Abstract: A method and apparatus for monitoring the concentration of a component of a gas stream. The gas stream to be monitored is heated to a desired temperature and passed through an insulated gas passageway of a conduit member. The heated gas passes sequentially through a perforate metal shield and a body of a particulate catalyst. The temperature of the heated gas entering and leaving the conduit member is monitored and any increase in temperature is correlatable with the component concentration in the gas stream. The method and apparatus are particularly suitable for monitoring the concentration of hydrogen or oxygen in a gas stream.

Abstract: Disclosure is made of an apparatus for reacting carbonaceous material with heated hydrogen to form hydrocarbon gases and liquids suitable for conversion to fuels wherein the reaction involves injection of carbonaceous material such as pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at near ambient temperature with a separate source of heated hydrogen. The hydrogen is heated in a coil having an increasing inside diameter. The heated hydrogen and entrained coal are injected through a rocket engine type injector device. The coal particles are reacted with hydrogen in a reaction chamber downstream of the injector. The products of reaction are rapidly quenched as they exit the reaction chamber and are subsequently collected.

Abstract: A method of testing fibrous elements for their ability to effectively coalesce and separate water from an impure petroleum compound selected from the group consisting of crude oil and distillate fractions thereof. The method comprises introducing a reproducible emulsion consisting essentially of water and a substantially pure organic solvent into contact with a fibrous, coalescer element contained in a test zone. Separate streams of coalesced water and organic solvent are withdrawn from the zone. The predominant stream is passed between a source of light and a light-measuring means. The intensity of the light received by the light-measuring means is indicative of, and used as, the criterion for determining the acceptability of the coalescer element.

Abstract: A process for the recovery of copper or lead from a sulfide ore concentrate containing the same. The ore concentrate, a carbonaceous material, an alkali metal carbonate and gaseous oxygen are introduced into a reaction zone to form a reaction mixture. The amount of carbonaceous material introduced is sufficient to reduce all of the copper or lead constituent of the sulfide ore to its elemental state in a single stage. A sufficient excess of carbonaceous material is provided to react with the oxygen and generate heat in situ to maintain the reaction zone at a temperature of from about 600.degree. to 1350.degree. C. thereby causing reduction of the metal sulfide to substantially pure copper or lead for recovery. The sulfur constituents of the ore react with the alkali metal carbonate to form sulfides. The other metal constituents of the ore are retained in the molten reaction mixture.

Abstract: A method of treating an aqueous alkali metal sulfide-containing liquor to remove the sulfur values therefrom. Broadly, the method comprises introducing an alkaline liquor containing an alkali metal sulfide into a neutralization zone where it is intimately contacted and reacted with a sufficient amount of a gas containing a major amount of H.sub.2 S and a minor amount of CO.sub.2 to produce a product liquor of reduced alkalinity consisting essentially of a slurry of alkali metal bicarbonate and alkali metal bisulfide. The product liquor is withdrawn from the neutralization zone and introduced into a carbonation zone where it is contacted with a sufficient amount of a CO.sub.2 -containing gas to produce a product stream comprising a slurry of alkali metal bicarbonate crystals substantially free of alkali metal bisulfide and an H.sub.2 S-rich product gas containing a minor amount of CO.sub.2. The H.sub.

Abstract: A method of assembling a lithium alloy/molten salt/metal chalocogenide, high-energy density electrochemical device. Broadly, the method comprises providing a negative electrode structure in intimate contact with an electrolyte, which is conductive at elevated temperatures. There also is provided in contact with the electrolyte a positive electrode structure which includes a current-collecting substrate containing a sulfur and oxygen compound of at least one alkali metal in intimate admixture with a particulate metal. An electric current is passed from one electrode to the other to cause such device to be in a desired state of elecrochemical charge, whereby when said device is in a charged state a negative electrode active material comprises an alkali metal alloy and the positive electrode active material comprises a mixture of oxides and sulfides of the particulate metal.

