Abstract: Disclosed are compositions and methods of making a liquid fertilizer additive of biodegradable polymeric and/or oligomeric nitrification inhibitors comprised of utilizing a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with cyano-containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols.

Abstract: The present invention relates to compositions for increasing a nitrogen source life span in plant growth mediums as well as methods of making these compositions. The invention also relates to compositions and methods of reacting a nitrogen source with one or more nitrification inhibitors using standard equipment for producing nitrogen sourced particles.

Abstract: The present invention relates to bioavailable (which may also be referred to as plant available) silicon, such as in the form of a concentrate or solid, and processes for producing and using bioavailable silicon.

Abstract: Disclosed are compositions and methods of making a liquid fertilizer additive solution of polymeric and/or oligomeric heterocyclic nitrogen containing nitrification inhibitors comprising a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with heterocyclic nitrogen containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols.

Abstract: Disclosed are compositions and methods of making a liquid fertilizer additive of biodegradable polymeric and/or oligomeric nitrification inhibitors comprised of utilizing a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with cyano-containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary amines, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols.

Abstract: Disclosed are compositions and methods of making a liquid fertilizer additive of biodegradable polymeric and/or oligomeric nitrification inhibitors comprised of utilizing a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with cyano-containing nitrification inhibitors that have one or more aldehyde reactive groups selected from the group consisting of a) primary, b) secondary amines, c) amides, d) thiols, e) hydroxyls and f) phenols.

Abstract: The invention relates to a particulate urea-based composition comprising elemental sulphur and a urease inhibitor of the type phosphoric triamide, wherein the urea-based composition comprising elemental sulphur is further characterized in that it comprises a magnesium sulphate. The composition according to the invention has improved properties for reducing ammonia loss by urease activity in the soil and is in particular suitable as a fertilizer. The invention further relates to a method for the manufacture of a particulate urea-based composition comprising urea, elemental sulphur and a urease inhibitor of the type phosphoric triamide, in particular N-(n-butyl) thiophosphoric triamide (nBTPT), as well as to a composition of kit of parts comprising a magnesium sulphate.

Abstract: In embodiments, the present invention relates to liquid formulations containing hydrophobic, biodegradable polymers dispersed within a Non-aqueous Organic Solvent Delivery System (NOSDS) that is designed to coat fertilizer granules with a hydrophobic film utilizing simple application equipment such as mixers, blenders and tumblers. This film can impede the dissolution of fertilizer components by water improving fertilizer efficiency. The NOSDS can be aprotic solvents, protic solvents and mixtures of protic and aprotic solvents which are environmentally friendly, have flashpoints above 145° F., and are inherently rated safe for contact with humans and animals. The hydrophobic polymers are the reaction product of aldehyde(s) and nitrogen containing compounds.

Abstract: Precipitation of an ammonium salt is prevented while suppressing an increase in water content of the aqueous urea solution which is to be supplied to a urea granulation step, when recovering and using urea and NH3 in a gas which contains urea dust and NH3 and which arises from a urea granulation step.

Abstract: Reaction products and methods for making and using such reaction products are provided. For example, a reaction product comprising an adduct formed from two or more of a first nucleophile (e.g., including, but not limited to, a urease inhibitor), a second nucleophile, and an electrophile is described, which can be provided in various forms. Such a reaction product can be in the form of a solid or solution. Such a reaction product can also be combined with one or more additional components, including but not limited to, free urease inhibitor and/or a nitrogen-based fertilizer composition.

Abstract: Disclosed are compositions and methods of making a liquid fertilizer additive of biodegradable polymers and/or oligomers comprised of utilizing a non-aqueous polar, aprotic organo liquid (NAPAOL) as the reaction medium for the reaction of aldehyde(s) with cyano-containing nitrification inhibitors that have one or more groups that react with the aldehyde(s) wherein said reactive groups are selected from the group consisting of a) primary and secondary amines, b) amides, c) thiols, d) hydroxyls and e) phenol.

