Sulfur-containing Aryl Compound Patents (Class 528/295)
  • Patent number: 6468632
    Abstract: A method for coating the sawed edges of gypsum wallboard to prevent dusting of gypsum particles in clean rooms. The method includes applying a water-dispersible polymers to the sawed edges of gypsum wallboard. The polymer forms a water-insoluble salt through an ion exchange with the calcium found in gypsum wallboard. The result is a tough, tack free, fast-drying coating that substantially reduces the levels of airborne gypsum particles that come from the sawed edges of gypsum wallboards.
    Type: Grant
    Filed: December 6, 2000
    Date of Patent: October 22, 2002
    Assignee: National Gypsum Properties, LLC
    Inventor: Daniel A. Winkowski
  • Patent number: 6455142
    Abstract: The present invention provides a coated polymer film having an essentially streak-free coated surface that resists the formation of fog. The film includes a self-supporting polymer film layer, and an anti-fog coating on the film layer. The anti-fog coating, which can also be applied to alternate substrates, consisting essentially of a copolyester binder and an anionic surfactant, wherein the surfactant contains less than about 0.5 weight percent of a fluorosurfactant. A slip agent can also be included in the anti-fog coating.
    Type: Grant
    Filed: December 17, 1999
    Date of Patent: September 24, 2002
    Assignee: Mitsubishi Polyester Film, LLC
    Inventors: John M. Heberger, Robin M. Donald, Jan C. Westermeier, F. Gene Funderburk, John G. Rollins
  • Patent number: 6444781
    Abstract: The invention relates to resin intermediates and their preparation. The invention also relates to hydroxyl-functional, water-dispersible polymers formed from the intermediates and compositions containing the water-dispersible polymers. A preferred composition of the invention is a zero volatile organic content (VOC), ambient-cure enamel composition which contains a hydroxyl-functional, water-dispersible polyester.
    Type: Grant
    Filed: June 16, 2000
    Date of Patent: September 3, 2002
    Assignee: Eastman Chemical Company
    Inventors: Thauming Kuo, Jeffery E. G. Powell
  • Patent number: 6433107
    Abstract: A fiber-forming polyamide composition including a combination of a fiber-forming polyamide with a concentrate having one or more sulfonated aromatic acid reagents in a thermoplastic carrier resin. The concentrate preferably comprises an alkali metal salt of 5-sulfoisophthalic acid, preferably carried in a matrix comprising one or more thermoplastic polyesters or polyamides.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: August 13, 2002
    Assignee: Prisma Fibers, Inc.
    Inventor: Matthew B. Studholme
  • Publication number: 20020091228
    Abstract: The invention relates to resin intermediates and their preparation. The invention also relates to hydroxyl-functional, water-dispersible polymers formed from the intermediates and compositions containing the water-dispersible polymers. A preferred composition of the invention is a zero volatile organic content (VOC), ambient-cure enamel composition which contains a hydroxyl-functional, water-dispersible polyester.
    Type: Application
    Filed: November 27, 2001
    Publication date: July 11, 2002
    Applicant: Eastman Chemical Company
    Inventors: Thauming Kuo, Jeffery E.G. Powell
  • Patent number: 6414108
    Abstract: Biodegradable polyether esters P1 obtainable by the reaction of a mixture consisting essentially of: (a1) a mixture essentiall) of 20 to 95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5 to 80 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0 to 5 mol % of a sulphonate group-containing compounds In which the sum of the individual mol percentages is 100; and (a2) a mixture of dihydroxy compounds consisting essentially of (a21) 15 to 99 mol % of a dihydroxy compound selected from the group consisting of C2-C6 alkane diols and C5-C10 cycloalkane diols; (a22) 85 to 0.2 mol % of an ether function-containing dihydroxy compound as in formula I HO—[(CH2)n—O]m—H in which n is 2, 3 or 4 and m is a whole number from 2 to 250, or mixtures thereof, in which the molar ratio of (a1) to (a2) is in the range from 0.4:1 to 1.
