Abstract: An apparatus includes a captured carbon dioxide input. The captured carbon dioxide input is coupled to receive captured carbon dioxide from a direct air capture system. The apparatus uses the captured carbon dioxide as a low global warming refrigerant to provide cooling functionality in automotive, commercial, and industrial applications, or other operations involving low global warming refrigerants. In various embodiments, the apparatus is a refrigeration apparatus or a heat pump apparatus. Low global warming carbon dioxide refrigerant is natural, non-toxic, non-flammable, and abundant when obtained from a direct air capture system. Moreover, carbon dioxide refrigerant has a high heat transfer coefficient and has a global warming potential (GWP) of one. Carbon dioxide refrigerant is a more sustainable and efficient coolant option than common refrigerants, such as R22, R152, R404a, and R1234yf refrigerants.

Abstract: An efficient low-energy carbon dioxide removal system comprises an automated air mover equipped with sensing devices to measure flow rate, volume, level, pressure, temperature and concentration. Packing materials and air-liquid distributors are used in a multi-stage catalytic reactor. The multi-stage catalytic reactor processes ambient air and generates pure carbon dioxide gas and generates exhausted gas released to ambient air. In operation, air contacts the base solution in the presence of a catalyst via the air mover, distributor, and packing materials. The air reacts with the base solution thereby generating a base solution having carbon dioxide and generating exhaust (absorption reaction). Next, the exhaust is released from the reactor. Next, a catalyst is added, heat is applied to the base solution having carbon dioxide thereby generating carbon dioxide and generating a base solution without carbon dioxide (desorption reaction).

Abstract: According to certain embodiments, an adsorption heat exchanger (AdHEX) part is provided. The AdHEX part comprises a linear guiding element, and a plurality of planar structures that include fins. Each of the planar structures is: mounted on the linear guiding element via a joint element, the joint element configured to cooperate with the linear guiding element to form a slider joint, coated with an adsorbent coating, and fixed on the linear guiding element, at a respective position, by a fixing means that restricts linear sliding movement of each of the planar structures to form an arrangement of coated planar structures that are stacked along the linear guiding element.

Abstract: A valve apparatus includes a valve block with a main flow path, a first valve installed on the valve block and connected to the main flow path so that when the first valve turns on, a first fluid is supplied from the main flow path to a process chamber via the first valve, and a second valve installed on the valve block and connected to the main flow path so that when the first valve turns off and the second valve turns on, a second fluid is supplied from the main flow path to a waste gas treatment system via the second valve. The main flow path is disposed parallel to a central axis passing through a center of the valve block and two opposing surfaces of the valve block perpendicularly thereto. The main flow path is disposed to be offset from the central axis toward the first valve.

Abstract: A process is presented for the removal of contaminants like sulfur compounds from hydrocarbons. The sulfur compounds are removed from hydrocarbons that may be a feed to cracking units. A feed stream is treated with a clinoptilolite or a barium exchanged zeolite adsorbent to effectively remove carbon disulfides from the feed hydrocarbon. The adsorbent may be regenerated by a hydrogen stream, a hydrocarbon stream or a mixture thereof.

Abstract: A process is presented for the removal of contaminants like sulfur compounds from hydrocarbons. The sulfur compounds are removed from hydrocarbons that may be a feed to cracking units. A feed stream is treated with a clinoptilolite or a barium exchanged zeolite adsorbent to effectively remove carbon disulfides from the feed hydrocarbon. The adsorbent may be regenerated by a hydrogen stream, a hydrocarbon stream or a mixture thereof.

Abstract: The present disclosure relates to the selective separation of carbon dioxide (CO2) from multi-component gas feedstreams containing CO2 utilizing a GME framework type zeolite substantially free of non-GME framework type material.

Abstract: Articles for capturing or separating a target gas from a gas stream may include a porous substrate such as a flexible sheet or mat, or a rigid ceramic monolith impregnated or coated with a sorbent composition. The sorbent composition may include a polyamine and a coexistent polymer chemically bonded to the polyamine. The polyamine may include a polyethylenimine. The coexistent polymer may include a polyurethane, a polyolefin-acrylic acid copolymer, or a combination thereof. The sorbent composition may be substantially less water-insoluble than compositions containing only a polyamine and may have high durability and good adsorption capacity for acidic target gases such as carbon dioxide. Methods for preparing the articles using aqueous polymer solutions are provided. Methods for capturing or separating target gases using the articles are provided.

