Abstract: High analysis fertilizer formulations of a low bulk density powdered ureaformaldehyde, having soluble and insoluble components combined with soluble monopotassium phosphate and polyamino acid in which the resulting mixtures are dry homogeneous blends and may be carried in liquid for application to surface or subsurface areas by conventional liquid fertilizer applying equipment.

Abstract: Disclosed herein are methods of inhibiting chemical self-heating in organic-containing materials by the addition of phosphate and or other buffering agents which control the pH of the organic-containing material and alter the organic nature of the material such that self-heating reaction is inhibited, and fertilizer produced by these methods. Also disclosed are methods for producing an improved, i.e., self-heating resistant, organically-enhanced inorganic fertilizer and methods for improving the management of soil pH and the interaction of fertilizers with the soil and associated agricultural crops.

Abstract: The present invention is directed to liquid fertilizer composition having a high nitrogen content comprising an aqueous mixture of a urea-formaldehyde resin and a nitrogen fertilizer source selected from the group consisting of urea, ammonium nitrate, and a mixture of urea and ammonium nitrate, wherein the liquid fertilizer possess surprisingly depressed freeze points and salt-out temperatures.

Abstract: Liquid fertilizer compositions and methods of making liquid fertilizer compositions are set forth herein. In one embodiment, a liquid fertilizing composition includes an aqueous ammonium chloride solution having a pH between 6.5 and 8.5, a dispersant selected from anionic polyacrylamides, and a corrosion inhibitor. In another embodiment, a liquid fertilizing composition includes an aqueous solution having a pH between 6.5 and 8.5. The solution includes at least 16.5 percent by weight of ammonium chloride and between 0.5 and 1.0 percent by weight of dispersant. In yet another embodiment, a liquid fertilizing composition has a pH between 7.5 and 8.5. The composition consists essentially of at least 16.5 percent by weight ammonium chloride, between 0.5 and 1.0 percent by weight dispersant, an effective amount of corrosion inhibitor, and water.

Abstract: A technique is provided for delivering plant supportive materials to plants. The technique utilizes encapsulation of a plant growth facilitator, such as a plant nutrient, water or pesticide, in small structures that may be taken in through the stomata of plants. This enables a more efficient treatment, watering and/or feeding of plants by foliar application.

Abstract: A method of using trace amounts of certain compounds to reduce or inhibit corrosion on metal surfaces exposed to corrosive materials is disclosed. The compounds include hydroxlamines, acrylate polymers or copolymers, certain organic acids, tannic acid, carbohydrazide and its derivates and salts, and combinations of these compounds. The metal surfaces may include any ferrous metal piping or equipment surfaces, such as that used during storage, transport, and other processing of such materials. A corrosion-inhibited UAN solution having about 20 to about 50 percent by weight water and from less than 10 to about 1,000 ppm of one or more of the described corrosion inhibitors, and a pH from about 7 to about 8 is also disclosed.

Abstract: A trace amount of a tungstate added together with an ortho-phosphate and/or phosphonite is disclosed for inhibiting corrosion by a nitrogen fertilizer solution. In particular, an ammonium nitrate fertilizer solution is in contact with ferrous metal storage tanks, piping, and equipment surfaces. Tungstate added with an iron stabilizer including a dispersant polymer is also effective for inhibiting corrosion.

Abstract: Colourfast urea composition having reduced compressibility, cake formation and tendency of re-crystallization of the urea granulate, wherein the granulate further contains at least two different biodegradable polymers, of which at least one polymer is preferably a polyalkenyl amine compound. The other polymer is preferably polyaspartic acid or polyvinyl alcohol. The invention further relates to a process for the preparation of such a urea composition.

Abstract: The present invention relates to an improved nitrification inhibitor composition and its use in agricultural applications.

Abstract: The present invention relates to a method for making formulated nitrogenous and complex fertilizers, in granule form, suitable for slowly releasing nitrogen, comprising the steps of preparing an aqueous urea/formaldehyde dispersion with a molar ratio from 0.8:1 to 2:1, adding an aqueous catalyzer solution in a weight ratio from 0.1 to 4%, controlling the pH of the aqueous dispersion to hold it within a range from 4.0 to 7.0, and supplying the aqueous dispersion to a recirculating granulating device, as a growth seed.

Abstract: A trace amount of a tungstate is disclosed for inhibiting corrosion by nitrogen fertilizer solution, in particular, an ammonium nitrate fertilizer solution, (UAN) in contact with ferrous metal storage tanks, piping, and equipment surfaces. Tungstate added with a dispersant polymer is also effective for inhibiting corrosion.

