Liquid Contacting (e.g., Sorption, Scrubbing, Etc.) Patents (Class 95/149)
  • Patent number: 5925167
    Abstract: A method for the scrubbing of noxious substances from an exhaust gas stream from an evacuated process chamber containing a tool for the processing of semiconductor devices. The method comprises directing the stream from the chamber in to a duct containing a multi-way valve and selectively adjusting the valve to cause different fractions of the stream to be directed to relevant treatment/collection/exhaust points.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: July 20, 1999
    Assignee: The BOC Group plc
    Inventor: James Robert Smith
  • Patent number: 5919285
    Abstract: Processes and systems to recover at least one perfluorocompound gas from a gas mixture are provided. In one embodiment the inventive process comprises the steps of a) providing a gas mixture comprising at least one perfluorocompound gas and at least one carrier gas, the gas mixture being at a predetermined pressure; b) providing at least one glassy polymer membrane having a feed side and a permeate side; c) contacting the feed side of the at least one membrane with the gas mixture; d) withdrawing from the feed side of the membrane as a non-permeate stream at a pressure which is substantially equal to the predetermined pressure a concentrated gas mixture comprising essentially the at least one perfluorocompound gas; and e) withdrawing from the permeate side of the membrane as a permeate stream a depleted gas mixture comprising essentially the at least one carrier gas.
    Type: Grant
    Filed: April 3, 1998
    Date of Patent: July 6, 1999
    Assignees: American Air Liquide, Inc., l'Air Liquide, Societe Anonyme Pour l'Etude et, l'Exploitation Des Procedes Georges Claude
    Inventors: Yao-En Li, Joseph E. Paganessi, David Vassallo, Gregory K. Fleming
  • Patent number: 5900216
    Abstract: A venturi eduction and scrubbing system comprising a first container and a second container in fluid communication each having a liquid treatment reagent therein. The liquid treatment reagent establishes liquid levels in the first and second containers. A waste inlet which contains waste gas or liquid to be processed is connected to at least one venturi eductor. The venturi eductors are also connected to the first container and are disposed above the liquid level of the first and second container. A pump is connected to the second container and each venturi eductor. The pump enables liquid treatment reagent to be pumped from the second container into the venturi eductors such that the waste gas or liquid is drawn from the waste inlet into the venturi eductors where it combines with the liquid treatment reagent and is thereby neutralized. The arrangement of contains and venturies provide a failsafe mechanism for preventing suckback into the waste container.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: May 4, 1999
    Assignee: Earth Resources Corporation
    Inventors: Dan A. Nickens, Charles C. Mattern
  • Patent number: 5861049
    Abstract: A process for separating chlorine from other low-boiling components of a gas-phase mixture. The invention involves three separation steps: condensation, flash evaporation and membrane separation. The steps are integrated together in such a way as to provide a good separation between the components, and to avoid creation of secondary streams that need additional treatment. The invention is particularly useful for treatment of gas streams from chlor-alkali processes.
    Type: Grant
    Filed: July 22, 1997
    Date of Patent: January 19, 1999
    Assignee: Membrane Technology and Research, Inc.
    Inventor: Kaaeid A. Lokhandwala
  • Patent number: 5827356
    Abstract: A continuous process for recovery of acetylene-free gaseous mixture from gaseous feedstreams containing acetylene and optionally other low molecular weight hydrocarbons by contacting the acetylene-containing feedstream with an alkanol in combination with a super acid catalyst, Lewis acid, Bronsted acids, or mixtures thereof, under conditions of reaction sufficient to form a mixture containing at least one acetal organic compound, and a gaseous product substantially free of acetylene. Preferred catalysts include boron trifluoride in methanol with mercuric oxide. Processes according to the invention are, advantageously, used for recovery of acetylene-free gaseous mixture from gaseous feedstreams containing a mixture of acetylene, a synthesis gas comprising dihydrogen and carbon monoxide, and optionally one or more members of the group consisting of dimethyl ether, formaldehyde, ethylene, and propylene.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: October 27, 1998
    Assignee: Amoco Corporation
    Inventor: Gary P. Hagen
  • Patent number: 5759237
    Abstract: Processes and systems to recover at least one perfluorocompound gas from a gas mixture are provided. In one embodiment the inventive process comprises the steps of a) providing a gas mixture comprising at least one perfluorocompound gas and at least one carrier gas, the gas mixture being at a predetermined pressure; b) providing at least one glassy polymer membrane having a feed side and a permeate side; c) contacting the feed side of the at least one membrane with the gas mixture; d) withdrawing from the feed side of the membrane as a non-permeate stream at a pressure which is substantially equal to the predetermined pressure a concentrated gas mixture comprising essentially the at least one perfluorocompound gas; and e) withdrawing from the permeate side of the membrane as a permeate stream a depleted gas mixture comprising essentially the at least one carrier gas.
