Patents Represented by Attorney A. W. Breiner
  • Patent number: 4855211
    Abstract: Phosphonium mordanting polymer, that is capable of fixing acid dyes and that comprises randomly distributed recurring units corresponding to the general formula (I) ##STR1## wherein: A represents a unit that is derived from a copolymerizable monomer capable of quenching singlet oxygen e.g. N-vinylimidazole or 2-methyl-1-vinylimidazole;B represents a unit that is derived from a copolymerizable monomer having a hydrophobic character e.g. acrylonitrile or methacrylonitrile;n represents an integer of from 1 to about 12;each of R.sub.1, R.sub.2 and R.sub.3 (same or different) represents a C.sub.1 -C.sub.8 alkyl group e.g. n-butyl, a substituted C.sub.1 -C.sub.8 alkyl group e.g. a methylol group, a cyanoethyl group or an aralkyl group, a cycloalkyl group, an aryl group e.g. phenyl, or a substituted aryl group;X.sup.- represents an acid anion e.g. a halogen anion e.g. Cl.sup.-, Br.sup.- or I.sup.-, or an anion derived from an inorganic acid e.g. NO.sub.3.sup.-, HSO.sub.4.sup.-, SO.sub.4.sup.--, H.sub.2 PO.sub.4.sup.
    Type: Grant
    Filed: August 4, 1988
    Date of Patent: August 8, 1989
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Wilhelmus Janssens, Daniel M. Timmerman, Daniel A. Claeys
  • Patent number: 4855223
    Abstract: A photographic silver halide emulsion material for carrying out a dye diffusion transfer process which material contains a compound that is capable of releasing a diffusible light-fast azo dye from a non-diffusible carrier moiety, wherein said dye contains the following group: --Ar.sup.1 --SO.sub.2 NR--Ar.sup.2 --NR--SO.sub.2 -- as defined herein.
    Type: Grant
    Filed: March 9, 1988
    Date of Patent: August 8, 1989
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Luc J. Vanmaele, Janssens Wilhelmus, Christian C. Van de Sande
  • Patent number: 4851486
    Abstract: Self-crosslinking cationic paint binders based on ureide-modified epoxy resins; the preparation of these binders and their use, particularly in electrodeposition paints, is described. The modification is effected with carboxylic compounds carrying ureide groups, blocked isocyanate groups and, optionally, tertiary amino groups. The carboxylic compounds are obtained through reaction of dicarboxylic acid anhydrides or compounds carrying dicarboxylic acid anhydrides with a substituted urea or a substituted biuret. The products show excellent resistance and adhesion characteristics.
    Type: Grant
    Filed: May 18, 1988
    Date of Patent: July 25, 1989
    Assignee: Vianova Kunstharz, A.G.
    Inventor: Willibald Paar
  • Patent number: 4848965
    Abstract: An improved scuba weight having a hex-nut locking device molded into the weight is described. The hex-nut locking device secures the weight to a diver's belt, but can be easily loosened, permitting the casting off of the weight, including in underwater operations, if desired.
    Type: Grant
    Filed: June 13, 1988
    Date of Patent: July 18, 1989
    Inventor: Robert L. Peterson
  • Patent number: 4849475
    Abstract: Water-dilutable paint binders based on acrylates for cathodically depositable paints particularly suited for the formulation of decorative single coats or pale primers are described. The binders are partial condensation products of from 60% to 90% by weight of a hydroxy and amino group containing acrylic copolymer, the basic groups of which were obtained through reaction of glycidyl groups with secondary amines, with 10% to 40% by weight of an oliogomeric or polymeric compound carrying CH-active ester groups, preferably malonic acid ester groups, capable of transesterification or transamidation. The paint films afford particularly good yellowing resistance, detergent resistance, and abrasion resistance.
    Type: Grant
    Filed: November 16, 1987
    Date of Patent: July 18, 1989
    Assignee: Vianova Kunstharz, A.G.
