Abstract: A method is provided for producing a selected metal nitride utilizing a salt bath. The selected metal is introduced into the salt bath in the presence of gaseous nitrogen and at least a certain amount of a halide of the selected metal. The salt bath is maintained at a temperature above its melting point for time sufficient to form a precipitate of the desired amount of a nitride of the selected metal. In accordance with a preferred embodment, the pressure is thereafter reduced to less than atmospheric and the temperature increased above the boiling point of the salt for a time sufficient to volatilize the molten salt which is removed to leave a precipitate of the selected metal nitride. The method is particularly applicable to the production of the mononitrides of uranium, plutonium, thorium, and mixtures thereof.

Abstract: A process for the production of a synthesis gas, capable of being upgraded to a high BTU pipeline gas, by the partial oxidation and substantially complete gasification of a carbonaceous material under CO-promoting conditions wherein the carbonaceous material, oxygen, and recycled carbon dioxide from the process are introduced into a molten salt containing an alkali metal carbonate and a minor portion of an alkali metal sulfide, the system being operated at a selected temperature and pressure between 1400.degree. and 2000.degree. F and between 1 and 100 atmospheres. The molar ratio of carbon dioxide to oxygen employed is controlled at from about 0.6:1 to about 1.2:1 to control the CO production and also to maintain the molten salt at a desired operating temperature. Sulfur and ash introduced with the fuel are retained in the molten salt.

Abstract: A compact modular electrical energy storage device comprising one or more cell modules in which certain components of the device are maintained in a substantially fixed position in the device by utilizing a resilient porous body of compressed carbon fibers to resiliently urge the components into physical contact with one another. The invention further provides means for maintaining the cell components in such fixed position during cell operation at elevated temperatures for extended periods of time.A preferred compact cell module construction particularly suitable for use in a high-temperature, high-energy-density lithium battery includes two positive electrode assemblies positoned in opposing relationship by a U-shaped spacer member maintained in contact with a separator member of each positive electrode assembly by a resilient porous body of compressed graphite fibers, a unitary double-faced negative electrode assembly being positioned between the two positive electrode assemblies.

Abstract: A rechargeable electric energy storage device including a negative electrode, a positive electrode and an electrolyte, at least one electrode including a plurality of wall members, forming a plurality of cells having a certain open cross-sectional area, a substantially planar electrolyte-permeable member affixed to the wall members and covering the open end of the cells, and a body of electrochemically active material in said cells; the active material being a solid at the operating temperature of the device and retained in the cells of the wall members by the electrolyte-permeable member.

Abstract: An apparatus for thermally recombining gases comprising a first (heating) chamber in which the gases to be combined are initially heated to a temperature above the threshold for thermal combination or recombination, a second (reaction) chamber is formed to provide for mixing of previously reacted gases with the gases delivered from the first chamber, and a temperature control means responsive to the temperature in the second chamber for controlling the temperature to which the gases are initially heated in the first chamber.

Abstract: A compact modular electrical energy storage device comprising one or more cell modules in which certain components of the device are maintained in a substantially fixed position in the device by utilizing a resilient porous body of compressed carbon fibers to resiliently urge the components into physical contact with one another. The invention further provides means for maintaining the cell components in such fixed position during cell operation at elevated temperatures for extended periods of time.A preferred compact cell module construction particularly suitable for use in a high-temperature, high-energy-density lithium battery includes two positive electrode assemblies positioned in opposing relationship by a U-shaped spacer member maintained in contact with a separator member of each positive electrode assembly by a resilient porous body of compressed graphite fibers, a unitary double-faced negative electrode assembly being positioned between the two positive electrode assemblies.

Abstract: Small amounts of NO.sub.2 and O.sub.3 in air are determined by utilizing the reactions of these gases with solid alkali metal halides to produce halogen, and the reaction of NO.sub.2 with various salts such as PbI.sub.2 to produce NO; halogens produced from the reaction may be measured by the use of an electrolytic cell, the output of which is dependent on the halogen concentration of the gas contacting one electrode thereof, while the NO concentration may be determined by the chemiluminescence technique.

Abstract: A bonded electrical contact and method for a thermoelectric element. A thin layer of a ductile diffusion barrier, which is non-poisonous to thermoelectric materials, such as iron, tungsten, molybdenum, or niobium, is disposed between the thermoelectric material and a contacting shoe, such as stainless steel, which has poisonous alloy constituents. The thermal expansion coefficient of the diffusion barrier, which does not match that of the thermoelectric material, is overridden by that of the shoe, whose coefficient does correspond with that of such high expansion thermoelectrics as the telluriden.

Abstract: An ultrasonic inspection system is disclosed having a skate remotely controlled from a main console for positioning an ultrasonic transducer. A transmission line is used to couple drive pulses from the main control console to the transducer. Each drive pulse is generated at the console by timing means for firing a first silicon-controlled rectifier (SCR) to discharge a precharged capacitor into the line, and for firing a second SCR to shunt discharge current from the capacitor to ground. The line is terminated at its input end by its characteristic impedance. The length of the line may be changed without requiring any change at the transducer or the pulse generating circuit, except that the size of the precharged capacitor may be varied to assure delivery of a pulse of desired amplitude to the transducer.