Abstract: Methods are described for preventing corrosion in a corrosion-aggressive media. The methods include combining a stannous corrosion inhibitor composition with a corrosion-aggressive media (such as a nitrogen-based solution, or more specifically a liquid solution of AN or UAN) to provide a treated solution. The stannous corrosion inhibitor composition may include a caustic. Also described is a liquid including from 0.1 wt % to 25 wt % of a stannous salt and from 1 wt % to 50 wt % of a caustic, and a liquid composition including a solution of urea ammonium nitrate and a stannous material. The liquid and stannous corrosion inhibitor compositions substantially prevent corrosion of a metal surface even when used in very small amounts and at a low pH.

Abstract: The invention is directed to manufacturing fertilizers having commercial levels of nitrogen reacted with organic substances. The process comprises treatment of organics with acid that acidifies and heats a mix causing the hydrolysis of polymers. The acidified organic mix is injected sequentially with a nitrogen base under conditions that result in a partially neutralized melt. The sterilized and liquefied organic matter is disbursed over recycled material for production of granules in a granulator before final drying. The process is green scalable, and safe for the location of community organics processing facilities in locations without generating a nuisance to local communities. Fertilizers also provide a green, dual nitrogen-release profile when applied to crops releasing a bolus of nitrogen over one to two weeks following application followed by a continued slow or enhanced efficiency release of nitrogen over a growing season.

Abstract: A dry, flowable fertilizer is provided that includes multiple dry, flowable biosolids pellets. Each of the pellets has a pellet surface. Potassium salt grains are adhered to the pellet surfaces and a dust control agent coating is applied to retain the grains on the pellet surfaces. The resultant dry, flowable fertilizer has higher potassium loadings to the potassium salt grains than previous biosolids based fertilizers. A process of forming a fertilizer is also provided that includes tumbling dry, flowable biosolids pellets with powdered potassium salt grains to form a mixture. An aqueous spray is added to adhere the salt grains to the pellet surfaces. With the application of a dust control agent, the salt grains are retained. Potassium levels in NPK units of from 1 to 15 are routinely achieved with greater than 90 elemental % of the potassium is from the surface decorating potassium salt grains.

Abstract: An improved composition comprising substantial spherical UFP particles and an active agent, such as NBPT, and optionally other components is used as an additive for liquid and solid fertilizers, typically containing urea. Methods of making the compositions and their use are also disclosed.

Abstract: The invention is directed to processes for treating biosolids that result in high-value, nitrogen-containing, slow-release, organically-augmented inorganic fertilizer that are competitive with less valuable or more costly conventional commercially manufactured fertilizers. The process involves conditioning traditional waste-water biosolids and processing the conditioned biosolids continuously in a high throughput manufacturing facility. The exothermic design and closed loop control of the primary reaction vessel decreases significantly the amount of power necessary to run a manufacturing facility. The process utilizes green technologies to facilitate decreased waste and enhanced air quality standards over traditional processing plants. The fertilizer produced from recovered biosolid waste is safe and meets or exceeds the United States Environment Protection Agency (USEPA) Class A and Exceptional Quality standards and is not subject to restrictions or regulations.

Abstract: An agricultural fertigation method includes the continuous charging of crop-quality-enhancer-feedstock comprised of one or more crop-quality enhancers (fertilizers, soil amendments and the like) to an irrigation system upstream of the agricultural field being irrigated. The crop-quality-enhancer-feedstock is diluted upon so charging to a level within the system solubility limits and the stream of flowing irrigation water dampens the resultant dissolution exotherm. A system wherein crop-quality enhancers are efficiently continuously fed to the irrigation system main line or a side-arm mixing chamber efficiently implements the method.

Abstract: An agricultural fertigation method includes the continuous charging of crop-quality-enhancer-feedstock comprised of one or more crop-quality enhancers (fertilizers, soil amendments and the like) to an irrigation system upstream of the agricultural field being irrigated. The crop-quality-enhancer-feedstock is diluted upon so charging to a level within the system solubility limits and the stream of flowing irrigation water dampens the resultant dissolution exotherm. A system wherein crop-quality enhancers are efficiently continuously fed to the irrigation system main line or a side-arm mixing chamber efficiently implements the method.

