Patents Represented by Attorney Marion C. Staves
  • Patent number: 4247576
    Abstract: It has been found that thin oriented polypropylene film can be coated with a submicron thickness of an alkali metal silicate. The thus coated film gives excellent results when used to separate the negative from the liquid photopolymer in preparing plastic printing plates.
    Type: Grant
    Filed: March 9, 1979
    Date of Patent: January 27, 1981
    Assignee: Hercules Incorporated
    Inventor: Abraham Kutner
  • Patent number: 4243702
    Abstract: It has been discovered that pastes of particulate thermoplastic polymers dispersed in a soft resinous phase can be prepared which heat-set by fusion of the thermoplastic binder. Polyesters and polyamides have been found to be particularly useful. When pigmented or otherwise colored, these formulations have utility as printing inks. When uncolored, they can be used as clear overprint coatings. In addition, these fusible pastes have utility as specialty coatings in adhesives and can be fabricated into self-supporting shapes.
    Type: Grant
    Filed: June 29, 1979
    Date of Patent: January 6, 1981
    Assignee: Hercules Incorporated
    Inventor: Robert M. Walsh
  • Patent number: 4240971
    Abstract: Disclosed are epoxy-sulfonylazide compounds of the formula ##STR1## where R is a polyvalent organic radical, R' is a hydrogen, alkyl, cycloalkyl, aryl, or aralkyl radical, and n and m are integers from 1 to 100. Also disclosed is the use of said epoxy-sulfonylazide compounds in modifying polymers, cross-linking polymers, and adhering polymers to certain substrates, e.g., glass and other polymers.
    Type: Grant
    Filed: December 31, 1975
    Date of Patent: December 23, 1980
    Assignee: Hercules Incorporated
    Inventor: David S. Breslow
  • Patent number: 4223109
    Abstract: The calcium salts of the solid cyclic copolymers of divinyl ether and maleic anhydride, soluble in water, have been found to be as effective in treating tumors and viruses as the prior art alkali metal salts (e.g., the sodium salt) but much less toxic. These copolymers are characterized by containing divinyl ether and maleic anhydride in a mole ratio of about 1:2, having a molecular weight of from about 2000 to about 100,000 and from about 5% to about 70% of its carboxylic acid groups converted to calcium salts.
    Type: Grant
    Filed: February 22, 1979
    Date of Patent: September 16, 1980
    Assignee: Adria Laboratories Inc.
    Inventor: Richard L. Wolgemuth
  • Patent number: 4198396
    Abstract: Macroreticular resins have shown biological activity for gallstone removal and lowering serum cholesterol by selective adsorption of cholesterol from the bile.
    Type: Grant
    Filed: December 10, 1975
    Date of Patent: April 15, 1980
    Assignee: Warren-Teed Laboratories, Inc.
    Inventors: Michael C. Seidel, Evan H. Crook
  • Patent number: 4182800
    Abstract: Methotrexate can be reacted with cyclic copolymers of divinyl ether and maleic anhydride to prepare reaction products which are useful in retarding the growth of malignant tumors.
    Type: Grant
    Filed: June 28, 1978
    Date of Patent: January 8, 1980
    Assignee: Hercules Incorporated
    Inventors: Helmut Ringsdorf, Michael Przybylski
  • Patent number: 4174218
    Abstract: It has been found that excellent quality photopolymer printing plates having hardness, flexibility, resilience, abrasion resistance and resistance to alcohol-based inks can be prepared from photopolymer compositions comprising a liquid polymer containing at least two terminal olefin groups attached to the polymer through a combination of at least two ether, thioether, ester, keto or amide groups, from about 1 to about 50% by weight based on the polymer of at least one ethylenically unsaturated monomer, from about 0.1 to about 10% by weight of a photoinitiator and about 0.01 to about 2% of a stabilizer.
    Type: Grant
    Filed: August 16, 1978
    Date of Patent: November 13, 1979
    Assignee: Hercules Incorporated
    Inventor: Rudolph L. Pohl
  • Patent number: 4168173
    Abstract: It has been found that high quality relief printing plates can be made using a photosensitive composition comprising at least one unsaturated polyester, at least one ethylenically unsaturated, addition polymerizable monomer, at least one photosensitive initiator and a poly(hydroxylether) derived from a diphenol and an epihalohydrin, such as bisphenol A-epichlorohydrin resin. The poly(hydroxylether) increases the viscosity of the photosensitive resin such that the resin is less likely to flow during platemaking process, thereby avoiding undesirable blemishes on the finished plate.
    Type: Grant
    Filed: September 7, 1978
    Date of Patent: September 18, 1979
    Assignee: Hercules Incorporated
    Inventor: Rudolph L. Pohl
  • Patent number: 4162997
    Abstract: It has been discovered that pastes of particulate thermoplastic polymers dispersed in a soft resinous phase can be prepared which heat-set by fusion of the thermoplastic binder. Polystyrene-type and polyacrylate-type polymers have been found to be particularly useful. When pigmented or otherwise colored, these formulations have utility as printing inks. When uncolored, they can be used as clear overprint coatings. In addition, these fusible pastes have utility as specialty coatings in adhesives and can be fabricated into self-supporting shapes.
    Type: Grant
    Filed: March 2, 1978
    Date of Patent: July 31, 1979
    Assignee: Hercules Incorporated
    Inventor: Robert M. Walsh
  • Patent number: 4143130
    Abstract: Water soluble and colloidially water soluble polymers of carboxylic acid-containing monomers useful for treating kidney stones are disclosed.
    Type: Grant
    Filed: August 29, 1977
    Date of Patent: March 6, 1979
    Assignee: Warren-Teed Laboratories, Inc.
