Abstract: The present invention relates to detergent compositions comprising a high activity cellulase in combination with a softening clay. In the detergent compositions herein, the cellulase comprises a cellulase of high activity defined by the C14CMC-method. Preferably the detergent composition comprises a softening clay together with a clay flocculating agent and in case of liquid composition an anti-settling agent for the clay.
Type:
Grant
Filed:
July 15, 1993
Date of Patent:
August 22, 1995
Assignee:
The Procter & Gamble Company
Inventors:
Andre Convents, Alfred Busch, Andre C. Baeck
Abstract: Disclosed is a fiber comprising, chemically bonded together, (a) a conventional cellulosic fiber, such as a Kraft fiber or a chemithermomechanical pulp fiber; (b) poly(acrylate-co-itaconate) copolymer, such as the acid form of a poly(acrylate-co-itaconate) copolymer comprising 90-95 mole % acrylate and 5-10 mole % itaconate having weight average molecular weight of about 600,000-900,000; and (c) a polyol, such as polyethylene glycol; also disclosed are methods for making such fibers, especially evaporatively depositing an intimate mixture of the copolymer and polyol on the fiber followed by thermally crosslinking at specific temperatures for limited periods; absorbent paper which can be made by wet-laying the fiber, especially in admixture with conventional fiber; and derivative paper structures, such as multi-ply disposable absorbent towels.
Abstract: The subject invention relates to pharmaceutical compositions comprising a safe and effective amount of a compound having the structure: ##STR1## wherein each R is alkyl or hydrogen, at least two being alkyl; R' is hydrogen, alkyl or aryl; R" is alkyl or halo; and each X is independently oxygen or sulfur; and a pharmaceutically-acceptable carrier. The subject invention also relates to methods for preventing damage to skin by topically applying a safe and effective amount of such compounds to the skin.
Abstract: A process for producing a high density detergent composition having a density of about 650 g/l is provided. The process comprises the step of forming detergent agglomerates by feeding several streams of materials into a mixer/densfier. Specifically, the following materials are continuously fed into the mixer/densifier: (i) from about 1% to about 50% by weight of a C.sub.10-18 linear alkylbenzene sulfonate surfactant; (ii) from about 1% to about 50% by weight of a C.sub.12-16 alkyl sulfate surfactant, wherein the linear alkylbenzene sulfonate and the alkyl sulfate are in the form of dry particles; (iii) from about 20% to about 50% by weight of a builder; and (iv) from about 0.1% to about 35% by weight of an agglomerating agent which substantially prevents the intimate mixing of the linear alkylbenzene sulfonate surfactant and the alkyl sulfate surfactant in the mixer/densifier.
Abstract: Liquid laundry detergents containing a protease and at least one additional enzyme wherein the additional enzyme is protected from degradation by the protease during storage by the presence of certain ortho substituted phenylboronic acids.
Type:
Grant
Filed:
November 5, 1993
Date of Patent:
July 11, 1995
Assignee:
The Procter & Gamble Company
Inventors:
Rajan K. Panandiker, David W. Bjorkquist
Abstract: A process for improving the color and purity of dark-colored potassium or magnesium alkyl ester sulfonate surfactant compositions, and particularly alpha-sulfo fatty acid methyl ester compositions, without the need for bleaching or other process steps. The process comprises the steps of (1) forming a mixture comprising (i) an alkyl ester sulfonate surfactant composition containing impurities including dark-colored impurities, organic and inorganic salts, and disalts, and (ii) water, and (2) separating the ester sulfonate surfactant from the mixture. The process may further comprise step (3) recovering the alkyl ester sulfonate surfactant. Methyl ester sulfonate surfactant compositions are most preferred. After processing in accordance with the invention, the alkyl ester sulfonate surfactant composition has improved color, purity, and odor properties.