Abstract: The invention relates to an aqueous solution of a mixture for treating urea-based fertilizers/fertilizers containing ammonium that contains 1,2,4-triazole and 3-methylpyrazole in the weight ratio 2/1 and at least one polyvinyl alcohol, polyvinylpyrrolidone and a tenside.

Abstract: An agricultural fertigation method includes the continuous charging of crop-quality-enhancer-feedstock comprised of one or more crop-quality enhancers (fertilizers, soil amendments and the like) to an irrigation system upstream of the agricultural field being irrigated. The crop-quality-enhancer-feedstock is diluted upon so charging to a level within the system solubility limits and the stream of flowing irrigation water dampens the resultant dissolution exotherm. A system wherein crop-quality enhancers are efficiently continuously fed to the irrigation system main line or a side-arm mixing chamber efficiently implements the method.

Abstract: An improved composition comprising a non-UFP solid carrier and an active agent, such as NBPT, and optionally other components is used as an additive for liquid and solid fertilizers, typically containing urea. Methods of making the compositions and their use are also disclosed.

Abstract: A method for producing urea granules having low moisture absorption capacity, with a urea granulator, having a granule flow inlet side and oppositely a granule flow outlet side, forming an axis alongside which granules from a urea solution and a urea/ammonium salt-stream are formed, whereby the solution and the salt-stream are sprayed as a mixture or separately via a feed system unit via various nozzles into the granulator onto a seed material. In this process the highest amount of the salt-stream is sprayed into the granulator at the granule flow inlet side and the amount of the salt-stream is decreased alongside the axis of the granulator from the granule flow inlet side to the granule flow outlet side.

Abstract: Methods of treating a plant exposed to a phytotoxicant are provided. Embodiments of the subject methods include identifying a plant exposed to a phytotoxicant and applying an assimilable carbon-skeleton energy component-comprising composition to the identified plant. Embodiments of the subject compositions may include one or more of a macronutrient component, micronutrient component, vitamin/cofactor component, complexing agent and microbe. Kits for use in practicing the subject invention are also provided. The subject methods find use in a variety of different applications in which a plant is phytotoxic or at least in danger of becoming phytotoxic due to exposure or potential exposure to a phytotoxicant.

Abstract: A method for producing coated water-soluble particles in a manner to form two or more coating layers on surfaces of the water-soluble particles, characterized by including: a step A wherein after supplying a first coating material that contains a polyol component and an isocyanate component, a second coating material is additionally supplied to surfaces of first coating bodies that have coating layers formed of the first coating material that has not been sufficiently cured, so that second coating bodies that are provided with coating layers of the second coating material are obtained.

Abstract: A method employing a composition of bioavailable minerals directed at supplementing nutritional intake of a living plant. The composition includes the ionic mineral(s) copper and zinc in a ligand complex and a pharmaceutically acceptable carrier including water, H2SO4 and (NH4)2SO4. The composition for use in the method may also include other supporting plant nutrients such as botanical extracts, urea, plant hormones, vitamins and mineral supplements necessary for plant health.

Abstract: A controlled release fertilizer material comprising a particulate plant nutrient surrounded by a coating of a mixture including an isocyanate and a polyol, and further comprising a modified wax that may include a polyhydroxyl compound in which the wax and/or the polyhydroxyl compound are cross-linked with a sulfur or oxygen or a peroxide cross-linking moiety. In certain embodiments, the wax and polyhydroxyl compound are cross-linked at unsaturated sites in the wax or polyhydroxyl compound using heat, UV or ionizing radiation.

Abstract: The present invention provides a boron-containing synergistic urea and preparation method and application thereof, the boron-containing synergistic urea is a product obtained by mixing, dehydrating and pelletizing a mixed aqueous solution of polyaspartic acid chelated potassium (also referred to as “polypeptide chelated potassium”) and a borate amine salt together with molten urea, wherein the above three components are 0.04-0.12%, 0.08-0.24% and 99.64-99.88% by weight, respectively. The boron-containing synergistic urea provided by the present invention is obtained by effectively compositing polypeptide acid chelated potassium, borate amine salt and urea, which also can guarantee the application amount of effective boron, and meanwhile can help avoid excessive high local concentrations of boron, and achieve the purposes of prompting effective absorption of the plant to boron and of improving urea utilization rate.