    Type: Grant
    Filed: June 14, 1996
    Date of Patent: June 2, 1998
    Assignees: L'Air Liquide Societe Anonyme pour l'Etude et, l'Exploitation des Procedes Georges Claude, American Air Liquide Inc.
    Inventors: Yao-En Li, Eric L. Duchateau
  • Patent number: 5747331
    Abstract: The invention relates to a process and an apparatus for the removal of sparingly-soluble gaseous substances, especially sulfur-containing substances from waste gases with the aid of microorganisms. The waste gas containing the sparingly-soluble gas is directed (24) in the form of small gas bubbles into a suspension (16) of degrading microorganisms. A gas which has been pre-cleaned in this way is preferably led to another bioreactor (10), where microorganisms degrade the contaminant. The invention also relates to a new microorganism which is capable of degrading carbon disulfide and hydrogen sulfide.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: May 5, 1998
    Assignee: Vapo Oy
    Inventors: Tarja Terttu Hartikainen, Pertti Juhani Martikainen, Arvo Aukusti Juhani Ruuskanen, Kari Antero Mutka, Timo Martti Tapio Nyronen, Markku Tapio Kallstrom, Minna Kristiira Vanhatalo
  • Patent number: 5738699
    Abstract: An apparatus for the removal of particles existing in exhaust gases by directly sprinkling the gases with water to congeal the particles. The apparatus also mixes surfactants into the water, and the mixture is driven by a pump to clean out the condensation deposited in a transmitting conduit in order to eliminate settled congealed particles that could block the transmitting conduit.
    Type: Grant
    Filed: September 6, 1996
    Date of Patent: April 14, 1998
    Assignee: United Microelectronics Corporation
    Inventors: Chu Lin Hu, Chia Hsing Huang, Ching Wen Deng, Kuo Cheng Chang
  • Patent number: 5730779
    Abstract: A method for the separation and recovery of fluorochemicals from a gas stream containing a diluent gas and fluorochemicals by contact of the gas stream with a membrane, comprising the steps of: compressing a gas stream containing a diluent gas and fluorochemicals to an elevated pressure; heating the gas stream containing a diluent gas and fluorochemicals to an elevated temperature sufficient to increase the flux of the permeate stream and to increase the selectivity of the membrane for the permeation of the diluent gas relative to the permeation of the fluorochemicals; contacting the gas stream with a membrane which is selectively more permeable to the diluent gas than the fluorochemicals to result in a permeate stream rich in the diluent gas and a retentate rich in fluorochemicals; contacting the gas stream with one or more additional membranes which are selectively more permeable to the diluent gas than the fluorochemicals to result in a second permeate stream rich in the diluent gas and a second retentate
    Type: Grant
    Filed: October 31, 1996
    Date of Patent: March 24, 1998
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Iosif Chernyakov, Thomas Hsiao-Ling Hsiung, Alexander Schwarz, James Hsu-Kuang Yang
  • Patent number: 5725634
    Abstract: A suction pump draws by suction an atmosphere sample into a gas component collecting section to collect a gas component in the atmosphere into an absorption liquid 48a and thereafter collect a particle component into absorption liquids. A liquid transfer pump transfers the absorption liquids to a measurement standby vessel to make them stand by. When measurement of the absorption liquid is completed, a liquid transfer on-off valve opens to transfer the absorption liquids to an analysis apparatus to make it execute measurement. A liquid transfer pump supplies new absorption liquid when a gas component collecting use absorption liquid vessel and first and second stage impinger sections are emptied. By thus executing collecting, condensation and measurement in parallel by the gas component and the particle component, a state-by-state analysis of the impurities in the atmosphere can be automatically executed in real time.