    Type: Grant
    Filed: September 21, 1999
    Date of Patent: July 2, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Warzelhan, Bernd Bruchmann, Dieter Boeckh, Ursula Seeliger, Motonori Yamamoto, Peter Bauer
  • Publication number: 20020082381
    Abstract: A polyester ionomer composition comprises an alkylene aryl polyester copolymer having metal sulfonate units represented by the formula IA: 1
    Type: Application
    Filed: December 21, 2000
    Publication date: June 27, 2002
    Inventors: Bret Ja Chisholm, William David Richards, Timothy Edward Banach
  • Patent number: 6380349
    Abstract: The present invention relates to golf equipment, such as golf shoes, golf clubs, golf gloves, or portions thereof, formed from compositions comprising a sulfonated, carboxylated, or phosphonated acid moieties, or a mixture thereof. The preferred ionomer composition comprises sulfonated thermoplastic elastomers, sulfonated thermoplastic polymers, sulfonated thermoset polymers, and mixtures thereof. The compositions include a blend of about 1 weight % to about 99 weight % of at least one sulfonated, carboxylated, or phosphonated ionomer and about 99 weight % to about 1 weight % of at least co-component polymer. The co-component polymer may be a conventional ionomer, a thermoplastic, a thermoplastic elastomer, a thermoset polymer, or mixtures thereof.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: April 30, 2002
    Assignee: Acushnet Company
    Inventor: Murali Rajagopalan
  • Patent number: 6368710
    Abstract: A sulfonated copolyester of the reaction product of: (a) one or more aromatic dicarboxylic acids or an ester thereof; (b) one or more aliphatic dicarboxylic acids or an ester thereof; (c) one or more sulfonated compound; and (d) isosorbide. The polyesters are useful to form articles of increased biodegradability.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: April 9, 2002
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Richard Allen Hayes
  • Patent number: 6365315
    Abstract: The invention relates to a process for the production of spherical, polyester particles, wherein the particle size can be exactly adjusted in the range of 1 to 200 &mgr;m and a particle size distribution with a span (=d90−d10/d50)≦1.5, as well as the use of the produced particles for toner compositions in electrophotographic and direct printing systems and powder coatings.
    Type: Grant
    Filed: October 18, 2000
    Date of Patent: April 2, 2002
    Assignee: Ticona GmbH
    Inventors: Stefan Wulf, Alexandra Jacobs, Volker Mörs, Toshio Shiwaku, Benett Clayton Ward
  • Patent number: 6362313
    Abstract: Allyl pendent benzazole polymer system having repeating units of the formula: wherein Bz is a benzazole unit selected from the group consisting of wherein X is —O—, —S— or —NH—, and R is selected from the group consisting of wherein Ar is an aromatic group; and wherein x has a value of about 1.0 to 0.1 and y has a value of 1.0−x.
    Type: Grant
    Filed: February 13, 2001
    Date of Patent: March 26, 2002
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Fred E. Arnold, Thuy D. Dang
  • Patent number: 6355764
    Abstract: The invention provides a new soluble thermosetting polyethersulfone resin, which can dissolve in ether solvent such as THF and 1,4-Dioxane. The soluble thermosetting polyethersulfone resin can be introduced the unsaturated olefin functional group, after high temperature (>180° C.) curing the unsaturated olefin functional group gets high heat resistant polyethersulfone resin. The soluble thermosetting polyethersulfone resin is made by two steps reaction, the dihalodiphenylsulfone reacts with dihydroxy aromatic compound and dihydroxybenzoic acid to form carboxy group terminated polyethersulfone resin, then the carboxy group terminated polyethersulfone resin react with unsaturated olefin alcohol or glycidyl acrylate or their derivatives to make soluble thermosetting polyethersulfone resin.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: March 12, 2002
    Assignee: Lead Data Inc.
    Inventors: Shung-Yaw Hun, Fu-Kang Huang, Tsung-Yi Yeh, Tsu Hsien Han, Ro Ching Liu
  • Patent number: 6353083
    Abstract: This invention relates to: (a) fluorene copolymers comprising at least 10% (by residual monomeric units) of 9-substituted and/or 9,9-disubstituted fluorene moieties and at least two other monomeric units containing delocalized p-electrons, (b) polymer blends comprising at least 10 weight % of a copolymer specified in (a), and (c) electronic devices (such as polymer light emitting diodes) containing one or more films derived from these copolymers.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: March 5, 2002
    Assignee: The Dow Chemical Company
    Inventors: Michael Inbasekaran, Weishi Wu, Edmund P. Woo, Mark T. Bernius
  • Patent number: 6348561
    Abstract: An alkali sulfonated polyester-amine resin generated from the reaction of an organic diol, and a mixture of an organic diacid, an alkali sulfonated diacid and an amino-organic diacid.