Abstract: The present invention relates to an improved nitrification inhibitor composition and its use in agricultural applications.

Abstract: Disclosed herein are fluid ionized compositions, such as fluid calcium cyanamide fertilizer compositions, methods of preparation and uses thereof. In some examples, a fluid composition includes a mixture of about 40 to 20 parts of dissolved acid or acid-formed approximately neutral pH nitrogen plant nutrient compounds (such as urea ammonium nitrate and H2O) and about 1 to about 5 parts of a mixture of insoluble or weakly soluble high pH calcium-formed plant nutrient compounds (such as calcium cyanamide and H2O). The disclosed compositions and methods stabilize the compositions' contained active nutrient ions and digested carbon. The disclosed compositions and methods facilitate controllable site-directed delivery of the contents of the compositions. The compositions and methods are effective for microbes nourishment plant fertilizing, soil amending, heavy metals leaching inhibition and, digesting organic proteinaceous excreta.

Abstract: This invention relates to a coating composition for a fertilizer comprising at least 50 wt % of a cross-linked lipid; and less than 0.20 wt %, relative to the total weight of the lipid, of a catalyst for cross-linking an unsaturated lipid. The cross-linked lipid has a viscosity at 20 degree Celsius (° C.) in the range of 110 and 800 mPa·s.

Abstract: A nitrogen fertilizer composition includes urea and a nitrate-based fertilizer such as ammonium nitrate, calcium ammonium nitrate and mixtures of ammonium nitrate and calcium ammonium in which the urea and total nitrogen are at concentrations of 20 percent by weight or greater and the concentration of ammonium nitrate is at 30 percent or greater by weight. One or both of the urea and nitrate-based fertilizer are coated with an agriculturally compatible material. The fertilizer composition provides significant nitrate nitrogen for legitimate agricultural use yet is not amenable to the production of an explosive by crushing or by aqueous extraction. A pleasant smelling odorant is added to the composition to facilitate detection.

Abstract: Controlled release of one or more agricultural chemicals is provided by microcapsules adapted to rupture in a magnetic field. The microcapsules, which may be applied to soil, seeds and/or plants, each have a shell that encapsulates an agricultural chemical, such as a fertilizer, herbicide or insecticide. One or more organosilane-coated magnetic nanoparticles is/are covalently bound into the shell of each microcapsule. For example, (3-aminopropyl)trimethylsilane-coated magnetite nanoparticles may be incorporated into the shell of a urea-formaldehyde (UF) microcapsule during in situ polymerization. In one embodiment, microcapsules encapsulating a fertilizer are applied during seed planting. Controlled release is subsequently triggered after an appropriate period of dormancy by positioning a magnetic field generating device proximate the microcapsules to generate a magnetic field sufficient to rupture the microcapsule shells through magnetic stimulation of the organosilane-coated magnetic nanoparticles.

Abstract: Animal waste is processed to form a biomaterial that is employed as a coating layer for typical fertilizer particles. The biomaterial coating layer can be used neat or with additives and serves to do one or more or any combination of the following: (a) impart a slow or controlled release property to the fertilizer, (b) prevent or reduce the tendency of the fertilizer particles to cake together, or (c) prevent or reduce the tendency of the fertilizer particles to create dust. The biomaterial coating layer can also release nutrients when used as part of a fertilizer composition.

Abstract: The present invention relates to a method and system for producing electric power and fertiliser. The method comprises the steps of: (a) combusting biomass to produce energy for the generation of electric power and an exhaust gas; (b) producing a liquor from compounds extracted from the exhaust gas; and (c) producing a fertiliser by composting organic materials in the presence of the liquor.

Abstract: A controlled release fertilizer composition and methods to produce the controlled release fertilizer composition are described. The controlled release fertilizer composition comprises a water soluble fertilizer core that is coated with a polymeric layer, intermediate layer, and a sulfur layer. If desired, the sulfur layer can be coated with an outer water-insoluble layer.

