Sulfur-containing Aryl Compound Patents (Class 528/295)
-
Patent number: 6468632Abstract: A method for coating the sawed edges of gypsum wallboard to prevent dusting of gypsum particles in clean rooms. The method includes applying a water-dispersible polymers to the sawed edges of gypsum wallboard. The polymer forms a water-insoluble salt through an ion exchange with the calcium found in gypsum wallboard. The result is a tough, tack free, fast-drying coating that substantially reduces the levels of airborne gypsum particles that come from the sawed edges of gypsum wallboards.Type: GrantFiled: December 6, 2000Date of Patent: October 22, 2002Assignee: National Gypsum Properties, LLCInventor: Daniel A. Winkowski
-
Patent number: 6455142Abstract: The present invention provides a coated polymer film having an essentially streak-free coated surface that resists the formation of fog. The film includes a self-supporting polymer film layer, and an anti-fog coating on the film layer. The anti-fog coating, which can also be applied to alternate substrates, consisting essentially of a copolyester binder and an anionic surfactant, wherein the surfactant contains less than about 0.5 weight percent of a fluorosurfactant. A slip agent can also be included in the anti-fog coating.Type: GrantFiled: December 17, 1999Date of Patent: September 24, 2002Assignee: Mitsubishi Polyester Film, LLCInventors: John M. Heberger, Robin M. Donald, Jan C. Westermeier, F. Gene Funderburk, John G. Rollins
-
Patent number: 6444781Abstract: The invention relates to resin intermediates and their preparation. The invention also relates to hydroxyl-functional, water-dispersible polymers formed from the intermediates and compositions containing the water-dispersible polymers. A preferred composition of the invention is a zero volatile organic content (VOC), ambient-cure enamel composition which contains a hydroxyl-functional, water-dispersible polyester.Type: GrantFiled: June 16, 2000Date of Patent: September 3, 2002Assignee: Eastman Chemical CompanyInventors: Thauming Kuo, Jeffery E. G. Powell
-
Patent number: 6433107Abstract: A fiber-forming polyamide composition including a combination of a fiber-forming polyamide with a concentrate having one or more sulfonated aromatic acid reagents in a thermoplastic carrier resin. The concentrate preferably comprises an alkali metal salt of 5-sulfoisophthalic acid, preferably carried in a matrix comprising one or more thermoplastic polyesters or polyamides.Type: GrantFiled: August 28, 2000Date of Patent: August 13, 2002Assignee: Prisma Fibers, Inc.Inventor: Matthew B. Studholme
-
Publication number: 20020091228Abstract: The invention relates to resin intermediates and their preparation. The invention also relates to hydroxyl-functional, water-dispersible polymers formed from the intermediates and compositions containing the water-dispersible polymers. A preferred composition of the invention is a zero volatile organic content (VOC), ambient-cure enamel composition which contains a hydroxyl-functional, water-dispersible polyester.Type: ApplicationFiled: November 27, 2001Publication date: July 11, 2002Applicant: Eastman Chemical CompanyInventors: Thauming Kuo, Jeffery E.G. Powell
-
Patent number: 6414108Abstract: Biodegradable polyether esters P1 obtainable by the reaction of a mixture consisting essentially of: (a1) a mixture essentiall) of 20 to 95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5 to 80 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0 to 5 mol % of a sulphonate group-containing compounds In which the sum of the individual mol percentages is 100; and (a2) a mixture of dihydroxy compounds consisting essentially of (a21) 15 to 99 mol % of a dihydroxy compound selected from the group consisting of C2-C6 alkane diols and C5-C10 cycloalkane diols; (a22) 85 to 0.2 mol % of an ether function-containing dihydroxy compound as in formula I HO—[(CH2)n—O]m—H in which n is 2, 3 or 4 and m is a whole number from 2 to 250, or mixtures thereof, in which the molar ratio of (a1) to (a2) is in the range from 0.4:1 to 1.Type: GrantFiled: September 21, 1999Date of Patent: July 2, 2002Assignee: BASF AktiengesellschaftInventors: Volker Warzelhan, Bernd Bruchmann, Dieter Boeckh, Ursula Seeliger, Motonori Yamamoto, Peter Bauer
-
Publication number: 20020082381Abstract: A polyester ionomer composition comprises an alkylene aryl polyester copolymer having metal sulfonate units represented by the formula IA: 1Type: ApplicationFiled: December 21, 2000Publication date: June 27, 2002Inventors: Bret Ja Chisholm, William David Richards, Timothy Edward Banach
-