Type:
Grant
Filed:
February 5, 1993
Date of Patent:
July 4, 1995
Assignee:
The Procter & Gamble Company
Inventors:
Alan E. Sherry, Benjamin E. Chapman, Michael T. Creedon
Abstract: Heavy duty liquid detergent compositions containing high levels of anionic synthetic surfactant, carboxylate detergency builder, proteolytic enzyme, and alkanolamine are disclosed. The high level of alkanolamine, preferably monoethanolamine, prevents or minimizes crystallization of the protease during storage of the compositions. The compositions are preferably clear, homogeneous, and stable, and are particularly useful as laundry detergents that provide good cleaning performance on enzyme-sensitive stains.
Abstract: The present invention provides an aqueous liquid bleach composition which remains stable over an extended period of time. The liquid bleach is easily pourable since it has a relatively low viscosity. The liquid bleach generally comprises (a) from about 1% to about 25% by weight of a water-soluble bleach activator; (b) from about 0.1% to about 10% by weight of hydrogen peroxide; (c) from about 1% to about 20% by weight of a phase stabilizer; (d) from about 0.001% to about 2% by weight of a chelating agent; and (e) the balance water. The liquid bleach composition is isotropic, translucent and has a viscosity of less than about 500 cps.
Type:
Grant
Filed:
May 13, 1993
Date of Patent:
May 30, 1995
Assignee:
The Procter & Gamble Company
Inventors:
Michael S. Showell, Josephine L. Kong-Chan, Philip G. Sliva, Kermit W. Kinne, Kathleen B. Hunter
Abstract: Homogeneous polymer blends are prepared from otherwise thermodynamically immiscible polymers, especially including block copolymers. Thus, polymers such as polystyrene/poly(methyl methacrylate) block copolymer or polystyrene/poly(1,2-butadiene) block copolymer are dissolved under pressure in supercritical fluid solvents such as chlorodifluoromethane and n-butane, respectively, and expanded through a fine nozzle. As the SCF solvent evaporates, the polymer deposits as a substantially homogeneous material.
Type:
Grant
Filed:
November 19, 1993
Date of Patent:
May 2, 1995
Assignees:
The Procter & Gamble Company, The Univ. of Deleware
Inventors:
Annetta D. Shine, Steven D. Smith, Isao Noda
Abstract: An aqueous cleaning and bleaching composition with a pH of from about 0.5 to about 6, which contains amidoperoxyacid, hydrogen peroxide, and acylated citrate ester which has been emulsified in two or more ethoxylated alcohols is described.
Type:
Grant
Filed:
November 16, 1992
Date of Patent:
April 25, 1995
Assignee:
The Procter & Gamble Company
Inventors:
Michael S. Showell, Philip G. Sliva, Stefano Scialla, Anna M. Vercillo-Martino, Elisabetta L. Russo
Abstract: Laundry detergents and automatic dishwashing compositions with activated bleaching systems which are effective under mixed soil conditions, especially mixtures of hydrophobic and hydrophilic soils and stains are presented. The preferred bleach activators are N-acyl caprolactams and nonanoyloxybenzene sulfonate. A particularly preferred embodiment comprises a 1:2.2:7.7 molar ratio of N-acyl caprolactam to alanoyloxybenzenesulfonate to peroxygen bleaching compound. This mixed caprolactam, alkanoyloxybenzenesulfonate bleaching composition delivers stronger than expected performance on both hydrophobic and hydrophilic stains and on dingy clean up.
Type:
Grant
Filed:
April 13, 1915
Date of Patent:
April 11, 1995
Assignee:
The Procter & Gamble Company
Inventors:
Alan D. Willey, Michael E. Burns, Jerome H. Collins
Abstract: Laundry detergents and bleaching systems comprise acyl valerolactam bleach activators. The bleach activators are effective under mixed soil conditions, especially mixtures of hydrophobic and hydrophilic soils and stains.
Type:
Grant
Filed:
June 24, 1993
Date of Patent:
April 11, 1995
Assignee:
The Procter & Gamble Co.
