Abstract: A system for collecting carbon dioxide from a process gas including an adsorbent material for adsorbing carbon dioxide molecules from the process gas, a dielectric heater proximate the adsorbent material, and a vessel having an internal volume enclosing the adsorbent material and, optionally, the dielectric heater.

Abstract: A temperature swing adsorption process to purify a gas comprising at least one adsorption step and at least one regeneration step wherein the regeneration step takes place at a higher pressure than the adsorption step. The pressure is increased by a repressurization step between the regeneration step and the adsorption step, and then a purge step takes place after said repressurization step.

Abstract: A method of removing mercury from a process gas by means of a sorbent and a filter (10) involves applying said sorbent to at least one filtering surface (12) of the filter (10). A first parameter, which is indicative of the amount of mercury that needs to be removed in said filter (10), and a second parameter, which is indicative of the amount of material that has been collected on said filtering surface (12), are measured. A measured value of said first parameter is compared to a mercury set point. When said measured value of said first parameter is higher than said mercury set point, the cleaning of said filtering surface (12) is delayed, compared to the point in time suggested by a measured value of said second parameter.

Abstract: The invention provides gas purification systems for the recovery and liquefaction of low boiling point organic and inorganic gases, such as methane, propane, CO2, NH3, and chlorofluorocarbons. Many such gases are in the effluent gas of industrial processes and the invention can increase the sustainability and economics of such industrial processes. In a preferred system of the invention, low boiling point gases are adsorbed with a heated activated carbon fiber material maintained at an adsorption temperature during an adsorption cycle. During a low boiling point desorption cycle the activated carbon fiber is heated to a desorption temperature to create a desorption gas stream with concentrated low boiling point gases. The desorption gas stream is actively compressed and/or cooled to condense and liquefy the low boiling point gases, which can then be collected, stored, re-used, sold, etc.

Abstract: Some embodiments of the disclosure correspond to, for example, a system for scrubbing a mixture of gases and/or contaminants from indoor air from an enclosed space to remove at least one gas and/or contaminant from the mixture of gases and/or contaminants. The system may include one or more adsorbent materials configured to be cycled between adsorption and regeneration of at least one of gas and/or contaminant from the mixture of gases and/or contaminants via a temperature swing adsorption cycle (for example), regeneration means configured to regenerate one or more adsorbent materials. The regeneration means may be configured at a regeneration temperature to regenerate the one or more adsorbent materials.

Abstract: A device for selectively regenerating and performing tank leakage diagnosis of a tank ventilation system has a sorption filter and a pump. The sorption filter is configured to temporarily store fuel evaporating from a fuel tank. The pump is arranged at a fresh-air side of the sorption filter and is connected in fluid-conducting fashion to the sorption filter. The pump is configured to generate a fluid flow to regenerate the sorption filter.

Abstract: A method and apparatus for regenerating the media of a rotary sorption concentrator system includes passing a 600° F. to 1000° F. regeneration fluid stream through a rotating media in a first isolated zone to regenerate the media and remove contaminants from the media that are not removed during a typical desorption cycle of a rotary sorption concentrator system.

Abstract: Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced N2 adsorption rates and capacities when used in air separation processes.

Abstract: One exemplary embodiment can be a method of minimizing wear of a rotary valve. The method can include regulating a velocity of the rotary valve having a controller for communicating one or more fluids to and from an adsorption zone.

Abstract: Pressure swing adsorption system comprising two or more vessels, each having a feed end, a product end, and adsorbent material adapted to adsorb one or more components from a multi-component feed gas mixture; piping adapted to (1) introduce the feed gas mixture into the feed ends, withdraw a product gas from the product ends, and withdraw a waste gas from the feed ends of the vessels, and (2) place the product ends of any pair of vessels in flow communication; a feed pipe adapted to supply the feed gas mixture to the system; a product pipe adapted to withdraw the product gas from the system; and a waste gas pipe adapted to withdraw the waste gas from the system. An indexed rotatable multi-port valve is adapted to place the product end of each vessel in sequential flow communication with the product end of each of the other vessels.