Patent number: 6380349Abstract: The present invention relates to golf equipment, such as golf shoes, golf clubs, golf gloves, or portions thereof, formed from compositions comprising a sulfonated, carboxylated, or phosphonated acid moieties, or a mixture thereof. The preferred ionomer composition comprises sulfonated thermoplastic elastomers, sulfonated thermoplastic polymers, sulfonated thermoset polymers, and mixtures thereof. The compositions include a blend of about 1 weight % to about 99 weight % of at least one sulfonated, carboxylated, or phosphonated ionomer and about 99 weight % to about 1 weight % of at least co-component polymer. The co-component polymer may be a conventional ionomer, a thermoplastic, a thermoplastic elastomer, a thermoset polymer, or mixtures thereof.Type: GrantFiled: December 13, 1999Date of Patent: April 30, 2002Assignee: Acushnet CompanyInventor: Murali Rajagopalan
-
Patent number: 6368710Abstract: A sulfonated copolyester of the reaction product of: (a) one or more aromatic dicarboxylic acids or an ester thereof; (b) one or more aliphatic dicarboxylic acids or an ester thereof; (c) one or more sulfonated compound; and (d) isosorbide. The polyesters are useful to form articles of increased biodegradability.Type: GrantFiled: December 19, 2000Date of Patent: April 9, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard Allen Hayes
-
Patent number: 6365315Abstract: The invention relates to a process for the production of spherical, polyester particles, wherein the particle size can be exactly adjusted in the range of 1 to 200 &mgr;m and a particle size distribution with a span (=d90−d10/d50)≦1.5, as well as the use of the produced particles for toner compositions in electrophotographic and direct printing systems and powder coatings.Type: GrantFiled: October 18, 2000Date of Patent: April 2, 2002Assignee: Ticona GmbHInventors: Stefan Wulf, Alexandra Jacobs, Volker Mörs, Toshio Shiwaku, Benett Clayton Ward
-
Patent number: 6362313Abstract: Allyl pendent benzazole polymer system having repeating units of the formula: wherein Bz is a benzazole unit selected from the group consisting of wherein X is —O—, —S— or —NH—, and R is selected from the group consisting of wherein Ar is an aromatic group; and wherein x has a value of about 1.0 to 0.1 and y has a value of 1.0−x.Type: GrantFiled: February 13, 2001Date of Patent: March 26, 2002Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Fred E. Arnold, Thuy D. Dang
-
Patent number: 6355764Abstract: The invention provides a new soluble thermosetting polyethersulfone resin, which can dissolve in ether solvent such as THF and 1,4-Dioxane. The soluble thermosetting polyethersulfone resin can be introduced the unsaturated olefin functional group, after high temperature (>180° C.) curing the unsaturated olefin functional group gets high heat resistant polyethersulfone resin. The soluble thermosetting polyethersulfone resin is made by two steps reaction, the dihalodiphenylsulfone reacts with dihydroxy aromatic compound and dihydroxybenzoic acid to form carboxy group terminated polyethersulfone resin, then the carboxy group terminated polyethersulfone resin react with unsaturated olefin alcohol or glycidyl acrylate or their derivatives to make soluble thermosetting polyethersulfone resin.Type: GrantFiled: November 13, 2000Date of Patent: March 12, 2002Assignee: Lead Data Inc.Inventors: Shung-Yaw Hun, Fu-Kang Huang, Tsung-Yi Yeh, Tsu Hsien Han, Ro Ching Liu
-
Patent number: 6353083Abstract: This invention relates to: (a) fluorene copolymers comprising at least 10% (by residual monomeric units) of 9-substituted and/or 9,9-disubstituted fluorene moieties and at least two other monomeric units containing delocalized p-electrons, (b) polymer blends comprising at least 10 weight % of a copolymer specified in (a), and (c) electronic devices (such as polymer light emitting diodes) containing one or more films derived from these copolymers.Type: GrantFiled: April 9, 1999Date of Patent: March 5, 2002Assignee: The Dow Chemical CompanyInventors: Michael Inbasekaran, Weishi Wu, Edmund P. Woo, Mark T. Bernius
-
Patent number: 6348561Abstract: An alkali sulfonated polyester-amine resin generated from the reaction of an organic diol, and a mixture of an organic diacid, an alkali sulfonated diacid and an amino-organic diacid.Type: GrantFiled: April 19, 2001Date of Patent: February 19, 2002Assignee: Xerox CorporationInventors: Walter Mychajlowskij, Daniel A. Foucher, Raj D. Patel, Guerino G. Sacripante
-