    Type: Grant
    Filed: April 19, 2001
    Date of Patent: February 19, 2002
    Assignee: Xerox Corporation
    Inventors: Walter Mychajlowskij, Daniel A. Foucher, Raj D. Patel, Guerino G. Sacripante
  • Patent number: 6334877
    Abstract: A fiber-forming polyamide composition contains a fiber forming polyamide and a sulfonated polyester concentrate, the concentrate disabling and dye sites in the polyamide so that fibers formed from the composition will have enhanced stain and soil resistance. The sulfonated polyester concentrate contains a reagent, preferably an alkali metal salt of 5-sulfoisophthalic acid, and thermoplastic polyester, preferably one or more of PET PTT, PBT, PETG and poly(ethylene terephthalate-co-isophthalate).
    Type: Grant
    Filed: June 14, 2000
    Date of Patent: January 1, 2002
    Assignee: Prisma Fibers, Inc.
    Inventor: Matthew B. Studholme
  • Patent number: 6331606
    Abstract: A composition and a process for producing the composition are provided. The composition comprises repeat units derived from 1,3-propanediol; an organic acid, preferably a dicarboxylic acid, its salt, its ester, or combinations of two or more thereof; a polyether diol; and a sulfonated comonomer. The polyether diol can be present in the composition in the range of from about 10 to about 80 weight %. The process comprises contacting 1,3-propanediol with the organic acid, the polyether diol, and the sulfonated comonomer. The sulfonated comonomer can have the formula of (R′OC(O))2A(R)zS(O)2OM in which each R′ can be the same or different and is each independently hydrogen, a C1 to C4 alkyl group, or a C1 to C4 hydroxyalkyl group; each R is independently a C1 to C4 alkyl group; A is an alkylene or arylene group; z is a number of from 0 to 2; and M is hydrogen, alkali metal ion, alkaline earth metal ion, quaternary ammonium, or ammonium ion.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: December 18, 2001
    Assignee: E. I. du Pont de Nemours and Comapny
    Inventor: Yanhui Sun
  • Publication number: 20010051706
    Abstract: This invention relates to water-dispersible sulfopolyesters comprising residues of (i) terephthalic acid; (ii) an amount sufficient to provide water-dispersibility to the sulfopolyester of at least one difunctional sulfomonomer containing at least one sulfonate group bonded to an aromatic ring; (iii) less than 5 mole % of at least one dicarboxylic acid that is not terephthalic acid or a sulfomonomer; (iv) 25 to 90 mole % of at least one polyethylene glycol having the structure:
    Type: Application
    Filed: December 3, 1999
    Publication date: December 13, 2001
    Inventors: SCOTT E. GEORGE, BERNARD J. MENTRO, MICHAEL J. ABROSINI
  • Patent number: 6316586
    Abstract: A copolyether composition that can be used to produce a dyeable polyester is provided. The composition can comprise repeat units derived from a first diol such as, for example, 1,3-propanediol and a sulfonated dicarboxylic acid such as, for example, 5-sulfo-isophthalic acid. The dyeable polyester composition can comprise repeat units derived from the copolyether composition, an acid such as, for example, terephthalic acid, and a second diol such as, for example, 1,3-propanediol. Also disclosed is a process that can be used for producing the copolyether composition. The process comprises contacting the first diol with the sulfonated dicarboxylic acid.
    Type: Grant
    Filed: August 15, 2000
    Date of Patent: November 13, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Hari Babu Sunkara, Yali Yang
  • Patent number: 6300424
    Abstract: Hyperbranched polyester and polyamide polymers are prepared by a one-step process of polymerizing a monomer of the formula A—R—B2 so that high molecular weight globular polymers having a multiplicity of a particular functional group on the outside surface are obtained.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: October 9, 2001
    Assignee: Cornell Research Foundation, Inc.
    Inventors: Jean M. J. Frechet, Craig J. Hawker, Kathryn Uhrich
  • Patent number: 6287656
    Abstract: Amorphous copolyesters containing residues derived from 2,2′-[2,2-](sulfonylbis(4,1-phenyleneoxy))bis(ethanol). They exhibit enhanced heat distortion temperatures and glass transition temperatures without a significant increase in viscosity at low shear rates. The amorphous copolyesters also have improved resistance to attack by lipid solutions and are readily molded and extruded to form medial devices such as connectors, tubes, etc. which are useful for transport of lipids and other medical solutions.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: September 11, 2001
    Assignee: Eastman Chemical Corporation
    Inventors: S. Richard Turner, Gary W. Connell, Bobby J. Sublett
  • Patent number: 6245862
    Abstract: The present invention relates to a golf ball, comprising a cover, a core and optional intermediate layers, wherein the various ball components are formed from compositions comprising a sulfonated and/or phosphonated ionomer. The sulfonated and/or phosphonated ionomer preferably comprises sulfonated thermoplastic elastomers, sulfonated thermoplastic polymers, sulfonated thermoset polymers and mixtures thereof. The compositions include a blend of about 1 wt. % to about 99 wt. % of at least one sulfonated and/or phosphonated ionomer and about 99 wt. % to about 1 wt. % of at least co-component polymer. The co-component polymer may be a conventional ionomer, a thermoplastic, a thermoplastic elastomer, a thermoset polymer or mixtures thereof.