Abstract: Disclosed herein is a method and system for separating carbon dioxide (CO2) from a CO2 containing gas stream containing water vapor and additional impurities, for example, nitrogen, oxygen, sulfur oxides, nitrogen oxides, and mercury. The CO2 is captured by subjecting the CO2 gas feed stream to a temperature swing adsorption step. The temperature swing adsorption step comprises an adsorption step for producing a substantially dry carbon dioxide-depleted stream, and an adsorbent regeneration step comprising heating the adsorbent bed to produce a substantially water vapor-free carbon dioxide stream. Moisture from the gas stream containing CO2 is optionally removed by pressure swing adsorption, temperature swing adsorption, membrane separation, or absorption prior to CO2 capture.

Abstract: A method for producing a gas comprising at least 80 vol % carbon monoxide from a Fischer-Tropsch off-gas comprises: (1) feeding Fischer-Tropsch off-gas through a column comprising an adsorbent bed at high pressure and discharging effluent; (2) reducing the pressure in the column and the bed slightly; (3) rinsing the column and the adsorbent bed with methane or a mixture of methane and carbon dioxide; (4) reducing the pressure of the column and adsorbent bed to a low pressure; (5) rinsing the column and adsorbent bed with a mixture of hydrogen and nitrogen; (6) pressurizing the column and adsorbent bed to a high pressure using a mixture of hydrogen and nitrogen. The product stream obtained in step (3) comprising at least 80 vol % carbon monoxide can be sent as feed to a Fischer-Tropsch reaction. In an embodiment, a gas comprising at least 80 vol % hydrogen is also produced.

Abstract: Various equipment and methods associated with providing a concentrated product gas are provided. In one embodiment, the equipment includes an input device first and second sieve tanks, a variable restrictor, and a controller. In one embodiment, the method includes: a) selecting a desired output setting for the concentrated product gas from a plurality of output settings, b) separating one or more adsorbable components from a pressurized source gaseous mixture via first and second sieve tanks in alternating and opposing pressurization and purging cycles to form the concentrated product gas, and c) selectively controlling a variable restrictor based at least in part on the desired output setting to selectively provide flow between the first and second sieve tanks such that the flow for at least one output setting is different from the flow for at least one other output setting in relation to corresponding pressurization cycles.

Abstract: Methods and systems for regenerating a purification bed take advantage of inert gas pressure, such as, for example, supplied by a pipeline. The inert gas (102) is provided at a first pressure and combined with a recycle composition (116) from the vessel (110, 110a) containing the material being regenerated. These streams form a regeneration fluid composition (114) at a second pressure less than the inert gas pressure, which is then routed to the vessel to regenerate the purification bed. A jet compressor (108) may be used for the combining of the inert gas and recycle streams. The recycled composition allows reduction in inert gas usage, while a portion is flared or otherwise disposed of.

Abstract: Hydrogen sulfide is removed from a hydrogen rich gas stream using adsorbents having a low loss of carbon dioxide adsorption capacity upon sulfur loading including high purity silica gels, titania or highly cross-linked, non-chemically reactive resins. The adsorbents may be used to adsorb both carbon dioxide and hydrogen sulfide, or may be used as a guard bed upstream of a separate carbon dioxide adsorbent.

Abstract: Methods and/or systems using magnetically assisted pressurization of a gas for the generation of useful power from heat transfer using heat sources at lower temperatures in a manner that does not require the emission of CO2.

