Patents Represented by Attorney Jack H. Hall
  • Patent number: 4530937
    Abstract: A method for the manufacture of polyisocyanurate foams which comprises blending a "B" side with an "A" side comprising an isocyanate. The "B" side comprises a diol, an amine/quaternary ammonium borate ester blend, a surfactant, a blowing agent, and a catalyst which is present in amounts up to about 20% of the total weight of the "B" side. The "B" side remains a homogeneous liquid for at least three days without the need for agitation and the foam formed by this method has a friability not exceeding 30%.
    Type: Grant
    Filed: March 21, 1984
    Date of Patent: July 23, 1985
    Assignee: Akzona Incorporated
    Inventor: Kenneth B. White
  • Patent number: 4522880
    Abstract: A laminate comprising an insoluble, intractable relatively thick layer of a polyimide bonded tightly onto a metallic substrate without the necessity for an intermediate adhesive bonding layer and a process for preparing such by directly extruding a polyamic acid polyimide-precursor onto said substrate and converting said polyamic acid to the polyimide in a single pass in at least two heating stages.
    Type: Grant
    Filed: September 21, 1983
    Date of Patent: June 11, 1985
    Assignee: Akzona Incorporated
    Inventors: Werner Klostermeier, Jeffery D. Lasher, Gerhard Meyer, Hans Zengel
  • Patent number: 4502415
    Abstract: Floor covering material for stables, in particular for tie-stall cowsheds, consisting of a top layer impermeable to moisture and a compressible central layer, the underside showing a honeycomb-like structure, having hump-like projections on the surfaces thereof and a fabric attached to the humps of the honeycomb structure is arranged on the back of the matting.
    Type: Grant
    Filed: January 14, 1983
    Date of Patent: March 5, 1985
    Assignee: Akzona Incorporated
    Inventors: Udo Schwarzkopff, Horst Fischer
  • Patent number: 4490281
    Abstract: There is disclosed an anticaking composition comprising a dispersion of an alkyl or cycloalkyl amine, either unneutralized or as a salt, in a liquid medium comprising a water-in-oil emulsion containing from about 5 to about 60 percent, by weight, of water.There is also disclosed a method of treating hygroscopic or water soluble material in particulate form comprising contacting said material with an anticaking composition which comprises a dispersion of an alkyl or cycloalkylamine in a liquid medium comprising a water-in-oil emulsion containing from about 5 to about 60 percent, by weight, of water, in an amount sufficient to reduce the tendency of said material to agglomerate.
    Type: Grant
    Filed: November 26, 1982
    Date of Patent: December 25, 1984
    Assignee: Akzona Incorporated
    Inventors: Alan D. James, Roy Senior
  • Patent number: 4490431
    Abstract: There is disclosed a substantially skinless microporous polypropylene membrane characterized by having(a) a bubble point of about 25 to about 50 psi;(b) a thickness of about 3 to about 7 mils;(c) a nitrogen flow rate of at least 0.5 liters per square centimeter-minute;(d) a burst strength of at least 10 psi; and(e) an S value of about 15, or less.There is also disclosed a method of preparing a microporous polypropylene membrane comprising heating a mixture of about 30 percent polypropylene and about 70 percent, N,N-bis(2-hydroxyethyl)tallowamine, by weight, to a temperature and for a time sufficient to form a homogeneous solution, casting or extruding said solution at a thickness of about 3 to about 7 mils, onto a chill roll maintained at a temperature of from about 50.degree. to about 80.degree. C.
    Type: Grant
    Filed: November 3, 1982
    Date of Patent: December 25, 1984
    Assignee: Akzona Incorporated
    Inventors: Gunter H. Vitzthum, Michael A. Davis
  • Patent number: 4488929
    Abstract: A composite material consisting of at least three layers joined by welds, wherein, in order to prevent the intrusion of cold, as well as to improve the hand, the points of fusion do not join all layers, but in each case only a part thereof. It is especially suitable for the manufacture of clothing and bedding. A new process and apparatus for its manufacture is also disclosed.
    Type: Grant
    Filed: July 20, 1983
    Date of Patent: December 18, 1984
    Assignee: Akzona Incorporated
    Inventor: Karl Ostertag
  • Patent number: 4488985
    Abstract: Novel phosphoramidates of the general formula: ##STR1## wherein R, R' and R" represent certain specified substituent groups, are useful as stabilizing agents for organic materials, such as natural and synthetic rubbers and lubricating oils. The combined use of these compounds with certain sulfur-containing compounds shows a surprising synergistic effect.