Abstract: An improved granular-type urea fertilizer having an extended or slow release nitrogen component in which a non-thermosetting urea-formaldehyde resin concentrate is used to provide the granular fertilizer with an extended-release nitrogen component.

Abstract: A fertilizer composition containing a urea-aldehyde polymer and boric acid wherein said boric acid is not in its salt form.

Abstract: A corrosion inhibitor for use with Urea Ammonium Nitrate solutions is disclosed, comprising a blend of molybdate and one or more of the inorganic phosphates (including phosphates, polyphosphates, and pyrophosphates) and organic phosphates or phosphonates. Inorganic phosphates include, but are not limited to, SHMP (Sodium Hexametaphosphate) and TKPP (Tetra-Potassium Pyrophosphate). There are numerous other inorganic phosphates that will also serve as suitable secondary inhibitors. Organic phosphates or phosphonates include, but are not limited to, HEDP (1-Hydroxyethylidine-1,1-diphosphonic acid; also known as ethanol diphosphonate, acetodiphosphonic acid, or etidronic acid), ATMP or AMP (aminotri(methylenephosphonic acid)), PBTC (Phosphonobutane tricarboxylic acid), DETPMP (Diethylenetriaminepenta(methylene phosphonic acid)), and HPA (hydroxyphosphono acetic acid). There are numerous other organic phosphates and phosphonates that will also serve as suitable secondary inhibitors.

Abstract: Mechanically strong, water-disintegrable agglomerates made from a particulate calcium source, a water-soluble binder and optionally containing a primary plant nutrient source and/or micronutrient source and a process for forming such agglomerates are disclosed. The agglomerates may be used as a soil liming agent and for introducing nutrient values into cultivated soil. Also disclosed is a method for introducing nutrient values into cultivated soil so as to inhibit leaching of the nutrient values from the soil and improve utilization of the nutrient values by plants grown in the soil.

Abstract: A water-dispersible particle for delivery of nitrogen to a plant is disclosed. The water-dispersible particle also delivers an active ingredient such as a plant hormone to a desirable plant or a pesticide or herbicide to an undesirable organism. Methods for making and using the water-dispersible particle are described.

Abstract: The present invention provides a one-stage method of preparing a urea-formaldehyde plant nutrient solution with high percentage of Slow Release Nitrogen (SRN) moiety and low amounts of methylol by-products. A solution of formalin is reacted with urea in the presence of small amount of alkaline material to maintain a pH greater than 7. After the urea has dissolved, an ammonia reactant is added to the reaction mixture. The reaction mixture is exothermically (and, if needed, externally) heated to at least about 90° C. and held for about 70-75 minutes, during which a calculated amount of alkaline material is added, typically in three portions over the first 45 minutes of the 70-75 minute period.

Abstract: This invention concerns the formulation and preparation of ammonium- and urea-free solid-chemical compositions for the anaerobic bioremediation of environmental contamination using the biological process of denitrification. The composition includes nitrate salts and may also include additional sources of nutrient phosphorus, potassium and trace elements. The use of complex phosphates (i.e., salts of phosphoric acid) is used as a combined binder-nutrient system. The use of complex phosphates in this manner enables the water-based agglomeration of the composition into granular forms in a manner which greatly improves upon the safety of the commonly known “Tennessee Valley Authority” type granulation processes by reducing or eliminating the use of the highly toxic and dangerous chemicals anhydrous ammonia, sulfuric acid, and phosphoric acid.

Abstract: A controlled release urea-formaldehyde liquid resin having a nitrogen level of at least 28 wt % and its method of manufacture. The controlled release urea-formaldehyde resin is useful as a fertilizer.

Abstract: A controlled release liquid urea formaldehyde fertilizer which has a nitrogen level at least 31% and its method of manufacture.

Abstract: Controlled release fertilizers are provided and methods for their preparation, wherein the controlled release fertilizers are obtained through self-assembling molecules on the surfaces of the fertilizer particles, and then, preferably, linking these molecules into a network with another component. The designed molecules have a hydrophilic portion, which can interact with fertilizers, and a hydrophobic portion that make the molecule self-assemble and setup a moisture barrier. The molecules also preferably have at least two functional groups in order to form a network.

Abstract: A method of forming a methylol urea prepolymer and a particle coated in with the prepolymer. The method involves providing a source of methylol urea and a source of aldehyde and reacting the urea and the aldehyde in the presence of an excess of urea to form the methylol urea prepolymer. The coated particle is preferably a controlled-release fertilizer particle. The particle is a substrate coated with a substantially uniform coating comprising a total nitrogen content ranging from about 39N to about 42N. The coating includes a low molecular weight methylene urea compounds.