Abstract: An apparatus for capture and sequestration of CO2 from fossil fuel-fired power plant flue gas includes a polymer matrix embedded with a sorbent suitable for removing CO2 from the flue gas and a spacer mated with the polymer matrix. The spacer is adapted to create channels between adjacent portions of the polymer matrix such that the flue gas flows through the channels and comes in contact with the sorbent. Further, an apparatus for the capture and sequestration of CO2 from fossil fuel-fired power plant flue gas includes a hollow fiber membrane embedded with an adsorbent or other suitable material for removing CO2 from the flue gas. The adsorbent particles may be embedded into a wall of the membrane.

Abstract: The removal of one or more of the gases CO2, N2 and H2S from gas mixtures containing at least one of said gases with use of an 8-ring zeolite having a Si:Al ratio from about 1:1 to about 1000:1. The preferred gas mixture is a natural gas feedstream and the preferred 8-ring zeolite is DDR.

Abstract: The Microwave System and method of reactivation is designed to provide an indirect, safe and energy efficient source of heat and temperature rise required in the reactivation section of the desiccant unit for the release into atmosphere of the water vapors which are accumulated in the desiccant rotor. This microwave reactivation system and method is based on heat transfer produced from a heated fluid which is pumped through a closed loop coil assembly. This closed loop coil assembly is located and runs through both the isolated heating chamber of the microwave section and the reactivation / regeneration section in the dehumidification system. The airstream passing through the reactivation intake section comes in contact with the coil assembly and is heated to the desired temperature prior to reaching the desiccant rotor.

Abstract: An adsorption unit comprising an adsorbent hollow fiber in which the fiber includes an active component and means for transmitting heat.

Abstract: Certain aspects and examples are directed to sorbent devices and methods of using them. In certain embodiments, a sorbent device comprising a body comprising a sampling inlet, a sampling outlet and a cavity between the inlet and the outlet, the cavity comprising a serial arrangement of at least four different sorbent materials is described. In some embodiments, the sorbent materials are arranged from a material with a weakest sorbent strength to a material with a strongest sorbent strength with the weakest sorbent strength material adjacent to the sampling inlet.

Abstract: An apparatus, system, and method are disclosed for removing ethylene from a gaseous environment. Ethylene is a gaseous growth hormone produced by plants that triggers the ripening of some flowers, fruits, vegetables, and other plants. The apparatus includes an ethylene filter and a composition. The filter includes a frame and a trapping medium. The composition is attached to the trapping medium of the ethylene filter. The ethylene filter is positioned within a gaseous environment and is configured to encounter a gas flow within the gaseous environment. The composition contains at least some titanium dioxide which is configured to attach to the ethylene as the gas flow moves through and around the ethylene filter. In this manner, some ethylene may be removed from the gaseous environment.

Abstract: The present system is an adsorption system for separating air into a concentrated gas component, which has an air supply, a compressor for receiving and compressing the air supply, providing a compressed air supply, and molecular sieve material for separating the compressed air supply into a concentrated gas component. The adsorption system delivers at least 5 liters per minute (LPM) of concentrated gas component from the molecular sieve material in which the system has a specific total weight per LPM <9 lbs/LPM. Additionally, an output quantity of the concentrated gas is delivered by the adsorption system and a purging quantity of the concentrated gas is dispensed into a sieve chamber of the adsorption system undergoing a purge cycle. The purging quantity has a value equal to or less than the difference between the maximum quantity and the output quantity, and the purging quantity is controlled based on the output quantity.

Abstract: Systems and processes are provided for gas separation using high-speed induction variable-speed motors to accelerate and decelerate centrifugal compressors suitable for use in pressure swing adsorption (PSA) or vacuum pressure swing adsorption (VPSA) processes.

Abstract: A process for the separation of one or more heavy hydrocarbon gases from a gas mixture containing heavy hydrocarbon gas components and methane. The process is conducted in swing adsorption apparatus containing adsorbent contactor having a plurality of flow channels and wherein 20 volume percent or less of the open pore volume of the contactors, is in the mesopore and macropore range.