Abstract: The present invention relates to an improved nitrification inhibitor composition and its use in agricultural applications.

Abstract: The invention is directed to processes for treating biosolids that result in high-value, nitrogen-containing, slow-release, organically-augmented inorganic fertilizer that are competitive with less valuable or more costly conventional commercially manufactured fertilizers. The process involves conditioning traditional waste-water biosolids and processing the conditioned biosolids continuously in a high throughput manufacturing facility. The exothermic design and closed loop control of the primary reaction vessel decreases significantly the amount of power necessary to run a manufacturing facility. The process utilizes green technologies to facilitate decreased waste and enhanced air quality standards over traditional processing plants. The fertilizer produced from recovered biosolid waste is safe and meets or exceeds the United States Environment Protection Agency (USEPA) Class A and Exceptional Quality standards and is not subject to restrictions or regulations.

Abstract: An agricultural fertigation method includes the continuous charging of crop-quality-enhancer-feedstock comprised of one or more crop-quality enhancers (fertilizers, soil amendments and the like) to an irrigation system upstream of the agricultural field being irrigated. The crop-quality-enhancer-feedstock is diluted upon so charging to a level within the system solubility limits and the stream of flowing irrigation water dampens the resultant dissolution exotherm. A system wherein crop-quality enhancers are efficiently continuously fed to the irrigation system main line or a side-arm mixing chamber efficiently implements the method.

Abstract: A fertilizer supplying animal nutrients including a core particle having an outer surface and comprising compounds containing animal nutrients, and a coating of urea on the outer surface of the core particle, and further a process of making the fertilizer including the steps of: screening animal nutrient core particles comprising a powdered substance containing an animal nutrient, to a preselected particle size; spraying melted urea onto the surface of the nutrient core particles to produce a coating on the nutrient core particles; granulating the nutrient core particles with sprayed melted urea to produce nutrient core granules; and cooling the nutrient core granules.

Abstract: The invention relates to a method for recovery of urea dust and ammonia from a gas stream by contacting said gas stream with an aqueous sulphuric acid solution, thus forming an acid solution of ammonium sulphate and urea, characterized in that the acid solution is concentrated to a melt comprising less than 5 wt % of water, which melt is subsequently transferred into solid particles comprising urea and ammonium sulphate.

Abstract: Multiple-component fertilizer materials and methods of use are provided, wherein the fertilizer materials include first and second fertilizer products respectively including an ammoniacal fertilizer (e.g., urea) in combination with a partial calcium salt of a selected copolymer, and a phosphorous fertilizer (e.g., DAP) in combination with a partial sodium salt of a selected copolymer. The copolymer fractions of the first and second fertilizer products are most preferably copolymers of itaconic acid and maleic anhydride. The fertilizer materials give synergistically enhanced crop yields when applied to soil or growing plants.

Abstract: Solutions are prepared by dissolving N-(n-butyl)-thiophosphoric triamide (NBPT) in one or more N-alkyl amino alcohols, N,N-dialkyl amino alcohols, N-alkyl-N-alkoxy amino alcohols, and mixtures thereof. The solutions may be used in urea fertilizers to reduce nitrogen volatilization, or to reduce the odor of animal waste. Methods of preparing urea fertilizers and the resultant products are also described.

Abstract: An agricultural fertigation method includes the continuous in situ manufacture of one or more fertilizers within the irrigation system upstream of the agricultural field being irrigated. Co-reactant raw materials, namely sulfuric acid, phosphoric acid, nitric acid, potassium hydroxide, urea, ammonium hydroxide, ammonia, calcium nitrate and/or magnesium nitrate, are intermixed with each other and with the stream of the flowing irrigation water. The stream of flowing irrigation water dampens the resultant dissolution and reaction exotherms. A system wherein raw materials are efficiently continuously fed to the irrigation system main line or a side-arm reactor efficiently implements the method.

