Abstract: Calcium carbonate (CaCO3; calcite) and CaCO3-containing materials are known to have high adsorption capacities for polar organic compounds. This invention includes the use of CaCO3 and CaC O3-containing materials (e.g., synthetic calcite, calcite coated sorbents) and their mixture with other materials (e.g., activated carbon, resins) for removing bioagents (viruses, bacteria, hormones, pharmaceutical intermediates, and other hazardous biological agents) from waters.

Abstract: An air filter having a low pressure drop and adsorbent capabilities when placed in a fluid stream is disclosed. The air filter contains activated carbon incorporated into a filter media that can be shaped into a fluted configuration. The fluted shape is maintained during operation of the air filter through the use of flow restrictors along the length of the flute. The fluted material can be rolled or stacked.

Abstract: A porous crystalline material has a tetrahedral framework comprising a general structure, M1-IM-M2, wherein M1 comprises a metal having a first valency, wherein M2 comprises a metal having a second valency different from said first valency, and wherein IM is imidazolate or a substituted imidazolate linking moiety.

Abstract: Pressure swing adsorption (PSA) assemblies and hydrogen-producing fuel processing assemblies and/or fuel cell systems including the same. The PSA assemblies include, or are utilized with, combustion fuel stream supply systems that are adapted to regulate the flow of a byproduct stream from the PSA assembly for delivery to a heating assembly for use as a combustible fuel stream, such as to maintain at least a hydrogen-producing region of the fuel processing system at a hydrogen-producing temperature or range of temperatures. In some embodiments, the combustion fuel stream supply system is configured to ensure that the supply of combustible fuel from the PSA assembly to the heating assembly contains at least a sufficient fuel value, such as to maintain at least the hydrogen-producing region at or within a predetermined hydrogen-producing temperature or range of temperatures.

Abstract: Fluorinated metal-organic frameworks (“FMOFs”) are capable of adsorbing and desorbing gases and molecules. The FMOFs can be arranged in a variety of configurations and have internal hollow channels and cavities. In the FMOFs, hydrogen atoms have been substituted completely or partially with fluorine atoms or fluorinated groups in each linking organic ligand. The FMOFs have high densities, leading to an enhanced volumetric capacity for gas storage.

Abstract: A method of separating a target component from a chemical mixture comprising contacting a chemical mixture with a microporous coordination polymer. The microporous polymer is described by the formula: [M2(C8H2O6)] where M is a transition metal, rare earth metal, or other element from the groups consisting of HA through VB.

Abstract: The system and method for recycling the compress heat generated at a bio-gas treatment plant that includes the assembly of a heat exchanger at each stage of compression designed to utilizing all of the gas flow and to harvest the heat in gas delivered to the air exchangers. After the heat is harvested, it is then conveyed either as hot air, or as a hot liquid, to a jacketed vessel containing media that requires regeneration or stripping of harmful VOCs picked up during the purification of contaminated landfill or municipal digester gas. The harvesting and conveyance of the heat of compression of the gases to a jacket around the vessel interior (indirect contact) and simultaneously heating the vessel interior containing the spent media through hot gas from another source (direct contact), reduces the heat-up time. This also reduces the overall the cycle time between the contaminant pick-up step and contaminant stripping step in regenerable treatment systems.

Abstract: It is intended to provide a volatile organic compound treatment apparatus having: an absorption treatment chamber in which absorption frames having absorbents for absorbing volatile organic compounds are aligned in a direction of a gas flow; an absorbent recovery treatment chamber that is provided with a discharge unit having a high voltage electrode, a ground electrode, and a dielectric; and a transfer mechanism for transferring the absorption frames present in an upstream of the gas flow to the absorbent recovery treatment chamber and transferring the absorption frames in the absorbent recovery treatment chamber to a downstream of the gas flow. The volatile organic compound treatment apparatus is capable of decomposing VOC without generating a large amount of harmful NOx and reduced in apparatus cost.

Abstract: The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.

Abstract: The disclosure relates generally to a gas-separation system for separating one or more components from a multi-component gas using Zeolitic imidazolate or imidazolate-derived framework.

Abstract: A process and system for the purification of germane containing phosphine to provide a purified germane product. One aspect of the present invention is a process for making a purified germane product containing less than 50 ppb of phosphine which comprises providing a phosphine contaminated germane gas hydrogen gas mixture; passing the germane gas hydrogen gas mixture through an adsorbent which selectively adsorbs phosphine and withdrawing therefrom a purified germane gas hydrogen mixture; and separating the purified germane gas from the hydrogen germane gas mixture.

