Abstract: Apparatus and process is herein disclosed by which a polymerizable monomer or mixture thereof can be economically and efficiently converted to polymeric substances with a high yield catalyst and, optionally, co-catalyst by a vapor phase, essentially isobaric, polymerization process using a horizontal, stirred-bed, quench-cooled, essentially total reactor off-gas recycle reactor.
Abstract: Polyethylene or ethylene copolymer containing up to about twenty percent of a C.sub.3 to C.sub.8 olefin can be made by using a solid catalyst component prepared from (1) a lower alkyl magnesium alkoxide or magnesium hydroxide, (2) a titanium-aluminum compound, and (3) a lower alkyl alkylaluminum dichloride. Said solid component can be used in conjunction with a trialkylaluminum promoter in a slurry or vapor phase polymerization process at moderate polymerization temperatures and pressures.
Abstract: Paper sizing process comprising (1) adding a sizing composition of a cationic retention aid and a monoester of a benzene carboxylic acid anhydride having from 6 to 60 carbon atoms in the ester group to an aqueous pulp suspension or paper stock prior to web formation, and (2) heating said sized paper web to a temperature of from 80.degree. to 150.degree. C.
Abstract: A process for producing shaped articles of polyalkylene terephthalate resins involves thermoforming a substantially unoriented sheet of said resin which sheet has an average crystallinity thermally induced in the range of about 0% to 18% and an average temperature in the range of about 210.degree.-300.degree. F., in contact with a mold at a temperature in the range of about 240.degree.-350.degree. F. which mold is preferably at a higher temperature than said sheet. Optionally a differential in applied pressure below about 5 atmospheres can be utilized in the thermoforming.
Abstract: A stable free sulfur containing mineral oil is produced in a two-step process. The first step of the process comprises producing a sulfurized solubilizing oil by reacting a lubricant oil with elemental sulfur until the uncombined sulfur content is less than about 0.5%. The second step comprising dissolving in the oil a quantity of sulfur such that the final concentration of uncombined sulfur is less than 2.0%.
Type:
Grant
Filed:
August 3, 1977
Date of Patent:
November 14, 1978
Assignee:
Standard Oil Company a corporation of Indiana
Inventors:
Paul C. Vienna, Marvin J. Den Herder, Alex Zletz
Abstract: Polyalkylenetrimellitate imide polyalkylenetrimellitate ester imides suitable for use as self-bonding varnish coatings for magnet wire, which can be produced by condensation of a trimellitic acid compound, a diprimary amine, an alkanol amine and a glycol.
Abstract: An improved primary backing for tufted carpets having excellent tuftability comprises a woven, nonwoven, or knitted substrate capable of being tufted to which a web of blended fibers is heat fused.
Type:
Grant
Filed:
December 22, 1976
Date of Patent:
October 31, 1978
Assignee:
Standard Oil Company (Indiana)
Inventors:
Morton I. Port, Juergen Nebe, Bernhard H. Ladeur
Abstract: This invention relates to the preparation of the subject aqueous solution from a non-bromine manganous salt. More specifically this invention pertains to a critical order of dissolving such salt and elemental bromine and to the use of an anti-oxidant for the manganous ion to prevent its conversion to hydrated manganous dioxide: MnO(OH).sub.2. According to "A Comprehensive Treatise On Inorganic And Theoretical Chemistry", J. W. Mellor, Vol. XII at pages 189 and 259 (published by Longmans, Green and Co., 1947) hydrated manganous dioxide results from the oxidation of a solution of manganous salt with chlorine, bromine, hypochlorous acid, hydrogen peroxide, etc. Such oxidation of a solution of manganous acetate was specifically mentioned. Such hydrated manganous dioxide is described as a white solid product which upon standing in contact with air becomes a dark brown to black product identified as MnO.sub.2.
Type:
Grant
Filed:
December 16, 1977
Date of Patent:
October 24, 1978
Assignee:
Standard Oil Company a corporation of Indiana
Inventors:
Joseph D. Fox, George E. Kuhlmann, Ricky L. Wittman
Abstract: A method is disclosed for moving and eventually recovering oil from a subterranean oil-bearing formation which comprises injecting into the formation an aqueous fluid containing a succinamate surface-active agent and method for mobility control (imparting viscosity) to a surfactant system used for recovery or moving of oil in an oil-bearing formation.
Abstract: A catalytic composition is produced by reacting in an aqueous medium, vanadium and phosphorus compounds together with a hydrogen halide and removing liquid from the resulting reactants to form a solid which in an improved manner is heated at a temperature of about less than 470.degree. C. to effect liberation of water of hydration from the solid and thereafter contacting with a reducing material selected from the group of carbon monoxide, hydrogen and hydrogen sulfide at a temperature of from about 300.degree. to about 600.degree. C. and in the substantial absence of gaseous oxygen other than that liberated from the solid. The specific reduction step as taught and claimed herein improves catalyst activity performance by increasing the catalyst conversion and selectivity to a desired oxygenated product, and the ultimate yield of the oxygenated product per quantity of feed component converted. It also minimizes formation of inactive VPO.sub.
