Abstract: Porous metallosilicate catalyst (e.g. Zeolite Beta) is active at low temperature for converting lower alkanol (e.g. methanol) and C.sub.4 -C.sub.7 tertiary alkenes to high octane ether product. Such catalytic reaction is especially useful in multizone catalytic reactor systems employing catstill rectification.

Abstract: A process for upgrading low octane naphthas to produce gasoline products with low levels of benzene and aromatics while retaining a high pool octane uses a paraffinic naphtha reformer feed which is dehexanized to provide a C.sub.7 + fraction which is fed to the reformer and a C.sub.6 fraction which is fed together with the C.sub.6 fraction from the reformer effluent to a catalytic upgrading step where the low octane components from the naphtha and the benzene from the reformate are converted to a low benzene, high octane gasoline by alkylation of the benzene and other aromatics present in the reformate. The process has the advantage that benzene make in the reformer is reduced by the partial by-passing of the C.sub.6 benzene precursors around the reformer; in addition, improved benzene alkylation results from the presence of additional light olefins generated by the cracking of paraffins from the paraffinic naphtha. the reaction is preferably carried out in a turbulent fluidized bed reaction zone.

Abstract: The present invention provides an acid catalyzed isoparaffin-olefin alkylation process which improves process stability and safety by storing the acid in an excess of an additive which reduces the fuming tendency of the mixture, for example, a sulfone. Acid is stripped from the additive and concentrated prior to charging the acid to the alkylation reaction zone. Specifically, because the stored solution of acid in the additive is more dilute than can be effectively used for isoparaffin-olefin alkylation, the acid is concentrated prior to charging the catalyst mixture to the reaction zone. The invention solves the problem of conjunct polymer accumulation by diluting the conjunct polymer with a relatively large volume of the additive and continuously regenerating a slipstream of the dilute acid/additive mixture.

Abstract: Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by treatment over an acidic catalyst containing, preferably an intermediate pore size zeolite such as ZSM-5 and a zeolite such as MCM-22. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. In favorable cases, using feeds of extended end point such as heavy naphthas with 95 percent points above about 380.degree. F. (about 193.degree. C.), improvements in both product octane and yield relative to the feed may be obtained.

Abstract: A method for enhanced oil recovery from a low permeability diatomaceous reservoir by imbibition is described. In this method, oil is displaced from the reservoir with a horizontal wellbore by a combination of applied fluid pressure, plus "enhanced imbibition." Enhanced imbibition is accomplished by adding chemical additives, water, or brine to an injection fluid so that rock in the tight diatomaceous reservoir has a stronger affinity for the water present therein, thus releasing oil from the rock. The method is either continuous or cyclic.

Abstract: A method for increasing the efficiency by which fracture fluids are produced back from a hydrocarbonaceous fluid bearing formation. To remove said fracture fluid, agglomerated particles or granules containing a chemical blowing agent are placed into the formation. After placement of the agglomerated particles and granules containing the blowing agent and fracturing the formation, the blowing agent decomposes thereby providing a driving force for fluid load removal from the formation matrix. Increased porosity enhances communication between the formation and the fracture, thus increasing the efficiency of fracture fluid production. Gas liberation within the matrix establishes communication pathways for subsequently removing hydrocarbonaceous fluids by displacing load fluids into the fracture and the well.

Abstract: A method for enhanced hydraulic fracturing which comprises injecting a proppant laden fracturing fluid into a formation or reservoir at a rate and pressure sufficient to fracture said formation. Next, a thin spacer fluid is injected into the created fracture. Afterwards, a proppant laden fracturing fluid is injected into the formation at a rate and pressure sufficient to hold the created fracture open which allows proppant to be more evenly distributed throughout the created fracture as proppant falls through the spacer fluid thereby avoiding proppant convection in the created fracture while obtaining substantially improved propping of the fracture.

Abstract: A method for enhanced oil recovery from a low permeability diatomaceous reservoir by imbibition is described. In this method, oil is displaced from a single injection well, or series of injection wells into a single producer or series of producing wells by a combination of applied fluid pressure, plus "enhanced imbibition." Enhanced imbibition is accomplished by adding chemical additives to the injection fluid so that rock in the tight reservoir has a stronger affinity for the water present therein, thus releasing oil from the rock.

Abstract: Low sulfur gasoline of relatively high octane number is produced from a cracked, sulfur-containing olefinic naphthas by hydrodesulfurization followed by treatment over an acidic catalyst comprising zeolite beta with a metal hydrogenation component, preferably a mild hydrogenation component such as molybdenum. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. In favorable cases, using feeds of extended end point such as heavy naphthas with 95 percent points above about 380.degree. F. (about 193.degree. C.), improvements in both product octane and yield relative to the feed may be obtained.

