Abstract: Polyester polymers and copolyester polymers incorporating flame retardant amounts of cyclotri (or tetra) phosphazenes. These cyclotri (or tetra) phosphazenes can be added at the start of ester interchange, prior to, for example polycondensation and conventional melt spinning, or if desired, after polycondensation but before melt spinning. Specific examples of cyclotriphosphazenes and cyclotetraphosphazenes are hexa(dialkylphosphinylmethyleneoxy)cyclotriphosphazene, octa(dialkylphosphinylmethyleneoxy)cyclotetraphosphazene, tris(alkylphosphinyldimethyleneoxy)cyclotriphosphazene, tetra(alkylphosphinyldimethyleneoxy)cyclotetraphosphazene, hexa(dialkylphosphinylmethylene)cyclotriphosphazene, and octa(dialkylphosphinylmethylene)cyclotetraphosphazene.
Abstract: A multi-component filament consisting of at least two polymer components and having a cross-section in which a matrix component separates several peripherally arranged segments of one or more segment components from each other, and a process for the production of such matrix/segment filaments, wherein the segment component is injected into the matrix component and fed to the spinneret opening in a combined stream with a plurality of segment components separated by the matrix. The multicomponent filament can be drawn to obtain individual microfilaments of less than 1 dtex after splitting, e.g. by false twist texturing.
Abstract: A multi-component filament consisting of at least two polymer components and having a cross-section in which a matrix component separates several peripherally arranged segments of one or more segment components from each other, and a process for the production of such matrix/segment filaments, wherein the segment component is injected into the matrix component and fed to the spinneret opening in a combined stream with a plurality of segment components separated by the matrix. The multicomponent filament can be drawn to obtain individual microfilaments of less than 1 dtex after splitting, e.g. by false twist texturing.
Abstract: A filament of a thermoplastic synthetic polymer having a plurality of adjacent, separate discontinuous cavities is made by a process wherein a silicone oil and an inert gas or gas-forming substance are dispersed in a polymer melt, and the melt is extruded into a filament. The melt contains up to and including 1% by weight of the silicone oil, based on the weight of the melt, at the time it is extruded and up to and including 10% by weight of an inert gas.
Type:
Grant
Filed:
October 14, 1980
Date of Patent:
April 19, 1983
Assignee:
Akzona Incorporated
Inventors:
Erhard Siggel, Gerhard Wick, Heinz Linhart, Erich Kessler
Abstract: Process and apparatus for the separation of mixtures of liquids insoluble in each other, e.g., water and oil, where the mixture of liquids is brought into contact, from one side, with a fabric allowing only one of the liquids to pass so that the liquids can be collected separately.
Type:
Grant
Filed:
February 3, 1981
Date of Patent:
February 1, 1983
Assignee:
Akzona Incorporated
Inventors:
Nikolaus Mathes, Hans J. Pitowski, Gunther Vitzthum
Abstract: Fiber structures such as staple fibers, filaments, yarns as well as textile sheet structures such as woven or knitted fabrics as well as non-woven fabrics and the like made from multicomponent fibers of the matrix-segment type having in their cross sections a plurality of segments arranged peripherally without being fully surrounded by the matrix and being composed of polyalkylene terephthalate and copolyamides based on .epsilon.-caprolactam and hexamethylene diamine/adipic acid salt, are split by treatment with liquid or vaporous water. The difference in shrinkage between copolyamide and polyalkylene terephthalate in water is temporarily at least 10%. Corresponding short-staple fibers are particularly well suited for making wet-laid non-woven fabrics. The water used for treatment of the fiber structures may contain inorganic salts.
Abstract: A multifilament yarn consisting of single filaments of the multicomponent matrix-segment type where the individual components of the yarn show a false-twist crimp and where all or part of the individual components, consisting of the matrix and at least three segment fibers split off such matrix, said segment fibers having shrunk by at least 10% in relation to the matrix fiber, are bonded to each other at irregular intervals.
Type:
Grant
Filed:
February 27, 1980
Date of Patent:
December 21, 1982
Assignee:
Akzona Incorporated
Inventors:
Walter Brucher, Karl H. Hense, Reiner Modtler
Abstract: Fibrillatable multicomponent fibers of the matrix segment type and a process for production of fiber structures by splitting shrinkable, basically unset, multi-component fibers consisting of at least two incompatible components which in the fiber cross section are arranged in the form of a matrix and several segments, the latter accounting for about 20% to 80% of the total cross section. After having been processed into fiber structures such as staple fibers, yarns or fabrics, the multicomponent fibers are treated with a liquid or gaseous organic solvent, particularly chlorinated lower alkanes, to partially or completely split the segment filaments from the matrix component. Useful solvents are those which will reduce the zero-shrinkage temperature of the matrix or the segment polymer by at least 160.degree. C. and in which the polymer components constituting the fiber show different shrinkage behavior. Splitting may be further enhanced by the application of mechanical agitation, e.g. by ultrasonic waves.
Type:
Grant
Filed:
July 17, 1980
Date of Patent:
November 30, 1982
Assignee:
Akzona Incorporated
Inventors:
Klaus Gerlach, Nikolaus Mathes, Friedbert Wechs
Abstract: Segmented copolyesters/copolyethers in which the soft segment polyethers incorporate a thermally stable heterocyclic unit, e.g., hydantoin, are found to be useful as biomedical materials since the heterocyclic ring prevents crystallization of the soft segment, and further provides a chemically reactive site for incorporating other moieties to enhance certain properties, e.g., heparin for increasing the non-thrombogenicity of the biocompatible material.