    Type: Grant
    Filed: May 28, 1998
    Date of Patent: June 12, 2001
    Assignee: Acushnet Company
    Inventor: Murali Rajagopalan
  • Patent number: 6228975
    Abstract: A polyalkylene naphthalate for a film, which comprises a naphthalenedicarboxylic acid component as a main dicarboxylic acid component and an aliphatic glycol component as a main glycol component, and contains (a) an antimony compound and (b) a quaternary phosphonium sulfonate compound unit having an ester-forming functional group in such amounts that satisfy the following expressions (1) and (2): 0<Sb≦80  (1) 0<S/Sb≦0.4  (2) wherein Sb and S are the molar ratios (mmol %) of the antimony compound and the quaternary phosphonium sulfonate compound unit having an ester-forming functional group to the total of all the dicarboxylic acid components forming the polyalkylene naphthalate, respectively. The film of the present invention has excellent surface flatness and is suitable for use as a base film for a magnetic recording medium. It is also excellent in high-speed winding properties and can be formed into a film stably and produced industrially advantageously.
    Type: Grant
    Filed: December 8, 1999
    Date of Patent: May 8, 2001
    Assignee: Teijin Limited
    Inventors: Tomokatsu Ura, Masahiko Kosuge, Hideshi Kurihara
  • Patent number: 6171685
    Abstract: Provided are water-dispersible sulfopolyester compositions having relatively large proportions of pigments and/or fillers. Such compositions are useful as packaging materials and are substantially non-blocking when processed using packaging rolls and are comprised of at least one sulfopolyester as described herein, about 10 to about 75 weight percent of a pigment and/or filler, and a wax.
    Type: Grant
    Filed: November 26, 1999
    Date of Patent: January 9, 2001
    Assignee: Eastman Chemical Company
    Inventors: Scott Ellery George, Richard Anthony Miller, Jimmy Ray Trotter, Jayne Webb Lettich, Sammy Ray Repass
  • Patent number: 6165701
    Abstract: A base film for photographic films formed from a copolyester comprising 97 to 100 mol % of 2,6-naphthalenedicarboxylic acid and 0 to 3 mol % of a dicarboxylic acid other than 2,6-naphthalenedicarboxylic acid and (i) 87 to 99.8 mol % of ethylene glycol, 0.2 to 10 mol % of bis[4-(.omega.-hydroxyalkoxy)phenyl]sulfone and 0 to 3 mol % of a glycol other than ethylene glycol and bis[4-(.omega.-hydroxyalkoxy)phenyl]sulfone or (ii) 97 to 100 mol % of ethylene glycol, 0 to 3 mol % of a diol other than ethylene glycol and 1 to 7 mol % of an oxycarboxylic acid. This base film has an endothermic peak having a peak top temperature, measured by a differential scanning calorimeter, of 120 to 160.degree. C. and showing an endothermic energy of 0.3 mJ/mg or more.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: December 26, 2000
    Assignee: Teijin Limited
    Inventors: Mitsuru Teramoto, Manabu Kimura, Shinya Watanabe, Koji Furuya, Kenji Suzuki
  • Patent number: 6162890
    Abstract: Disclosed are linear, water-dispersible sulfopolyesters incorporating a low molecular weight polyethylene glycol and blocks of a high molecular weight polyethylene glycol. The block sulfopolyesters have improved toughness, abrasion resistance, flexibility, and adhesion. Particular utility is realized in polyester fiber sizing applications and as an adhesive.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: December 19, 2000
    Assignee: Eastman Chemical Company
    Inventors: Scott Ellery George, Bobby Jones Sublett, Richard Anthony Miller
  • Patent number: 6133382
    Abstract: A fiber-forming polyamide composition contains a fiber forming polyamide and a sulfonated polyester concentrate, the concentrate disabling and dye sites in the polyamide so that fibers formed from the composition will have enhanced stain and soil resistance. The sulfonated polyester concentrate contains a reagent, preferably an alkali metal salt of 5-sulfoisophthalic acid, and thermoplastic polyester, preferably one or more of PET, PTT, PBT, PETG and poly(ethylene terephthalate-co-isophthalate).