Abstract: A soil distribution system, and particularly a method of blowing topsoil, using an improved topsoil blend and specialized equipment, onto selected surfaces, including sloped surfaces. The topsoil blend may be placed either via traditional or selected placement means including placement by blowing the mixture into place. The topsoil blend may be blown through a manipulatable distribution line onto the surface, including areas which may be substantially inaccessible. A selected aerobic compost tea may be combined with the soil distribution operations such that the tea is distributed and intermixed with the soil as the soil is blown into place. Greensand may be distributed over the surface prior to blowing the soil in place and the soil is then distributed over the layer of greensand.

Abstract: A process for making homogeneous granules of slow-release fertilizer to deliver high doses of slow-release nitrogen in pellets that disperse or fall apart when contacted by moisture. The method includes mixing particles of slow-release nitrogen with particles of a potassium source and particles of a phosphorus source, to make a homogeneous blend of the particles. Then, the blended particles are moistened with water or an aqueous solution of urea to moisten the homogeneous blend. After moistening, the blended particles are contacted with an aqueous suspension of urea-formaldehyde resin to bind the particles into homogeneous granules. The aqueous suspension of urea formaldehyde resin preferably has a urea:formaldehyde ratio of about 1:1.

Abstract: A method of forming a methylol prepolymer and a particle coated in with the prepolymer. The method involves providing a source of methylol urea and a source of aldehyde and reacting the urea and the aldehyde in the presence of an excess of urea to form the methylol urea prepolymer. The coated particle is preferably a controlled-release fertilizer particle. The particle is a substrate coated with a substantially uniform coating compromising a total nitrogen content ranging from about 39N to about 42N. The coating includes a low molecular weight methylene urea compounds.

Abstract: Mechanically strong, water-disintegrable agglomerates made from a particulate calcium source, a water-soluble binder and optionally containing a primary plant nutrient source and/or micronutrient source and a process for forming such agglomerates are disclosed. The agglomerates may be used as a soil liming agent and for introducing nutrient values into cultivated soil. Also disclosed is a method for introducing nutrient values into cultivated soil so as to inhibit leaching of the nutrient values from the soil and improve utilization of the nutrient values by plants grown in the soil.

Abstract: I have developed an agglomeration process by which granules are formed by the steps of:

Abstract: A controlled release urea-formaldehyde liquid resin having a nitrogen level of at least 28 wt % and its method of manufacture. The controlled release urea-formaldehyde resin is useful as a fertilizer.

Abstract: A process for making homogeneous granules of slow-release fertilizer to deliver high doses of slow-release nitrogen in pellets that disperse or fall apart when contacted by moisture. The method includes mixing particles of slow-release nitrogen with particles of a potassium source and particles of a phosphorus source, to make a homogeneous blend of the particles. Then, the blended particles are moistened with water or an aqueous solution of urea to moisten the homogeneous blend. After moistening, the blended particles are contacted with an aqueous suspension of urea-formaldehyde resin to bind the particles into homogeneous granules. The aqueous suspension of urea formaldehyde resin preferably has a urea:formaldehyde ratio of about 1:1.

Abstract: A free-flowing fertilizer comprising:

Abstract: Compositions for and method of degrading organic chemicals in soil. The composition is a nutrient medium serving as a substrate for micro-organisms in the soil, preferably containing a major proportion of a source of carbon skeleton and energy, a macronutrient component preferably including nitrogen and other macronutrients, and a micronutrient component, preferably also a complexing agent and a vitamin/co-factor component. This nutrient material is added to soil, e.g. soil contaminated by a pesticide, to cause proliferation of micro-organisms which are effective, or which develop effectiveness to degrade the organic chemicals. Preferably the micro-organisms are those naturally present in the soil but useful micro- organisms may be added with the nutrient medium.

Abstract: Mechanically strong, water-disintegrable agglomerates for use as a soil conditioner produced from cement kiln dust and other particulate calcium sources containing CaO or Ca(OH)2 and other calcium-containing compounds having the potential to be hydrated and a process for forming such agglomerates are disclosed. The process comprises combining the particulate calcium source and a water-soluble binder to produce agglomerates which are then subjected to controlled drying such that the dried agglomerates having a size ranging from −7 to +8 Tyler Standard Sieve Series exhibit an average green crush strength of at least about 2 pounds (about 0.9 kg).

Abstract: A process for treating animal manure, particularly poultry feces, with concentrated sulfuric acid (about 93 to 95% H2SO4). The product of the process can be used for treating agricultural soils.

