Abstract: A method of and apparatus for removing particulate contaminants from a gaseous stream. Broadly, the apparatus comprises a housing containing a substantially vertical granular material retention member having upstream and downstream faces, a substantially vertical microporous gas filter element, said member and element being spaced apart to provide a zone for the passage of granular material therethrough. The housing further comprises a gas inlet means, a gas outlet means and means for moving a body of granular material through said zone. In operation, a gaseous stream containing particulate contaminants passes through the gas inlet means and upstream face of the granular material retention member, passing through said member, said body of granular material, the microporous gas filter element and then out the gas outlet means. The particulates carried in the gaseous stream pass into the granular material and are retained in the body of granular material and upon the upstream face of the gas filter element.

Abstract: A method of treating a nuclear reactor fuel pellet which has been irradiated and is at least partially depleted of its initial fissile material content to substantially reduce the amount of fuel which would have to be reprocessed before it could be reused. The pellet is pulverized to a median particle size of less than about 300 microns and thereafter is separated into two fractions by size. In accordance with the present invention, it has been found that one of said fractions will contain a significantly greater proportion of the fissile content of the pellet than the other of said fractions. The fissile-rich fraction is suitable for reforming into pellets for use in a nuclear reactor with little or no further enrichment required. The method of the present invention is applicable to the metallic, oxide, and carboxide forms of nuclear reactor fuels such as uranium and thorium, which have been in service in a light water reactor or a fast breeder reactor.

Abstract: A system for plugging holes in vessels which comprises the combination of a storage and delivery system for a foam-forming material, and a hole-plugging assembly. The hole-plugging assembly includes a flexible nonelastic bag member which is inserted in a folded position into the hole to be plugged and properly positioned with an associated locating means. Thereafter, a unitary foamable material is injected into the bag member to expand it and seal the hole. The locating means further assists in maintaining the inflated bag member in proper orientation and sealing engagement while the foam is curing.

Abstract: An apparatus for reacting carbonaceous material such as pulverized coal with heated hydrogen to form hydrocarbon gases and liquids suitable for conversion to fuels wherein the reaction involves injection of pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at ambient temperature with a separate source of heated hydrogen. The heated hydrogen and entrained coal are injected through a rocket engine type injector device. The coal particles are reacted with hydrogen in a reaction chamber downstream of the injector. The products of reaction are rapidly quenched as they exit the reacting chamber and are subsequently collected.

Abstract: A self-actuating, self-locking flow cutoff valve particularly suited for use in a nuclear reactor of the type which utilizes a plurality of fluid support neutron absorber elements to provide for the safe shutdown of the reactor. The valve comprises a substantially vertical elongated housing and an aperture plate located in the housing for the flow of fluid therethrough, a substantially vertical elongated nozzle member located in the housing and affixed to the housing with an opening in the bottom for receiving fluid and apertures adjacent a top end for discharging fluid. The nozzle further includes two sealing means, one located above and the other below the apertures.

Abstract: A method of decladding an assembly comprising an element selected from the group consisting of uranium, thorium and mixtures thereof, clad in stainless steel, zirconium, or an alloy consisting essentially of zirconium and containing minor amounts of nickel, chromium, tin, iron or combinations thereof. In a first step the cladding is scored or perforated to expose the selected element. Thereafter, the assembly is exposed to a hydrogen atmosphere at an elevated temperature for a time sufficient for the hydrogen and selected element to react and form a hydride. The temperature then is further increased to decompose the hydride back to gaseous hydrogen and the selected element. The hydriding-dehydriding preferably are repeated at least two additional times to ensure complete release of any volatile gases present.

Abstract: Hydrogenation reaction apparatus comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1100.degree. to 1900.degree. C., while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products.