    Type: Grant
    Filed: July 21, 1983
    Date of Patent: December 18, 1984
    Assignee: Akzona Incorporated
    Inventors: Paul K. Battey, Peter Hope
  • Patent number: 4486603
    Abstract: A process is disclosed for selectively making trans-cyclohexane-1,4-diisocyanate, trans-cyclohexane-1,4-diamine, a trans-cyclohexane-1,4-diurethane, a trans-cyclohexane-1,4-diurea and trans-cyclohexane-1,4-disulphonyl urea by reacting ammonia with a mixture of cis and trans cyclohexane-1,4-dicarboxylic acid, a lower alkyl ester, a glycol ester, an oligomeric ester or a polyester to make a solid trans-dicarboxylic acid diamide in a first step. The diamide is chlorinated to form trans-cyclohexane-1,4-dicarboxylic acid-bis-N-chloramide.
    Type: Grant
    Filed: September 20, 1982
    Date of Patent: December 4, 1984
    Assignee: Akzona Incorporated
    Inventors: Hans Zengel, Manfred Bergfeld
  • Patent number: 4485048
    Abstract: Novel compounds having the general formula: ##STR1## are disclosed, wherein R.sub.1 is selected from the group including C.sub.5 -C.sub.22 alkyl or alkenyl; R.sub.3 and R.sub.5 are independently selected from the group including hydrogen or C.sub.1 -C.sub.12 alkyl or alkenyl; R.sub.4 is either --(CH.sub.2 CH.sub.2 O).sub.z H, or ##STR2## or C.sub.5 -C.sub.22 alkyl or alkenyl; x, y, and z are integers of 1 or more and whose sum is between 2 and 15; and X.sup..crclbar. is an anion, preferably bis-(ethylene)borate. These ethoxylated quaternary benzyl compounds are useful as fabric softeners.
    Type: Grant
    Filed: August 9, 1982
    Date of Patent: November 27, 1984
    Assignee: Akzona Incorporated
    Inventors: James M. Richmond, Keith D. Stanley
  • Patent number: 4479887
    Abstract: New polyether derivatives obtained by gradually adding at temperatures between 100.degree. and 200.degree. C. a long-chain 1,2-epoxide having a chain length of 10 to 32 carbon atoms to either (1) polyethylene glycol monoalkyl ether whose mean molecular weight is 400 to 2500 and whose alkyl group contains 1 to 3 carbon atoms; or to (2) a polyethylene glycol-polypropylene glycol monoalkyl ether whose mean molecular weight is 450 to 3100, whose recurring ethylene oxide units and propylene oxide units form a block each, the polypropylene glycol block having a mean molecular weight of not more than 600 and whose alkyl group forms the end of the polyethylene glycol block and contains 1 to 3 carbon atoms, using 0.1 to 1% by weight of alkali hydroxide related to the total amount of the starting substances.These polyether derivatives correspond to the general formula: ##STR1## wherein R.sub.1 represents an aliphatic hydrocarbon radical containing 1 to 3 carbon atoms;R.sub.
    Type: Grant
    Filed: February 28, 1983
    Date of Patent: October 30, 1984
    Assignee: Akzona Incorporated
    Inventor: Karl Seibert
  • Patent number: 4469575
    Abstract: The present invention relates to a photopolymerizable composition comprising a polymerizable, polyethylenically unsaturated compound, benzil and/or fluorenone, a specific biphenyl ketone such as para-phenyl benzophenone, and a reducing agent such as a tertiary amine. The present composition permits rapid and complete curing. Moreover, in the photopolymerization of compounds sensitive to air inhibition non-tacky surfaces are obtained. The effect observed is based on a synergism between the present photoinitiators. The advantages of the invention are most manifest in curing relatively thick layers of materials.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: September 4, 1984
    Assignee: Akzona
    Inventors: Tjerk van der Hauw, Hans Jaspers
  • Patent number: 4468526
    Abstract: A process for the preparation of thiuram disulfides substituted with aliphatic, cycloaliphatic, araliphatic, or aromatic hydrocarbon radicals, said process comprising reacting a suitably substituted secondary amine with carbon disulfide and in the presence of a tertiary amine or ammonia, oxygen or oxygen-containing gas, a solvent, and a metalliferous catalyst, at a temperature of between 0.degree. C. and 200.degree. C.
    Type: Grant
    Filed: February 16, 1982
    Date of Patent: August 28, 1984
    Assignee: Akzona Incorporated
    Inventors: Ludwig Eisenhuth, Hans G. Zengel, Manfred Bergfeld
  • Patent number: 4467595
    Abstract: This invention relates to melt extruded latent contractable elastic filaments which are formed by melt extruding certain segmented crosslinked thermoplastic polymers to form filaments, which filaments, when heat processed at elevated temperatures, significantly contract to yield an elastic filament. This invention also relates to the formation of composite covered yarn comprising said latent contractable melt extruded filaments. In addition, this invention relates to processes for forming articles from said latent contractable filaments or covered yarns comprising said contractable filaments and subsequently contracting said yarns to form an elastic article.