    Type: Grant
    Filed: November 12, 1998
    Date of Patent: October 17, 2000
    Assignee: Prisma Fibers, Inc.
    Inventor: Matthew B. Studholme
  • Patent number: 6121351
    Abstract: Thermoplastic compositions containing certain anthraquinone polysulfonamide colorants incorporated therein as toners or colorants. The anthraquinone colorant moieties which are incorporated into the polymer chain of the polysulfonamide colorants are not leachable, sublimable or extractable and do not exude from the thermoplastic compositions. The anthraquinone polysulfonamide colorants may be added to the thermoplastic polymers during production or melt blended with the polymer by conventional techniques to produce transparent thermoplastic compositions useful for a variety of end uses where nonmigrating or nonextractable colorants are needed.
    Type: Grant
    Filed: August 7, 1997
    Date of Patent: September 19, 2000
    Assignee: Eastman Chemical Company
    Inventors: Max Allen Weaver, Wayne Payton Pruett, Kay Hunt Shackelford, Samuel David Hilbert
  • Patent number: 6120889
    Abstract: The invention relates to an amorphous copolyester having a maximum melt viscosity at 1 radian/second and at about 260 to about 290.degree. C. of about 12000 poise, a glass transition temperature ranging from about 88.degree. C. to about 120.degree. C., and an inherent viscosity of at least about 0.6 dl/g. The amorphous copolyesters comprise the reaction product of a diol component and a dicarboxylic acid component. The diol component comprises residues of from about 5.0 to about 50 mole % of 2,2'-(sulfonylbis(4,1 -phenyleneoxy))-bis(ethanol) which has the following chemical formula: ##STR1## and from about 50 to about 95 mole % of a mixture of at least two diols selected from the group consisting of ethylene glycol, neopentyl glycol, 1,3-propanediol, 1,4-butanediol, 1,4-cyclohexanedimethanol, and mixture thereof. The dicarboxylic acid component comprises residues of terephthalic acid, isophthalic acid, 1,4-cyclohexandedicarboxylic acid, 2,6-naphthalene dicarboxylic acid and mixtures thereof.
    Type: Grant
    Filed: June 3, 1999
    Date of Patent: September 19, 2000
    Assignee: Eastman Chemical Company
    Inventors: S. Richard Turner, Bobby J. Sublett
  • Patent number: 6117532
    Abstract: An oriented polyester film coated on at least one surface with a coating that improves its adhesion to gelatin is disclosed. The dry coating contains one or more sulfopolyesters; one or more tetrablock copolymer resins; and one or more non-volatile polyamines. Other ingredients, such as particulate materials and surfactants, may be present in the coating. The coating is preferably applied at the interdraw stage.
    Type: Grant
    Filed: October 30, 1997
    Date of Patent: September 12, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Junaid Ahmed Siddiqui, Cornell Chappell, Jr
  • Patent number: 6074758
    Abstract: A poly(hydroxy ester ether) is prepared by reacting a) a diacid containing a hetero moiety of the formula:HO.sub.2 CCH.sub.2 X(RX).sub.y CH.sub.2 CO.sub.2 Hwherein X is selected from the group consisting of --O--, --S--, and NH; y is the whole number 0 or 1; and R is selected from the group consisting of an aromatic moiety and a heterocyclic moiety having from 6 to 30 carbon atoms; andb) a diglycidyl ether generally represented by the formula: ##STR1## wherein R.sup.2 is an aromatic moiety or divalent aliphatic hydrocarbon having 2 to 20 carbon atoms. Films, articles and laminations made from the composition exhibit an oxygen permeability of less than about 8 cc-mil/100 in.sup.2 -24 hour-atmosphere. The present invention is further directed to a miscible blend having the poly(hydroxy ester ether) of the present invention and a second component selected from a saturated polyester of an aromatic diacid, such as PET and PEN.
    Type: Grant
    Filed: November 4, 1999
    Date of Patent: June 13, 2000
    Assignee: Eastman Chemical Company
    Inventor: Robert Boyd Barbee
  • Patent number: 6066694
    Abstract: A thermoplastic resin composition comprising:(a) Alkylene aryl polyester copolymers having metal sulfonate units represented by the formula IA: ##STR1## or the formula IB:(M.sup.+n O.sub.3 S).sub.d --A--(OR"OH).sub.pwhere p=1-3, d=1-3, p+d=2-6, n=1-5, and A is an aryl group containing one or more aromatic rings where the sulfonate substituent is directly attached to an aryl ring, R" is a divalent alkyl group and the metal sulfonate group is bound to the polyester through ester linkages;(b) An essentially amorphous polycarbonate, polyester carbonate or polyarylate polymer containing recurring units of the formula II: ##STR2## wherein Ar is divalent aromatic residue of a dicarboxylic acid or mixture of dicarboxylic acids and Ar' is the divalent aromatic residue of a dihydric phenol or mixture of dihydric phenols. The composition may further comprise acidic phosphorus based quenchers, rubbery impact modifiers, mineral fillers or reinforcements.