Patent number: 6334877Abstract: A fiber-forming polyamide composition contains a fiber forming polyamide and a sulfonated polyester concentrate, the concentrate disabling and dye sites in the polyamide so that fibers formed from the composition will have enhanced stain and soil resistance. The sulfonated polyester concentrate contains a reagent, preferably an alkali metal salt of 5-sulfoisophthalic acid, and thermoplastic polyester, preferably one or more of PET PTT, PBT, PETG and poly(ethylene terephthalate-co-isophthalate).Type: GrantFiled: June 14, 2000Date of Patent: January 1, 2002Assignee: Prisma Fibers, Inc.Inventor: Matthew B. Studholme
-
Patent number: 6331606Abstract: A composition and a process for producing the composition are provided. The composition comprises repeat units derived from 1,3-propanediol; an organic acid, preferably a dicarboxylic acid, its salt, its ester, or combinations of two or more thereof; a polyether diol; and a sulfonated comonomer. The polyether diol can be present in the composition in the range of from about 10 to about 80 weight %. The process comprises contacting 1,3-propanediol with the organic acid, the polyether diol, and the sulfonated comonomer. The sulfonated comonomer can have the formula of (R′OC(O))2A(R)zS(O)2OM in which each R′ can be the same or different and is each independently hydrogen, a C1 to C4 alkyl group, or a C1 to C4 hydroxyalkyl group; each R is independently a C1 to C4 alkyl group; A is an alkylene or arylene group; z is a number of from 0 to 2; and M is hydrogen, alkali metal ion, alkaline earth metal ion, quaternary ammonium, or ammonium ion.Type: GrantFiled: December 1, 2000Date of Patent: December 18, 2001Assignee: E. I. du Pont de Nemours and ComapnyInventor: Yanhui Sun
-
Publication number: 20010051706Abstract: This invention relates to water-dispersible sulfopolyesters comprising residues of (i) terephthalic acid; (ii) an amount sufficient to provide water-dispersibility to the sulfopolyester of at least one difunctional sulfomonomer containing at least one sulfonate group bonded to an aromatic ring; (iii) less than 5 mole % of at least one dicarboxylic acid that is not terephthalic acid or a sulfomonomer; (iv) 25 to 90 mole % of at least one polyethylene glycol having the structure:Type: ApplicationFiled: December 3, 1999Publication date: December 13, 2001Inventors: SCOTT E. GEORGE, BERNARD J. MENTRO, MICHAEL J. ABROSINI
-
Patent number: 6316586Abstract: A copolyether composition that can be used to produce a dyeable polyester is provided. The composition can comprise repeat units derived from a first diol such as, for example, 1,3-propanediol and a sulfonated dicarboxylic acid such as, for example, 5-sulfo-isophthalic acid. The dyeable polyester composition can comprise repeat units derived from the copolyether composition, an acid such as, for example, terephthalic acid, and a second diol such as, for example, 1,3-propanediol. Also disclosed is a process that can be used for producing the copolyether composition. The process comprises contacting the first diol with the sulfonated dicarboxylic acid.Type: GrantFiled: August 15, 2000Date of Patent: November 13, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Hari Babu Sunkara, Yali Yang
-
Patent number: 6300424Abstract: Hyperbranched polyester and polyamide polymers are prepared by a one-step process of polymerizing a monomer of the formula A—R—B2 so that high molecular weight globular polymers having a multiplicity of a particular functional group on the outside surface are obtained.Type: GrantFiled: July 19, 1993Date of Patent: October 9, 2001Assignee: Cornell Research Foundation, Inc.Inventors: Jean M. J. Frechet, Craig J. Hawker, Kathryn Uhrich
-
Patent number: 6287656Abstract: Amorphous copolyesters containing residues derived from 2,2′-[2,2-](sulfonylbis(4,1-phenyleneoxy))bis(ethanol). They exhibit enhanced heat distortion temperatures and glass transition temperatures without a significant increase in viscosity at low shear rates. The amorphous copolyesters also have improved resistance to attack by lipid solutions and are readily molded and extruded to form medial devices such as connectors, tubes, etc. which are useful for transport of lipids and other medical solutions.Type: GrantFiled: December 1, 2000Date of Patent: September 11, 2001Assignee: Eastman Chemical CorporationInventors: S. Richard Turner, Gary W. Connell, Bobby J. Sublett
-