Abstract: A process for removing epoxides from a process stream over a wide range of temperature and relative humidity, comprising the step of contacting the process stream with a filtration media comprising an acid form of a mesoporous zeolite produced from pentasil zeolite treated with a caustic agent, for a sufficient time to remove the epoxides therefrom.

Abstract: Embodiments of the invention relate to a composite hydrogen storage material comprising active material particles and a binder, wherein the binder immobilizes the active material particles sufficient to maintain relative spatial relationships between the active material particles.

Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.

Abstract: Apparatus and methods for reducing or eliminating undesirable air-borne substances, such as odors, bacteria, viruses, fungi, and toxins, are provided. A filter containing nanocrystalline metal oxide or metal hydroxide particles may be installed within an air handling apparatus such as an existing HVAC unit located within a building, and particularly within a home, or a portable air processor or purifier. The air handling apparatus comprises a blower which pulls air containing various undesirable substances from within the enclosed environment and directs it through a filtering device containing the nanocrystalline particles. The undesirable substances are sorbed by the nanocrystalline particles thereby creating a deodorized stream of air that may then be directed back into various portions of the enclosed environment or vented to the atmosphere.

Abstract: An adsorbent for organic compounds consisting of filler granules, which contain 20 to 99.9 wt. % of fillers and a binder. The adsorbent is produced by mixing at least one binder with at least one filler and performing granulation in a mixing or granulation apparatus. The adsorbent may be used for adsorbing and/or absorbing organic and/or inorganic substances from a liquid or gaseous phase.

Abstract: A processing system according to the present invention is provided including: an adsorption apparatus in which a volatile organic compound contained in gas to be treated is adsorbed in a predetermined absorption agent, and said volatile organic compound thus adsorbed is desorbed using steam under a pressurized environment and mixed with the steam; a gas turbine having a combustor in which the steam mixed with the volatile organic compound is burnt; and a steam generating apparatus which generates steam through the use of the heat of the combustion gas discharged from the gas turbine; and wherein, by supplying compressed air discharged from the gas turbine to the adsorption apparatus, condensation of the steam in the adsorption apparatus at the time of the desorption of the volatile organic compound is suppressed.

Abstract: A filter material for removing toxins and/or environmental contaminants from a body of gas, comprising bentonite disposed within a support arranged so as to allow contact between the body of gas and the bentonite.

Abstract: Hydrogen gas at a hydrogen refueling site is cooled below liquid nitrogen temperature (e.g., about 80K) for more efficient adsorption of hydrogen on hydrogen adsorbent particles in the fuel storage of a hydrogen powered vehicle. When compressed hydrogen gas is available it may be cooled with liquid nitrogen and then sub-cooled below about 70K by a Joule-Thompson expansion. When liquid hydrogen provides hydrogen gas it may be cooled below liquid nitrogen temperatures by mixing with liquid hydrogen or by heat exchange with liquid hydrogen.

Abstract: A method for processing an organic solvent-containing air is disclosed. The method can be operated in spite of a rapid fluctuation of the concentration of the organic solvents in the air to be processed, specifically, the method does not increase the organic solvent content in the air to be emitted into the atmosphere after processing, even if the concentration of the organic solvents rapidly changes. The method comprises carrying out simultaneously and continuously an adsorbing-removing step, a regenerating step, and a combustion step, while mixing a purified air produced in the adsorbing-removing step with an exhaust gas from a combustion furnace produced in the combustion step, and decomposing the organic solvents in the mixture by oxidation.

Abstract: An apparatus and methods for concentrating or removing hydrophobic organic compounds (HOCs) are provided. A biodegradable polyhydroxyalkanoate (PHA) polymer is provided and the HOC (or a material containing a HOC) is contacted with the PHA. PHA polymers can be used to easily concentrate or remove microcontaminant levels as low as 0.01 ppm of hydrophobic organic compounds without using large solvent volumes. Methods for synthesizing the PHAs are also provided. Methods are further provided for degrading HOCs that have been sequestered from a HOC-contaminated material using isolated bacterial strains or microbes such as Escherichia, Pseudomonas and others. The method comprises contacting at least one isolated bacterial strain (or microbe) to the sequestered HOC for a time sufficient to effect removal of the HOC. The provided methods are advantageous for concentrating HOCs and providing a platform for microbial remediation of these compounds.

Abstract: A process for the abatement of carbonyl sulphide, carbon disulphide, metal carbonyl compounds, hydrogen sulphide and hydrogen cyanide, ammonia and arsenic and chlorine compounds from a feed gas comprising the steps of contacting the gas in succession with a first purification agent comprising activated carbon, with a second purification agent comprising alumina, with a third purification agent comprising zinc oxide, with a fourth purification agent comprising a zeolitic material and a fifth purification agent comprising zinc oxide and copper oxide.

