, wherein the process fluid streams include any stream that is formed predominately of the reaction medium and/or the at lea
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: June 19, 2012
    Assignee: Grupo Petrotemex, S.A. de C.V.
    Inventors: Alan George Wonders, James Donald Simpson, Bruce Roger DeBruin
  • Patent number: 8198397
    Abstract: Integrated processes for making polyesters are disclosed, that include the steps of: (a) producing an aromatic polycarboxylic acid in a monomer production facility; (b) producing a polyester in a polyester production facility, wherein the producing of the polyester comprises the substeps of: (i) forming a polyester reaction medium comprising at least a portion of the aromatic polycarboxylic acid from the monomer production facility, (ii) subjecting at least a portion of the polyester reaction medium to one or more chemical reactions to thereby produce the polyester, (iii) heating the polyester reaction medium at one or more locations in the polyester production facility via indirect heat exchange with high-pressure steam, wherein the heating causes at least a portion of the high-pressure steam to condense and thereby provide pressurized condensed water, and (iv) flashing at least a portion of the pressurized condensed water to thereby produce lower-pressure steam; and (c) using at least a portion of the lower
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: June 12, 2012
    Assignee: Grupo Petrotemex, S.A. de C.V.
    Inventors: Alan George Wonders, James Donald Simpson, Bruce Roger DeBruin
  • Patent number: 8192649
    Abstract: A method of preparing a capped poly(arylene ether) resin includes reacting a capping agent with a blend of two or more poly(arylene ether) resins having different intrinsic viscosities. Cured compositions prepared from these capped poly(arylene ether) resins exhibit improved balances of stiffness, toughness, and dielectric properties compared to compositions with two or more separately capped and isolated poly(arylene ether) resins.
    Type: Grant
    Filed: April 20, 2007
    Date of Patent: June 5, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Gary William Yeager, Hua Guo, Zhiqing Lin, Shahid Murtuza
  • Publication number: 20120123083
    Abstract: This invention is to provide a polyester carbonate copolymer suitable for an optical lens that has high refractivity and transparency and low birefringence and little optical strain, and optical lenses formed therefrom. This invention is a polyester carbonate copolymer for an optical lens, which comprises 67 to 95 mol % of a unit of the following formula (I) and 33 to 5 mol % of a unit of the following formula (II) and has a specific viscosity of 0.12 to 0.30, wherein Y in the formula (II) is a phenylene group or a naphthalenediyl group.
    Type: Application
    Filed: July 16, 2010
    Publication date: May 17, 2012
    Applicant: TEIJIN CHEMICALS, LTD.
    Inventors: Kazunori Nunome, Manabu Matsui, Kazushi Tando, Teruyuki Shigematsu, Tetsuya Motoyoshi, Tomokiyo Doi
  • Patent number: 8163671
    Abstract: The present invention relates to a dye receiving layer composition for thermal transfer image-receiving sheets which includes a resin containing a polyester produced by using an alcohol component containing 50 mol % or more of an alkyleneoxide adduct of 2,2-bis(4-hydroxyphenyl)propane and an oxazoline group-containing compound. There are provided a composition for a dye receiving layer of a thermal transfer image-receiving sheet which is excellent in not only dyeability upon thermal transfer but also releasability from a transfer sheet, and a thermal transfer image-receiving sheet having a dye receiving layer obtained from the above composition which is capable of obtaining transferred images having excellent properties.
    Type: Grant
    Filed: August 13, 2008
    Date of Patent: April 24, 2012
    Assignee: KAO Corporation
    Inventors: Nobumichi Kamiyoshi, Takashi Mukai, Shinichi Sata
  • Patent number: 8163847
    Abstract: A thermoset composition exhibiting reduced water absorption in the cured state includes an olefinically unsaturated monomer and a capped poly(arylene ether) prepared by the reaction of an uncapped poly(arylene ether) with an anhydride capping agent. The capped poly(arylene ether) is isolated and/or purified by methods that reduce the concentrations of polar impurities that contribute to water absorption by the cured composition.
    Type: Grant
    Filed: December 10, 2009
    Date of Patent: April 24, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Kenneth Paul Zarnoch, John Robert Campbell, Amy Rene Freshour, Hua Guo, John Austin Rude, Prameela Susarla, Michael Alan Vallance, Gary William Yeager
  • Patent number: RE43880
    Abstract: This invention relates to the composition and a solvent-free process for preparing novel imide oligomers and polymers specifically formulated with effective amounts of a dianhydride such as 2,3,3?,4-biphenyltetra carboxylic dianydride (a-BPDA), at least one aromatic diamine and an endcapped of 4-phenylethynylphthalic anhydride (PEPA) or nadic anhydride to produce imide oligomers that possess a low-melt viscosity of 1-60 poise at 260-280° C. When the imide oligomer melt is cured at about 371° C. in a press or autoclave under 100-500 psi, the melt resulted in a thermoset polyimide having a glass transition temperature (Tg) equal to and above 310° C. A novel feature of this process is that the monomers; namely the dianhydrides, diamines and the endcaps, are melt processable to form imide oligomers at temperatures ranging between 232-280° C. (450-535° F.) without any solvent.
    Type: Grant
    Filed: May 8, 2006
    Date of Patent: December 25, 2012
    Assignee: The United States of America as Represented by the Administrator of National Aeronautics and Space Administration
    Inventor: Chun-Hua Chuang