    Type: Grant
    Filed: March 4, 1998
    Date of Patent: May 23, 2000
    Assignee: General Electric Company
    Inventors: Bret Ja Chisholm, Robert R. Gallucci, William P. England, Patricia A. Hubbard, William D. Richards, Jenny Z. Bu
  • Patent number: 6046253
    Abstract: An ink jet ink composition comprising from about 0.5% to about 30% by weight of a pigment, a carrier and a sulfonated polyester dispersant in a ratio of dispersant:pigment from about 0.1:1 to about 5:1.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: April 4, 2000
    Assignee: Eastman Kodak Company
    Inventors: David Erdtmann, Elizabeth G. Burns, John Dicillo
  • Patent number: 6031043
    Abstract: A topical composition comprising an aqueous phase containing a hydrophilic gelling agent of polyester sulphone type selected from water-soluble or water-dispersible terephthalic copolyester oligomers comprising repeating dicarboxylate units of formula (I):CO--A--CO--O(CH.sub.2 CH.sub.2 O).sub.nwherein the weight-average molecular mass of the copolyester oligomer is less than 20,000, preferably less than 15,000, and a cosmetic treatment process for the skin, mucous membranes or the exoskeleton, in which a composition according to the invention is applied to the skin, mucous membranes or the exoskeleton.
    Type: Grant
    Filed: March 16, 1998
    Date of Patent: February 29, 2000
    Assignee: L'Oreal
    Inventors: Christine Dupuis, Henri Samain
  • Patent number: 6020420
    Abstract: This invention provides crystalline, water-dispersible polyesters comprising residues of 4,4'-biphenyl dicarboxylic acid. The polyesters comprise residues of 4,4'-biphenyl dicarboxylic acid, at least one difunctional sulfomonomer in an amount sufficient to provide water dispersibility to the polyester, and a glycol or a mixture of glycols. The polyesters of the invention are useful in ink and adhesive compositions.
    Type: Grant
    Filed: March 10, 1999
    Date of Patent: February 1, 2000
    Assignee: Eastman Chemical Company
    Inventor: Scott Ellery George
  • Patent number: 6001910
    Abstract: A remoistenable hot melt adhesive composition comprising (i) 25 to 80% by weight of a sulfonated polyester;(ii) 3 to 40% by weight of an anionic or cationic plasticizer;(iii) 0 to 40% by weight of a polar tackifier;(iv) 0 to 3% by weight of an antioxidant; and(v) 10 to 35% by weight of a polar wax; and(vi) optionally 0 to 30% nonionic plasticizer, wherein the total of (i)-(vi) to equal 100% by weight.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: December 14, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Mitchell J. Blumenthal, Charles W. Paul, Matthew L. Sharak
  • Patent number: 5985437
    Abstract: An oriented polyester film coated on at least one surface with a coating that improves its adhesion to water-based coatings is disclosed. The coating contains at least one sulfopolyester; at least one tetrablock copolymer resin; and at least one acrylamide/acrylic acid copolymer or salts thereof. Other ingredients, such as particulate materials and surfactants, may be present in the coating. The coating is preferably applied at the interdraw stage.
    Type: Grant
    Filed: December 4, 1997
    Date of Patent: November 16, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Cornell Chappell, Jr., Junaid A. Siddiqui
  • Patent number: 5958552
    Abstract: A laminated film comprising (A) an aromatic polyester film; and (B) a hydrophilic coating layer which is present on at least one side of the aromatic polyester film (A) and has a surface energy of at least 54 dyne/cm, the coating layer comprising (a) 50 to 80% by weight of a copolyester which contains a dicarboxylic acid component having a sulfonate group in an amount of 1 to 16 mol % of the total of all dicarboxylic acid components and has a secondary transition point of 20 to 90.degree. C., (b) 10 to 30% by weight of poly(alkylene oxide) homopolymer having a number average molecular weight of 600 to 2,000, and (c) 3 to 25% by weight of fine particles having an average particle diameter of 20 to 80 nm, based on the total of components (a), (b) and (c). The above laminated film is useful as a transparency for an overhead projector and a recording paper for an ink jet printer.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: September 28, 1999
    Assignee: Teijin Limited
    Inventors: Masayuki Fukuda, Hiroshi Tomita
  • Patent number: 5928460
    Abstract: Disclosed is an essentially odorless water dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. The copolyester adhesive composition can be used neat or formulated and exhibits broad compatibility with a variety of adhesive additives, including non polar tackifiers.