Abstract: The present invention relates to a metal organic framework comprising of a metal ion (M) and an organic ligand wherein more than one hydroxy ligand are present about the metal ion. Also provided is a method for synthesising the metal-organic frameworks and their application in areas including scrubbing exhaust gas streams of acidic gases, scrubbing natural gas of acidic gases by separation or sequestration and separating C2Ha or other VOC gases from other gas mixtures.

Abstract: A method of reducing the concentration of at least one sulfur compound in a process stream and for recovering at least one sulfur compound from a process stream are provided. A process stream is delivered to a vessel, wherein the vessel comprises an adsorbent material. At least one solvent is transferred into the vessel. One or more fluids are then removed from the vessel. At least one of the fluids removed from the vessel comprises a clean gas. The adsorbent material may be regenerated to yield a high concentration of the at least one sulfur compound.

Abstract: Articles for capturing or separating a target gas from a gas stream may include a porous substrate such as a flexible sheet or mat, or a rigid ceramic monolith impregnated or coated with a sorbent composition. The sorbent composition may include a polyamine and a coexistent polymer chemically bonded to the polyamine. The polyamine may include a polyethylenimine. The coexistent polymer may include a polyurethane, a polyolefin-acrylic acid copolymer, or a combination thereof. The sorbent composition may be substantially less water-insoluble than compositions containing only a polyamine and may have high durability and good adsorption capacity for acidic target gases such as carbon dioxide. Methods for preparing the articles using aqueous polymer solutions are provided. Methods for capturing or separating target gases using the articles are provided.

Abstract: The present disclosure relates generally to contaminant removal from gas streams. In certain embodiments, the present disclosure relates to a process for removing one or more contaminants from a gas stream via contact with a regenerable sorbent at high temperature and pressure, utilizing a unique arrangement of reactors operating in parallel.

Abstract: A device for gas analysis includes a detector tube (2) and can be used in the area of explosive or combustible gases. A filter material, which consists of a granular, porous material and has an impregnation for absorbing toxic gases, is provided between the detector tube (2) and a pump (6).

Abstract: A method is provided for forming a zeolitic imidazolate framework composition using at least one reactant that is relatively insoluble in the reaction medium. Also provided herein is a material made according to the method, designated either as EMM-19 or as EMM-19*, and a method of using same to adsorb and/or separate gases, such as carbon dioxide.

Abstract: An apparatus and a method for recovery of sulfur hexafluoride is provided. Sulfur hexafluoride (SF6) may be separated with high-concentration and improved recovery ratio through a multi-stage separation and recovery processes using a plurality of separation membrane modules, and as well, SF6 gas may be concentrated to maximize the SF6 recovery ratio before the separation and recovery processes through the separation membrane modules. Furthermore, sulfur dioxide (SO2) and moisture included in the SF6 waste gas may be removed effectively so as to extend the service life of the separation membrane modules.

Abstract: A method is provided for forming a zeolitic imidazolate framework composition using at least one reactant that is relatively insoluble in the reaction medium. Also provided herein is a material made according to the method, designated either as EMM-19 or as EMM-19*, and a method of using same to adsorb and/or separate gases, such as carbon dioxide.

Abstract: Embodiments of the present disclosure provide for collection devices, methods of making collection devices, methods of collecting gases and aerosol particles, and the like.

Abstract: With a method and a system for treatment of a hot crude gas generated by an entrained flow gasification system, removal of the compounds that contain sulfur and carbon is supposed to be undertaken in such a manner that hot gas is made available for further use. This is achieved in that a desulfurization (7) follows the gasifier (2), in series, in the flow path of the hot gas, followed by a solid separation (8, 9), whereby behind the solid separation (8, 9), a partial stream (13) of the gas is provided downstream by way of a water quench (14), a Venturi scrubber (15), a crude gas cooler (16), as well as an H2O separation (17) and a compressor (18), the flow path (19) of which is passed back, cooled, into the circuit, behind the gasification (2) and ahead of the desulfurization system.

Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.

Abstract: The present invention discloses a carbon dioxide capture power generation system provided with a boiler to combust a fuel in the oxygen atmosphere, a carbon dioxide capture equipment to remove carbon dioxide in the wake flow of the boiler, a piping branching from the wake flow of the boiler to recycle the combustion exhaust gas to the boiler, and a desulfurization equipment to remove sulfur oxides and a sulfuric acid removal equipment to remove a sulfuric acid gas in the upstream of carbon dioxide capture equipment and in the wake flow of the boiler.

Abstract: The present disclosure relates generally to contaminant removal from gas streams. In certain embodiments, the present disclosure relates to a process for removing one or more contaminants from a gas stream via contact with a regenerable sorbent at high temperature and pressure, utilizing a unique arrangement of reactors operating in parallel.

