Abstract: Calcium and barium bis-O,S-dialkyl-N-alkanoylphosphoroamidothioate salts have high insecticidal activity and are substantially more stable than the corresponding O,S-dialkyl-N-alkanoylphosphoroamidothioate compound.

Abstract: This invention relates to novel N-alkyl-N-cyanoformyl carbamates and N-alkyl-N-cyanoformyl thiolcarbamates and their use as nematocides.

Abstract: A process for dehydrogenating an alkane which comprises contacting the alkane under dehydrogenation conditions including a temperature between 400 and 800.degree. C with a catalyst comprising platinum, chromium, lithium and alumina.Preferably the catalyst comprises 0.1 to 1 weight percent platinum, 0.1 to 1 weight percent chromium, 0.1 to 1 weight percent lithium, and 97 to 99.7 weight percent alumina.

Abstract: Novel N-haloacetyl-1,2-dihydro-4H-3,1-benzoxazines which have utility as herbicides.

Abstract: A method for preparing an alpha,beta-dehydro-gamma-butyrolactone which comprises contacting a carboxylic acid of the formula ##STR1## wherein R is H or C.sub.1 to C.sub.10 alkyl group, with oxygen and a catalyst comprising a noble metal halide, a variable valence transition metal halide and an alkali metal halide at a temperature between 50.degree. and 300.degree. C and superatmospheric pressure.

Abstract: A method for preparing a gamma-chloromethyl-gamma-butyrolactone which comprises contacting 4-pentenoic acid with air or oxygen and a catalyst comprising a noble metal halide, a variable valence transition metal halide and an alkali metal halide at a temperature between 50.degree. and 200.degree. C and superatmospheric pressure.

Abstract: Vinyl 2-arylthiovinyl and vinyl 2-alkylthiovinyl sulfones, having fungicidal and algicidal activity, are prepared by the addition of arylsulfenyl halides or alkylsulfenyl halides to divinyl sulfone and the dihydrohalogenation of the resulting 1,2-addition product.

Abstract: A process for preparing 4-hydroxy-n-butyraldehyde which comprises contacting allyl alcohol with formaldehyde in the presence of hydrogen fluoride at a temperature in the range from about -100.degree. C to about 10.degree. C.

Abstract: A composition containing sulfur, a sulfur plasticizer and mica. The composition is surprisingly strong even without glass fiber in the composition. The composition can be used as a coating formulation or as a binder.

Abstract: Compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are independently alkyl of 1 to 8 carbon atoms, or alkenyl of 2 to 8 carbon atoms, R.sub.3 is hydrogen or alkyl of 1 to 4 carbon atoms, and R.sub.4 is hydrogen, alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 4 carbon atoms, aryl of 6 to 15 carbon atoms optionally substituted with halogen atoms or alkyl groups of 1 to 4 carbon atoms or an acyl group of 2 to 4 carbon atoms, with the proviso that R.sub.3 and R.sub.4 may be joined to form an alkylene radical of 2 to 5 carbon atoms. The compounds possess insecticidal and herbicidal activity.

Abstract: Triazines of the formula ##STR1## wherein R is chlorine, methoxy or methylthio, R' is alkyl, alkenyl or alkoxyalkyl; R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are hydrogen or alkyl; R.sup.6 is alkyl, aryl or haloaryl; and Y is oxygen or sulfur, are useful as herbicides.

Abstract: Sulfur-based foams are produced by heating to liquid state a sulfur formulation containing a minor amount of a gas-producing component in a first (molten) zone; passing the mixture maintained in liquid form to a second (mixing) zone where it is mixed with a foaming agent which in combination with the gas-produced compound releases gas, and the gas-containing mixture is passed from the second zone for use as a cellular construction material. Apparatus for carrying out the process is provided.

Abstract: A process for the preparation of citric acid which comprises contacting an unsaturated compound selected from 3-methylene-1,5-pentanediol and its esters with a nitric acid solution in an amount of 2 to 50 mols of nitric acid feed per mol of unsaturated compound feed, and at least 0.005 mol percent nitrogen dioxide based on nitric acid, at a temperature between -10.degree. and 120.degree. C., to thereby oxidize said unsaturated compound to citric acid. Preferably the contacting of the unsaturated compound so as to synthesize citric acid is carried out in the absence of any substantial amount of vanadium as the presence of vanadium catalysts has been found to effectively prevent the recovery of good yields of citric acid from the process.The citric acid synthesis preferably is carried out by an overall process wherein isobutene is reacted with two mols of formaldehyde to produce 3-methylene-1,5-pentanediol, which is then converted to citric acid by reaction with nitrogen dioxide/nitric acid.

Abstract: A process is set forth for the production of ketones by the action of water and a hydrated molybdenum(VI)-oxygen compound upon an alkene feed. The reaction occurs in the range from 200.degree. to 400.degree. C.

Abstract: Compounds of the formula ##STR1## wherein R is an alkyl group or an alkenyl group, each substituted with 1 to 5 halogen atoms of atomic number 9 to 35, and X is halogen of atomic number 9 to 35, nitro, cyano, lower alkyl, lower alkoxy or trifluoromethyl and n is 0 or an integer of 1 to 3, possess fungicidal activity.

Abstract: A process for polymerizing 2-pyrrolidone utilizing an agitated reaction mixture containing an inert nonsolvent and an insoluble salt in order to produce a particulate, or easily comminuted, solid product.

Abstract: Compounds of the formula ##STR1## wherein R, R.sup.1 and R.sup.2 are hydrogen, halogen, hydroxy, alkyl or alkenyl optionally substituted with halogen atoms and R.sup.3 is a haloalkyl, haloalkenyl or aryl group, possess morphogenetic hormonal mimetic insecticidal activity.

Abstract: An improved process for the production of poly-2-pyrrolidone in which the solid product is washed with monomer to remove the catalyst and the monomer wash, containing catalyst and monomer, is recycled for further polymerization reaction.

Abstract: This invention is directed to 2,3-dihydro-2,2-dialkyl benzofuranyl N-thio-substituted carbamates and their use as insecticides.

Abstract: N-substituted-thio N-alkyl carbamoyl chlorides are prepared by reacting an N-arylthio- or N-aliphaticthio-N-alkylamine with phosgene. The N-arylthio- or N-aliphaticthio-N-alkyl carbamoyl chlorides are useful intermediates for the preparation of pesticides.