Abstract: Aqueous black liquor is gasified in a molten salt by spraying the black liquor into an enclosed zone above the surface of a turbulent molten salt pool. The black liquor is dried by means of hot gases rising from the surface of the pool and the resulting solid particles falling into the turbulent molten salt pool are dispersed and converted into a combustible gas and a reduced melt in which sulfide comprises at least about 95% of the total sulfur present. In a preferred embodiment the product gas is purified, burned and utilized in a gas turbine.

Abstract: A pyrochemical process is utilized to recover 99% of the remaining transuranium materials from plutonium-uranium extraction waste. One step of the overall pyrochemical process involves the electrochemical separation of the waste components. A solid anode and a solid cathode are used in this electrochemical separation step to electrorefine in single or multiple steps. The solid anode and solid cathode are selected from certain preferred anodic and cathodic materials. Where multiple electrorefining steps are used to obtain more complete electroseparation, this is achieved by employing in the multiple electrorefining steps both a solid anode, suitably graphite, and a molten metal anode containing a mixture of the actinide and rare earth elements. This results in greater separation than can be realized through electroseparation by use of either anode alone.

Abstract: A spray calcination process is provided for decomposing a metal nitrate solution to form fine grain multicomponent metal oxide powders of selected composition of particular utility as superconductor precursor powders. Such precursor powders are produced in bulk quantities as high purity, reproducible, intimately mixed powders for conversion to high temperature superconductors.A metal nitrate solution containing two or more metal constituents in a preselected ratio is sprayed as a finely atomized spray into a spray calcination zone where it is contacted with a hot gas stream for a residence time of less than 15 seconds at a high temperature between 200.degree. C. and 1100.degree. C. sufficient to vaporize the water of the nitrate solution and convert the metal nitrates to their corresponding oxides.

Abstract: The products of a molten salt combustion of hazardous wastes are converted into a cooled gas, which can be filtered to remove hazardous particulate material, and a dry flowable mixture of salts, which can be recycled for use in the molten salt combustion, by means of gas/liquid contact between the gaseous products of combustion of the hazardous waste and a solution produced by quenching the spent melt from such molten salt combustion.The process results in maximizing the proportion of useful materials recovered from the molten salt combustion and minimizing the volume of material which must be discarded. In a preferred embodiment a spray dryer treatment is used to achieve the desired gas/liquid contact.

Abstract: A process for the removal of sulfur oxides from two gas streams containing the same. One gas stream is introduced into a spray dryer zone and contacted with a finely dispersed spray of an aqueous medium containing an absorbent for sulfur oxides. The aqueous medium is introduced at a controlled rate so as to provide water to the gas in an amount to produce a cooled product gas having a temperature at least 7.degree. C. above its adiabatic saturation temperature and from about 125-300% of the stoichiometric amount of absorbent required to react with the sulfur oxides to be removed from the gas stream. The effluent from the spray dryer zone comprises a gas stream of reduced sulfur oxide content and contains entrained dry particulate reaction products including unreacted absorbent. This gas stream is then introduced into a particulate removal zone from which is withdrawn a gas stream substantially free of particles and having a reduced sulfur oxide content.

Abstract: A method and apparatus is disclosed for calibrating an ultrasonic inspection system having a plurality of transducers (12a, 12b, 12c) coupled by a common amplifier (16) to a distance-amplitude correction (D-AC) circuit comprised of a multiplying digital-to-analog converter (26') which receives, as a function of the transit time of an ultrasonic signal measured by a clock counter (34), a D-AC correction stored in a look-up table in a random access memory (24'). The D-AC correction function stored in the look-up table for each transducer is the inverse of a return signal response curve determined by measuring the peak amplitude of return signals from calibration holes at known depths in a test block (10) while in a calibrate mode, i.e., with a switch (SW) in a state to bypass the MDAC.

Abstract: An organic waste containing halogen is destroyed by treatment in a molten salt pool comprising a mixture of a basic alkaline earth metal compound with an alkaline earth metal halide. An oxygen-containing gas is introduced into the pool containing the waste to produce a gaseous combustion product and to cause the halogen present in the waste to react with the basic alkaline earth metal compound to produce additional alkaline earth metal halide.