Abstract: A desulfurizer includes a filled chamber having a raw fuel passage through which a raw fuel flows, the filled chamber being filled with a desulfurizing agent, a supply chamber disposed upstream of the filled chamber, for uniformly supplying the raw fuel to the raw fuel passage, and a discharge chamber disposed downstream of the filled chamber, for uniformly discharging the raw fuel from the raw fuel passage. The raw fuel passage has first and second reversers for reversing the direction in which the raw fuel flows. The raw fuel passage has a cross-sectional area which is smaller in a downstream portion thereof than in an upstream portion thereof.

Abstract: A method for the purification of a feed gas stream containing CO2 and water and at least one impurity chosen from NOx and SOx, comprising the incorporation of a purification step for the preferential elimination of water is provided.

Abstract: A sorption agent comprising activated carbon and an impregnation of the activated carbon for the sorption of air pollutants, wherein the impregnation contains a zinc compound and a molybdenum compound, as well as a gas-filtering element, such as a respirator canister, containing said sorption agent.

Abstract: A method and system for automated control of the operating temperature setpoint of a circulating fluidized bed (CFB) scrubber within a pre-determined range of approach temperatures to the adiabatic saturation temperature of the CFB scrubber exhaust stream to maintain an optimal operating temperature, thereby reducing low temperature sulfuric acid corrosion and deposition of wet materials, and high temperature excess reagent use. A Dewcon® Moisture Analyzer (or equivalent) is connected in the exhaust stream of the CFB scrubber. The Dewcon® Moisture Analyzer transmits adiabatic saturation temperature data of the exhaust stream to the CFB scrubber system controller. Based on pre-programmed parameters, the system controller adjusts the CFB scrubber temperature setpoint.

Abstract: Carbon dioxide-containing feed stream such as flue gas is treated to produce a high-purity carbon dioxide stream by a series of steps including removing SOx and NOx with activated carbon, carrying out subambient-temperature processing to produce a product stream and a vent stream, and treating the vent stream by pressure swing adsorption or by physical or chemical absorption to produce a product stream which is recycled to the feed stream.

Abstract: A method includes using an element which includes a monoblock concrete body with a volume greater than 1 L and a surface porosity greater than 8%, which body includes in the body and/or on a surface thereof a compound having a BET specific surface greater than 100 m2/g, and which element does not include a photocatalytic agent, to absorb from the atmosphere a gas selected from the group consisting of nitrogen oxides, carbon oxides, sulphur oxides, and ozone, or a volatile organic compound.

Abstract: Carbon dioxide-containing feed stream such as flue gas is treated to produce a high-purity carbon dioxide stream by a series of steps including removing SOx and NOx with activated carbon, carrying out subambient-temperature processing to produce a product stream and a vent stream, and treating the vent stream by pressure swing adsorption or by physical or chemical absorption to produce a product stream which is recycled to the feed stream.

Abstract: An air quality control system (AQCS) (4) useful for processing a gas stream (DG), such as a flue gas stream emitted from a fossil fuel fired boiler (2), combustion process or the like, for at least partial removal of acidic and like contaminants. The air quality control system (4) includes a plurality of integrated components (12) equipped with both a dry scrubber system (8) and a fabric filter (10). The air quality control system (4) such as described possesses increased “turn down” capabilities thus increasing the efficiency thereof.

Abstract: Dry-scrubbing media compositions, methods of preparing same, and methods of use are provided. The compositions contain activated alumina and potassium carbonate. Optionally, activated carbon and other impregnates, such as sulfates of group 1A metals, are included in the compositions. The compositions exhibit improved efficiency and capacity for the removal of compounds such as chlorine or sulfur dioxide from an air-stream. The compositions are particularly useful for reducing or preventing the release of toxic gaseous compounds from the areas such as petroleum storage areas, refineries, drinking water systems, sewage treatment facilities, swimming pools, hospital morgues, animal rooms, and pulp and paper production sites.

Abstract: A system is provided that prevents inhibition of adsorption of Hg and other heavy metals by activated carbon or other heavy metal adsorbent due to prior adsorption of sulfur trioxide (SO3) in an exhaust gas containing SO3. As it has been found that while SO3 is adsorbed, the adsorption of SO3 precedes the adsorption of Hg and other heavy metals onto activated carbon, a basic substance injection system is disposed along an exhaust gas flow channel at an upstream side of an activated carbon injection system, thereby attaining effective removal of Hg and other heavy metals from the exhaust gas by adsorption thereof onto surface pores of the activated carbon. The SO3 concentration after removal by basic substance conversion is computed from the SO3 concentration before removal, and the activated carbon injection rate can be controlled based on the concentration after removal.