Patent number: 6245862Abstract: The present invention relates to a golf ball, comprising a cover, a core and optional intermediate layers, wherein the various ball components are formed from compositions comprising a sulfonated and/or phosphonated ionomer. The sulfonated and/or phosphonated ionomer preferably comprises sulfonated thermoplastic elastomers, sulfonated thermoplastic polymers, sulfonated thermoset polymers and mixtures thereof. The compositions include a blend of about 1 wt. % to about 99 wt. % of at least one sulfonated and/or phosphonated ionomer and about 99 wt. % to about 1 wt. % of at least co-component polymer. The co-component polymer may be a conventional ionomer, a thermoplastic, a thermoplastic elastomer, a thermoset polymer or mixtures thereof.Type: GrantFiled: May 28, 1998Date of Patent: June 12, 2001Assignee: Acushnet CompanyInventor: Murali Rajagopalan
-
Patent number: 6228975Abstract: A polyalkylene naphthalate for a film, which comprises a naphthalenedicarboxylic acid component as a main dicarboxylic acid component and an aliphatic glycol component as a main glycol component, and contains (a) an antimony compound and (b) a quaternary phosphonium sulfonate compound unit having an ester-forming functional group in such amounts that satisfy the following expressions (1) and (2): 0<Sb≦80 (1) 0<S/Sb≦0.4 (2) wherein Sb and S are the molar ratios (mmol %) of the antimony compound and the quaternary phosphonium sulfonate compound unit having an ester-forming functional group to the total of all the dicarboxylic acid components forming the polyalkylene naphthalate, respectively. The film of the present invention has excellent surface flatness and is suitable for use as a base film for a magnetic recording medium. It is also excellent in high-speed winding properties and can be formed into a film stably and produced industrially advantageously.Type: GrantFiled: December 8, 1999Date of Patent: May 8, 2001Assignee: Teijin LimitedInventors: Tomokatsu Ura, Masahiko Kosuge, Hideshi Kurihara
-
Patent number: 6171685Abstract: Provided are water-dispersible sulfopolyester compositions having relatively large proportions of pigments and/or fillers. Such compositions are useful as packaging materials and are substantially non-blocking when processed using packaging rolls and are comprised of at least one sulfopolyester as described herein, about 10 to about 75 weight percent of a pigment and/or filler, and a wax.Type: GrantFiled: November 26, 1999Date of Patent: January 9, 2001Assignee: Eastman Chemical CompanyInventors: Scott Ellery George, Richard Anthony Miller, Jimmy Ray Trotter, Jayne Webb Lettich, Sammy Ray Repass
-
Patent number: 6165701Abstract: A base film for photographic films formed from a copolyester comprising 97 to 100 mol % of 2,6-naphthalenedicarboxylic acid and 0 to 3 mol % of a dicarboxylic acid other than 2,6-naphthalenedicarboxylic acid and (i) 87 to 99.8 mol % of ethylene glycol, 0.2 to 10 mol % of bis[4-(.omega.-hydroxyalkoxy)phenyl]sulfone and 0 to 3 mol % of a glycol other than ethylene glycol and bis[4-(.omega.-hydroxyalkoxy)phenyl]sulfone or (ii) 97 to 100 mol % of ethylene glycol, 0 to 3 mol % of a diol other than ethylene glycol and 1 to 7 mol % of an oxycarboxylic acid. This base film has an endothermic peak having a peak top temperature, measured by a differential scanning calorimeter, of 120 to 160.degree. C. and showing an endothermic energy of 0.3 mJ/mg or more.Type: GrantFiled: November 14, 1997Date of Patent: December 26, 2000Assignee: Teijin LimitedInventors: Mitsuru Teramoto, Manabu Kimura, Shinya Watanabe, Koji Furuya, Kenji Suzuki
-
Patent number: 6162890Abstract: Disclosed are linear, water-dispersible sulfopolyesters incorporating a low molecular weight polyethylene glycol and blocks of a high molecular weight polyethylene glycol. The block sulfopolyesters have improved toughness, abrasion resistance, flexibility, and adhesion. Particular utility is realized in polyester fiber sizing applications and as an adhesive.Type: GrantFiled: October 20, 1997Date of Patent: December 19, 2000Assignee: Eastman Chemical CompanyInventors: Scott Ellery George, Bobby Jones Sublett, Richard Anthony Miller
-
Patent number: 6133382Abstract: A fiber-forming polyamide composition contains a fiber forming polyamide and a sulfonated polyester concentrate, the concentrate disabling and dye sites in the polyamide so that fibers formed from the composition will have enhanced stain and soil resistance. The sulfonated polyester concentrate contains a reagent, preferably an alkali metal salt of 5-sulfoisophthalic acid, and thermoplastic polyester, preferably one or more of PET, PTT, PBT, PETG and poly(ethylene terephthalate-co-isophthalate).Type: GrantFiled: November 12, 1998Date of Patent: October 17, 2000Assignee: Prisma Fibers, Inc.Inventor: Matthew B. Studholme
-