    Inventors: Herbert Zima, Josef Forstner
  • Patent number: 4845010
    Abstract: A method for the production of a photographic image by silver complex diffusion transfer processing wherein a negative working silver halide emulsion material having particularly high exposure latitude and being manipulatable under room light conditions without prohibitive fogging is used, said material having a low intensity reciprocity failure (L.I.R.F). The material is contact-exposed with visible light through a sheet support carrying paper paste-up material with its information facing the silver halide emulsion layer of the photographic material, and the resulting latent image is developed in the presence of a silver halide complexing agent and the thus developed silver halide emulsion material is contacted with an image-receiving material to form according to a preferred embodiment a planographic printing plate.
    Type: Grant
    Filed: June 9, 1988
    Date of Patent: July 4, 1989
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul J. Coppens, Marcel Stroobants, Herman L. Matthe
  • Patent number: 4845170
    Abstract: A process for producing self-crosslinking cationic paint binders, water-dilutable upon protonation, on the basis of urea group carrying reaction products of modified phenols and epoxy resins as well as with the binders produced according to the process and their use in stoving paints, particularly in electrodeposition paints is described. The process is characterized in that either an aminoalkylation product of a phenol and a semi-blocked diisocyanate carrying an average of at least one secondary amino group, or a substituted urea prepared from a semi-blocked diisocyanate and an amine, which is further reacted with formaldehyde and a phenol, are reacted with an epoxy compound. The paints formulated with these products, at stoving temperatures of from 150.degree. to 170.degree. C., give films with excellent corrosion resistance and adhesion.
    Type: Grant
    Filed: December 3, 1987
    Date of Patent: July 4, 1989
    Assignee: Vianova Kunstharz, A.G.
    Inventors: Willibald Paar, Michael Honel, Johann Gmoser
  • Patent number: 4845171
    Abstract: A process for producing self-crosslinking cationic paint binders, water-dilutable upon protonation, on the basis of urea and urethane group carrying reaction products of modified phenols and monoepoxy compounds as well as with the binders produced according to this process and their use in stoving paints, particularly electrodeposition paints are described. The process is characterized in that a substituted urea-phenol-formaldehyde condensate obtained through reaction of an aminoalkylation product of a phenol, carrying an average of at least one secondary amino group with a semi-blocked diisocyanate, or a substituted urea prepared from a semi-blocked diisocyanate and an amine and further reacted with formaldehyde and a phenol, is reacted with a monoepoxy compound, the free aliphatic hydroxy groups of the reaction product being reacted in a further reaction step with di- or polyisocyanates. The paints formulated with these products, at stoving temperatures of from 150.degree. to 170.degree. C.
    Type: Grant
    Filed: December 3, 1987
    Date of Patent: July 4, 1989
    Assignee: Vianova Kunstharz, A.G.
    Inventors: Johann Gmoser, Willibald Paar, Michael Honel
  • Patent number: 4839194
    Abstract: A method is described for preparing tissue samples for use in diagnostic evaluation involving the rapid fixation, dehydration, and embedding of a tissue sample as well as rapid mounting of plastic sections to glass slides, dissolution of plastic and optimal staining of tissure components. The rapid and controllable fixation and the dehydration of the tissue sample utilizes the denaturing effects of microwaves on the proteins in combination with a heat sink. Alternatively, the dehydration of the tissue sample utilizes the principles of freeze drying. The tissue sample can be embedded using conventional paraffin embedding or plastic embedding techniques. Rapid penetration of plastic into the tissue is facilitated by microwaves, adhesion of plastic sections to glass slides is promoted by microwaves, as is the fast and optimal staining of tissue components. The method of this invention provides a very rapid technique for processing of tissue for diagnostic and analytic evaluation.
    Type: Grant
    Filed: July 5, 1985
    Date of Patent: June 13, 1989
    Assignee: Bone Diagnostic Center
    Inventors: Hartmut H. Malluche, Gisela Malluche
  • Patent number: 4839393
    Abstract: Polyurethane foams based on reactive polyols and polyisocyanates containing a filler are modified with an organofunctional silane containing a hydrolyzable group and an ethylenically unsaturated linkage. The polyurethane foams have improved physical properties including improved stability, compression set, tear resistance, elongation, and tensile strength.
    Type: Grant
    Filed: July 8, 1988
    Date of Patent: June 13, 1989
    Assignee: Wm. T. Burnett & Co., Inc.
