Patents Represented by Attorney David M. Bunnell
  • Patent number: 4117093
    Abstract: Amorphous silicon dioxide particles for polishing semiconductor surfaces are prepared by boiling, at reflux, a mixture of surplus organic amine, a hydroxybenzene, water and silicon in the presence of oxygen to precipitate silicon dioxide.
    Type: Grant
    Filed: June 17, 1977
    Date of Patent: September 26, 1978
    Assignee: International Business Machines Corporation
    Inventors: Friedrich Christian Brunner, Friedrich Wilhelm Schwerdt, Hans-Heinz Steinbeck
  • Patent number: 4116714
    Abstract: Semiconductor materials are cleaned after silica polishing by treatment with an aqueous phosphoric acid containing solution followed by rinsing in water. The treatment dissolves the silica sols so that they are removed from the semiconductor surface.
    Type: Grant
    Filed: August 15, 1977
    Date of Patent: September 26, 1978
    Assignee: International Business Machines Corporation
    Inventor: Jagtar Singh Basi
  • Patent number: 4104070
    Abstract: The invention relates to a method of making a negative photoresist image on a substrate, where a normally positive working photoresist material containing 1-hydroxyethyl-2-alkyl-imidazoline is applied to a substrate, image-wise exposed with actinic radiation, heated, and blanket exposed to actinic radiation. The material which was not exposed originally is then removed with a solvent to give a negative image.
    Type: Grant
    Filed: May 3, 1976
    Date of Patent: August 1, 1978
    Assignee: International Business Machines Corporation
    Inventors: Holger Moritz, Gabor Paal
  • Patent number: 4099062
    Abstract: In an electron beam lithography process, shapes are formed which differ from the beam spot size and the grid by employing multiple overlapping exposures having a reduced exposure level.
    Type: Grant
    Filed: December 27, 1976
    Date of Patent: July 4, 1978
    Assignee: International Business Machines Corporation
    Inventor: James Robert Kitcher
  • Patent number: 4096290
    Abstract: A positive relief image is produced by coating a substrate with a layer of a copolymer containing about 90-98 mole percent of polymerized lower alkyl methacrylate units and about 2-10 mole percent of polymerized lower haloalkyl methacrylate units, heating the layer to cause cross-linking between polymer chains by removal of hydrogen halide, patternwise exposing the layer with high energy radiation such as a scanning electron beam, and removing the exposed portion of the layer with a solvent developer.The purpose of this abstract is to enable the public and the Patents and Trademark Office to rapidly determine the subject matter of the technical disclosure of the application. This abstract is neither intended to define the invention of the application nor is it intended to be limiting as to the scope thereof.
    Type: Grant
    Filed: October 4, 1976
    Date of Patent: June 20, 1978
    Assignee: International Business Machines Corporation
    Inventor: Edward Carmine Fredericks
  • Patent number: 4078098
    Abstract: The development of high energy radiation exposed positive acrylate polymer resist layers by organic liquid developers, such as methyl isobutyl ketone, is improved by adding water to the ketone.
    Type: Grant
    Filed: May 28, 1974
    Date of Patent: March 7, 1978
    Assignee: International Business Machines Corporation
    Inventor: Charles A. Cortellino
  • Patent number: 4078102
    Abstract: Organic polymer resist layers are stripped from substrates by treating the layers with a mixture of an aldehyde or a ketone and an alcoholic solution of a compound selected from the group consisting of ammonium, alkali metal, and alkaline earth metal hydroxides and carbonates.
    Type: Grant
    Filed: October 29, 1976
    Date of Patent: March 7, 1978
    Assignee: International Business Machines Corporation
    Inventors: Diana Jean Bendz, Gerald Andrei Bendz
  • Patent number: 4077815
    Abstract: A water soluble flux composition includes a vehicle portion of polyoxyethylene-polyoxypropylene block copolymers and their adducts of trimethylolpropane along with an activator portion of tetrakis hydroxyalkyl derivatives of alkalene diamines such as N,N,N',N'-tetrakis (2-hydroxypropyl) ethylenediamine and/or a long chain alkyldiethanolamine, such as polyoxyethylene soyamine.
    Type: Grant
    Filed: December 20, 1976
    Date of Patent: March 7, 1978
    Assignee: International Business Machines Corporation
    Inventor: Philipp William Hans Schuessler
  • Patent number: 4063812
    Abstract: In a projection printing system the pattern mask, whose image is projected onto a light sensitive layer, is encased in a glass sandwich so that any dirt particles on the surfaces of the sandwich are out of focus and are not printed in the light sensitive layer.
    Type: Grant
    Filed: August 12, 1976
    Date of Patent: December 20, 1977
    Assignee: International Business Machines Corporation
    Inventors: Gerard Abraham, Gaston Bergasse
  • Patent number: 4052603
    Abstract: Objects, such as a pattern mask and a photoresist coated substrate, are placed in translational and/or rotational alignment by a system in which a target on one object is successively aligned to two targets on the other object so that the accuracy of each alignment can be verified. The system compares a known stored distance between alignment targets with the distance determined from the successive alignments. When the distances agree within a preselected tolerance, then the objects are moved into alignment.