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: July 27, 1999
    Assignee: Eastman Chemical Company
    Inventors: Richard Anthony Miller, Scott Ellery George
  • Patent number: 5922829
    Abstract: Disclosed is are high molecular weight copolyester compositions which possess high melt viscosity and melt strength which render them foamable with a wide range of foaming agents. The copolyesters consist essentially of (A) diacid residues comprising (i) from about 99.9 to about 95 mol % of residues of an aromatic dicarboxylic acid having 8 to 12 carbon atoms and (ii) from about 0.1 to about 5.0 mol % of residues of an aromatic dicarboxylic acid sulfonate monomer containing at least one divalent metal sulfonate group attached to an aromatic nucleus, and (B) diol residues comprising residues of at least one aliphatic or cycloaliphatic diol having 2 to 8 carbon atoms, the mol % being based on 100 mol % dicarboxylic acid residues and 100 mol % diol residues.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: July 13, 1999
    Assignee: Eastman Chemical Company
    Inventor: Kishan Chand Khemani
  • Patent number: 5919403
    Abstract: This invention relates to homopolyester compositions having fluorescence quenchers polymerized therein ("poly quenchers"). Specifically the "poly quencher" polymeric compositions comprises repeating units from(a) a dicarboxylic acid component and(b) a diol component, wherein at least one of (a) and (b) is comprised of at least one fluorescence polyquencher capable of reducing fluorescence of a polymer below the fluorescence displayed when said polyquencher is not included.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: July 6, 1999
    Assignee: Eastman Chemical Company
    Inventors: Allan Scott Jones, Jean Carroll Fleischer, Max Allen Weaver
  • Patent number: 5817721
    Abstract: A biodegradable polyester obtainable by reacting a mixture comprising(a1) from 95 to 99.9% by weight of a polyester P1 obtainable by reacting a mixture essentially comprising(b1) a mixture comprising35-95 mol % of adipic acid or ester-forming derivatives thereof,5-65 mol % of terephthalic acid or ester-forming derivatives thereof, and0-5 mol % of a compound containing sulfonate groups, and(b2) a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,with the proviso that a compound D with at least three groups capable of ester formation is employed to prepare the polyester P1,(a2) from 0.1 to 5% by weight of a divinyl ether C1 and(a3) from 0 to 5 mol %, based on component (b1) from the preparation of P1, of compound D,and other biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings and adhesives.
    Type: Grant
    Filed: May 12, 1997
    Date of Patent: October 6, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Warzelhan, Gunnar Schornick, Matthias Kroner, Ursula Seeliger, Motonori Yamamoto, Rainer Buschl
  • Patent number: 5817740
    Abstract: New polyester composition for new polyester staple fiber that provides fabrics having a combination of excellent pilling performance, aesthetics and tactility ("hand"). Preferred fibers have non-round cross-sections that are retained, especially such non-round cross-sections having multi-grooved scalloped-oval cross-sections that provide fabrics having outstanding comfort qualities of moisture-management, dryness and comfort, along with minimal pilling.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: October 6, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Harvey Gene Anderson, Arun Pal Aneja, Robert Lee Edmundson, Adrian Charles Snyder
  • Patent number: 5807962
    Abstract: A sulfonated dicarboxylic acid and a diaromatic carbonate are reacted by a solution process to form a sulfonated aromatic diester such as diphenyl sodium 5-sulfoisophthalate. The sulfonated aromatic diester is reacted with an aromatic polymer precursor mixture such as bisphenol A and diphenyl carbonate, polymer or combination thereof, at a temperature above the melting point of the polymer or a member of the aromatic polymer precursor to form a randomly positioned sulfonated aromatic moiety in a polymer chain of a thermoplastic non-crosslinked aromatic polymer such as a linear polycarbonate.