Abstract: The present invention relates to a solid water soluble fertilizer composition containing one or more fertilizer materials and a phosphate free, organic acid which is solid at ambient temperatures. The fertilizer materials include primary macro nutrients, secondary macro nutrients, micro nutrients and mixtures thereof. The organic acid has a water solubility of at least 10 g/l (at 25° C.) and an acidifying effect in the range of 0.5 to 1.3 g HCO3−/g acid. The acidifying effect is defined as the amount of HCO3− that can be transformed into H2CO3 per gram of acid and is calculated in accordance with the following formula: 61 ⁢ n M w , acid wherein Mw,acid is the molecular weight of said acid and n represents the number of dissociation constants (i.e., pKa values) of the acid below the value of 6.35.

Abstract: Composition for and method of stimulating growth of plants, e.g. increase in crop production. The composition comprises a carbon skeleton/energy component, typically a sugar or mixture of sugars; a macronutrient component providing the elements nitrogen, phosphorus, potassium and calcium, preferably also magnesium and sulfur; a micronutrient component providing zinc, iron and manganese, preferably also copper, boron, molybdenum and cobalt. The composition also preferably contains a vitamin/cofactor component and an enhancement component. The composition may be in the form of an aqueous solution or in a form suitable for coating seeds or coating pollen. It may be applied as a foliar spray, as a soil amendment, as a root dip or as an injectable solution. Preferably where, for example, it is used as a foliar spray it is applied at intervals at different stages of growth.

Abstract: A controlled release liquid urea formaldehyde fertilizer which has a nitrogen level at least 31% and its method of manufacture.

Abstract: Fertilizer granulation method for incorporating urea directly into the matrix of fertilizer pellets. The process involves introducing the urea in a liquid form into the matrix and then progressively cooling the mixture of pellet and urea to recrystallize the urea within the matrix of the pellet. The result is a substantially harder particle relative to pretreatment hardness, reduced solubility for longer lasting pellets and substantially reduced dust and other handling problems of the formed pellets.

Abstract: Mechanically strong, water-disintegrable agglomerates for use as a soil conditioner produced from cement kiln dust and other particulate calcium sources containing CaO or Ca(OH)2 and other calcium-containing compounds having the potential to be hydrated and a process for forming such agglomerates are disclosed. The process comprises combining the particulate calcium source and a water-soluble binder to produce agglomerates which are then subjected to controlled drying such that the dried agglomerates having a size ranging from −7 to +8 Tyler Standard Sieve Series exhibit an average green crush strength of at least about 2 pounds (about 0.9 kg).

Abstract: A dry, concentrated, fertilizer which is readily water-soluble and a method of applying the solubilized dilute fertilizer to crops to enhance crop production are described. The dry fertilizer contains a contains nitrogen, phosphorus and potassium compounds, as well as a mixture of plant growth stimulators including at least one of each of growth promoters, vitamins, amino acids, carbohydrates/polysaccharides, and adjuvants.

Abstract: Provided is a granular fertilizer coated with a thermosetting resin coating, characterized in that a dissolution rate of the fertilizer is retarded by containing a hydrophobic compound in at least one of the coating portion and the fertilizer portion thereof. The dissolution rate is further retarded than that of a conventional granular coated fertilizer coated with a thermosetting resin.

Abstract: There is disclosed a process to produce fertilizer granules containing urea and ammonium sulfate with a high ammonium sulfate concentration of ≦60 wt. % in a fluidized bed granulator, which process comprises the steps of: a) a molten urea suspension consisting of ammonium sulfate having an average particle size of 30 to 300 &mgr;m and urea having a temperature range of 120 to 155° C. is produced, b) the molten urea suspension produced at the stage a) is then injected from below on the fine particles of urea/ammonium sulfate in a fluidized bed granulator by means of at least a nozzle, while the fluidized bed is loosened by a spouting air flow in the injection area, and subsequently, c) the fertilizer granules generated in the fluidized bed are separated and, if necessary, treated. Homogeneous urea/ammonium sulfate granules of an ammonium sulfate content between 30 and 60 wt.

Abstract: A method preparing controlled release nitrogen in particulate fertilizers which exhibit single growing season availabilities to plants of about 80 percent or higher. The method utilizes relatively low urea and ammonia to formaldehyde mol ratios of about 1.7 urea to 0.1 ammonia to 1 formaldehyde to assure high conversions to controlled release nitrogen with low free ureas, and carefully controlled elevated temperatures, acid dehydration condensation catalyst concentrations and short dehydration reaction times of about 2-4 minutes to provide effective conversion of hydroxymethyl nitrogen compounds by dehydration condensation reaction to controlled release methylene nitrogen compounds. Quick neutralization of the dehydration catalyst in a turbulent mixing reactor minimizes the formation of undesirable methylene nitrogen polymers which are hot water insoluble and unavailable to plants in a single growing season.