Abstract: A gas-shielded, metal-arc, pulse welding process which comprises establishing an arc with a consumable metal electrode in a gas-shielded environment. A direct current in the range of from about 15 to 80 amps is applied to the electrode and pulsated at a frequency of from about 5000 to 25,000 pulses per second to a first maximum amplitude of from 100 to 125% of the minimum current required to produce a spray transfer of metal from the electrode. The pulsating current applied to the electrode is cyclically increased at a frequency of from about 90 to 400 cycles per second to a second maximum amplitude of from about 150 to 600% of the minimum current required to produce a spray transfer of metal from the electrode and is maintained at the second maximum amplitude for a time within the range of from 5 to 50% of each cycle. The process is particularly applicable to automatic welding processes wherein the weld must be accomplished out-of-position.

Abstract: A method of producing high yields of olefins from hydrocarbon feedstocks which is particularly applicable to heavy hydrocarbons. In accordance with the present method, a stream of gaseous oxygen is introduced into a first reaction zone and a cocurrent flow of hydrogen is introduced about the periphery of the gaseous oxygen stream, the hydrogen being introduced at a temperature at which it will spontaneously react with the oxygen. The hydrogen and oxygen are introduced in amounts to provide a gas stream of reaction products having an average temperature within the range of from about 1,000.degree. to 2,000.degree. C. and which comprises a major amount of hydrogen and a minor amount of water vapor. The gas stream so produced is introduced into a second reaction zone and impinged upon a stream of hydrocarbon which is heated to a temperature in excess of its melting point but below the temperature at which any substantial coke or tar forms.

Abstract: A process for the decomposition of polychlorinated biphenyls (PCB's) with negligible environmental pollution. The process comprises feeding the PCB and a source of oxygen to a molten salt comprising an alkali metal carbonate and preferably also an alkali metal sulfate to decompose the PCB by pyrolysis and oxidation. Some of the resulting decomposition products react with and are retained in the molten salt; the remaining gaseous products pass through the melt and are safely exhaustable to the atmosphere or, alternatively, the PCB is introduced into a first zone for partial pyrolysis and oxidation and then into a second reaction zone for further oxidation of any remaining combustible gases.

Abstract: A method and composition for detecting the presence of an alkali metal on the surface of a body such as a metal plate, tank, pipe or the like is provided. The method comprises contacting the surface with a thin film of a liquid composition comprising a light-colored pigment, an acid-base indicator, and a nonionic wetting agent dispersed in a liquid carrier comprising a minor amount of water and a major amount of an organic solvent selected from the group consisting of the lower aliphatic alcohols, ketones and ethers. Any alkali metal present on the surface in elemental form or as an alkali metal hydroxide or alkali metal carbonate will react with the acid-base indicator to produce a contrasting color change in the thin film, which is readily discernible by visual observation or automatic techniques.

Abstract: Disclosure is made of a method and apparatus for reacting carbonaceous material such as pulverized coal with heated hydrogen to form hydrocarbon gases and liquids suitable for conversion to fuels wherein the reaction involves injection of pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at ambient temperature with a separate source of heated hydrogen. The heated hydrogen and entrained coal are injected through a rocket engine type injector device. The coal particles are reacted with hydrogen in a reaction chamber downstream of the injector. The products of reaction are rapidly quenched as they exit the reaction chamber and are subsequently collected.

Abstract: A new composition of matter comprising europium carboxide and method of preparing the same and other lanthanide carboxides, wherein a particulate mass of the lanthanide and carbon monoxide gas in an amount sufficient to form a lanthanide carboxide of the formula M.sub.2 CO, wherein M is at least one element having an atomic number of from 57 thru 71, inclusive, are introduced into a reaction zone. The reaction zone is maintained at a temperature of from about 400.degree. to 1500.degree. C. for a time sufficient to form the desired lanthanide carboxide.

Abstract: The rechargeable electrical energy storage device including spaced-apart negative electrode and positive electrode structures immersed in an electrolyte which is molten at the operating temperature of the device wherein the positive electrode structure comprises a housing for containing a body of electropositive active material, said housing having at least one open face, an electrolyte permeable member affixed to the housing and covering said open face for retaining said active material in said housing and said housing and electrolyte permeable member comprising material selected from the group consisting of steel, nickel, copper and alloys thereof having at least an 8 .mu.m thick electroless nickel coating thereon. In accordance with the present invention it has been found that such an electroless nickel coating permits the use of relatively inexpensive conductive materials such as steel, nickel, copper and alloys thereof and provides the corrosion resistance required in the molten electrolyte.