Abstract: A desorption process and a process for producing a catalytically deactivated formed zeolitic adsorbent, whereby both processes are suitable to improve the lifetime of a formed zeolitic adsorbent in the removal of sulfur compounds from sulfur contaminated gas and liquid feed streams. The adsorbent is in particular a synthetic 13X or LSX faujasite with a silica to alumina ratio from 1.9:1.0 to about 3.0:1.0. The cations of the faujasite include alkali and alkaline earth metals. The formed zeolite mixture is preferably catalytically deactivated due to a phosphate treatment. The desorption is carried out thermally, wherein the heat treatment is done at different temperature stages to avoid decomposition of the organic sulfur compounds.

Abstract: The mercaptan-laden natural gas is contacted with a mercaptan-adsorbing sieve T1. The mercaptan-rich gaseous effluent obtained upon regeneration of sieve T2 is then contacted with an olefin-containing liquid feed in the presence of an acid catalyst. Under suitable conditions, the mercaptans are absorbed in the liquid feed and they react with the olefins so as to form solvent-soluble sulfides. A solvent regeneration stage allows the capture agent to be recycled.

Abstract: The present invention concerns a process for capturing organosiliceous complexes in the gaseous or liquid phase on a solid containing at least 80% by weight of alumina after calcining at 1000° C. The alumina has a total pore volume of more than 30 ml/100 g, a fraction of the pore volume in pores with a diameter of 70 ? or more of more than 10 ml/100 g and a specific surface area of more than 10 m2/g.

Abstract: The invention relates to an installation for separating or purifying gases comprising at least one gas treatment vessel, characterized in that the vessel comprises at least one plane structure comprising a matrix and at least one phase change material (PCM).

Abstract: An adsorbent for organic compounds consisting of filler granules, which contain 20 to 99.9 wt. % of fillers and a binder. The adsorbent is produced by mixing at least one binder with at least one filler and performing granulation in a mixing or granulation apparatus. The adsorbent may be used for adsorbing and/or absorbing organic and/or inorganic substances from a liquid or gaseous phase.

Abstract: Use of molecular sieves to reduce the amount of trifluoromethane (HFC-23) present in a mixture of HFC-23 with other materials, particularly from mixtures containing HFC-23 and trifluoroiodomethane (CF3I).

Abstract: A method and an apparatus for desorption and a dehumidifier are provided in the present invention, in which an electrical potential is applied to electrodes disposed on both ends of an absorbing material so as to desorb the substances absorbed within the absorbing material whereby the absorbing material is capable of being maintained for cycling the absorbing operation. By means of the method and the apparatus of the present invention, the desorbing efficiency can be enhanced and the energy consumption can be reduced during desorption.

Abstract: A method for processing an organic solvent-containing air capable of being operated in spite of a rapid fluctuation of the concentration of organic solvents in the air to be processed and capable of using a combustion furnace exhaust gas as an air for regenerating dehumidifying member is provided. The method comprises carrying out simultaneously and continuously a dehumidification step (a), an adsorption-removing step (b), an adsorbing member-regeneration step (c), a combustion step (d), and a dehumidifying member-regeneration step (e) comprising mixing the adsorption-treated air produced in the adsorbing-removing step (b) with a combustion furnace exhaust gas produced in the combustion step (d) to obtain a mixed gas, decomposing the organic solvents in the mixed gas by oxidation, and causing the resulting purified gas to flow through the dehumidifying member which has adsorbed moisture, thereby regenerating the dehumidifying member.

Abstract: Isopotential heaters used in the preconcentration stage of sample detection systems are described. The heaters have at least two electrically conducting paths of which the resistances of the electrically conducting baths are substantially equal such that in use uniform heat distribution is achieved.

Abstract: An underground fuel tank releases vapors depending upon air pressure. A vapor pressure management system has a canister for a vapor recovery system that connects with piping from an underground tank and has carbon therein along with appurtenant pipes and valves. When an ORVR vehicle refuels, the pressure lowers in an underground tank that draws air through the valves into the canister. After refueling an ORVR vehicle, environmental conditions generate hydrocarbon vapors. Barometric pressure drops and evaporated fuel during long refueling lulls produce hydrocarbon vapors at an increased pressure. Those hydrocarbon rich vapors then return to the canister of the system where the carbon binds the hydrocarbons while releasing air to the atmosphere. The refueling of the next ORVR vehicle draws in atmospheric air to purge the hydrocarbons retained in the canister of the system.