    Inventors: Michael S. Buchanan, Gregory B. Davis, Walter V. V. Greenhouse
  • Patent number: 4839267
    Abstract: Color photographic motion picture elements adapted to form a multicolor photographic dye image and an integral, infrared-absorbing, dye sound track and comprising a 1-hydroxy-2-N-(5-ballasted-thiazol-2-yl)-naphthamide coupler dispersed with the aid of a water-immiscible, high-boiling, oil-type hydrocarbon oil-former, said coupler bearing a phenyl group or a substituted phenyl group at the 4-position of the thiazol-2-yl ring and being capable of forming infrared-absorbing quinone imine dyes by reaction with an oxidized aromatic primary amino developing agent.
    Type: Grant
    Filed: October 21, 1987
    Date of Patent: June 13, 1989
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Marcel J. Monbaliu, Paul L. Van Meerbeeck
  • Patent number: 4837291
    Abstract: Cationic paint binders, water-dilutable upon protonation, which crosslink internally at elevated temperatures are obtained through reaction of beta-hydroxyamines of the general formula- ##STR1## wherein R.sub.1 is a (cyclo)alkyl radical and/or a hydroxyalkyl radical and/or a tertiary amino(cyclo)alkyl radical, or optionally a radical resulting from the reaction of glycidyl groups with a primary-secondary amine or a diprimary amine and R.sub.2 is an aliphatic and/or aromatic radical of a polyepoxy compound, with partially blocked polyisocyanates and subsequent reaction with formaldehyde. In addition to having excellent film properties, the products show particularly favorable characteristics for processing, since they do not exhibit the thixotropy effects normal with such systems. The products are particularly suited for the formulation of cathodically depositable electrodeposition paints.
    Type: Grant
    Filed: June 19, 1987
    Date of Patent: June 6, 1989
    Assignee: Vianova Kunstharz, A.G.
    Inventor: Willibald Paar
  • Patent number: 4832728
    Abstract: Relates to a fertilizer product in granular form, to processes for making and using it. The granules have strength, sizes and weights suitable for mechanical dispensing and application to and into the soil. These granules combine particles of a nitrogen source of poor solubility in pH 7 water at 20.degree. C., that converts slowly to a useful form, together with a binder that holds these fine particles together.
    Type: Grant
    Filed: September 18, 1985
    Date of Patent: May 23, 1989
    Assignee: Melamine Chemicals, Inc.
    Inventors: G. Graham Allan, Donald E. Freepons, George M. Crews
  • Patent number: 4828927
    Abstract: A sheet or web comprising a substrate which is composed of or coated with a hydrophobic resin and carries an antistatic layer, characterized in that the antistatic layer consists essentially of a blockcopolyetherester of dibasic carboxylic acid(s) esterified with ethylene glycol and with a polyoxyethylene glycol having an average molecular weight in the range 1,000 to 10,000, at least 20% by weight of such blockcopolyetherester being constituted by polyoxyethylene-ester chain parts.
    Type: Grant
    Filed: April 21, 1987
    Date of Patent: May 9, 1989
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Daniel M. Timmerman, August M. Marien, Jan E. Van Havenbergh, Etienne A. Van Thillo
  • Patent number: 4822729
    Abstract: Cyan-forming color couplers according to the formula: ##STR1## wherein Z is hydrogen or a coupling off group, R.sup.1 is hydrogen, a halogen atom, alkyl, or alkoxy, R.sup.2 is hydrogen or alkyl, R.sub.3 is hydrogen, a halogen atom, alkyl, alkoxy, alkylsulphonyl, alkanamidosulphonyl, alkoxycarbonyl, alkanamidocarbonyl, alkanamido, alkylsulphonamido, or cyano, R.sup.4 is a substituent standing at the 3- or 6-position of the phenol and selected from hydrogen, a halogen atom, and alkyl, and n is 0 or 1. These couplers can be incorporated into (a) red-sensitized silver halide emulsion layer(s) of a photographic multilayer color element or in a non-light-sensitive colloid layer in water-permeable relationship with the red-sensitized emulsion layer(s).