Abstract: A thermal energy storage system and method for storing substantial quantities of heat for extended periods of time. The system includes a heat collecting liquid which is in a heat-exchange relationship with a source of heat or thermal energy, a housing containing a large volume of particulate material such as rocks for the storage of thermal energy, a heat transfer gas in a heat-exchange relationship with the rocks and means for causing the heat collecting liquid and the heat transfer gas to flow in counter-current, indirect heat-exchange relationship with one another, the means further includes provisions for reversing the direction of flow of the liquid and gas for the introduction and removal of heat from a portion of the body of rock.

Abstract: A method for reacting pulverized coal with heated hydrogen-rich gas to form hydrocarbon liquids suitable for conversion to fuels wherein the reaction involves injection of pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at ambient temperature with a separate source of heated hydrogen. In accordance with the present invention, the hydrogen is heated by reacting a small portion of the hydrogen-rich gas with oxygen in a first reaction zone to form a gas stream having a temperature in excess of about 1000.degree. C. and comprising a major amount of hydrogen and a minor amount of water vapor. The coal particles then are reacted with the hydrogen in a second reaction zone downstream of the first reaction zone. The products of reaction may be rapidly quenched as they exit the second reaction zone and are subsequently collected.

Abstract: A process for removing sulfur oxides from a hot gas by sequential absorption of the sulfur oxides in two zones. In each zone the hot gas is contacted with an aqueous scrubbing medium which may be a solution or slurry containing an absorbent for the sulfur oxides. The absorbent is selected from the group consisting of alkali metal carbonates, bicarbonates and mixtures thereof. The preferred absorbent is sodium carbonate. The aqueous solution is introduced into the first zone in an amount to produce (1) a dry powder reaction product containing alkali metal sulfites, and sulfates, substantially free of unreacted absorbent and (2) a substantially water-unsaturated gaseous reaction product of reduced sulfur oxide content.

Abstract: A method of removing particulates and sulfur oxides from a hot gas by controllably contacting the hot gas in a first spray-dryer zone with a selected chemically reactive absorbent for the sulfur oxides and then sequentially contacting the hot gas with the absorbent in a second fabric filter zone. The preferred absorbents are calcium oxide, calcium hydroxide, sodium carbonate, sodium bicarbonate and sodium hydroxide. The selected absorbent dissolved or dispersed in an aqueous medium is controllably introduced into the spray dryer, together with the hot gas, in an amount and at a rate to react in the spray dryer with only a portion of the sulfur oxides in the hot gas to produce a dry particulate reaction product consisting of calcium or sodium sulfites and sulfates, together with sufficient unreacted absorbent of enhanced reactivity for subsequent reaction in the second zone with the remaining sulfur oxides, all being entrained in a substantially water-unsaturated gas of reduced sulfur oxide content.

Abstract: A method for the dense-phase flow of particulate solids utilizes a pressurized feeder and flow splitter which transports and equally divides particulate material at essentially the bulk density with only the gas contained in interstices of the solid particles being used to transport the particles. The feeder comprises a vessel which is pressurized, a gas source for pressurization and an outlet line with a full opening valve located immediately adjacent to the feeder. The loaded vessel containing particulate matter is pressurized, followed by opening the valve adjacent the feeder, the valve and relatively empty downstream line when flow is initiated being the key to successful operation of the dense-phase feeder. The downstream flow divider evenly distributes the dense-phase material to, for example, a multiplicity of feed passages in a multi-passage injector.

Abstract: An apparatus for and method of collecting and storing oxide impurities contained in high-temperature liquid alkali metal. A method and apparatus are provided for nucleating and precipitating oxide impurities by cooling, wherein the nucleation and precipitation are enhanced by causing a substantial increase in pressure drop and corresponding change in the velocity head of the alkali metal. Thereafter the liquid alkali metal is introduced into a quiescent zone wherein the liquid velocity is maintained below a specific maximum whereby it is possible to obtain high oxide removal efficiencies without the necessity of a mesh or filter.