Abstract: An organic waste containing at least one element selected from the group consisting of strontium, cesium, iodine and ruthenium is treated to achieve a substantial reduction in the volume of the waste and provide for fixation of the selected element in an inert salt. The method of treatment comprises introducing the organic waste and a source of oxygen into a molten salt bath maintained at an elevated temperature to produce solid and gaseous reaction products. The gaseous reaction products comprise carbon dioxide and water vapor, and the solid reaction products comprise the inorganic ash constituents of the organic waste and the selected element which is retained in the molten salt. The molten salt bath comprises one or more alkali metal carbonates, and may optionally include from 1 to about 25 wt.% of an alkali metal sulfate.

Abstract: An electrochemical device for sensing fluid components, particularly gases, comprises a composition with which the component reacts to liberate elemental chlorine, bromine, fluorine or iodine. The chlorine, bromine, fluorine or iodine passes through a particulate layer of vitreous carbon and activates the positive electrode of a solid ionic electrolyte battery of the type: halogen/solid ionic electrolyte/metal electrode, whereby a voltage is generated across a measuring device, the voltage being a known measure of the concentration of the fluid component.

Abstract: A method for forming an improved lithium electrode structure which comprises an alloy of lithium, silicon, and boron in specified proportions and a supporting current-collecting matrix in intimate contact with said alloy. The lithium formed by the method of the present invention is utilized as the negative electrode in a rechargeable electrochemical cell.

Abstract: The production of hydrogen by reacting an ash containing material with water and at least one halogen selected from the group consisting of chlorine, bromine and iodine to form reaction products including carbon dioxide and a corresponding hydrogen halide. The hydrogen halide is decomposed to separately release the hydrogen and the halogen. The halogen is recovered for reaction with additional carbonaceous materials and water, and the hydrogen is recovered as a salable product. In a preferred embodiment the carbonaceous material, water and halogen are reacted at an elevated temperature. In accordance with another embodiment, a continuous method for the production of hydrogen is provided wherein the carbonaceous material, water and at least one selected halogen are reacted in one zone, and the hydrogen halide produced from the reaction is decomposed in a second zone, preferably by electrolytic decomposition, to release the hydrogen for recovery and the halogen for recycle to the first zone.

Abstract: Hydrocarbonaceous materials such as petroleum residuums, coal, lignite or the like are introduced into a molten salt bath maintained in a reaction zone at elevated temperature and pressure. Hydrogen also is introduced into the reaction zone in an amount sufficient to provide a pressure in the reaction zone within the range of from about 30 to 400 atmospheres. The hydrocarbonaceous material is reacted for a time sufficient to produce cracked products including a major amount of liquid and a minor amount of gaseous and solid products of enriched hydrogen content. The molten salt bath comprises at least one alkali metal hydroxide which preferably is sodium hydroxide. Substantially all of the sulfur and ash constituents of the hydrocarbonaceous material are retained in the molten salt. When the hydrocarbonaceous material is a normally solid material such as coal, it advantageously is crushed and slurried in an organic hydrogen donor solvent prior to its introduction into the molten salt bath.

Abstract: A method of removing and preferably recovering sulfur values from an alkali metal sulfide and carbonate mixture comprising the steps of (1) introducing the mixture in an aqueous medium into a first carbonation zone and reacting the mixture with a gas containing a major amount of CO.sub.2 and a minor amount of H.sub.2 S; (2) introducing the resultant product from step 1 into a stripping zone maintained at subatmospheric pressure, and contacting this product with steam to produce a gaseous mixture, comprising H.sub.2 S and water vapor, and a liquor of reduced sulfide content; (3) introducing the liquor of reduced sulfide content into a second carbonation zone, and reacting the liquor with substantially pure gaseous CO.sub.2 in an amount sufficient to precipitate bicarbonate crystals and produce an offgas containing CO.sub.2 and H.sub.