Abstract: The present invention relates the separation of a target gas from a mixture of gases through the use of engineered structured adsorbent contactors in pressure swing adsorption and thermal swing adsorption processes. Preferably, the contactors contain engineered and substantially parallel flow channels wherein 20 volume percent or less of the open pore volume of the contactor, excluding the flow channels, is in the mesopore and macropore range.

Abstract: The separation of a target gas selected from a high pressure gas mixture containing said target gas as well as a product gas using a swing adsorption process unit. A turboexpander is used upstream of the swing adsorber to reduce the pressure of the high pressure gas mixture. A compressor is optionally used downstream of the swing adsorber to increase the pressure of the target gas-containing stream for injecting into a subterranean formation.

Abstract: An acid-gas sorbent comprising an amine-composite. The present composite may comprise a first component comprising an amine compound at a concentration of from about 1 wt % to about 75 wt %; a second component comprising a hydrophilic polymer and/or a pre-polymer compound at a concentration of from about 1 wt % to about 30 wt %; and a third component comprising a cross-linking agent, and/or a coupling agent at a concentration of from about 0.01 wt % to about 30 wt %.

Abstract: Hydrogen can be recovered in a refinery network using a combination of a cycling adsorber unit and a membrane separation unit. A membrane separation unit can be used to generate at least a portion of the purge hydrogen stream for the cycling adsorber unit. This can reduce the portion of the hydrogen product stream from the cycling adsorber unit required for regeneration of the adsorbent.

Abstract: The present invention relates to a pre-concentration device and method for an ion mobility detection apparatus. According to an aspect of the invention, there is provided a pre-concentration device comprising: a collecting passage configured to collect a gas mixture including substances to be detected: a sieve provided, in a deploy state, within the collecting passage and configured to separate the substances from the gas mixture, the separated substances being absorbed to the sieve; at least one desorption unit configured to desorb the substances that have been absorbed to the sieve, the sieve being received in a wound state in the desorption unit; and a driving device configured to drive movement of the sieve between an absorption position in which the substances are absorbed to the sieve in the collecting passage, and a desorption position in which the substances are desorbed from the sieve in the at least one desorption unit.

Abstract: An off gas extraction system provides superior results to other systems for cleaning polluted soil. Off gas is extracted, followed by compression and condensation. Compression and condensation produce an off gas further treated to produce pollutant-free exhaust. A regenerative adsorber cleans the influent gas/air by adsorbing residual chemical vapor and concentrates the removed chemical vapor and reprocesses them. Conventional scrubbers are used on the back end of the system to produce a final exhaust as prescribed by environmental regulation. Methods of accomplishing the same are likewise taught including combinations and additions consistent with schemes as they evolve.

Abstract: A pre-concentration device is provided for a gas analysis system (10) for collecting molecular contamination in a vacuum environment (11). The pre-concentration device (13) comprises a hollow element (15) having an entrance opening (20) for receiving molecules from the vacuum environment (11) in a collection phase, a gas outlet for transferring collected molecules to a vacuum compatible detector or second preconcentration device in a transfer phase. The device has an inner wall for adsorbing molecules in the collection phase and desorbing molecules in the transfer phase. The device has a filler element (14) that is movable from a first position outside the hollow element in the collection phase to a second position inside the hollow element in the transfer phase which second position leaves open a transfer channel to the gas outlet along the inner wall.

Abstract: The disclosure provides a CO2 absorption method using an amine-based solid sorbent for the removal of carbon dioxide from a gas stream. The method disclosed mitigates the impact of water loading on regeneration by utilizing a conditioner following the steam regeneration process, providing for a water loading on the amine-based solid sorbent following CO2 absorption substantially equivalent to the moisture loading of the regeneration process. This assists in optimizing the CO2 removal capacity of the amine-based solid sorbent for a given absorption and regeneration reactor size. Management of the water loading in this manner allows regeneration reactor operation with significant mitigation of energy losses incurred by the necessary desorption of adsorbed water.