    Type: Grant
    Filed: July 11, 1996
    Date of Patent: March 10, 1998
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Masami Takasuga, Toshio Mukai
  • Patent number: 5681360
    Abstract: A process for concentrating and recovering methane and carbon dioxide from landfill gas includes absorption of commonly occurring pollutants using a reduced amount of carbon dioxide absorbent which itself may be an in situ derived and recoverable constituent. Separated methane may be concentrated into a high heating value fuel, and a highly pure food-grade carbon dioxide product may also be recovered. Process streams may be used to provide fuel for compression and refrigeration and/or to regenerate carbon dioxide absorbent.
    Type: Grant
    Filed: January 11, 1995
    Date of Patent: October 28, 1997
    Assignee: Acrion Technologies, Inc.
    Inventors: Lawrence A. Siwajek, W. Jeffrey Cook, William R. Brown
  • Patent number: 5679135
    Abstract: In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector's centerline in proceeding toward the downstream side of the collector.
    Type: Grant
    Filed: February 8, 1996
    Date of Patent: October 21, 1997
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Daniel E. Carl
  • Patent number: 5656152
    Abstract: A continuous water washing process for removing salts from refinery process streams is disclosed. The salt and salt precursor content of a process stream is determined, and iterative calculations made to ensure an aqueous phase forms downstream of the water injection point with a salt and ion concentration within acceptable limits. Preferably chemical speciation calculations are used to check for corrosive, transient aqueous phases intermediate the point of water injection and the process outlet.
    Type: Grant
    Filed: December 5, 1994
    Date of Patent: August 12, 1997
    Assignee: Mobil Oil Coporation
    Inventors: Bruce D. McLaughlin, Yiing-Mei Wu
  • Patent number: 5656151
    Abstract: A process for determining if intermittent water injection is the best way to remove deposits such as salts from refinery process streams. A water vapor pressure, P1, at stream conditions and a water vapor pressure, Ps, at saturation conditions in the stream, are used to calculate a ratio P1/Ps. If the ratio is less than 0.1 intermittent water washing is preferred. An optimized intermittent injection procedure, frequency, duration, and constraints, is disclosed. Chemical speciation calculations ensure that all accumulated salts are removed, and that an aqueous phase forms downstream of the water injection point having a salt concentration within acceptable limits.
    Type: Grant
    Filed: December 5, 1994
    Date of Patent: August 12, 1997
    Assignee: Mobil Oil Corporation
    Inventors: Bruce D. McLaughlin, Yiing-Mei Wu
  • Patent number: 5597402
    Abstract: This invention relates to a self-regulated apparatus and method for extracting biodegradable and/or strippable constituents from a gaseous stream by the action of biomass which consumes or degrades such substances. Such self-regulation permits the monitoring and optimization of the bioactivity of the system and the overall degree of treatment of the gaseous stream.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: January 28, 1997
    Assignee: The Dow Chemical Company
    Inventors: Mark A. LaPack, Terry J. Nestrick, William F. Martin, Gary M. Klecka
  • Patent number: 5595663
    Abstract: A method for processing chemical cleaning solvent waste that combines evaporation, purification, and absorption. The method is mobile and thus allows the processing to be done at the site of the cleaning where the entire processing can be completed. Evaporation produces a concentrated solvent and vapor and gas. The concentrated solvent is absorbed to produce a dry residue for long term storage or disposal and a liquid that is filtered and then released to the surrounding environment. The vapor and gas are scrubbed and condensed to produce a gas that is suitable for release and a distillate. The distillate is purified by filtration and reverse osmosis to produce a distillate that is suitable for release.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: January 21, 1997
    Assignee: Framatome Technologies, Inc.
    Inventors: Cary R. Bowles, Sidney D. Jones, Gary A. Peters
  • Patent number: 5575834
    Abstract: A forced recirculation of a part of the untreated flue gas is established along the inside wall of a dry scrubber by providing a counterflowing gas flow along the length of a dry scrubber housing wall to prevent deposition of wet particulate material on the inside walls caused by recirculation of particulates and flue gas thereon.
    Type: Grant
    Filed: June 3, 1996
    Date of Patent: November 19, 1996
    Assignee: The Babcock & Wilcox Company
    Inventors: Thomas W. Strock, Paul Dykshoorn
  • Patent number: 5549831
    Abstract: A method for processing chemical cleaning solvent waste that combines evaporation, purification, and detoxification. The method is mobile and thus allows the processing to be done at the site of the cleaning where the entire processing can be completed. Evaporation produces a concentrated solvent and vapor and gas. The concentrated solvent is detoxified to produce a dry residue for long term storage or disposal and a liquid that is filtered and then released to the surrounding environment. The vapor and gas are scrubbed and condensed to produce a gas that is suitable for release and a distillate. The distillate is purified by filtration and reverse osmosis to produce a distillate that is suitable for release.