Abstract: A macronutrient sustained release composition for a plant locus having nitrogen containing macronutrient compound adsorbed on the surface of hydroxyapatite phosphate nanoparticles, and a process for preparation thereof. The macronutrient adsorbed hydroxyapatite phosphate nanoparticles are encapsulated within cavities present in wood such that the biodegradation of the wood releases the adsorbed macronutrient compounds in a slow and sustained manner to the soil. Further, the macronutrient particles are encapsulated within the cell cavities of wood and wood is coated with cellulose modified hydroxyapatite phosphate nanoparticles such that the rupture of the nanocoating initiates the nitrogen release followed by the biodegradation of the wood releases the rest of the adsorbed macronutrient compounds in a slow and sustained manner to the soil.

Abstract: A mixture for the treatment of urea-containing fertilizers comprises a) at least one (thio)phosphoric acid triamide of the general formula (I) R1R2N—P(X)(NH2)2 and/or (thio)phosphoric acid diamide of the general formula (II) R1O—P(X)(NH2)2, X denoting oxygen or sulfur, R1 and R2 independently from each other being hydrogen, substituted or unsubstituted 2-nitrophenyl, C1-10-alkyl, C3-10-cycloalkyl, C3-10-heterocycloalkyl, C6-10-aryl, C6-10-heteroaryl or diaminocarbonyl, where R1 and R2 together with the nitrogen atom connecting them can also form a 5 or 6-membered saturated or unsaturated heterocyclic group, which optionally may also comprise one or two additional heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, as component A, and b) at least one compound comprising an amino group having a boiling point of more than 100° C. as component B.

Abstract: A dust suppressing aggregate includes a core particle and a dust suppressing agent. The dust suppressing agent comprises polyurethane and is disposed about the core particle for suppressing dusting of the core particle. A method of forming the dust suppressing aggregate includes the steps of providing the core particle and encapsulating the core particle with the polyurethane.

Abstract: An agricultural fertigation method includes the in situ manufacture of one or more fertilizers within the irrigation upstream of the agricultural field being irrigated. Co-reactant raw materials, namely sulfuric acid, phosphoric acid, nitric acid, potassium hydroxide, urea, ammonium hydroxide, ammonia, calcium nitrate and/or magnesium nitrate, are intermixed with each other and with the stream of the flowing irrigation water. The stream of flowing irrigation water dampens the resultant dissolution and reaction exotherms. A system wherein raw materials are efficiently fed to the irrigation system main line or a side-arm reactor efficiently implements the method.

Abstract: A dry flowable additive for aqueous urea-based fertilizers made of solid urea formaldehyde polymer (UFP), N-(n-butyl) thiophosphoric triamide (NBPT), and, optionally, dicyandiamide (DCD), wherein the liquid fertilizer containing the additive provides reduced nitrogen loss from the soil. Optionally, the dry additive may also be blended with molten or solid urea to form a solid urea-based fertilizer with reduced nitrogen loss from the soil.

Abstract: A dry flowable additive for aqueous urea-based fertilizers made of solid urea formaldehyde polymer (UFP), N-(n-butyl) thiophosphoric triamide (NBPT), and, optionally, dicyandiamide (DCD), wherein the liquid fertilizer containing the additive provides reduced nitrogen loss from the soil. Optionally, the dry additive may also be blended with molten or solid urea to form a solid urea-based fertilizer with reduced nitrogen loss from the soil.

Abstract: The invention is directed to processes for treating biosolids that result in high-value, nitrogen-containing, slow-release, organically-augmented inorganic fertilizer that are competitive with less valuable or more costly conventional commercially manufactured fertilizers. The process involves conditioning traditional waste-water biosolids and processing the conditioned biosolids continuously in a high throughput manufacturing facility. The exothermic design and closed loop control of the primary reaction vessel decreases significantly the amount of power necessary to run a manufacturing facility. The process utilizes green technologies to facilitate decreased waste and enhanced air quality standards over traditional processing plants. The fertilizer produced from recovered biosolid waste is safe and meets or exceeds the United States Environment Protection Agency (USEPA) Class A and Exceptional Quality standards and is not subject to restrictions or regulations.