Abstract: A room temperature trap for the purification and concentration of gaseous methane. The trap utilizes the adsorption and desorption properties of microporous spherical carbon molecular sieves to purify and concentrate radiolabelled methane for application in an automated synthesis module without the need for cryogenic cooling.

Abstract: In a method of capturing carbon dioxide in a gas, carbon dioxide in a gas is adsorbed to the hybrid adsorbent prepared by mixing an adsorbent with iron oxide nanoparticles, microwaves are irradiated to the hybrid adsorbent and the carbon dioxide adsorbed to the hybrid adsorbent is desorbed from the hybrid adsorbent, and the carbon dioxide desorbed from the hybrid adsorbent is captured.

Abstract: The invention provides gas purification methods and systems for the recovery and liquefaction of low boiling point organic and inorganic gases, such as methane, propane, CO2, NH3, and chlorofluorocarbons. Many such gases are in the effluent gas of industrial processes and the invention can increase the sustainability and economics of such industrial processes. In a preferred method of the invention, low boiling point gases are adsorbed with a heated activated carbon fiber material maintained at an adsorption temperature during an adsorption cycle. During a low boiling point desorption cycle the activated carbon fiber is heated to a desorption temperature to create a desorption gas stream with concentrated low boiling point gases. The desorption gas stream is actively compressed and/or cooled to condense and liquefy the low boiling point gases, which can then be collected, stored, re-used, sold, etc.

Abstract: The present invention relates to a process for the separation of gases which comprises putting a mixture of gases in contact with a zeolite of the ESV type to obtain the selective adsorption of at least one of the gases forming the gaseous mixture. The present invention also relates to particular zeolitic compositions suitable as adsorbents.

Abstract: The present application provides a protected solid adsorbent that includes a solid adsorbent substrate and a surface layer at least partially coating the solid adsorbent substrate, the surface layer being generally permeable to an active agent. Additionally, a process for protecting a solid adsorbent and an adsorption system that includes a vessel containing the protected solid adsorbent is provided.

Abstract: A regeneration controller for an air dryer on a vehicle includes a location identifier that determines a current location, a regeneration profile identifier that selects a regeneration profile based on the current location, and a regeneration initiator that initiates regenerations of the air dryer based on the regeneration profile.

Abstract: A method for capturing CO2 from the ambient air by the use of solid tethered amine adsorbents, where the amine adsorbents are tethered to a substrate selected from the group of silica, metal oxides and polymer resins. The tethered amines are joined to the substrate by covalent bonding, achieved either by the ring-opening polymerization of aziridine on porous and non-porous supports, or by the reaction of mono-, di-, or tri-aminosilanes, with silica or a metal oxide having hydroxyl surface groups. The method includes the adsorption of CO2 from ambient air, the regeneration of the adsorbent at elevated temperatures not above 120° C. and the separation of purified CO2, followed by recycling of the regenerated tethered adsorbent for further adsorption of CO2 from the ambient atmosphere.

Abstract: Methods, apparatus, and systems for removing contaminant in a fluid (e.g., chemical and petrochemical gas streams) using nanostructures of a sorbent material coated on plates such as a silicon wafer. A plurality of such coated plates can be assembled to form a sorption structure having channels between the plates. When a fluid containing the contaminant is directed through the channels, the contaminant is adsorbed by the nanostructures of the sorbent material.

Abstract: A hydrogen manufacturing system for performing offgas flow control includes: a vaporizer (1) for heating a material mixture containing a hydrocarbon material; a reforming reactor (2) for generating hydrogen-containing reformed gas by reforming reactions of the material; a PSA separator (5) for repeating a cycle of adsorption and desorption, where in the adsorption PSA separation is performed with an adsorption tower loaded with an adsorbent to adsorb unnecessary components in the reformed gas and extract hydrogen-enriched gas out of the tower, and in the desorption the offgas containing the unnecessary components from the adsorbent and remaining hydrogen is discharged from the tower; and a buffer tank (6) for holding the offgas before supplying to the vaporizer. The offgas flow supply from the tank (6) to the vaporizer is changed continuously over time when the cycle time is changed according to load change on the separator (5).

