Abstract: An aluminum layer formed over an integrated circuit structure is patterned to form a plurality of aluminum metal lines. The patterned aluminum metal lines are then anodized in an acid anodizing bath to form anodized aluminum oxide on the exposed sidewall surfaces of the patterned aluminum. The anodization may be carried out until the anodized aluminum films on horizontally adjacent aluminum metal lines contact one another, or may be stopped prior to this point, leaving a gap between the anodized aluminum oxide films on adjacent aluminum metal lines. This gap may then be either filled with other low k dielectric material or by standard (non-low k) dielectric material. A capping layer of non-porous dielectric material is then formed over the porous anodized aluminum oxide.

Abstract: The invention provides a process for selectively polishing a main electrically conductive layer of an integrated circuit structure by the steps of forming a polishing barrier layer over depressed regions of the main electrically conductive layer; and polishing the portion of the main electrically conductive layer not covered by the polishing barrier layer. The integrated circuit structure treated by the process of the invention contains one or more openings in a layer of dielectric material, and the main electrically conductive layer fills the one or more openings such that the depressed regions of the main electrically conductive layer overlie said one or more openings.

Abstract: A composite layer of dielectric material is first formed over the integrated circuit structure, comprising a thin barrier layer of dielectric material, a layer of low k dielectric material over the barrier layer, and a thin capping layer of dielectric material over the layer of low k dielectric material. A photoresist mask, formed over the capping layer, is baked in the presence of UV light to cross-link the mask material. The composite layer is then etched through the resist mask using an etchant gas mixture including CO, but not oxygen. Newly exposed surfaces of low k dielectric material are then optionally densified to harden them. The resist mask is then removed using a plasma of a neutral or reducing gas. Exposed surfaces of low k dielectric material are then passivated by a low power oxygen plasma. Preferably, optional densification, mask removal, and passivation are all done in the same vacuum apparatus.

Abstract: A composite layer of low k dielectric material for integrated circuit structures comprising a thick lower conformal barrier layer of low k dielectric material, a low k center layer of carbon-doped silicon oxide dielectric material having good gap filling capabilities, and a thick upper conformal barrier layer of low k dielectric material. The thick lower conformal barrier layer of low k dielectric material protects the lower surface of the main low k dielectric layer and also protects against misaligned vias entering the main low k dielectric material below the height of the metal line without raising the capacitance of the structure as would a lower barrier layer of non-low k dielectric material.

Abstract: A planarization process for an integrated circuit structure which inhibits or prevents cracking of low k dielectric material which comprises one of one or more layers of dielectric material formed over raised portions of the underlying integrated circuit structure. Prior to the planarization step, a removable mask is formed over such one or more dielectric layers formed over raised portions of the integrated circuit structure. Openings are formed in the mask to expose a portion of the upper surface of the one or more dielectric layers in the region over at least some of these raised portions of the integrated circuit structure. Exposed portions of the underlying one or more dielectric layers are then etched through such openings in the mask to reduce the overall amount of the one or more dielectric layers overlying such raised portions of the integrated circuit structure.

Abstract: An integrated circuit structures such as an SRAM construction wherein the soft error rate is reduced comprises an integrated circuit structure formed in a semiconductor substrate, wherein at least one N channel transistor is built in a P well adjacent to one or more deep N wells connected to the high voltage supply and the deep N wells extend from the surface of the substrate down into the substrate to a depth at least equal to that depth at which alpha particle-generated electron-hole pairs can effectively cause a soft error in the SRAM cell. For a 0.25 &mgr;m SRAM design having one or more N wells of a conventional depth not exceeding about 0.5 &mgr;m, the depth at which alpha particle-generated electron-hole pairs can effectively cause a soft error in the SRAM cell is from 1 to 3 &mgr;m. The deep N well of the 0.25 &mgr;m SRAM design, therefore, extends down from the substrate surface a distance of at least about 1 &mgr;m, and preferably at least about 2 &mgr;m.

Abstract: A process is disclosed for forming low k dielectric material between and over a plurality of spaced apart metal lines previously formed over a dielectric layer of an integrated circuit structure. The steps include: depositing, over and between the plurality of metal lines, a layer of a first low k dielectric material resistant to via poisoning; then planarizing the layer of first low k dielectric material sufficiently to open voids formed in. the first low k dielectric material between the metal lines; then depositing, over the layer of first low k dielectric material and into the opened voids, a layer of second low k dielectric material capable of filling the opened voids in the layer of first low k dielectric material; and then depositing a layer of a third low k dielectric material resistant to via poisoning over the first low k dielectric material and the voids filled with the second low k dielectric material.