Patent number: 6121351Abstract: Thermoplastic compositions containing certain anthraquinone polysulfonamide colorants incorporated therein as toners or colorants. The anthraquinone colorant moieties which are incorporated into the polymer chain of the polysulfonamide colorants are not leachable, sublimable or extractable and do not exude from the thermoplastic compositions. The anthraquinone polysulfonamide colorants may be added to the thermoplastic polymers during production or melt blended with the polymer by conventional techniques to produce transparent thermoplastic compositions useful for a variety of end uses where nonmigrating or nonextractable colorants are needed.Type: GrantFiled: August 7, 1997Date of Patent: September 19, 2000Assignee: Eastman Chemical CompanyInventors: Max Allen Weaver, Wayne Payton Pruett, Kay Hunt Shackelford, Samuel David Hilbert
-
Patent number: 6120889Abstract: The invention relates to an amorphous copolyester having a maximum melt viscosity at 1 radian/second and at about 260 to about 290.degree. C. of about 12000 poise, a glass transition temperature ranging from about 88.degree. C. to about 120.degree. C., and an inherent viscosity of at least about 0.6 dl/g. The amorphous copolyesters comprise the reaction product of a diol component and a dicarboxylic acid component. The diol component comprises residues of from about 5.0 to about 50 mole % of 2,2'-(sulfonylbis(4,1 -phenyleneoxy))-bis(ethanol) which has the following chemical formula: ##STR1## and from about 50 to about 95 mole % of a mixture of at least two diols selected from the group consisting of ethylene glycol, neopentyl glycol, 1,3-propanediol, 1,4-butanediol, 1,4-cyclohexanedimethanol, and mixture thereof. The dicarboxylic acid component comprises residues of terephthalic acid, isophthalic acid, 1,4-cyclohexandedicarboxylic acid, 2,6-naphthalene dicarboxylic acid and mixtures thereof.Type: GrantFiled: June 3, 1999Date of Patent: September 19, 2000Assignee: Eastman Chemical CompanyInventors: S. Richard Turner, Bobby J. Sublett
-
Patent number: 6117532Abstract: An oriented polyester film coated on at least one surface with a coating that improves its adhesion to gelatin is disclosed. The dry coating contains one or more sulfopolyesters; one or more tetrablock copolymer resins; and one or more non-volatile polyamines. Other ingredients, such as particulate materials and surfactants, may be present in the coating. The coating is preferably applied at the interdraw stage.Type: GrantFiled: October 30, 1997Date of Patent: September 12, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: Junaid Ahmed Siddiqui, Cornell Chappell, Jr
-
Patent number: 6074758Abstract: A poly(hydroxy ester ether) is prepared by reacting a) a diacid containing a hetero moiety of the formula:HO.sub.2 CCH.sub.2 X(RX).sub.y CH.sub.2 CO.sub.2 Hwherein X is selected from the group consisting of --O--, --S--, and NH; y is the whole number 0 or 1; and R is selected from the group consisting of an aromatic moiety and a heterocyclic moiety having from 6 to 30 carbon atoms; andb) a diglycidyl ether generally represented by the formula: ##STR1## wherein R.sup.2 is an aromatic moiety or divalent aliphatic hydrocarbon having 2 to 20 carbon atoms. Films, articles and laminations made from the composition exhibit an oxygen permeability of less than about 8 cc-mil/100 in.sup.2 -24 hour-atmosphere. The present invention is further directed to a miscible blend having the poly(hydroxy ester ether) of the present invention and a second component selected from a saturated polyester of an aromatic diacid, such as PET and PEN.Type: GrantFiled: November 4, 1999Date of Patent: June 13, 2000Assignee: Eastman Chemical CompanyInventor: Robert Boyd Barbee
-
Patent number: 6066694Abstract: A thermoplastic resin composition comprising:(a) Alkylene aryl polyester copolymers having metal sulfonate units represented by the formula IA: ##STR1## or the formula IB:(M.sup.+n O.sub.3 S).sub.d --A--(OR"OH).sub.pwhere p=1-3, d=1-3, p+d=2-6, n=1-5, and A is an aryl group containing one or more aromatic rings where the sulfonate substituent is directly attached to an aryl ring, R" is a divalent alkyl group and the metal sulfonate group is bound to the polyester through ester linkages;(b) An essentially amorphous polycarbonate, polyester carbonate or polyarylate polymer containing recurring units of the formula II: ##STR2## wherein Ar is divalent aromatic residue of a dicarboxylic acid or mixture of dicarboxylic acids and Ar' is the divalent aromatic residue of a dihydric phenol or mixture of dihydric phenols. The composition may further comprise acidic phosphorus based quenchers, rubbery impact modifiers, mineral fillers or reinforcements.Type: GrantFiled: March 4, 1998Date of Patent: May 23, 2000Assignee: General Electric CompanyInventors: Bret Ja Chisholm, Robert R. Gallucci, William P. England, Patricia A. Hubbard, William D. Richards, Jenny Z. Bu