Abstract: A hydrocarbon adsorber and a thermoplastic resin combined and formed to a porous scavenger for insertion into the air intake system of a motor vehicle engine. The resulting porous scavenger adsorbs volatile hydrocarbon molecules from raw fuel remaining in the air intake when the engine is shout off. The adsorbed molecules are then stripped or purged from the scavenger and reintroduced into the air intake when the engine is next started.

Abstract: A method for the purification of a feed gas stream containing at least CO2 and at least one impurity with by the incorporation of a purification step, enabling water to be at least partially removed is provided.

Abstract: A fluid treatment device is disclosed. The device includes a vessel having a fluid entrance and exit. Within the vessel hollow fiber of nano-porous material are arranged so as to define two volumes separated by the nano-porous material. In one embodiment the fluid, air, passes up the center of the hollow fiber drying as the air contacts the inner walls of the fiber. The device is purged by stopping the flow through the device and allowing the air pressure that builds up between the fibers to be released through the nano-porous material.

Abstract: A process is provided for recovering methane from landfill feed gas and other anaerobic digestors. The process comprising the following steps: firstly treating the feed gas to remove H2S; subsequently compressing the gas; and then treating the gas to remove further impurities. Additionally, there is provided a chiller for reducing the temperature of a gas flow. The chiller comprising: a shell arranged to be chilled, a plurality of bores through the shell and through which the gas flows, in use, and forming, together with the shell, a heat exchanger, a tangential inlet to each bore for creating a spiral flow of the gas through the bore, in use. Furthermore, a process is provided for purifying a gas feed using a reversible gas absorber unit comprising two hollow fiber gas/liquid contactors, each of which is arranged to provide a counter-current flow.

Abstract: Method for drying compressed gas using a dryer with pressure vessels. The method having the steps of guiding a first part of the gas to a cooler via a regulating valve, and of subsequently drying this first part of the gas in the drying pressure vessel; and of heating a second part of the gas so as to regenerate the regenerating pressure vessel. When the temperature in the regenerating pressure vessel rises above an upper limit value, the regulating valve will be gradually moved in the direction of the shut position and, when the temperature in the regenerating pressure vessel drops under a predetermined bottom limit, the regulating valve will be gradually moved in the direction of the entirely open position, which adjustment allows to set the compressed gas at a desired temperature.

Abstract: The present invention relates to the separation of one or more of CO2, N2, and H2S gas components from a gas mixture containing at least a second gas using a swing adsorption process unit. The adsorbent contactors of the swing adsorption process unit are engineered structured adsorbent contactors having a plurality of flow channels wherein 20 volume percent or less of the open pore volume of the contactors is in the mesopore and macropore range.

Abstract: Methods for releasing associated guest materials from a metal organic framework are provided. Methods for associating guest materials with a metal organic framework are also provided. Methods are provided for selectively associating or dissociating guest materials with a metal organic framework. Systems for associating or dissociating guest materials within a series of metal organic frameworks are provided. Gas separation assemblies are provided.

Abstract: An apparatus and method for adsorption of organic and inorganic volatile compounds in gas flows by continuous and simultaneous distribution of a plurality of primary and secondary flows, through particular distribution and shut-off devices, to a plurality of chambers, in which the individual energy and mass transfer operations associated with such adsorption occur. High flow-rate and/or concentration are accommodated, following a cyclic adsorption/regeneration process, in which a part of the adsorbent material is used to separate the compounds in gas flows, while the rest of the material sequentially undergoes two or more desorption steps in a stabilized atmosphere suitable to carry the desorbed compounds at very high concentrations, and a final cooling step in a stabilized atmosphere, for preparing the material for continuing the process.