Patents Represented by Attorney Patrick J. Span
  • Patent number: 4252734
    Abstract: The present invention deals with unique substituted ammonium compounds for use in cationic electrodeposition processes.
    Type: Grant
    Filed: July 27, 1979
    Date of Patent: February 24, 1981
    Assignee: Henkel Corporation
    Inventors: Richard Barry, Don E. Floyd
  • Patent number: 4252731
    Abstract: The present invention describes a process for converting the amides of certain steroids to the corresponding carbamates of the steroid.
    Type: Grant
    Filed: February 19, 1980
    Date of Patent: February 24, 1981
    Assignee: Henkel Corporation
    Inventor: Leroy O. Krbechek
  • Patent number: 4252959
    Abstract: Certain sulfonylhydrazines, metal complexes thereof and solutions of said compounds in essentially water-immiscible, liquid hydrocarbon solvents are disclosed. The sulfonylhydrazines have the general structural formula:R--SO.sub.2 NHNH--R.sub.1wherein R and R.sub.1 are as defined in the specification and claims hereof. Particular metal values are recovered from their aqueous solutions by using sulfonylhydrazines dissolved in essentially water-immiscible, liquid hydrocarbon solvents. The extraction process involves contacting the metal value containing aqueous solution with the solution of the sulfonylhydrazines in essentially water-immiscible, liquid hydrocarbon solvent and stripping the metal from the loaded organic phase.
    Type: Grant
    Filed: June 28, 1979
    Date of Patent: February 24, 1981
    Assignee: Henkel Corporation
    Inventor: Ernest Spitzner
  • Patent number: 4252730
    Abstract: The present invention describes a process for converting the carbamate of a steroidal amino compound to the corresponding hydrohalide.
    Type: Grant
    Filed: February 19, 1980
    Date of Patent: February 24, 1981
    Assignee: Henkel Corporation
    Inventor: Leroy O. Krbechek
  • Patent number: 4252732
    Abstract: The present invention describes the conversion of steroids having a 20-amino functionality to progesterone and other useful steroids.
    Type: Grant
    Filed: February 19, 1980
    Date of Patent: February 24, 1981
    Assignee: Henkel Corporation
    Inventors: Leroy O. Krbechek, Ernest B. Spitzner, James P. Clark
  • Patent number: 4251450
    Abstract: The present invention describes the transhalogenation of amido compounds to obtain the corresponding N-haloamide through the use of an N-haloimide.
    Type: Grant
    Filed: February 19, 1980
    Date of Patent: February 17, 1981
    Assignee: Henkel Corporation
    Inventor: Leroy O. Krbechek
  • Patent number: 4251664
    Abstract: Certain sulfonamidothiadiazoles, metal complexes thereof and solutions of said compounds in essentially water-immiscible, liquid hydrocarbon solvents are disclosed. The sulfonamidothiadiazoles have the general structural formula: ##STR1## wherein R and A are as defined in the specification and claims hereof. Particular metal values are recovered from their aqueous solutions by using sulfonamidothiadiazoles dissolved in essentially water-immiscible, liquid hydrocarbon solvents. The extraction process involves contacting the metal value containing aqueous solution with the solution of the sulfonamidothiadiazole in essentially water-immiscible, liquid hydrocarbon solvent and stripping the metal from the loaded organic phase.
    Type: Grant
    Filed: May 24, 1978
    Date of Patent: February 17, 1981
    Assignee: Henkel Corporation
    Inventor: Ernest B. Spitzner
  • Patent number: 4247578
    Abstract: Curable resin compositions are prepared containing a radiation-sensitive reactive diluent and a saturated polyol. Curing is accomplished by mixing the reactive diluent and the polyol with a polyisocyanate, followed by exposure of the resultant composition to radiation to polymerize the reactive diluent and then, by thermal curing, to form the hydroxyisocyanate (urethane) linkage. The fully cured resin composition is described as interpenetrated or one in which there is no cross-linking between the reactive diluent and urethane linked co-polymer. The interpenetrated resin compositions form tough and hard coatings on various substrates.
    Type: Grant
    Filed: September 25, 1978
    Date of Patent: January 27, 1981
    Assignee: Henkel Corporation
    Inventors: Earl Skinner, Marvin Emeott, Allan Jevne
  • Patent number: 4243818
    Abstract: The present invention describes the production of high molecular weight unsaturated esters of polyhydric alcohols and their derivatives.
    Type: Grant
    Filed: October 4, 1979
    Date of Patent: January 6, 1981
    Assignee: Henkel Corporation
    Inventor: Edgar R. Rogier
  • Patent number: 4239699
    Abstract: Certain sulfonamidophenols, metal complexes thereof and solutions of said compounds in essentially water-immiscible, liquid hydrocarbon solvents are disclosed. The sulfonamidophenols have the structural formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as defined in the specification and claims hereof. Particular metal values are recovered from their aqueous solutions by using sulfonamidophenols dissolved in essentially water-immiscible liquid hydrocarbon solvents. The extraction process involves contacting the metal value containing aqueous solution with the solution of sulfonamidophenol in essentially water-immiscible liquid hydrocarbon solvent and stripping the metal values from the loaded organic phase.
    Type: Grant
    Filed: May 24, 1978
    Date of Patent: December 16, 1980
    Assignee: Henkel Corporation
    Inventor: Kenneth D. MacKay
  • Patent number: 4237062
    Abstract: Certain sulfonylthiosemicarbazides, metal complexes thereof and solutions of said compounds in essentially water-immiscible, liquid hydrocarbon solvents are disclosed. The sulfonylthiosemicarbazides have the general structural formula: ##STR1## wherein R and R.sup.1 are as defined in the specification and claims hereof. Particular metal values are recovered from their aqueous solutions by using sulfonylthiosemicarbazides dissolved in essentially water-immiscible, liquid hydrocarbon solvents. The extraction process involves contacting the metal value containing aqueous solution with the solution of the sulfonylthiosemicarbazide in essentially water-immiscible, liquid hydrocarbon solvent and stripping the metal from the loaded organic phase.