Abstract: A method for removing contaminating gaseous components, such as CO2 and/or H2S, from a contaminated natural gas stream. The method includes the steps of expanding the contaminated gas stream in an expander to form an expanded gas stream; allowing at least part of the contaminants in the expanded gas stream to liquefy to form a dispersion of a contaminants enriched liquid phase in a contaminants depleted gaseous phase; and separating at least part of the contaminants enriched liquid phase from the contaminants depleted gaseous phase in one or more centrifugal separators.

Abstract: A large single crystal of a complex such as an organic carboxylic acid metal complex, which crystal is useful as an adsorbent of various gases and vapors of organic solvents and as a hydrogen-absorbing material, as well as a process for producing the crystal, is disclosed. Two layers wherein an upper layer thereof is constituted by a solution containing a metal salt and an organic carboxylic acid having a conjugated system, or a solution containing a metal salt of the organic carboxylic acid having a conjugated system, and wherein a lower layer of the two layers is constituted by a solvent which is not miscible with the solvent of the solution, is formed. Vapor of pyrazine or a substituted pyrazine from a solution of pyrazine or the substituted pyrazine is introduced into the upper layer to allow reaction, thereby forming a large single crystal(s) of the organic carboxylic acid metal complex at the interface between the two layers, which crystal(s) has (have) a longer side with a size of not less than 0.8 mm.

Abstract: A filter includes at least two different adsorptive media. First, chemisorptive media, which is porous and includes an acidic functional group, is used to remove molecular bases, including ammonia, organic amines, imides and aminoalchols, from the atmosphere used in semiconductor fabrication and other processes that require uncontaminated gaseous environments of high quality. Second, physisorptive media is able to adsorb condensable contaminants, particularly those having a boiling point greater than 150 degrees C. The physisorptive media can include untreated, activated carbon.

Abstract: Provided herein are adsorbents and methods of using the adsorbents to at least partially remove one or more adsorbates. In an aspect, an adsorbate within a phase is at least partially removed by providing an adsorbent material and contacting the adsorbent material with the phase having an adsorbate, to at least partially remove the adsorbate. Various adsorbents are disclosed having the chemical formula RE1-x-y-zBxB?yB?zOw, where RE is RE is a rare earth metal, B is a trivalent metal ion, B? is a transition metal ion or an alkaline earth element, B? is a transition metal ion, 0?x?0.25, 0?y?0.95, 0?z?0.75, w is a number which results in charge balance, and x+y+z<1.

Abstract: Filters and smoking articles include at least one carbon fiber composite molecular sieve sorbent capable of selectively removing one or more selected constituents from mainstream smoke. Methods for making cigarette filters and smoking articles using the carbon fiber composite molecular sieve sorbent and methods for treating mainstream tobacco smoke in a cigarette comprising the carbon fiber composite molecular sieve sorbent are also provided.

Abstract: The invention provides a method of reusing an inert gas in a polymer production plant by removing impurities such as a polymerization solvent and polymerization monomers from an inert gas discharged from a polymer production plant. The method of reusing an inert gas comprises a step of adsorbing and removing a polymerization solvent and polymerization monomers contained in an inert gas by passing, through an adsorbent layer, an inert gas discharged from a polymer production plant, wherein an inert gas reaching a predetermined purity by removing the polymerization solvent and polymerization monomers in the step of adsorption and removal is reused in the polymer production plant.

Abstract: Porous-material-supported polymer sorbents and process for removal of undesirable gases such as H2S, COS, CO2, N2O, NO, NO2, SO2, SO3, HCl, HF, HCN, NH3, H2O, C2H5OH, CH3OH, HCHO, CHCl3, CH2Cl2, CH3Cl, CS2, C4H4S, CH3SH, and CH3—S—CH3 from various gas streams such as natural gas, coal/biomass gasification gas, biogas, landfill gas, coal mine gas, ammonia syngas, H2 and oxo-syngas, Fe ore reduction gas, reformate gas, refinery process gases, indoor air, fuel cell anode fuel gas and cathode air are disclosed. The sorbents have numerous advantages such as high breakthrough capacity, high sorption/desorption rates, little or no corrosive effect and are easily regenerated.

Abstract: Processes comprising: providing a crude gas stream having a temperature not exceeding 40° C., the crude gas stream comprising hydrogen chloride and at least one organic impurity; condensing at least a portion of the at least one organic impurity from the crude gas stream at a temperature not exceeding 0° C. to form a prepurified gas stream and a condensate comprising condensed organic impurity; subjecting at least a portion of the prepurified gas stream to adsorption on an adsorption medium to provide a purified gas stream; and separating the condensate into at least a head gas stream comprising residual hydrogen chloride and a sump stream comprising at least a portion of the condensed organic impurity.