Abstract: A capping layer of an insulator such as silicon oxynitride is formed over horizontally closely spaced apart metal lines on an oxide layer of an integrated circuit structure formed on a semiconductor substrate. Low k silicon oxide dielectric material which exhibits void-free deposition properties in high aspect ratio regions between the closely spaced apart metal lines is then deposited over and between the metal lines and over the silicon oxynitride caps on the metal lines. After the formation of such void-free low k silicon oxide dielectric material between the closely spaced apart metal lines and the silicon oxynitride caps thereon, the structure is planarized to bring the level of the low k silicon oxide dielectric material down to the level of the tops of the silicon oxynitride caps on the metal lines. A further layer of standard k silicon oxide dielectric material is then formed over the planarized void-free low k silicon oxide dielectric layer and the silicon oxynitride caps.

Abstract: A process is disclosed which inhibits cracking of the layer of low k silicon oxide dielectric material on an integrated circuit structure during subsequent processing of the layer of low k silicon oxide dielectric material. The process comprises: forming a layer of low k silicon oxide dielectric material on an integrated circuit structure on a semiconductor substrate, and forming over the layer of low k silicon oxide dielectric material a capping layer of dielectric material having: a dielectric constant not exceeding about 4, a thickness of at least about 300 nm, and a compressive stress of at least about 3×109 dynes/cm2. In a preferred embodiment, the capping layer comprises silicon oxide formed by reaction of silane and N2O in a PECVD process carried out within a pressure range of from about 600 milliTorr to about 1000 milliTorr; and a temperature range of from about 300° C. to about 400° C.

Abstract: A process for forming an integrated circuit structure wherein trenches and/or vias are formed in a predetermined pattern in a dielectric layer, lined with a barrier layer of a first electrically conductive material, and then filled with a second electrically conductive material, and the structure is then planarized to remove the first and second electrically conductive material from the upper surface of the dielectric layer, wherein the improvements comprise: a) before the planarizing step, forming over the second electrically conductive material a layer of a planarizable material capable of being planarized at about the same rate as the first electrically conductive material; and b) then planarizing the structure to remove: i) the planarizable material; ii) the second electrically conductive material; and iii) the first electrically conductive material; above the upper surface of the dielectric material; whereby the planarizable material above the second electrically conductive material in the trenche

Abstract: A process-is disclosed for planarizing an integrated circuit structure by chemical mechanical polishing (CMP) after filling, with at least one metal, a plurality of trenches and/or vias formed in a silicon oxide layer on the integrated circuit structure. The process, which is capable of inhibiting formation of concave surface portions on the silicon oxide surface, during the CMP process, in regions where said trenches and/or vias are closely spaced apart, comprises forming, over a layer of silicon oxide of an integrated circuit structure, an antireflective coating (ARC) layer of dielectric material capable of functioning as a stop layer in a CMP process to remove metal; and using this ARC layer as a stop layer to assist in removal of excess metal used to fill trenches and/or vias formed in the oxide layer. The particular material chosen for the ARC layer should have a lower etch rate, in a CMP process to remove metal, than does the underlying oxide dielectric layer.

Abstract: A composite layer of low k silicon oxide dielectric material is formed on an oxide layer of an integrated circuit structure on a semiconductor substrate having closely spaced apart metal lines thereon. The composite layer of low k silicon oxide dielectric material exhibits void-free deposition properties in high aspect ratio regions between the closely spaced apart metal lines, deposition rates in other regions comparable to standard k silicon oxide, and reduced via poisoning characteristics. The composite layer of low k silicon oxide dielectric material is formed by depositing, in high aspect ratio regions between closely spaced apart metal lines, a first layer of low k silicon oxide dielectric material exhibiting void-free deposition properties until the resulting deposition of low k silicon oxide dielectric material reaches the level of the top of the metal lines on the oxide layer.

Abstract: A dual damascene type of structure of vias and trenches formed using layers of low k dielectric material is disclosed, and a process for making same without damage to the low k dielectric material during removal of photoresist masks used respectively in the formation of the pattern of via openings and the pattern of trench openings in the layers of low k dielectric material. Damage to the low k dielectric material is avoided by forming a first layer of low k dielectric material on an integrated circuit structure; forming a first hard mask layer over the first layer of low k dielectric material; forming over the first hard mask layer a first photoresist mask having a pattern of via openings therein; and then etching the first hard mask layer through the first photoresist mask to form a first hard mask having the pattern of vias openings replicated therein, using an etch system which will also remove the first photoresist mask.