    Type: Grant
    Filed: September 14, 1983
    Date of Patent: August 28, 1984
    Assignee: Akzona Incorporated
    Inventor: Aloysius A. J. Kramers
  • Patent number: 4459424
    Abstract: A process for the preparation of thiuram disulfides substituted with aliphatic cycloaliphatic, araliphatic, or aromatic hydrocarbon radicals, said process comprising reacting a suitably substituted secondary amine having a pK.sub.a .gtoreq.8 with carbon disulfide in a solvent and in the presence of oxygen or oxygen-containing gas, a solvent, and a metalliferous catalyst, at a temperature of between 0.degree. C. and 200.degree. C.
    Type: Grant
    Filed: February 16, 1982
    Date of Patent: July 10, 1984
    Assignee: Akzona Incorporated
    Inventors: Ludwig Eisenhuth, Hans G. Zengel, Manfred Bergfeld
  • Patent number: 4457900
    Abstract: A finely divided silicic acid simultaneously suitable as a filtering auxiliary and as a beer stabilizing agent in the filtration of beer. The acid is particulate, and the particles are of an essentially spherical or spheroidal shape with SiO.sub.2 content of at least 95% and an Na.sub.2 O content of less than 0.25%.
    Type: Grant
    Filed: April 30, 1982
    Date of Patent: July 3, 1984
    Assignee: Akzona Incorporated
    Inventor: Gerhard Steenken
  • Patent number: 4442010
    Abstract: A process for the concentration and dewatering of an aqueous suspension of feldspathic minerals, comprising adding to the suspension a filter aid having the general formula: ##STR1## wherein R.sub.1 is an alkyl group of between 8 and 18 carbon atoms and wherein x and y are integers greater than 0 whose sum is between 2 and 15.
    Type: Grant
    Filed: November 12, 1982
    Date of Patent: April 10, 1984
    Assignee: Akzona Incorporated
    Inventor: Joseph L. Mehaffey
  • Patent number: 4433135
    Abstract: The use of aluminum sulfate as a dessicant for drying the starting materials used in polymerization reactions employing readily hydrolyzable catalysts is disclosed. The aluminum sulfate is allowed to remain in the reaction mixture during polymerization, and, indeed, may advantageously be allowed to remain in the reaction product without any deleterious effect.
    Type: Grant
    Filed: July 14, 1982
    Date of Patent: February 21, 1984
    Assignee: Akzona Incorporated
    Inventors: Ronald W. Worley, David A. Johnson
  • Patent number: 4421439
    Abstract: The invention relates to a supporting fabric having a width of at least 30 cm, and preferably more than 2-5 m, and containing warp and weft yarns of a synthetic material, for bearing one or more layers of sand, gravel, stones, clay, loam or similar bulk or other material to a height of at least 10 cm, which height is in actual practice often 5-15 m. The yarns extending in the warp direction of the fabric are formed by straight warp yarns and binder warp yarns, the straight warp yarns each having a higher strength than the binder warp yarns.The invention also comprises a method for building a road embankment, a dike, a dam, or some other structure formed from bulk material, such as, for instance, sand, gravel or stones. In such a structure, one or more layers of supporting fabric are incorporated.
    Type: Grant
    Filed: August 25, 1980
    Date of Patent: December 20, 1983
    Assignee: Akzona Incorporated
    Inventors: Antonius W. M. ter Burg, Gerrit den Hoedt
  • Patent number: 4416698
    Abstract: A solution containing cellulose dissolved in a tertiary amine N-oxide solvent containing a nonsolvent for cellulose such as water is shaped by extrusion or other shaping process to form a shaped cellulose fiber, rod, plate, tubing or film. The extruded shaped article is stretched in air while still a solution to impart improved physical properties thereto and the cellulose is precipitated from the shaped solution to set the properties without additional drawing. The solution may be prepared by dissolving cellulose in the tertiary amine N-oxide solvent in the barrel of an extrusion apparatus, extending the solution, orienting by stretching the resulting product in air while still a solution and then precipitating the cellulose from the shaped article before significant degradation of the cellulose. The cellulose and tertiary amine N-oxide may be ground to substantially the same particle size before charging the extruder barrel.
    Type: Grant
    Filed: April 3, 1980
    Date of Patent: November 22, 1983
    Assignee: Akzona Incorporated
    Inventor: Clarence C. McCorsley, III
  • Patent number: RE31599
    Abstract: A low density matting structure of improved transverse strength obtained by vertically laying continuous melt-spun thermoplastic macrofilaments (diameter=0.1-1.5 mm) onto a horizontally moving profiled support in overlapping rows of irregularly looped filaments to form a peak and valley three-dimensional structure undulating in its longitudinal and/or transverse directions. The matting articles consist essentially of the melt-spun filaments which are self-bonded or fused at random points of intersection without using any bonding agent or reinforcing inserts, and the resulting matting is especially distinguished by a high transverse strength per unit of surface weight of at least 2 Nm/g and preferably 4 Nm/g.
    Type: Grant
    Filed: August 3, 1981
    Date of Patent: June 12, 1984
    Assignee: Akzona Incorporated
    Inventors: Alfred Rasen, Rolf Vollbrecht, Klemens Schenesse