Abstract: Staple fibers made from crimped, in particular compression crimped, multicomponent filaments of the matrix/segment type, the cross section of which shows, in addition to the matrix, at least 6 peripheral wedge-shaped or lenticular segments, not completely covered by the matrix, are processed into a web, which is then mechanically bonded, preferably by needling. Subsequently, the fabric is subjected to a shrinkage process, by which its density is increased by more than 30%, the multicomponent fibers being completely or partly split up into their components. The difference in shrinkage between the components should be at least 10%. The liquids used for the shrinkage treatment are in particular organic liquids, such as methylene chloride, as well as other liquids producing a difference in shrinkage of at least 20%.
Type:
Grant
Filed:
December 16, 1980
Date of Patent:
August 3, 1982
Assignee:
Akzona Incorporated
Inventors:
Klaus Gerlach, Nikolaus Mathes, Hans-Jurgen Pitowski, Friedbert Wechs
Abstract: Zinc chelates of terephthaloyl-terephthalic/oxalic copolyhydrazides, the oxalic dihydrazide and terephthalic dihydrazide units having a molar ratio in the range of 19:6 to 6:19, as well as the products aftertreated with an oxalic acid solution.
Type:
Grant
Filed:
July 21, 1980
Date of Patent:
May 25, 1982
Assignee:
Akzona Incorporated
Inventors:
Walter Brodowski, Michael Wallrabenstein
Abstract: Matting for hydraulic engineering consisting of a gripper layer of melt-spun filaments fused with each other and having a diameter of 0.2 to 1.5 mm and a filter layer of fine fibers, where a layer of grain rearrangement inhibiting material runs through the hollow spaces of the gripper layer.
Abstract: A solution containing cellulose dissolved in a mixture of a tertiary amine N-oxide solvent for cellulose and a compound which increases the rate of dissolution of cellulose in the solvent such as a tertiary amine or other compound which increases the pH of the solvent, a process for making such a solution and a process for making shaped articles therefrom are provided. The solvent dissolves cellulose at a faster rate and at a lower temperature than a solvent consisting of the same tertiary amine N-oxide.
Abstract: Three-dimensional exchange element for heat exchange units for gas/liquid systems which consists of filaments with a diameter of 0.1 to 2.5 mm, such filaments, which are welded together at their interlacing points, being arranged in a level plane showing equidistantly spaced hump-like projections.
Abstract: Polyester/polyether segmented copolymers are stabilized against degradation by UV light via copolymerization with novel diesters and/or bis-hydroxyalkyl terminated derivatives of 2,2,6,6-tetramethylpiperidines.
Type:
Grant
Filed:
July 8, 1980
Date of Patent:
March 30, 1982
Assignee:
Akzona Incorporated
Inventors:
David A. Johnson, Robert L. Gilly, Kenneth B. Wagener
Abstract: There is disclosed a method for minimizing ozone fading in dyed polyamides by treating the dyed polyamide with a substituted piperidine thiourea of the formula ##STR1## where R is a lower alkyl radical having 1-5 carbon atoms or phenyl. The treated dyed polyamides, preferably in fiber form, display minimize ozone fade without a reduction in light stability.
Abstract: A filament of synthetic polymers which, in its cross section over the entire length of the thread, comprises at least three layers, of which at least two layers are electrically conductive and at least one layer located between the conductive layers consists of an electrically insulating synthetic polymer.
Abstract: A method for oven drying chemically modified cellulosic materials, especially fibers, having improved fluid absorbency involves incorporating into the cellulose structure while swollen an amphiphilic compound miscible with water which will not evaporate when the fiber is oven dried and will remain in the fiber to prevent collapse of the fiber as the water is removed. The improved method of drying the fibrous cellulosic material produces a product having saline absorbency about equal to that produced when the fibers are dried with a water-miscible solvent and avoids the use of volatile solvents and the disadvantages inherent therewith. The fibers provided by the invention are especially suitable for use in pads which are to be used for absorbing water and body fluids.
Abstract: This invention relates to the use of certain co-solvents in cellulose amine N-oxide solutions, which co-solvents increase the cellulose dissolution rate; lower the temperatures necessary to reasonably form a solution; lower the viscosity of the solution; provide solutions with improved color, amine oxide stability, and cellulose stability, provide a solution with improved flow characteristics; increase solution processability, e.g. wet spinning; permit the replacement of amine oxides by a less expensive co-solvent; and are recoverable and reusable in cellulose dissolution and processing.The co-solvents of the invention comprise compounds, miscible with cellulose-dissolving amine N-oxides, containing primary, or combinations of primary and secondary, amino groups wherein the amino groups are bonded to alkyl, alicyclic, dialkyl ether or alkyl/alicyclic radical(s) and wherein the number of carbon atoms divided by the number of primary amino groups is approximately equal to or less than 4; or#C/#NH.sub.2 .
Abstract: A stable floor for animals which is in structural combination with a floor covering sheet having at least two layers: a compressible sublayer of a resilient and highly porous filamentary matting partly embedded in a top layer which is impermeable to moisture. The floor covering sheet provides good insulation and has dimensional stability so as to remain resilient over a prolonged period of time.