Abstract: Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. In favorable cases, using feeds of extended end point such as heavy naphthas with 95 percent points above about 380.degree. F. (about 193.degree. C.), improvements in both product octane and yield relative to the feed may be obtained.

Abstract: Catalytically cracked naphthas containing C.sub.9 + hydrocarbons are hydrocracked over a crystalline zeolite, typically, mildly steamed zeolite beta then subjected to reforming to achieve a gasoline product of reduced end boiling range and higher octane than the feed. A hydrogen stream from the reformer which contains a catalytic promoter, such as chlorine, is separated into a first stream and a second stream. The first stream is treated over a solid sorbent to remove the promoter and recycled promoter to the hydrocracking step while the untreated second hydrogen stream which contains promoter is recycled to the reformer.

Abstract: The invention provides a method for converting a lactone of a diamondoid compound to the hydroxyketone of the diamondoid compound wherein the hydroxyl group and the carbonyl group are separated by at least one bridgehead carbon comprising reacting an anhydride containing from about 2 to about 20 carbon atoms with the lactone of the diamondoid compound in the presence of acid.

Abstract: Additives which improve the low-temperature properties of distillate fuels are the reaction products of (1) diaminodiols, and (2) the product of pyromellitic dianhydride and aminoalcohols and/or amines with long-chain hydrocarbyl groups attached.

Abstract: Low sulfur distillate fuel oils such as road diesel oil having a maximum sulfur content of 0.05 weight percent, are produced by segregation of a distillate range feed into a lower boiling fraction and higher boiling fraction with the cut point between the two fractions between about 600.degree. and 650.degree. F. (about 315.degree. to 345.degree. C.). The higher boiling fraction is hydrodesulfurized under relatively severe conditions and then combined with the lower boiling fraction to be hydrodesulfurized under less severe conditions. Operation in this manner enables the refractory dibenzothiophenes to be removed while maintaining a lower hydrogen consumption.

Abstract: A process and apparatus for fluidized catalytic cracking (FCC) with cooling of FCC catalyst during regeneration in a baffled heat exchanger attached to the regenerator. The heat exchanger has a vertical baffle defining an inlet and an outlet side. Lift gas added to the outlet side induces flow from the regenerator, around the baffle and back to the regenerator. A symmetrical design, with reversing flow can equalize wear on heat exchanger tubes and permit selected cooling if the heat exchanger outlet is near the regenerated catalyst outlet.

Abstract: The present invention relates to novel multi-layer coextruded thermoplastic stretch wrap films useful for the packaging or palletizing of goods. The films of this invention comprise at least three layers, the three layers having first and second outer layers and an intermediate layer positioned between the first and second outer layers, the first outer layer comprising about 70 to about 98 weight percent of a linear low density polyethylene and about 2 to about 30 weight percent of a low density polyethylene produced by high pressure polymerization, the intermediate layer comprising about 65 to about 85 weight percent of a linear low density polyethylene and about 15 to about 35 weight percent of a low density polyethylene produced by high pressure polymerization, and the second outer layer comprising about 90 to about 99 weight percent of a linear low density polyethylene and about 1 to about 10 weight percent of a low density polyethylene produced by high pressure polymerization.

Abstract: A lubricant of fuel composition contains a multifunctional antioxidant/metal deactivating and thermal stabilizing amount of a tolyltriazole-derived Mannich base made from a tolyltriazole, an aliphatic amine, such as diisobutylamine or bis(2-ethylhexyl)amine, a cyclic amine, such as 1,4-diaminocyclohexane or ether amines exemplified by C.sub.6 to C.sub.13 alkoxypropylamines and polyether primary amines such as those derived from nonylphenol ethyoxylates and formaldehyde. The reaction products are, optionally, treated with epoxide.

Abstract: Multimodal high-density ethylene polymers or copolymers (HDPE) of broad molecular weight distribution suitable for blow-molding and films are prepared with a chromium oxide catalyst mixed with a MgO-supported Ziegler catalyst, modified with an alkene and with alkyl aluminum hydride, and with an MgO additive.

Abstract: A process is provided for producing low sulfur gasoline of relatively high octane number from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by treatment over an acidic catalyst comprising crystals having the structure of ZSM-12. The treatment over the acidic catalyst comprising ZSM-12 in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. In favorable cases, using feeds of extended end point such as heavy naphthas with 95 percent points above about 380.degree. F. (about 193.degree. C.), improvements in both product octane and yield relative to the feed may be obtained.