Abstract: One exemplary embodiment can be a stack for a separation vessel adapted to receive a fluid having one or more phases. The stack may include one or more walls surrounding a void, a packed bed positioned within the void, and a distributor positioned above the packed bed. Generally, the stack has a height greater than its width. Usually, the separation vessel further includes a base having a length greater than its height, and the height of the stack is orientated substantially perpendicular to the length of the base.

Abstract: Acid mist may be removed efficiently from a gas stream using at least one fiber bed mist eliminator operating at elevated pressure of typically at least 2 bar (0.2 MPa), e.g. at about 4 bar (0.4 MPa) to about 50 bar (5 MPa). The invention has particular application in methods for processing carbon dioxide flue gas in which SO2 and/or NOx contaminants are converted at elevated pressure to sulfuric acid condensate and/or nitric acid condensate respectively.

Abstract: NO2 may be removed from a carbon dioxide feed gas comprising NOx and at least one “non-condensable” gas as contaminants by passing the feed gas at a first elevated pressure through a first adsorption system that selectively adsorbs at least NO2 to produce at least substantially NO2-free carbon dioxide gas. The adsorption system is at least partially regenerated using a carbon dioxide-rich gas recovered from the substantially NO2-free carbon dioxide gas after purification. The invention has particular application in removing NOx and water from flue gas generated by oxyfuel combustion.

Abstract: A panel air filter assembly, for use in heating, ventilating and air conditioning (HVAC) systems, which has a single filter element with multiple portions. The single filter element is sectioned into substantially equally-dimensioned and separate filter portions. Each of the filter portions includes a specific type of medium and is distinct from one another, so as to remove different types of contaminants from the outdoor supply air before entering heating, ventilating and air conditioning systems. A waterproof paperboard frame securely supports the filter element at the filter element's marginal edges.

Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.

Abstract: The invention relates to a hybrid nano sorbent that is capable of reducing and/or removing acidic gases in a gas stream. The hybrid nano sorbent includes at least (i) a nano-structured carbonous material including at least one organic functional group, (ii) at least one metal from at least one of groups 2A, 6B, 7B, 9B or 10B of the periodic table of elements, or (iii) a combination of (i) and (ii). The method for reducing and/or removing the acidic gases in a stream is also described.

Abstract: The present invention relates to a catalyst for reducing mercury, which comprises a reagent comprising any of the sulfites of potassium, sodium, calcium and magnesium, or any of the phosphates thereof, or a combination of them, as a main reagent of a catalyst component. And the present invention relates to the catalyst for reducing mercury, wherein the catalyst component is mixed with a different salt as an agent for inhibiting crystallization of the catalyst component.

Abstract: The present disclosure relates to a method for purifying exhaust gases from a waste incineration plant by utilizing a sorption method in a circulating fluidized bed. According to the disclosure, the mass flow of the supplied fresh sorbent is regulated as a function of the concentration of fresh sorbent and/or at least one sorbed pollutant in the recirculated solid matter.

Abstract: The present application is directed to a method and system for preparing gaseous utility streams from gaseous process streams, nitrogen process streams, and other types of streams. The methods and systems may include at least one swing adsorption process including pressure swing adsorption, temperature swing adsorption, and rapid-cycle adsorption processes to treat gaseous streams for use in dry gas seals of rotating equipment such as compressors, turbines and pumps and for other utilities. The systems and processes of the present disclosure are further applicable to high pressure gaseous streams, for example, up to about 600 bar.

Abstract: An air conditioning system comprising a gas-impermeable wall defining a space for air conditioning, and a selective separating member disposed in the wall as a part of the wall, having a function of allowing preferential permeation of oxygen and carbon dioxide and at the same time, blocking the permeation of hydrocarbon, nitrogen oxide, sulfur oxide and a fine solid component, in which the selective separating member comprises an organic polymer and satisfies the relationship of P1/P2>10 wherein P1 is the permeation coefficient of oxygen and carbon dioxide and P2 is the permeation coefficient of hydrocarbon, nitrogen oxide, sulfur oxide and a fine solid component.

Abstract: Powdered lime composition having a BET specific surface area that is equal to or greater than 25 m2/g and a BJH total pore volume obtained from nitrogen desorption that is equal to or greater than 0.1 cm3/g, and furthermore comprising an alkali metal. The alkali metal content is equal to or greater than 0.2% and equal to or less than 3.5% based on the total weight of the composition. There is also described a method of preparing the composition and use thereof to reduce flue gases.