    Inventors: Anthony R. Imondi, Richard L. Wolgemuth
  • Patent number: 4137081
    Abstract: It has been found that excellent quality photopolymer printing plates having hardness, flexibility, resilience, abrasion resistance and resistance to alcohol-based inks can be prepared from photopolymer compositions comprising a liquid polymer containing at least two terminal olefin groups attached to the polymer through a combination of at least two ether, thioether, ester, keto or amide groups, from about 1 to about 50% by weight based on the polymer of at least one ethylenically unsaturated monomer, from about 0.1 to about 10% by weight of a photoinitiator and about 0.01 to about 2% of a stabilizer.
    Type: Grant
    Filed: June 27, 1977
    Date of Patent: January 30, 1979
    Assignee: Hercules Incorporated
    Inventor: Rudolph L. Pohl
  • Patent number: 4128510
    Abstract: Halogen-containing polymers can be crosslinked by heating with certain derivatives of 2,5-dimercapto-1,3,4-thiadiazole, such as the monobenzoate derivative, and a basic material to produce useful vulcanizates of increased strength and insolubility in organic solvents. Concentrates of the derivatives of 2,5-dimercapto-1,3,4-thiadiazole may be prepared by incorporating the thiadiazole in a binder material such as a polymer, wax, rosin, etc. for subsequent compounding with the halogen-containing polymer to be crosslinked.
    Type: Grant
    Filed: April 18, 1977
    Date of Patent: December 5, 1978
    Assignee: Hercules Incorporated
    Inventor: John R. Richwine
  • Patent number: 4109006
    Abstract: 1,4-Dithiinoxides which may be substituted with various radicals, compositions containing said products and methods useful in the treatment of ulcers are disclosed. The products are prepared by oxidation of the correspondingly substituted dithiin.
    Type: Grant
    Filed: October 12, 1976
    Date of Patent: August 22, 1978
    Assignee: Warren-Teed Laboratories, Inc.
    Inventors: Richard C. Johnson, Peter L. DEBenneville
  • Patent number: 4094988
    Abstract: 5,6-Dihydro-1,4-dithiinoxides, compositions containing the 5,6-dihydro-1,4-dithiinoxides as their active ingredient and methods useful in the treatment of gastric ulcers are disclosed.
    Type: Grant
    Filed: October 12, 1976
    Date of Patent: June 13, 1978
    Assignee: Warren-Teed Laboratories, Inc.
    Inventor: Richard C. Johnson
  • Patent number: 4082730
    Abstract: Novel resins, useful as strengthening resins for imparting dry and temporary wet strength to paper, are disclosed. The resins are prepared by reacting branched water-soluble poly(.beta.-alanine) with glyoxal.
    Type: Grant
    Filed: January 21, 1976
    Date of Patent: April 4, 1978
    Assignee: Hercules Incorporated
    Inventor: Terence W. Rave
  • Patent number: 4079044
    Abstract: Novel resins, useful as strengthening resins for imparting dry and temporary wet strength to paper, are disclosed. The resins are prepared by reacting branched water-soluble poly(.beta.-alanine) with glyoxal.
    Type: Grant
    Filed: November 17, 1975
    Date of Patent: March 14, 1978
    Assignee: Hercules Incorporated
    Inventor: Terence W. Rave
  • Patent number: 4079043
    Abstract: Novel resins, useful as strengthening resins for imparting dry and temporary wet strength to paper, are disclosed. The resins are prepared by reacting branched water-soluble poly(beta-alanine) with glyoxal.
    Type: Grant
    Filed: February 12, 1976
    Date of Patent: March 14, 1978
    Assignee: Hercules Incorporated
    Inventor: Terence W. Rave
  • Patent number: 4079133
    Abstract: The administration of hyodeoxycholic acid (HDCA) with chenodeoxycholic acid (CDCA) effects a lowering of serum glutamic-oxaloacetic transaminase, serum glutamic-pyruvate transaminase and alkaline phosphatase in the blood relative to the administration of CDCA alone.
    Type: Grant
    Filed: February 6, 1976
    Date of Patent: March 14, 1978
    Assignee: Warren-Teed Laboratories, Inc.
    Inventors: David T. Drees, Anthony R. Imondi
  • Patent number: 4047963
    Abstract: It has been found that printing elements can be prepared from a water-soluble photopolymer composition comprising (1) a water-soluble thermoplastic ethylene oxide copolymer containing 50-96% ethylene oxide, (2) from about 0.5 to about 25% by weight based on the ethylene oxide copolymer of an ethylenically unsaturated monomer having its unsaturation in the form of at least two ##STR1## groups, wherein R is hydrogen or a C.sub.1 -C.sub.3 alkyl group, and (3) from about 0.1 to about 10% by weight based on the ethylene oxide copolymer of a photoinitiator thermally stable at temperatures up to about 150.degree. C. The above described photopolymer composition can be thermoformed, such as by extrusion or compression molding.
    Type: Grant
    Filed: June 17, 1976
    Date of Patent: September 13, 1977
    Assignee: Hercules Incorporated
    Inventor: David A. Simpson
  • Patent number: 4038253
    Abstract: It has been found that certain polymers containing pendant diazo ester groups are photosensitive and have utility in the preparation of both lithographic and relief printing plates, as well as for etching resists for printed circuits. This is a continuation of application Ser. No. 412,218, filed Nov. 2, 1973 now abandoned.
    Type: Grant
    Filed: June 2, 1976
    Date of Patent: July 26, 1977
    Assignee: Hercules Incorporated
    Inventor: Brian D. Kramer