Inventors:
Alan D. Willey, Michael E. Burns, Shuichi Tsunetsugu
Abstract: The present invention relates to a process for manufacturing improved color surfactant agglomerates, particularly comprising methyl ester sulfonates, for use in detergent compositions, said process comprising sulfonation of methyl ester, digestion of the sulfonation product, esterification of said sulfonated product to produce an acid product and agglomeration of said acid product, characterized in that said acid product is exposed to a solid bleaching agent immediately prior to or during agglomeration of said acid product.
Abstract: Disclosed is a process for manufacturing a linear glucamide surfactant comprising reacting an N-alkylglucamine, e.g., N-methylglucamine, a fatty ester, e.g., coconut oil in the presence of a phase transfer agent, generally a nonionic surfactant, preferably a preformed product of the process, the reaction preferably being conducted in the presence of an alkaline catalyst.
Type:
Grant
Filed:
June 11, 1993
Date of Patent:
January 10, 1995
Assignee:
The Procter & Gamble Company
Inventors:
Daniel S. Connor, Jeffrey J. Scheibel, Ju-Nan Kao
Abstract: A granular detergent composition having improved cleaning performance is provided. The detergent composition contains a detergent surfactant selected from the group consisting of anionics, nonionics, zwitterionics, ampholytics, cationics and mixtures thereof, and a mixture of non-phosphate detergent builders. The builder mixture comprises an aluminosilicate ion exchange material, crystalline layered sodium silicate and citrate/citric acid in an optimum ratio of from about 3.5:1:1 to about 4.5:1:1.
Abstract: A process for preparing high density detergent agglomerates having a density of at least 650 g/l is provided. The process comprises the steps of: (a) charging a viscous surfactant paste into a mixer/densifier wherein the surfactant paste has a viscosity of from about 10,000 cps to about 100,000 cps and contains at least about 10% water; (b) adding from about 1% to about 20% of an anhydrous material into the surfactant paste just prior to entrance into the mixer/densifier to absorb at least a minor amount of the water from the surfactant paste; and (c) agglomerating the surfactant paste and the anhydrous material in the mixer/densifier so as to form detergent agglomerates having a density of at least about 650 g/l. The detergent agglomerates have high surfactant levels.
Type:
Grant
Filed:
August 27, 1993
Date of Patent:
November 22, 1994
Assignee:
The Procter & Gamble Company
Inventors:
Scott W. Capeci, James W. Osborn, Adrian J. W. Angell, Paul van Dijk
Abstract: Polycationic wet-strength materials such as KYMENE are chemically modified to provide unsaturated hydrocarbon substituents. The modified KYMENE is cross-linked onto and into latex particles to provide improved wet-strength agents for use in paper treatments. Thus, KYMENE is reacted, for example, with acrylic acid and cross-linked with styrene/butadiene to provide a polycationic latex wet-strength agent.
Abstract: This invention relates to a pie or pastry dough, which provides a flaky tender pie crust when baked. The product is a laminate of two phases, a dough like mixture of flour, water, salt and oil, and a shortening and starch phase. One or both phases can contain a polyol. These phases are laminated to make a heterogeneous pastry dough which has a flaky tender texture when baked. The dough is characterized by having multiple, discontinuous layers which are interrupted by regions of gluten and the starch/fat/polyol phase, an increased dough strength and less water absorption over 24 hours.
Abstract: The subject invention relates to compositions and methods for regulating wrinkles in mammalian skin by topical application of a 2-deoxy- or 2-deoxy-2-halo-lysophosphatidic acid compound having the structure: ##STR1## or a pharmaceutically acceptable salt thereof, wherein --R is unsubstituted or substituted, saturated or unsaturated, straight or branched chain alkyl having from 11 to about 23 carbon atoms; each --X-- is independently --0-- or --S--; --Y-- is --0-- or --CH.sub.2 --; and Z is --H or halo.
Type:
Grant
Filed:
July 1, 1992
Date of Patent:
August 23, 1994
Assignee:
The Procter & Gamble Company
Inventors:
Gary A. Piazza, Adam W. Mazur, Gerald B. Kasting