Type:
Grant
Filed:
July 22, 1977
Date of Patent:
October 24, 1978
Assignee:
Standard Oil Company a corporation of Indiana
Abstract: Improved analysis of sulfur concentration in carbonaceous sample uses carbon dioxide produced by the sample as an internal monitor of sample density reflected in the derived sulfur concentration.
Abstract: Disclosed is a method for providing communication with a subterranean oil shale retort. This method can be used to provide a means of introducing fluids, such as a slurry of spent oil shale in water, into a retort. The method for providing lateral communication with a subterranean oil shale retort containing a rubblized retortable mass of oil shale, said retort being substantially surrounded by a mass of unmined formation comprises drilling at least one hole through the unmined formation adjacent to the retort; and providing communication between at least one of said holes and an adjacent retort; so that said drill hole can be used to communicate fluids to said retort. Fluids can be introduced into a spent retort which will form a supporting structure within said retort.
Abstract: A method is disclosed for moving and eventually recovering oil from a subterranean oil-bearing formation which comprises injecting into the formation an aqueous fluid containing a succinamate surface-active agent and method for mobility control (imparting viscosity) to a surfactant system used for recovery or moving of oil in an oil-bearing formation.
Abstract: There is disclosed a catalyst for the hydrodemetallization of petroleum hydrocarbon streams containing asphaltenes and large quantities of metals. This catalyst consists essentially of a small amount of a single hydrogenation metal selected from the group consisting of metals from Group VIB of the Periodic Table of Elements and metals from Group VIII of the Periodic Table deposed on a large-pore alumina. The hydrogenation metal may be present in the elemental form, as an oxide, as a sulfide, or mixtures thereof. The catalyst is characterized by a surface area of at least 120 square meters per gram, a pore volume of at least 0.7 cc per gram, and an average pore diameter of at least 125 Angstrom units. Suitable examples of a hydrogenation metal are nickel and molybdenum.
Type:
Grant
Filed:
June 30, 1977
Date of Patent:
October 10, 1978
Assignee:
Standard Oil Company (Indiana)
Inventors:
P. Donald Hopkins, Albert L. Hensley, Jr.
Abstract: Disclosed is a process for removing acidic impurities from off-gases generated in the retorting of oil shale comprising contacting a rubblized mass of oil shale which has been substantially depleted in hydrocarbonaceous materials with water, so as to extract basic components from the mass; and contacting off-gases, which were generated during the retorting of oil shale and which contain acidic impurities, with the water containing basic components so as to substantially remove said acidic impurities from said off-gases.
Abstract: Water-soluble polyesterimide resin compositions are prepared by in situ reaction of a mixture of glycol and triol with organic diacid and trimellitic anhydride/aromatic primary diamine. The product is reacted with additional trimellitic anhydride for use as wire enamel in water-base solution and chelated ethanolamine titanate is added to the solution as a crosslinking agent.
Type:
Grant
Filed:
June 1, 1976
Date of Patent:
September 26, 1978
Assignee:
Standard Oil Company, a corporation of Indiana
Abstract: The product of the reaction of an amine, an olefin and sulfur trioxide, or sulfur trioxide complex, is an effective ashless antistatic agent for hydrocarbons. A small amount of the antistatic agent, when added to hydrocarbons, increases the conductivity of the hydrocarbon. The increased conductivity of the hydrocarbon conducts away any static charges that may be generated on the hydrocarbon and thus prevents the buildup of the static charges. The antistatic additive is represented by the general formula ##STR1## where R.sub.1 is a hydrocarbon group of less than 24 carbon atoms and R.sub.2 is hydrocarbon group with less than 18 carbons, or ammonia.
Abstract: Disclosed is a continuous process for the sulfonation of an alkylaromatic reactant involving heating liquid sulfur trioxide in a vaporizer and mixing this sulfur trioxide gas stream with a hexane-alkylaromatic stream containing about 1 to about 3 wt. % quantity of a promoter, which can be either sulfuric acid or an alkyl benzene sulfonic acid, in a sulfonator - static inline mixer, mixing water with the sulfonated product as it passes to the water reactor - static inline mixer, passing the aqueous sulfonated product through degassing column-heat exchanger apparatus and separating the sulfonated product from the aqueous sulfuric acid. The reaction is conducted under controlled temperature and pressure conditions.
Abstract: Disclosed are a process for manufacturing metal diaryl dithiophosphates, certain metal diaryl dithiophosphates, and lubricating oil compositions containing said metal diaryl dithiophosphates. The process for the manufacture of metal diaryl dithiophosphate generally comprises reacting P.sub.2 S.sub.5 with a hydroxyl aryl compound to form a dithiophosphoric acid; and neutralizing said dithiophosphoric acid with zinc, barium, cadmium, magnesium or nickel base in the presence of an effective amount of a promoter, said promoter comprising dialkyl dithiophosphoric acid. Metal diaryl dithiophosphates, especially for use in lubricating oil compositions, can be made by the above process.