    Type: Grant
    Filed: December 23, 1974
    Date of Patent: October 4, 1977
    Assignee: International Business Machines Corporation
    Inventor: Karl Karlson
  • Patent number: 4040895
    Abstract: The seed to tail oxygen concentration gradient in silicon crystals, which are drawn from a silicon melt contained in a silica vessel according to the Czochralski process, is controlled by a process employing stop-go crucible rotation to provide fluid shearing at the melt-crucible interface.
    Type: Grant
    Filed: October 22, 1975
    Date of Patent: August 9, 1977
    Assignee: International Business Machines Corporation
    Inventors: William John Patrick, Wolfgang Alfred Westdorp
  • Patent number: 4036644
    Abstract: Carboxylic acids are included in resists to increase their speed and adhesion.
    Type: Grant
    Filed: January 15, 1975
    Date of Patent: July 19, 1977
    Assignee: International Business Machines Corporation
    Inventors: Leon H. Kaplan, John Baldwin Lounsbury, Steven Michael Zimmerman
  • Patent number: 4024629
    Abstract: Metallized through-holes are provided in insulating substrates by placing the substrate onto an absorbant carrier and screening a metallization paste, which contains a metal component dispersed in an organic solvent, into the holes. The carrier absorbs the solvent and a portion of the paste adheres to the carrier. When the carrier is stripped from the substrate it carries with it the center portion of the paste to leave a thin layer of paste on the inner surface of the substrate.
    Type: Grant
    Filed: November 26, 1975
    Date of Patent: May 24, 1977
    Assignee: International Business Machines Corporation
    Inventors: Jean Marie Lemonie, Jean Luc Mathis
  • Patent number: 4015986
    Abstract: Baked novolak resin based positive photoresists are either developed after exposure or stripped, following the use of the pattern resist layer as an etch mask, in aqueous solutions of a combination of permanganate and phosphoric acid.
    Type: Grant
    Filed: August 22, 1975
    Date of Patent: April 5, 1977
    Assignee: International Business Machines Corporation
    Inventors: Gabor Paal, Jurgen F. Wustenhagen
  • Patent number: 4013485
    Abstract: The electrical properties of MIS semiconductor devices, which have been damaged by radiation, are restored by treating the devices in a properly oriented RF field at low pressure.
    Type: Grant
    Filed: April 29, 1976
    Date of Patent: March 22, 1977
    Assignee: International Business Machines Corporation
    Inventors: Tso-Ping Ma, William Hsioh-Lien Ma
  • Patent number: 4010064
    Abstract: The oxygen content of silicon crystals, which are drawn from a silicon melt contained in a silica vessel according to the Czochralski process, is controlled by changing the surface characteristics of the portion of the silica vessel which is in contact with the melt so as to provide an increased oxygen concentration in the melt during the crystal drawing process.
    Type: Grant
    Filed: May 27, 1975
    Date of Patent: March 1, 1977
    Assignee: International Business Machines Corporation
    Inventors: William John Patrick, Salvatore James Scilla, Wolfgang Alfred Westdorp
  • Patent number: 4007047
    Abstract: Positive photoresist layers including a base soluble resin and a diazo ketone sensitizer are treated with hydrogen ion following initial exposure to achieve changes in the developed resist profile and/or development in a negative mode.
    Type: Grant
    Filed: December 10, 1975
    Date of Patent: February 8, 1977
    Assignee: International Business Machines Corporation
    Inventors: Leon H. Kaplan, Steven M. Zimmerman
  • Patent number: 4004936
    Abstract: Low temperature, vitreous-crystalline seal glass compositions and a process for their preparation are described. The composition consists essentially of the following constituents in percent by weight:______________________________________ Percent by Weight ______________________________________ PbO 63.5-64.6 B.sub.2 O.sub.3 13.0-13.9 Bi.sub.2 O.sub.3 1.2-1.5 ZnO 11.4-11.9 SiO.sub.2 2.4-2.8 Al.sub.2 O.sub.3 0.8-1.0 Cu.sub.2 O 4.3-5.
    Type: Grant
    Filed: May 19, 1976
    Date of Patent: January 25, 1977
    Assignee: International Business Machines Corporation
    Inventor: Jimmie Lee Powell
  • Patent number: 4000251
    Abstract: Newly precipitated MnO(OH).sub.2 is either added to an NH.sub.4 F solution that has been made slightly basic or this compound is formed in the NH.sub.4 F solution by adding an Mn (II) and an Mn (VII) salt solution. MnO(OH).sub.2 absorbs As and noble metal ions. The purity obtained is 10.sup..sup.-8 per cent by weight (starting from .ltoreq.10.sup..sup.-5 per cent by weight) of NH.sub.4 F solution.
    Type: Grant
    Filed: November 7, 1974
    Date of Patent: December 28, 1976
    Assignee: International Business Machines Corporation
    Inventors: Marian Briska, Wolfgang Hoffmeister
  • Patent number: 4000016
    Abstract: Water soluble fluxing bath compositions have particular value in immersion soldering of metallic surfaces and electrical connections in that they are characterized by good thermal and chemical stability and easy removal of flux residues without corrosion or insulation resistance hazards. The compositions comprise from about 2 to 8 percent by weight of chelating agents or salts dissolved in a solvent, such as glycerol. In some instances from about 0.1 to 1.0 percent of an inorganic acid, such as hydrochloric acid may be added.
    Type: Grant
    Filed: November 29, 1974
    Date of Patent: December 28, 1976
    Assignee: International Business Machines Corporation
    Inventors: Donald J. Lazzarini, Frank H. Sarnacki