    Type: Grant
    Filed: May 21, 1979
    Date of Patent: December 2, 1980
    Assignee: Henkel Corporation
    Inventor: Ernest B. Spitzner
  • Patent number: 4217256
    Abstract: There is disclosed a polyamide adhesive for bonding fabrics, particularly fusible interliners for fabrics, which are cleanable by laundering and/or dry cleaning. The polyamide adhesive is a terpolyamide of caprolactam and hexamethylene diamine with a mixture of polymeric fat acids and an aliphatic co-dicarboxylic acid having 20-22 carbon atoms.
    Type: Grant
    Filed: August 31, 1978
    Date of Patent: August 12, 1980
    Assignee: Henkel Corporation
    Inventors: Dwight E. Peerman, H. Gordon Kanten
  • Patent number: 4216344
    Abstract: The present invention describes the production of high molecular weight polyhydric alcohols and their derivatives. In particular the urethane reaction products of polyisocyantes and polyhydric alcohols are described.
    Type: Grant
    Filed: April 4, 1979
    Date of Patent: August 5, 1980
    Assignee: Henkel Corporation
    Inventor: Edgar R. Rogier
  • Patent number: 4216343
    Abstract: The present invention describes the production of high molecular weight polyhydric alcohols and their derivatives. In particular the urethane reaction products of polyisocyantes and polyhydric alcohols are described.
    Type: Grant
    Filed: April 4, 1979
    Date of Patent: August 5, 1980
    Assignee: Henkel Corporation
    Inventor: Edgar R. Rogier
  • Patent number: 4210759
    Abstract: Certain sulfonamido pyridines, pyrimidines, benzothiazoles and oxazoles, metal complexes thereof and solutions of said compounds in essentially water-immiscible, liquid hydrocarbon solvents are disclosed. The sulfonamide compounds have the structural formula: ##STR1## wherein R, R.sub.1, R.sub.2 and R.sub.3 are as defined in the specification and claims hereof. Particular metal values are recovered from their aqueous solutions by using heterocyclic sulfonamide compounds dissolved in essentially water-immiscible, liquid hydrocarbon solvents. The extraction process generally comprises contacting the metal value containing aqueous solution with the solution of the sulfonamide compound in an essentially water-immiscible liquid hydrocarbon solvent and stripping the metal values from the loaded organic phase.
    Type: Grant
    Filed: May 24, 1978
    Date of Patent: July 1, 1980
    Assignee: Henkel Corporation
    Inventor: Michael J. Virnig
  • Patent number: 4209419
    Abstract: Certain sulfonamidoquinolines and metal complexes thereof both of which are soluble in essentially water-immiscible organic solvents. The sulfonamidoquinolines have the structural formula ##STR1## where the R, R.sup.1 and R.sup.2 groups and m and n are as defined in the specification and claims hereof. Solutions of the sulfonamidoquinolines and the metal complexes thereof in essentially water-immiscible organic solvents.
    Type: Grant
    Filed: October 19, 1977
    Date of Patent: June 24, 1980
    Assignee: Henkel Corporation
    Inventor: Michael J. Virnig
  • Patent number: 4195152
    Abstract: There is disclosed a class of N-alkylpolyamines and their use as curing agents for epoxy resins, and in particular to such polyamines having the formula R--[NH(CH.sub.2).sub.x ].sub.y --NHR' where R is an aliphatic hydrocarbon radical having from 5 through 8 carbon atoms, R' is H, R or R", x is an integer of 2 or 3 and y is an integer of 2-4. A monoepoxide adduct of the monoalkyl substituted polyamine is also disclosed wherein R" may then become an aliphatic substituent (2-14 carbon atoms) which may contain (a) an oxygen atom, (b) a hydroxyl group or (c) an aromatic substituent such as a phenyl ring.
    Type: Grant
    Filed: July 20, 1978
    Date of Patent: March 25, 1980
    Assignee: Henkel Corporation
    Inventor: Don E. Floyd
  • Patent number: 4180487
    Abstract: The present invention describes epoxy curable polyamine resin compositions.
    Type: Grant
    Filed: May 4, 1978
    Date of Patent: December 25, 1979
    Assignee: Henkel Corporation
    Inventor: Don E. Floyd
  • Patent number: 4175012
    Abstract: New .beta.-diketones of the structure ##STR1## where R is phenyl or alkyl substituted phenyl, R' is alkyl, alkyl substituted phenyl or chloro substituted phenyl and R" is H or --CN with the provisos that; (1) when R is phenyl, R' is a branched chain alkyl group of at least seven carbon atoms and (2) when R is alkyl substituted phenyl, the number of carbon atoms in the alkyl substituent or substituents is at least 7 and at least one such alkyl substituent is branched chain. Process of recovering copper and nickel from their aqueous solutions by the use of the new .beta.-diketones.
    Type: Grant
    Filed: December 15, 1975
    Date of Patent: November 20, 1979
    Assignee: Henkel Corporation
    Inventors: Kenneth D. MacKay, Edgar R. Rogier
  • Patent number: 4172736
    Abstract: Thickening of "cellulose reactive dyes" with carboxyethyl guar.
    Type: Grant
    Filed: February 17, 1978
    Date of Patent: October 30, 1979
    Assignee: Henkel Corporation
    Inventors: William H. Minkema, Gerald J. Shelso