Abstract: A reinforced-resin coated, attrition resistant controlled release plant food containing water soluble central spheroids of plant nutrients amounting to between 75 and 98 percent and water insoluble resin coatings amounting to between 2 and 25 percent covering the central spheroids with the insoluble resin coatings reinforced with finely divided water insoluble plant nutrients formed in-situ by the chemical coreaction of a plurality of water soluble plant nutrients. The reinforcing nutrients amount to between 5 and 25 percent of the resin coating. A method is provided for preparing the new reinforced-resin coated plant foods with the reinforcing solids distributed throughout the insoluble resins or between thin layers of resins.

Abstract: Solids having a tendency to cake are treated with distillation heavies that are liquid at about 60.degree. C. or less and are obtained from production of a ketone having the formula:R.dbd.O,wherein R is substituted or unsubstituted, branched, straight chain or cyclic, C.sub.4 to C.sub.18. The solids so treated have a reduced tendency to cake.

Abstract: This invention relates to processes for the production of unsymmetrical polyurea-urethane coated granular fertilizer products, and to the unsymmetrical polyurea-urethane coated granular fertilizer products produced by these processes. These processes comprise coating fertilizer granules with compounds which react to form unsymmetrical polyurea-urethane coatings, then the compounds are polymerized. Suitable compounds comprise a) an organic polyisocyanate component, and b) an alkanolamine component containing at least one primary or secondary amine group and at least one hydroxyl group. These compounds are present in sufficient quantities that the NCO to active hydrogen group is from about 0.5:1.0 up to about 1.5:1.0. It is necessary that sufficient amounts of these compounds are applied to the fertilizer granules such that the unsymmetrical polyurea-urethane coated granular fertilizer particles contain from about 0.

Abstract: A method of making free-flowing moisture resistant calcium-containing particles that inhibit the water absorption characteristics of calcium products, hygroscopic and deliquescent, for example, the method comprising the steps of spraying molten soluble nitrogen-containing material onto the hygroscopic calcium-containing granules and recovering the coated granules. The core of the particle is a calcium-containing material, more particularly a soluble calcium-containing material. Moisture resistant or hydrophobic coatings are applied to the core to inhibit water absorption by the calcium-containing material. The coated particles may then be more easily shipped, stored and handled as a dry, anhydrous product. A core comprised of calcium chloride coated with urea is useful as both a soil conditioner and a fertilizer. Additional plant nutrients are mixed with either the core or the coating materials to improve fertilizing is qualities.

Abstract: Mechanically strong, water-disintegrable agglomerates for use as a soil conditioner produced from dust particles emitted from kilns during the manufacture of cement and a process for forming such agglomerates are disclosed. The process comprises combining cement kiln dust and a water-soluble binder to produce agglomerates which are then subjected to controlled drying such that the dried agglomerates having a size ranging from -7 to +8 Tyler Standard Sieve Series exhibit an average green crush strength of at least about 2 pounds (about 0.9 kg).

Abstract: The invention relates to a stable, concentrated aqueous fertilizer suspension, which can be diluted with water to provide a working solution. The suspension contains 10 to 60% by weight of water and 40 to 90% by weight of a plant nutrient composition based on at least a calcium, and/or a magnesium and a phosphate ion, and the suspension comprises at least one plant nutrient containing water-insoluble solid particles with a particle size less than 50 .mu.m, the pH of the suspension being in the range of 0.5 to less than 2.

Abstract: A substantially non-caking solid is treated with distillation bottoms that are liquid at about 60.degree. C. or less and are obtained from production of an alcohol having the formula:R2--R1--OH,wherein R1 is substituted or unsubstituted branched, straight chain or cyclic C.sub.4 to C.sub.12 and R2 is OH or H.

Abstract: Granular coated particles suitable for use alone or in combination with other fertilizer particles as an nitrogen-dispersing agricultural fertilizer, and a process for making the granular coated particles are disclosed. The granular coated particles include particles formed from at least one metal nitrate, and a first coating layer surrounding each of the metal nitrate particles. The first coating layer is formed from a mixture containing urea and at least one metal nitrate. The metal nitrate particles each is substantially free and discrete from other metal nitrate particles. The metal nitrate is preferably sodium nitrate or potassium nitrate.