Patent number: 4530916
Abstract: A catalyst having heteropoly-acid structure and the general formula:Mo.sub.a V.sub.b P.sub.c Cu.sub.d As.sub.e X.sub.f O.sub.gwherein, X represents one or more elements selected from the group consisting of tin, lead, cerium, cobalt, iron, zirconium, thorium, tungsten, germanium, nickel, rhenium, bismuth, antimony, chromium, boron, magnesium, silver, aluminum, zinc and titanium and a, b, c, d, e, f and g represent the atomic ratio of the elements where,a is 10,b is a number of 3 or less than 3 excluding 0,c is a number of 0.5 to 6,d is a number of 3 or less than 3 excluding 0,e is a number of 3 or less than 3 excluding 0,f is a number of 0 to 3,g is a number determined depending on the valency and atomic ratio of other elements.There is also provided a process for producing methacrylic acid by oxidizing methacrolein with molecular oxygen or molecular oxygen-containing gas in the presence of the catalyst defined above.
Type:
Grant
Filed:
November 28, 1983
Date of Patent:
July 23, 1985
Assignee:
Nippon Kayaku Kabushiki Kaisha
Inventors:
Mutsumi Matsumoto, Hideki Sugi
Patent number: 4467113
Abstract: A catalyst having heteropoly-acid structure and the general formula:Mo.sub.a V.sub.b P.sub.c Cu.sub.d As.sub.e X.sub.f O.sub.gwherein,X represents one or more elements selected from the group consisting of tin, lead, cerium, cobalt, iron, zirconium, thorium, tungsten, germanium, nickel, rhenium, bismuth, antimony, chromium, boron, magnesium, silver, aluminum, zinc and titanium and a, b, c, d, e, f and g represent the atomic ratio of the elements where,a is 10,b is a number of 3 or less than 3 excluding 0,c is a number of 0.5 to 6,d is a number of 3 or less than 3 excluding 0,e is a number of 3 or less than 3 excluding 0,f is a number of 0 to 3,g is a number determined depending on the valency and atomic ratio of other elements.There is also provided a process for producing methacrylic acid by oxidizing methacrolein with molecular oxygen or molecular oxygen-containing gas in the vapor phase in the presence of the catalyst defined above.
Type:
Grant
Filed:
November 19, 1979
Date of Patent:
August 21, 1984
Assignee:
Nippon Kayaku Kabushiki Kaisha
Inventors:
Mutsumi Matsumoto, Hideki Sugi