    Type: Grant
    Filed: November 24, 1987
    Date of Patent: April 18, 1989
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Marcel J. Monbaliu, Paul L. Van Meerbeeck
  • Patent number: 4822696
    Abstract: A process for the conversion of X-rays into blue and/or green light with a phosphor which on exposure to X-rays emits light the spectrum of which contains main intensity lines below 460 nm and/or main intensity lines between 530 and 570 nm, wherein said phosphor comprises a gadolinium gallium garnet compound having following empirical formula:Gd.sub.8-x-y Ln.sub.y Ga.sub.x O.sub.12wherein: 5.14.gtoreq.x.gtoreq.4.90 and 0.45.gtoreq.y.gtoreq.0.001, and Ln is scandium (Sc) and/or one or more rare earth elements other than gadolinium.The invention is directed particularly to the use of said phosphor in an X-ray conversion screen applied in medical radiography.
    Type: Grant
    Filed: August 5, 1987
    Date of Patent: April 18, 1989
    Assignee: Agfa-Gevaert N.V.
    Inventors: Marinus J. Lammers, George Blasse, David R. Terrell, Leo B. Alaerts
  • Patent number: 4820615
    Abstract: The present invention relates to photographic elements comprising a support and on one or on both sides of said support in the given order at least one photosensitive silver halide emulsion layer and at least one protective hydrophilic colloid layer comprising finely divided solid spherical beads having an average size ranging from 0.5 to about 20 .mu.m, said beads comprising at least one photographically inert hydrophobic polymeric resinous material and, distributed throughout said resinous material, at least one water-insoluble wax, in a ratio by weight ranging from 10:0.1 to 10:5.The present invention also relates to a method of making such photographic elements.
    Type: Grant
    Filed: August 4, 1988
    Date of Patent: April 11, 1989
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Hubert Vandenabeele, Jacques L. Vervecken
  • Patent number: 4820608
    Abstract: The present invention provides a dye diffusion transfer imaging process comprising transferring image-wise by diffusion an acid dye to an image-receiving layer incorporating a non-polymeric phosphonium mordanting agent and a copolymer latex comprising free weak acid groups as a stabilizer for the mordanting agent, wherein the image-wise transfer of said acid dye is performed in the presence of a heterocyclic compound corresponding to one of the following general formulae I, II, and III: ##STR1## wherein: Y represents the non-metallic atoms needed to complete a saturated or unsaturated 5- or 6-membered heterocyclic nucleus, which may carry a fused-on aromatic ring system, and M represents hydrogen, an alkali metal atom, a quaternary ammonium group, or a negative charge forming an inner salt with a quaternized nitrogen atom of the heterocyclic compound. The invention also provides an image receptor element for dye diffusion transfer imaging processes comprising a support and such image-receiving layer.
    Type: Grant
    Filed: October 21, 1987
    Date of Patent: April 11, 1989
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Daniel A. Claeys, Daniel M. Timmerman, Antonius A. Rutges, Eddy A. Michiels, Luc J. Vanmaele, Piet Kok
  • Patent number: 4820386
    Abstract: A fast response diffusion-type sensor cell for the detection of carbon monoxide and other oxidizable or reducible gases comprising a three-electrode hydrated proton-conducting membrane cell configuration, with all electrodes in intimate contact with the same proton-conducting membrane is described. The liquid electrolyte-free system has a porous gas-diffusion sensing electrode and a counter electrode located on the same side of and in intimate contact with the proton-conducting membrane. The reference electrode is spatially located on the same or opposite side of the membrane as are the sensing and counter electrodes.
    Type: Grant
    Filed: February 3, 1988
    Date of Patent: April 11, 1989
    Assignee: Giner, Inc.
    Inventors: Anthony B. LaConti, Arthur E. Griffith
  • Patent number: 4820613
    Abstract: The present invention provides a method of hardening a proteinaceous surface layer of a photographic silver halide element by incorporating a dextran derivative in said proteinaceous surface layer, said dextran derivative being the reaction product of dextran and an epihalohydrin. The invention also provides a photographic element comprising at least one silver halide emulsion layer and at least one proteinaceous surface layer comprising the reaction product of dextran and an epihalohydrin.
    Type: Grant
    Filed: July 29, 1987
    Date of Patent: April 11, 1989
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Joan T. Vermeersch, Hubert Vandenabeele, Jacques L. Vervecken, Daniel M. Timmerman