Abstract: A carbonaceous material is subjected to a hydrotreating process in which it is desulfurized, deasphalted and demetallized by reaction with hydrogen in a molten medium in the presence of potassium hydroxide and water. The water is present in an amount sufficient to minimize the formation of gaseous hydrocarbonaceous products but insufficient to significantly reduce the effectiveness of potassium hydroxide as the hydrotreating agent. The process is characterized by producing a very small amount of gaseous hydrocarbonaceous products, desulfurizing the carbonaceous feed to the extent of at least about 80%, deasphalting the feed to the extent of at least about 60%, and demetallizing the feed to the extent of at least about 90%. In a preferred embodiment, spent potassium hydroxide is regenerated and recycled to the molten medium.

Abstract: A system for the remote visual inspection of an annulus defined between two vessels. A conduit member is disposed in the annulus having one end adjacent an upper portion of the vessel and the other end terminating adjacent an area to be inspected. The conduit member is provided with at least one aperture adjacent the area to be inspected and sized to receive a housing containing a camera and a light source. The housing and light source are introduced into the conduit member by a support means which includes at least a first hollow, flexible hose member having a first end connected to the housing and a second end terminating adjacent an upper portion of the vessels. The flexible hose member is made sufficiently rigid for introducing the housing through the conduit member by pressurization with a fluid. The system further includes a source of electrical power for the camera, a light, and display means for receiving signals from the camera as well as means for maintaining the camera at a desired temperature.

Abstract: A gas turbine in which hot gas is directed only over a portion or preselected number of the turbine blades and means are provided for directing a flow of a cooling gas over another portion or different preselected number of blades. In accordance with a preferred embodiment, the means for providing cooling gas comprises a compressor means located adjacent the turbine. Preferably the gas turbine comprises a plurality of alternating compressor means and turbine stages wherein the direction of flow of cooling gas is countercurrent to that of the hot gas flowing through the turbine stages.

Abstract: A system for the remote visual inspection of a structure including two vessels, one disposed within the otherand defining an annulus therebetween. A guide member is provided circumferentially about an upper periphery of the two vessels. Mounted on the guide member are two motor-driven, diametrically opposed trolleys which support a flexible track member which extends downwardly through the annulus from one of the trolleys and back up the other side of the annulus to the other trolley. At least one motor-driven carrige is mounted on the track member and carries a camera and light source. By appropriate positioning of the trolleys and the carriage, all the surfaces of the vessels defining the annulus are accessible for visual inspection by the camera. In accordance with a particular preferred embodiment, markers are placed at preselected points in the annulus on one of the vessels to permit verification of the location of the camera and carriage.

Abstract: A method for substantially reducing emissions of nitrogenous compounds such as NO.sub.x formed during fuel combustion. The fuel is combusted with an oxygen-containing gas in an amount from about 45 to 75% of the total stoichiometric amount of oxygen required for complete combustion of the fuel. The resulting mixture of fuel and combustion products, including NO.sub.x, is maintained at a temperature of at least 1800.degree. K. for a time sufficient to reduce the NO.sub.x content of the mixture to a desired level. Thereafter, combustion may be completed in one or more additional zones at a temperature within the range of about 1600.degree. to 2000.degree. K. Alternatively, the mixture of combustion products and fuel having a reduced NO.sub.x content may be used for other applications without further combustion. For certain embodiments of the invention, various particulates may be added to the combustion zone so as to enhance the rate at which the NO.sub.x is destroyed.

Abstract: The present invention provides a process for upgrading a hydrocarbon material in the presence of a molten salt in a manner which reduces the requirements for expensive ceramic materials to withstand the corrosive nature of the salt. A molten salt containing carbon is introduced into a heat generation zone which is located in a lower portion of an upwardly extending elongated reactor. Oxygen is introduced into the heat generation zone in an amount sufficient to react with substantially all of the carbon and to heat the molten salt to a desired temperature. The heated molten salt together with the gaseous reaction products of the carbon-oxygen reaction flows upwardly through the reactor to a hydrocarbon material reaction zone which is located within the reactor and above the heat generation zone. The hydrocarbon material to be treated is introduced into the reaction zone and into the molten salt where it produces gaseous reaction products and unreacted carbon entrained in the flowing molten salt.