Abstract: A getter system (20) is described for the sorption of organic molecules at the inside of active systems (30) for the transdermal release of drugs, suitable to avoid the corrosion of electrical parts of these systems being caused by these organic molecules in the presence of water.

Abstract: Preferred embodiments of the invention relate to systems for removing dimethyl sulfoxide (DMSO) or related compounds, or odors associated with same. The systems include adsorbents, odor adsorbing fabrics, masks, clean air members and clean air supply assemblies.

Abstract: A hydrogen peroxide vapor generation unit (10) receives hydrogen peroxide and water solution at an interface (20) and interconnects with an air dryer (14) by way of nipples (72, 92). In one embodiment, the dryer includes a clamping assembly (42) which is latched (74, 94) with the nipples and which receives a disposable desiccant cartridge (40). In an alternate embodiment, a reusable desiccant cartridge (40?) is connected directly to the nipples (72, 92). When the desiccant cartridge (40?) is saturated, it is removed and placed in a regenerator unit (120). A regenerated cartridge is installed in its place.

Abstract: It is intended to provide a volatile organic compound treatment apparatus having: an absorption treatment chamber in which absorption frames having absorbents for absorbing volatile organic compounds are aligned in a direction of a gas flow; an absorbent recovery treatment chamber that is provided with a discharge unit having a high voltage electrode, a ground electrode, and a dielectric; and a transfer mechanism for transferring the absorption frames present in an upstream of the gas flow to the absorbent recovery treatment chamber and transferring the absorption frames in the absorbent recovery treatment chamber to a downstream of the gas flow. The volatile organic compound treatment apparatus is capable of decomposing VOC without generating a large amount of harmful NOx and reduced in apparatus cost.

Abstract: Filter and/or absorbent materials comprising an open cell foam having a surface, wherein the surface of the open cell foam is at least partially coated with a layer comprising photocatalytic titanium dioxide; methods for making such materials comprising: (a) providing a mixture comprising photocatalytic titanium dioxide in a binder; (b) immersing an open cell foam article in the mixture; (c) removing the article from the mixture and removing excess mixture from the article; and methods of treating gases or liquids by passing the gas or liquid through such a material wherein the material has been activated by UV radiation are described.

Abstract: A plurality of different layers of filter media are used to remove siloxanes from a gas stream. Based on an analysis of the specific gas stream to be filtered, a filter media having an average pore size enabling the preferential removal of a specific class of contaminants is selected for each different class of contaminants. The layers are arranged in sequential order such that contaminants having a higher molecular weight are preferentially removed by the first layers. Collectively, the layers define a segmented activity gradient that enables each class of contaminants present in the gas stream to be preferentially removed in a different layer, preventing removal competition between different classes of contaminants. Preferable adsorption media exhibit a relatively narrow range of pore sizes. Both inorganic adsorption media and carbon-based adsorption media exhibiting a relatively narrow range of pore sizes can be used.

Abstract: An odor adsorbing or deodorizing filter which comprises a matrix or substrate impregnated with a mixture of particulate chemically modified activated carbon and particulate activated carbon, together with a binder. The filter may be incorporated into an ostomy collection bag, wound dressing, respirator, air conditioning unit or the like.

Abstract: Contaminated fluids are treated by adsorbing contaminant onto a sorbent to concentrate the contaminant and then oxidizing the contaminant via the Fenton and related reactions. Iron is attached to the sorbent or can be added in solution with an oxidant. Both systems, iron attached to the sorbent or iron in solution, can be used to oxidize contaminants on or near the surface of the sorbent. The process can be used to treat contaminated water in above-ground and below-ground treatment systems, as well as contaminated gases.

Abstract: When a shutoff signal is entered to shut off a fuel gas manufacturing apparatus, it is determined whether a PSA mechanism is in a prescribed shutoff state or not. If the PSA mechanism is judged as not being in the prescribed shutoff state, the fuel gas manufacturing apparatus is continuously operated until the PSA mechanism is brought into the prescribed shutoff state. Then, if the PSA mechanism reaches the prescribed shutoff state, the fuel gas manufacturing apparatus is shut off.

Abstract: Use of molecular sieves to reduce the amount of trifluoromethane (HFC-23) present in a mixture of HFC-23 with other materials, particularly from mixtures containing HFC-23 and trifluoroiodomethane (CF3I).