Abstract: A process, system and sorbent for removal of mercury from a combustion exhaust gas stream in a combustion exhaust gas purification scheme that includes a combustion exhaust scrubber system that uses an aqueous liquid to remove acid gases from the combustion exhaust gas. A powdered mercury sorbent is used. The sorbent is introduced into the aqueous scrubber liquid in the scrubber system. After introduction of the mercury sorbent into the scrubber liquid, at least some of the mercury sorbent is separated from the scrubber liquid.

Abstract: Provided are a sorbent composition, the preparation method thereof, and the process for removing sulfur oxides and nitrogen oxides in a flue gas by the sorbent composition. The sorbent composition comprises at least one refractory inorganic oxide matrix, at least one metal component I and at least one metal component II, wherein each of the at least one refractory inorganic oxide matrix has a specific surface area of more than 130 m2/g, the at least one metal component I is selected from elements of Group IA and Group IIA in the Periodic Table of Elements, and the at least one metal component II is selected from transition metals of Group IIB, Group VIB, Group VIIB, and Group VIII in the Periodic Table of Elements, and wherein the at least one metal component II is present in at least two different valence-states, as characterized by the X-ray photoelectron spectroscopy.

Abstract: A process and system for recovering waste heat from a kiln used for lime or cement production. The system unifies the kiln, a waste heat recovery and power generation circuit and a dry scrubber for scrubbing the pollutants from the kiln offgas. Essentially, the system employs the boiler component of the waste heat recovery and power generation circuit as a heat exchanger to recover the waste heat from the kiln, which is used to drive the steam turbines. The heat absorption from the latter stage lowers the temperature of the kiln offgas sufficiently for optimum performance from the scrubber. The presence of lime particles in the offgas effectively protects the boiler tube surfaces from corrosion which would occur at optimum scrubber temperatures, and subsequently provides the lime required as a scrubbing medium for the dry scrubber. Further, the efficient scrubbing allows for the use of any fuel for firing the kiln inclusive of high sulphur content compounds.

Abstract: A composition of matter wherein the composition comprises a siliceous substrate having silanols on the surface and a polymer selected from the group consisting essentially of a water soluble polymer, a water soluble copolymer, an alcohol soluble polymer, an alcohol soluble copolymer, and combinations of such polymers, wherein the polymer is chemically bonded to the siliceous substrate by a silane linking material having the general formula O3/2SiQY that is derived from an alkoxy-functional silane having the general formula (RO)3SiQX and processes for preparing the crosslinked polymer that is chemically bonded to the surface of the siliceous substrate.

Abstract: Pollution reduction processes may be incorporated with, or retrofit to fit with, existing combustion processes to assist with the reduction of pollutants produced in the combustion process. The thermal treatment of oil shale in the pollution reduction process produces kerogen, shale sorbent particles, or mixtures thereof, which may be reacted with a pollutant-containing gas or pollutant-containing gas having particulate matter entrained therein to reduce the pollutants in the gas. Apparatuses employing the processes are also disclosed.

Abstract: The present invention relates to adsorbent honeycomb monoliths and other porous monoliths impregnated with alkaline and/or caustic salts of alkaline metal or alkaline earth metal. The impregnated monoliths have high adsorption capacity and low flow resistance, yet with minimized flammability, suitable for use in removal of acidic, malodorous and/or harmful gases.

Abstract: The present disclosure relates to a method for purifying exhaust gases from a waste incineration plant by utilizing a sorption method in a circulating fluidized bed. According to the disclosure, the mass flow of the supplied fresh sorbent is regulated as a function of the concentration of fresh sorbent and/or at least one sorbed pollutant in the recirculated solid matter.

Abstract: In a method of separating gaseous pollutants from hot process gases, the process gases are passed through a contact reactor (22), in which an absorbent material in a moistened state is introduced to convert the gaseous pollutants into separable dust. The dust is separated in a dust separator (10). The separated dust is cooled in a first step by being brought into direct contact with a cooling fluid. In a second step, the cooled dust is mixed with a gas containing water vapour, said gas having a saturation temperature that is higher than the temperature of the cooled dust. The dust moistened by condensation of the water vapour is introduced into the contact reactor (22) to be mixed with the process gases. A mixer (24) for moistening of absorbent material has a first end (26) and a second end (28) and is divided into two zones. A first zone is a cooling zone (68) located at the first end (26). A second zone is a moistening zone (80) located at the second end (28).