-
Patent number: 6046253Abstract: An ink jet ink composition comprising from about 0.5% to about 30% by weight of a pigment, a carrier and a sulfonated polyester dispersant in a ratio of dispersant:pigment from about 0.1:1 to about 5:1.Type: GrantFiled: September 10, 1998Date of Patent: April 4, 2000Assignee: Eastman Kodak CompanyInventors: David Erdtmann, Elizabeth G. Burns, John Dicillo
-
Patent number: 6031043Abstract: A topical composition comprising an aqueous phase containing a hydrophilic gelling agent of polyester sulphone type selected from water-soluble or water-dispersible terephthalic copolyester oligomers comprising repeating dicarboxylate units of formula (I):CO--A--CO--O(CH.sub.2 CH.sub.2 O).sub.nwherein the weight-average molecular mass of the copolyester oligomer is less than 20,000, preferably less than 15,000, and a cosmetic treatment process for the skin, mucous membranes or the exoskeleton, in which a composition according to the invention is applied to the skin, mucous membranes or the exoskeleton.Type: GrantFiled: March 16, 1998Date of Patent: February 29, 2000Assignee: L'OrealInventors: Christine Dupuis, Henri Samain
-
Patent number: 6020420Abstract: This invention provides crystalline, water-dispersible polyesters comprising residues of 4,4'-biphenyl dicarboxylic acid. The polyesters comprise residues of 4,4'-biphenyl dicarboxylic acid, at least one difunctional sulfomonomer in an amount sufficient to provide water dispersibility to the polyester, and a glycol or a mixture of glycols. The polyesters of the invention are useful in ink and adhesive compositions.Type: GrantFiled: March 10, 1999Date of Patent: February 1, 2000Assignee: Eastman Chemical CompanyInventor: Scott Ellery George
-
Patent number: 6001910Abstract: A remoistenable hot melt adhesive composition comprising (i) 25 to 80% by weight of a sulfonated polyester;(ii) 3 to 40% by weight of an anionic or cationic plasticizer;(iii) 0 to 40% by weight of a polar tackifier;(iv) 0 to 3% by weight of an antioxidant; and(v) 10 to 35% by weight of a polar wax; and(vi) optionally 0 to 30% nonionic plasticizer, wherein the total of (i)-(vi) to equal 100% by weight.Type: GrantFiled: April 9, 1999Date of Patent: December 14, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventors: Mitchell J. Blumenthal, Charles W. Paul, Matthew L. Sharak
-
Patent number: 5985437Abstract: An oriented polyester film coated on at least one surface with a coating that improves its adhesion to water-based coatings is disclosed. The coating contains at least one sulfopolyester; at least one tetrablock copolymer resin; and at least one acrylamide/acrylic acid copolymer or salts thereof. Other ingredients, such as particulate materials and surfactants, may be present in the coating. The coating is preferably applied at the interdraw stage.Type: GrantFiled: December 4, 1997Date of Patent: November 16, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Cornell Chappell, Jr., Junaid A. Siddiqui
-
Patent number: 5958552Abstract: A laminated film comprising (A) an aromatic polyester film; and (B) a hydrophilic coating layer which is present on at least one side of the aromatic polyester film (A) and has a surface energy of at least 54 dyne/cm, the coating layer comprising (a) 50 to 80% by weight of a copolyester which contains a dicarboxylic acid component having a sulfonate group in an amount of 1 to 16 mol % of the total of all dicarboxylic acid components and has a secondary transition point of 20 to 90.degree. C., (b) 10 to 30% by weight of poly(alkylene oxide) homopolymer having a number average molecular weight of 600 to 2,000, and (c) 3 to 25% by weight of fine particles having an average particle diameter of 20 to 80 nm, based on the total of components (a), (b) and (c). The above laminated film is useful as a transparency for an overhead projector and a recording paper for an ink jet printer.Type: GrantFiled: February 26, 1996Date of Patent: September 28, 1999Assignee: Teijin LimitedInventors: Masayuki Fukuda, Hiroshi Tomita
-
Patent number: 5928460Abstract: Disclosed is an essentially odorless water dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. The copolyester adhesive composition can be used neat or formulated and exhibits broad compatibility with a variety of adhesive additives, including non polar tackifiers.Type: GrantFiled: February 2, 1998Date of Patent: July 27, 1999Assignee: Eastman Chemical CompanyInventors: Richard Anthony Miller, Scott Ellery George