    Type: Grant
    Filed: August 20, 1997
    Date of Patent: September 15, 1998
    Assignee: The Dow Chemical Company
    Inventors: Ray E. Drumright, Michael J. Mullins, William B. Marshall, Edvins L. Daiga
  • Patent number: 5780151
    Abstract: Disclosed is a radiation crosslinkable water-dispersible adhesive composition that is useful in forming paper and plastic articles and other products that can be recycled through a process which includes washing or repulping in aqueous media. The cross-linkable water-dispersible adhesive composition is preferably used as a hot melt adhesive. The cross-linkable water-dispersible adhesive composition is a low molecular weight, branched copolyester containing a sulfomonomer and unsaturated moieties. The radiation crosslinked adhesive composition has more cohesive strength and viscosity than its corresponding uncross-linked adhesive, yet is still water-dispersible during product recycling.
    Type: Grant
    Filed: December 8, 1995
    Date of Patent: July 14, 1998
    Assignee: Eastman Chemical Company
    Inventors: Richard Anthony Miller, Scott Ellery George
  • Patent number: 5770558
    Abstract: The subject invention involves processes for making granular compositions comprising soil release polymers, the polymers comprising at least about 10% of substantially linear esters having a backbone; the esters being uncapped or end-capped on one or both ends of the backbone; the esters comprising in their backbones oxyalkyleneoxy units and hydrophobic aryldicarbonyl units; the esters having a molecular weight of from about 500 to about 20,000; the polymers if in solid state having the tendency when exposed to moisture to spontaneously rearrange from an amorphous form which is readily soluble in water to a crystalline form which is relatively insoluble in water; the process comprising the following steps:a) taking the soil release polymers, in which are dispersed from 0% to about 25% alkylaryl or alkyl sulfonate crystallization-reducing stabilizers, in molten state at a temperature of at least about 180.degree. C.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: June 23, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Benjamin Edgar Chapman, Michael Timothy Creedon
  • Patent number: 5756645
    Abstract: The yield of fully substituted, multidimensional aromatic hubs in the condensation of hydroxyl and acid halide functionalities is improved by adding a thallium catalyst, such as thallium ethoxide (Tl-OC.sub.2 H.sub.5), in the solvent.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: May 26, 1998
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard, Ronald R. Stephenson
  • Patent number: 5750635
    Abstract: This invention relates to a thermally stable polyester, comprising:a polyester resin prepared by adding a dicarboxylic acid to a glycol compound, said dicarboxylic acid selected from the group consisting of aliphatic dicarboxylic acids having a total of from 3 to 16 carbon atoms, alicyclic dicarboxylic acids having 7 to 12 carbon atoms, aromatic dicarboxylic acids containing a total of from 8 to 16 carbon atoms, and combinations thereof, and wherein said glycol is selected from the group consisting of glycols having from 2 to 12 carbon atoms, glycol ethers having from 4 to 12 carbon atoms, and combinations thereof,said polyester resin having been prepared in the presence of a catalyst system consisting essentially of one or more antimony compounds which is not reacted with .alpha.-hydroxy carboxylic acids, .alpha.,.beta.-dicarboxylic acids or derivatives thereof.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: May 12, 1998
    Inventors: Andrew Edwin Brink, Wayne Payton Pruett, Clinton Cherry, Kay Hunt Shackelford
  • Patent number: 5744538
    Abstract: Disclosed is an essentially odorless water dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. The copolyester adhesive composition can be used neat or formulated and exhibits broad compatibility with a variety of adhesive additives, including non polar tackifiers.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: April 28, 1998
    Assignee: Eastman Chemical Company
    Inventors: Richard Anthony Miller, Scott Ellery George
  • Patent number: 5739261
    Abstract: Oxysulfonylated polyesters, well suited for conversion into oriented composite polyester films, are prepared by polycondensing a lower alkyl diester of at least one aliphatic dicarboxylic acid and a lower alkyl diester of at least one aromatic dicarboxylic acid bearing an oxysulfonyl substituent, and optionally a lower alkyl diester of at least one aromatic dicarboxylic acid, with at least one diol, in the presence of a catalytically effective amount of at least one titanium compound and at least one manganese carboxylate.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 14, 1998
    Assignee: Rhone-Poulenc Films
    Inventors: Jean-Pierre Assante, Etienne Fleury, Didier Veyrat
  • Patent number: 5718790
    Abstract: Disclosed is a water-dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water-dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. Additional utility for the invention resides in the manufacture of recyclable articles where insolubility in body fluids combined with solubility in tap water are required.
    Type: Grant
    Filed: October 31, 1995
    Date of Patent: February 17, 1998
    Assignee: Eastman Chemical Company
    Inventors: Richard A. Miller, Theron E. Parsons, III, Mark A. Montgomery