Abstract: A low temperature process is described for forming a low dielectric constant (k) fluorine and carbon-containing silicon oxide dielectric material for integrated circuit structures. A reactor has a semiconductor substrate mounted on a substrate support which is maintained at a low temperature not exceeding about 25° C., preferably not exceeding about 10° C., and most preferably not exceeding about 0° C. A low k fluorine and carbon-containing silicon oxide dielectric material is formed on the surface of the substrate by reacting together a vaporous source of a mild oxidizing agent, such as a vaporized hydrogen peroxide, and a vaporous substituted silane having the formula (CFmHn)—Si—(R)xHy wherein m is 1-3; n is 3-m; R is an alkyl selected from the group consisting of ethyl (—C2H5), methyl (—CH3), and mixtures thereof; x is 1-3; and y is 3-x.

Abstract: A low k carbon-doped silicon oxide dielectric material dual damascene structure is formed by improvements to a process wherein a first photoresist mask is used to form via openings through a first layer of low k carbon-doped silicon oxide dielectric material, followed by removal of the first photoresist mask; and wherein a second photoresist mask is subsequently used to form trenches in a second layer of low k carbon-doped silicon oxide dielectric material corresponding to a desired pattern of metal interconnects for an integrated circuit structure, followed by removal of the second photoresist mask.

Abstract: Damaged surfaces of a low k carbon-containing silicon oxide dielectric material are treated with one or more carbon-containing gases, and in the absence of an oxidizing agent, to inhibit subsequent formation of silicon-hydroxyl bonds when the damaged surfaces of the low k dielectric material are thereafter exposed to moisture. The carbon-containing gas treatment of the invention is carried out after the step of oxidizing or “ashing” the resist mask to remove the mask, but prior to exposure of the damaged surfaces of the low k dielectric material to moisture. Optionally, the carbon-containing gas treatment may also be carried out after the initial step of etching the low k carbon-containing silicon oxide dielectric material to form vias or contact openings as well, particularly when exposure of the damaged surfaces of the low k dielectric material to moisture after the via etching step and prior to the resist removing oxidation step is possible.

Abstract: A process is described for using a silicon layer as an implant and out-diffusion layer, for forming defect-free source/drain regions in a semiconductor substrate, and also for subsequent formation of silicon nitride spacers. A nitrogen-containing dopant barrier layer is first formed over a single crystal semiconductor substrate by nitridating either a previously formed gate oxide layer, or a silicon layer formed over the gate oxide layer, to form a barrier layer comprising either a silicon, oxygen, and nitrogen compound or a compound of silicon and nitrogen. The nitridating may be carried out using a nitrogen plasma followed by an anneal. A polysilicon gate electrode is then formed over this barrier layer, and the exposed portions of the barrier layer remaining are removed. An amorphous silicon layer of predetermined thickness is then formed over the substrate and polysilicon gate electrode.

Abstract: A local interconnect for an integrated circuit structure is described capable of bridging over a conductive element to electrically connect together, at the local interconnect level, non-adjacent conductive portions of the integrated circuit structure. After formation of active devices and a conductive element of an integrated circuit structure in a semiconductor substrate, a silicon oxide mask is formed over the structure, with the conductive element covered by the silicon oxide mask. Metal silicide is then formed in exposed silicon regions beneath openings in the mask. The portion of the silicon oxide mask covering the conductive element is then retained as insulation. A silicon nitride etch stop layer and a planarizable dielectric layer are then formed over the structure. An opening is then formed through such silicon nitride and dielectric layers over the conductive element and exposed metal silicide regions adjacent the conductive element.

Abstract: A process for the formation of shaped Group III-V semiconductor nanocrystals comprises contacting the semiconductor nanocrystal precursors with a liquid media comprising a binary mixture of phosphorus-containing organic surfactants capable of promoting the growth of either spherical semiconductor nanocrystals or rod-like semiconductor nanocrystals, whereby the shape of the semiconductor nanocrystals formed in said binary mixture of surfactants is controlled by adjusting the ratio of the surfactants in the binary mixture.

Abstract: A low dielectric constant multiple carbon-containing silicon oxide dielectric material for an integrated circuit structure is described which comprises a silicon oxide material including silicon atoms which are each bonded to a multiple carbon-containing group consisting of carbon atoms and primary hydrogens. Preferably such multiple carbon-containing groups have the general formula —(C)y(CH3)z, where y is an integer from 1 to 4 for a branched alkyl group and from 3 to 5 for a cyclic alkyl group, and z is 2y+1 for a branched alkyl group and 2y−1 for a cyclic alkyl group.