-
Patent number: 5922829Abstract: Disclosed is are high molecular weight copolyester compositions which possess high melt viscosity and melt strength which render them foamable with a wide range of foaming agents. The copolyesters consist essentially of (A) diacid residues comprising (i) from about 99.9 to about 95 mol % of residues of an aromatic dicarboxylic acid having 8 to 12 carbon atoms and (ii) from about 0.1 to about 5.0 mol % of residues of an aromatic dicarboxylic acid sulfonate monomer containing at least one divalent metal sulfonate group attached to an aromatic nucleus, and (B) diol residues comprising residues of at least one aliphatic or cycloaliphatic diol having 2 to 8 carbon atoms, the mol % being based on 100 mol % dicarboxylic acid residues and 100 mol % diol residues.Type: GrantFiled: September 16, 1998Date of Patent: July 13, 1999Assignee: Eastman Chemical CompanyInventor: Kishan Chand Khemani
-
Patent number: 5919403Abstract: This invention relates to homopolyester compositions having fluorescence quenchers polymerized therein ("poly quenchers"). Specifically the "poly quencher" polymeric compositions comprises repeating units from(a) a dicarboxylic acid component and(b) a diol component, wherein at least one of (a) and (b) is comprised of at least one fluorescence polyquencher capable of reducing fluorescence of a polymer below the fluorescence displayed when said polyquencher is not included.Type: GrantFiled: December 22, 1995Date of Patent: July 6, 1999Assignee: Eastman Chemical CompanyInventors: Allan Scott Jones, Jean Carroll Fleischer, Max Allen Weaver
-
Patent number: 5817721Abstract: A biodegradable polyester obtainable by reacting a mixture comprising(a1) from 95 to 99.9% by weight of a polyester P1 obtainable by reacting a mixture essentially comprising(b1) a mixture comprising35-95 mol % of adipic acid or ester-forming derivatives thereof,5-65 mol % of terephthalic acid or ester-forming derivatives thereof, and0-5 mol % of a compound containing sulfonate groups, and(b2) a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,with the proviso that a compound D with at least three groups capable of ester formation is employed to prepare the polyester P1,(a2) from 0.1 to 5% by weight of a divinyl ether C1 and(a3) from 0 to 5 mol %, based on component (b1) from the preparation of P1, of compound D,and other biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings and adhesives.Type: GrantFiled: May 12, 1997Date of Patent: October 6, 1998Assignee: BASF AktiengesellschaftInventors: Volker Warzelhan, Gunnar Schornick, Matthias Kroner, Ursula Seeliger, Motonori Yamamoto, Rainer Buschl
-
Patent number: 5817740Abstract: New polyester composition for new polyester staple fiber that provides fabrics having a combination of excellent pilling performance, aesthetics and tactility ("hand"). Preferred fibers have non-round cross-sections that are retained, especially such non-round cross-sections having multi-grooved scalloped-oval cross-sections that provide fabrics having outstanding comfort qualities of moisture-management, dryness and comfort, along with minimal pilling.Type: GrantFiled: December 17, 1997Date of Patent: October 6, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Harvey Gene Anderson, Arun Pal Aneja, Robert Lee Edmundson, Adrian Charles Snyder
-
Patent number: 5807962Abstract: A sulfonated dicarboxylic acid and a diaromatic carbonate are reacted by a solution process to form a sulfonated aromatic diester such as diphenyl sodium 5-sulfoisophthalate. The sulfonated aromatic diester is reacted with an aromatic polymer precursor mixture such as bisphenol A and diphenyl carbonate, polymer or combination thereof, at a temperature above the melting point of the polymer or a member of the aromatic polymer precursor to form a randomly positioned sulfonated aromatic moiety in a polymer chain of a thermoplastic non-crosslinked aromatic polymer such as a linear polycarbonate.Type: GrantFiled: August 20, 1997Date of Patent: September 15, 1998Assignee: The Dow Chemical CompanyInventors: Ray E. Drumright, Michael J. Mullins, William B. Marshall, Edvins L. Daiga
-
Patent number: 5780151Abstract: Disclosed is a radiation crosslinkable water-dispersible adhesive composition that is useful in forming paper and plastic articles and other products that can be recycled through a process which includes washing or repulping in aqueous media. The cross-linkable water-dispersible adhesive composition is preferably used as a hot melt adhesive. The cross-linkable water-dispersible adhesive composition is a low molecular weight, branched copolyester containing a sulfomonomer and unsaturated moieties. The radiation crosslinked adhesive composition has more cohesive strength and viscosity than its corresponding uncross-linked adhesive, yet is still water-dispersible during product recycling.Type: GrantFiled: December 8, 1995Date of Patent: July 14, 1998Assignee: Eastman Chemical CompanyInventors: Richard Anthony Miller, Scott Ellery George