    Type: Grant
    Filed: August 8, 1995
    Date of Patent: August 27, 1996
    Assignee: B&W Nuclear Technologies, Inc.
    Inventors: Cary R. Bowles, Sidney D. Jones, Gary A. Peters
  • Patent number: 5510567
    Abstract: A method of separating a mixture of gases by the following stages:a) absorbing a part G2 of a gas mixture G1 by a solvent L1 in an absorption zone C1;b) expanding the solvent L1, leading to partial vaporization of the absorbed gases G2 and cooling of the solvent L1;c) desorbing the gas fraction G2 in a desorption apparatus D1 having a reboiling zone B1 and an internal heat exchange zone Z1, wherein the solvent L1 from stage (b) is circulated in countercurrent contact with the vapor phase, and simultaneously has counter-current heat exchange with the solvent phase from the reboiling zone B1;d) passing the regenerated solvent leaving the reboiling zone B1 into the heat exchange zone Z1, and transferring the regenerated solvent to the top of said internal heat exchange zone; ande) recycling the regenerated solvent to the absorption zone C1.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: April 23, 1996
    Assignee: Institut Francais du Petrole
    Inventors: Christophe Lermite, Joseph Larue, Alexandre Rojey
  • Patent number: 5478449
    Abstract: Disclosed is an improved waste gas processing method and apparatus using reduced water to contact waste gas, thereby removing noxious substances therefrom or turning it into nontoxic gas. Also, inactivation of acid effect is advantageously caused, and hence, acid erosion which otherwise, would be caused by acid solution originating from the noxious substances can be prevented, and accordingly the life of installations is extended. Such inactivation of acid effect facilitates collection of acid solutions.
    Type: Grant
    Filed: July 14, 1994
    Date of Patent: December 26, 1995
    Inventor: Hideo Hayakawa
  • Patent number: 5476986
    Abstract: A method for cleaning a mixture of air and vapour from volatile crude oil with recovery of the hydrocarbons, wherein the vapours are absorbed in an absorption means (3) by direct contact with a petroleum distillate, such as "petroleum" which has been cooled sufficiently beforehand to cause combined cooling condensation and absorption of the hydrocarbons, the petroleum distillate having a substantially constant hydrocarbon concentration is transferred from the absorption means (3) to a buffer tank (5), from which it is conveyed either to a stripping means (4) in which the hydrocarbons dissolved in the petroleum distillate are stripped so that the petroleum distillate circulates in a substantially closed circuit, or for further processing or use. Prior to absorption under pressure in the absorption means (3) the entering mixture of air and vapour is compressed in a compressor (1) and washed with crude oil under pressure in a washing column (2).
    Type: Grant
    Filed: July 22, 1994
    Date of Patent: December 19, 1995
    Inventor: Anker J. Jacobsen
  • Patent number: 5434330
    Abstract: A process and an apparatus for separating desired clathrate forming gases from a gas mixture containing the desired clathrate forming gases. The process includes providing a stream of the gas mixture, contacting the stream of the gas mixture with an aqueous solvent to form a solid clathrate hydrate suspension in the aqueous solvent. The forming of the solid clathrate hydrate suspension in the aqueous solution causing the gaseous stream to be thereafter leaner in the desired clathrate forming gases. The solid clathrate hydrate suspension and the aqueous solution are subjected to an elevated temperature and to a reduced pressure to produce a product gaseous stream which is richer in the desired clathrate forming gases.
    Type: Grant
    Filed: June 23, 1993
    Date of Patent: July 18, 1995
    Inventors: Miguel A. Hnatow, John Happel
  • Patent number: 5352335
    Abstract: A continuous process for the extraction of halogenated hydrocarbons from a dilute, halogenated hydrocarbon-containing aqueous fluid, in high efficiency, while dramatically reducing the stripping medium requirement for the extraction and without substantially increasing the amount of halogenated hydrocarbons discharged to the atmosphere.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: October 4, 1994
    Assignee: Albemarle Corporation
    Inventor: Phillip R. Beaver