Abstract: A nuclear reactor having an inherently safe automatic shutdown capability comprising a pressure vessel, a core located within the vessel and containing a sufficient amount of fissionable material to establish and sustain a chain-type fission reaction, and a plurality of elongated conduits disposed in a regular arrangement within the vessel. Each of the conduits defines a fluid flow path and comprises a first section located within and extending through the core, and a second section located exteriorly of the core and positioned above the first section. Each of the conduits contains a plurality of substantially spherical bodies in a sufficient quantity to substantially fill the first section of each of the conduits. The conduits are provided with a first fluid connection to a lower part of the first section and a second fluid connection to an upper part of the second section for the passage of a pressurized fluid therethrough while maintaining the reactor in operation.

Abstract: An improved lithium electrode structure comprises an alloy of lithium, silicon, and boron in specified proportions and a supporting current-collecting matrix in intimate contact with said alloy. The lithium electrode of the present invention is utilized as the negative electrode in a rechargeable electrochemical cell.

Abstract: An improved lithium electrode structure comprises an alloy of lithium, silicon, and iron in specified proportions and a supporting current-collecting matrix in intimate contact with said alloy. The lithium electrode of the present invention is utilized as the negative electrode in a rechargeable electrochemical cell.

Abstract: An apparatus and method for automatically monitoring dynamic signals, such as from vibration sensors, in an operating industrial or other plant to identify abnormal events, draw conclusions as to their severity, and indicate action to be taken, utilizing a computer to control the scanning of one or two sensor channels at a time through a matrix of analog switches, and to process one or two channel signals through a signal processor for power spectral density (PSD) analysis (two channel signals for cross PSD analysis). The computer compares spectra with predetermined sets of frequency dependent limits and indicates the abnormal condition of apparatus in the plant associated with the spectra as a function of which set of limits is exceeded. The computer also indicates from a stored table the action to be taken for the abnormal condition found.

Abstract: A system for the cyclic storage and recovery of thermal energy utilizing a particulate bed of a decomposable heat storage material selected from the group consisting of the hydroxides of magnesium, calcium, and barium. The bed of heat storage material is confined within a container adjacent a water-permeable wall of the container. Thermal energy of chemical decomposition is stored by heating the bed of selected hydroxide to a temperature within the range of from 300.degree. C to 900.degree. C and above the decomposition temperature of the selected hydroxide for a time sufficient to decompose at least a part of the selected hydroxide to form the corresponding oxide and water vapor. The water vapor is withdrawn by passing a carrier gas into contact with the water-permeable wall of the container to absorb the water vapor permeating therethrough.

Abstract: A method for the detection and quantitative analysis of certain selected constituent parts of a gas stream. A gas stream containing the selected constituent is introduced into a reaction zone and contacted with metastable mercury (6.sup.3 P.sub.o) atoms to form an excited complex of the selected constituent and the metastable mercury atom, which decomposes emitting light. The intensity of the light emission is measured and directly correlatable to the concentration of the constituent in the gas stream. The method of the present invention is particularly applicable to the measurement of ambient air containing selected constituents in an amount or concentration in the 1-100 ppb range. The method can be used to measure trace amounts of numerous selected constituents contained in a gaseous stream including such constituents as ammonia, hydrazine, water vapor, alcohols and various amines.

Abstract: An improved lithium electrode structure comprises an alloy of lithium, silicon, and iron in specified proportions and a supporting current-collecting matrix in intimate contact with said alloy. The lithium electrode of the present invention is utilized as the negative electrode in a rechargeable electrochemical cell.

Abstract: A gaseous medium containing aerosols is drawn through a quartz sampling tube and a filter located therein, with the aerosols becoming entrapped on the filter. The filter is located at the geometric center of a microwave cavity, and the principal resonance of the latter is tracked with the aid of an adaptive electronic circuit. The time rate of change of the resonant frequency is a function of the rate of deposition of particulate matter on the filter, and principally of the liquid water content of those aerosols. Water in the vapor phase passes through the filter and does not affect the measurement; solid particulate does affect the frequency shift but in a second order manner and is readily compensated for after measurement of total aerosol mass deposited and the determination of the dielectric constant of the solid species therein.