-
Patent number: 5770558Abstract: The subject invention involves processes for making granular compositions comprising soil release polymers, the polymers comprising at least about 10% of substantially linear esters having a backbone; the esters being uncapped or end-capped on one or both ends of the backbone; the esters comprising in their backbones oxyalkyleneoxy units and hydrophobic aryldicarbonyl units; the esters having a molecular weight of from about 500 to about 20,000; the polymers if in solid state having the tendency when exposed to moisture to spontaneously rearrange from an amorphous form which is readily soluble in water to a crystalline form which is relatively insoluble in water; the process comprising the following steps:a) taking the soil release polymers, in which are dispersed from 0% to about 25% alkylaryl or alkyl sulfonate crystallization-reducing stabilizers, in molten state at a temperature of at least about 180.degree. C.Type: GrantFiled: August 27, 1997Date of Patent: June 23, 1998Assignee: The Procter & Gamble CompanyInventors: Benjamin Edgar Chapman, Michael Timothy Creedon
-
Patent number: 5756645Abstract: The yield of fully substituted, multidimensional aromatic hubs in the condensation of hydroxyl and acid halide functionalities is improved by adding a thallium catalyst, such as thallium ethoxide (Tl-OC.sub.2 H.sub.5), in the solvent.Type: GrantFiled: June 6, 1995Date of Patent: May 26, 1998Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard, Ronald R. Stephenson
-
Patent number: 5750635Abstract: This invention relates to a thermally stable polyester, comprising:a polyester resin prepared by adding a dicarboxylic acid to a glycol compound, said dicarboxylic acid selected from the group consisting of aliphatic dicarboxylic acids having a total of from 3 to 16 carbon atoms, alicyclic dicarboxylic acids having 7 to 12 carbon atoms, aromatic dicarboxylic acids containing a total of from 8 to 16 carbon atoms, and combinations thereof, and wherein said glycol is selected from the group consisting of glycols having from 2 to 12 carbon atoms, glycol ethers having from 4 to 12 carbon atoms, and combinations thereof,said polyester resin having been prepared in the presence of a catalyst system consisting essentially of one or more antimony compounds which is not reacted with .alpha.-hydroxy carboxylic acids, .alpha.,.beta.-dicarboxylic acids or derivatives thereof.Type: GrantFiled: December 6, 1996Date of Patent: May 12, 1998Inventors: Andrew Edwin Brink, Wayne Payton Pruett, Clinton Cherry, Kay Hunt Shackelford
-
Patent number: 5744538Abstract: Disclosed is an essentially odorless water dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. The copolyester adhesive composition can be used neat or formulated and exhibits broad compatibility with a variety of adhesive additives, including non polar tackifiers.Type: GrantFiled: August 28, 1995Date of Patent: April 28, 1998Assignee: Eastman Chemical CompanyInventors: Richard Anthony Miller, Scott Ellery George
-
Patent number: 5739261Abstract: Oxysulfonylated polyesters, well suited for conversion into oriented composite polyester films, are prepared by polycondensing a lower alkyl diester of at least one aliphatic dicarboxylic acid and a lower alkyl diester of at least one aromatic dicarboxylic acid bearing an oxysulfonyl substituent, and optionally a lower alkyl diester of at least one aromatic dicarboxylic acid, with at least one diol, in the presence of a catalytically effective amount of at least one titanium compound and at least one manganese carboxylate.Type: GrantFiled: June 5, 1995Date of Patent: April 14, 1998Assignee: Rhone-Poulenc FilmsInventors: Jean-Pierre Assante, Etienne Fleury, Didier Veyrat
-
Patent number: 5718790Abstract: Disclosed is a water-dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water-dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. Additional utility for the invention resides in the manufacture of recyclable articles where insolubility in body fluids combined with solubility in tap water are required.Type: GrantFiled: October 31, 1995Date of Patent: February 17, 1998Assignee: Eastman Chemical CompanyInventors: Richard A. Miller, Theron E. Parsons, III, Mark A. Montgomery