Abstract: Sulphur dioxide is reacted with silver nitrite at room temperature to release nitrogen dioxide in a known ratio and the nitrogen dioxide may, then, be measured as an indication of the presence and amount of sulphur dioxide.

Abstract: A cyclic method of storing and recovering thermal energy utilizing a particulate bed of a decomposable heat storage material selected from the group consisting of the hydroxides of magnesium, calcium, and barium. The bed of heat storage material is confined within a container adjacent a water-permeable wall of the container. Thermal energy of chemical decomposition is stored by heating the bed of selected hydroxide to a temperature within the range of from 300.degree. to 900.degree.C and above the decomposition temperature of the selected hydroxide for a time sufficient to decompose at least a part of the selected hydroxide to form the corresponding oxide and water vapor. The water vapor is withdrawn by passing a carrier gas into contact with the water-permeable wall of the container to absorb the water vapor permeating therethrough.

Abstract: Apparatus and method are provided for concurrently decreasing the cyanide and heavy metal content of an aqueous solution, such as a waste water.The apparatus comprises an electrochemical cell provided with separate cathode and anode compartments. Each of the compartments contains a bed of electrically conductive particles. The compartments are separated by an electronically nonconductive foraminous member.In accordance with the method, an aqueous solution containing cyanide ion and at least one heavy metal in soluble form is passed sequentially through the beds of electrically conductive particles contained in each of two compartments of an electrochemical cell. A direct electric current is passed between the two compartments making one compartment cathodic and the other anodic. The heavy metal is deposited upon the particles in the cathodic compartment and the cyanide is oxidized in the anodic compartment.

Abstract: An improved lithium electrode structure comprises an alloy of lithium and silicon in specified proportions and a supporting current-collecting matrix in intimate contact with said alloy. The lithium electrode of the present invention is utilized as the negative electrode in a rechargeable electrochemical cell.

Abstract: A method for chemically removing phosphates from waste waters by treating the phosphate-containing waste water with a trivalent rare earth salt, generally as a mixture of such salts, to form an insoluble rare earth phosphate precipitate, and then separating the precipitate from the waste water. The rare earth precipitant salt, such as lanthanum chloride or sulfate, may be regenerated by treating the rare earth phosphate precipitate with a strong or weak alkali as regenerant, preferably aqueous sodium hydroxide or sodium carbonate, to form a soluble alkali metal phosphate. The aqueous alkali regenerant may be recovered by treatment of the formed sodium phosphate with lime to precipitate the phosphate as a calcium phosphate complex salt.Where it is desired to precipitate phosphate but avoid regeneration of the rare earth precipitant salt, a combination treatment using aluminum-lanthanum or iron-lanthanum as precipitant salt is preferred.

Abstract: Apparatus and method are provided for concurrently decreasing the cyanide and heavy metal content of an aqueous solution, such as a waste water.The apparatus comprises an electrochemical cell provided with separate cathode and anode compartments. Each of the compartments contains a bed of electrically conductive particles. The compartments are separated by an electronically nonconductive foraminous member.In accordance with the method, an aqueous solution containing cyanide ion and at least one heavy metal in soluble form is passed sequentially through the beds of electrically conductive particles contained in each of two compartments of an electrochemical cell. A direct electric current is passed between the two compartments making one compartment cathodic and the other anodic. The heavy metal is deposited upon the particles in the cathodic compartment and the cyanide is oxidized in the anodic compartment.

Abstract: A sintered filter trap is adapted for insertion in a gas stream of sodium vapor to condense and deposit sodium thereon. The filter is heated and operated above the melting temperature of sodium, resulting in a more efficient means to remove sodium particulates from the effluent inert gas emanating from the surface of a liquid sodium pool. Preferably the filter leaves are precoated with a natrophobic coating such as tetracosane.

Abstract: A method of fabricating a group IVB metal hydride body having a hydrogen content of at least 55 atom percent and a high density, which comprises mixing together powders of said metal hydride having less than about 55 atom percent hydrogen with powders of said metal hydride having at least about 60 atom percent hydrogen, and then hot forming the resulting mixture to cause flow of ductile powders and thereby give a high density compact.

Abstract: A method is shown for removing sulfur dioxide from a hot flue gas by absorption of the sulfur dioxide in an aqueous solution or slurry containing no more than 40 wt.% of an alkali metal carbonate or bicarbonate, preferably sodium carbonate and/or sodium bicarbonate using a spray-dryer scrubber to produce a dry mixture of sodium sulfite, sodium sulfate, and sodium carbonate and/or bicarbonate. Such a mixture is directly suitable as a feed to a regeneration stage.It is particularly preferred to regenerate the absorbent and recover commercial sulfur values in a closed-cycle process by next treating the solid absorption product in a molten salt reduction step with a reducing agent, preferably a carbonaceous material, to reduce the sodium sulfite and sulfate to sodium sulfide. Concurrently, a source of oxygen is fed to the reducer to generate sufficient heat therein for the reduction step by a combustion reaction.