Abstract: A carbonaceous material containing vanadium is reacted with an oxidizing gas in a molten salt pool containing an alkali metal carbonate. Vanadium values present in the carbonaceous material are converted to water-soluble vanadium compounds which are recovered from the melt and reacted with a strong acid to precipitate the vanadium values as insoluble vanadates. The vanadates are recovered as product or optionally further converted to vanadium pentoxide.

Abstract: A liquid metal-cooled nuclear reactor sealing system. The nuclear reactor includes a vessel sealed at its upper end by a closure head. The closure head comprises at least two components, one of which is rotatable; and the two components define an annulus therebetween. The sealing system includes at least a first and second inflatable seal disposed in series in an upper portion of the annulus. The system further includes a dip seal extending into a body of insulation located adjacent a bottom portion of the closure head. The dip seal comprises a trough formed by a lower portion of one of the components, and a seal blade pendently supported from the other component and extending downwardly into the trough. A body of liquid metal is contained in the trough which submerges a portion of the seal blade.

Abstract: Sulfur dioxide is converted to elemental surfur by reduction with a carbonaceous material in a reaction zone containing a molten salt. Heat is provided by reacting a portion of the carbonaceous material with oxygen. In a preferred embodiment alkali metal sulfates present in the molten salt are reduced to alkali metal sulfides.

Abstract: A thermal receiver assembly comprising a base member and a support structure affixed to said base member and extending vertically therefrom. The thermal receiver assembly further includes at least one thermal heat collecting assembly which is supported by the base member. The heat collecting assembly comprises a plurality of vertically extending, parallel, spaced-apart conduit members having inlet and outlet ends. The inlet ends terminate in an inlet manifold for receiving a coolant, and the outlet ends terminate in an outlet manifold for removal of heated coolant. The heat collecting assembly further includes a plurality of substantially horizontally extending and vertically flexible attachment members having an end affixed to the support structure and another end affixed to individual conduit members to permit vertical movement of individual conduit members while restraining said conduit members from any substantial horizontal movement.

Abstract: A process for treating a metal recovery byproduct which contains solid ash constituents entrained in a melt comprising a major amount of a molten salt and a minor amount of molten metal in which the melt is filtered through a high-temperature filter apparatus containing a cylindrical rotating filter element to separately and continuously recover a filter cake containing the solid ash constituents and a molten filtrate containing the molten salt and molten metal. This molten filtrate may be directly recycled to the metal recovery process. The filter cake may be treated in an aqueous process to recover the salt therefrom for recycle to the metal recovery process. The invention is particularly applicable to the recovery of aluminum from its dross while removing ecologically damaging materials present in the ash.

Abstract: A method and an optical sensing apparatus (1) are disclosed for measuring the polarization properties of light being scattered in the sky to obtain an accurate indication of visibility. The intensities (I.sub.1 and I.sub.2) of two linearly polarized components of the daylight are measured, so that a polarization ratio (P) can be calculated to provide a visibility index by which visual quality and visual range can be determined. The present method and apparatus may be extended to determine plume blight by comparing the polarization properties of light scattered by the plume with the polarization properties of the background sky, whereby theoretical visibility models may be validated. In an alternate embodiment, another apparatus (30) may be utilized with a sensing system (46) that employs polarization modulation techniques, so that the polarization properties of the entire sky can be measured in the ultraviolet and infrared regions of the electromagnetic spectrum.

Abstract: A thermal energy storage system and method for storing substantial quantities of heat for extended periods of time. The system includes a heat collecting fluid which is in a heat-exchange relationship with a source of heat or thermal energy, a housing containing a large volume of particulate material such as rocks for the storage of thermal energy, a heat transfer gas in a heat-exchange relationship with the rocks and means for causing the heat collecting fluid and the heat transfer gas to flow in counter-current, indirect heat-exchange relationship with one another, the means further includes provisions for reversing the direction of flow of the heat collecting fluid and gas for the introduction and removal of heat from a portion of the body of rock.