Abstract: There are disclosed novel 2,6-substituted-3,5-pyridinedicarboxylic acids, esters, salts, amides, halides, and cyano compounds useful as herbicides, and as intermediates which provide herbicides.
Abstract: Compounds of the formula ##STR1## are disclosed as herbicides. Disclosed herein are cyclic amides of pyridine 3,5-carboxylic acids substituted at the 2- and/or 6-position with a fluorinated methyl group. Also disclosed are herbicidal use of such compounds and compositions containing them.
Type:
Grant
Filed:
December 24, 1987
Date of Patent:
May 2, 1989
Assignee:
Monsanto Company
Inventors:
Yuen-Lung L. Sing, Maria L. Miller, Len F. Lee
Abstract: Disclosed herein is a novel process for the preparation of 4-amino-3,5-pyridinedicarboxylate derivatives by (a) reaction of an acetonediester with a primary amine to form an enamine, (b) reaction with a carboxylic acid anhydride or halide to form a 2-alkylcarbonyl-3-amino-2-pentenedicarboxylate, and (c) reaction with a halogenated alkylnitrile to form the pyridinedicarboxylate product. The product is useful as a herbicide or an intermediate in the formation of a herbicide.
Abstract: Disclosed herein are 3,5-pyridinedicarboxylic acid derivatives having heteroatom substitution at the 4 position which are useful as herbicides and herbicide precursors.
Abstract: Disclosed herein is a container having an improved pouring spout for easing the passage of air into the container as a liquid is poured from the container.
Abstract: Disclosed herein are 4,6-dialkoxy 3-pyridinecarboxylic acids and their derivatives which are useful as herbicides and herbicide intermediates.
Abstract: Disclosed herein are 3,5-pyridinedicarboxylic acid derivatives having heteroatom substitution at the 4 position which are useful as herbicides and herbicide precursors.
Abstract: There are disclosed novel 2,6-substituted-3,5-pyridinedicarboxylic acids, esters, salts, amides, halides, and cyano compounds useful as herbicides, and as intermediates which provide herbicides.
Abstract: There are disclosed novel 2,6-substituted-3-pyridinecarboxylic acids, esters, and salts useful as herbicides, and as intermediates which provide herbicides.
Abstract: Compounds of the formula ##STR1## wherein x is NH and wherein R.sub.1 is selected from branched-chain lower alkyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl, and cycloalkanylalkyl radicals, R.sub.2 is a C.sub.1-4 alkyl radical and R.sub.3 represents a C.sub.1-4 fluoroalkyl radical are disclosed as herbicides.
Abstract: Disclosed herein are 4,6-dialkoxy 3-pyridine carboxylic acids and their derivatives which are useful as herbicides and herbicide intermediates.
Abstract: The invention relates to compounds having the formula ##STR1## wherein R is equal to hydrogen, halogen or alkyl containing 1-5 carbon atoms; X is equal to oxygen, sulfur or --NH; n is equal to the integer 1 to 6; with the proviso when X is --NH, n may not equal 6. These compounds are useful in regulating the growth of leguminous plants.
Abstract: Paving-grade asphalt compositions having improved resistance to weathering are described which are obtained by incorporating into a paving-grade asphalt either (1) the product obtained by alkylating phenol with a resin oil, i.e., a hydrocarbon fraction of medium molecular weight compounds in the C.sub.9 carbon range primarily aromatic in nature, or (2) the condensation product of formaldehyde with the alkylation product of phenol and a C.sub.4 raffinate stream consisting mainly of butene-1, butene-2 and isobutylene.
Abstract: Toluene and toluene derivatives are oxidatively dehydrocoupled to produce stilbene and stilbene derivatives by heating toluene or a toluene derivative in the vapor phase with a metal- and oxygen-containing composition which functions as an oxidant or oxygen carrier and has the empirical formulaSb.sub.a Pb.sub.b Bi.sub.c O.sub.dwherein a is 1, b is 0.2-10, c is 0-5 and d is a number taken to satisfy the average valences of the Sb, Pb and Bi in the oxidation states in which they exist in said composition. Alternatively, the same metal- and oxygen - containing composition can be employed as a catalyst for the dehydrocoupling reaction when oxygen or an oxygen-containing gas is heated with the hydrocarbon reactant.
Abstract: Oxidation and ammoxidation catalysts are disclosed which have the empirical formula Sb.sub.a V.sub.b Ti.sub.c O.sub.x, wherein a is at least 6, b is 1, and c is a number such that the ratio c/a is at least 0.5, and x is a number taken to satisfy the valence requirements of the Sb, V and Ti present in the catalyst. Such catalysts may be optionally supported on conventional supports, or may be unsupported.
Abstract: A combination of zinc oxide and zinc bromide employed as a catalyst for the reaction between phenol and a 1,2-dihaloethane wherein the halogen is chlorine, bromine or iodine provides for increased reaction rates as compared to the use of either zinc compound separately as catalyst and elimination of the induction period characteristic of the reaction when zinc oxide is used as the catalyst.
Abstract: The rate of reaction of ethylenically unsaturated compounds, carbon monoxide and water in the presence of catalyst systems consisting essentially of a rhodium or iridium compound and a halogen promoter to produce carboxylic acids is accelerated by including a minor amount of a compound of cobalt, iron or manganese in the reaction system.
Abstract: An improved process for the simultaneous and continuous production of acetic and propionic acids in a single reactor wherein the rate of propionic acid production is enhanced over that which prevails when this acid is produced separately in the same reactor under the same conditions, said rate enhancement being achieved by the introduction of methanol at a critical rate.