Patents Represented by Attorney Patrick J. Span
  • Patent number: 4171317
    Abstract: The present invention relates to the conversion of 20-methylpregna-3,5,20(21)-triene-3,21-diol-diacetate to 3-oxo-20-methylpregna-4,20(21)-diene-21-yl-acetate through the use of a halogenated solvent and a halogenated acid. The benefits of the present invention include a substantial increase in the production of progesterone via ozonolysis technology.
    Type: Grant
    Filed: March 27, 1978
    Date of Patent: October 16, 1979
    Assignee: Henkel Corporation
    Inventor: LeRoy O. Krbechek
  • Patent number: 4159260
    Abstract: A blend of hydrolyzed polyacrylonitrile-starch graft copolymer and a fatty quaternary ammonium chloride which exhibits good wicking and dispersing properties.
    Type: Grant
    Filed: November 23, 1977
    Date of Patent: June 26, 1979
    Assignee: Henkel Corporation
    Inventors: Duane A. Jones, Lyle F. Elmquist
  • Patent number: 4156664
    Abstract: Film forming starch-hydrolyzed polyacrylonitrile graft copolymer and latex composition.
    Type: Grant
    Filed: January 31, 1978
    Date of Patent: May 29, 1979
    Assignee: Henkel Corporation
    Inventors: Earl L. Skinner, Lyle F. Elmquist
  • Patent number: 4156095
    Abstract: A method of preparing a C.sub.21 dicarboxylic acid using crystalline clay as a catalyst.
    Type: Grant
    Filed: October 31, 1977
    Date of Patent: May 22, 1979
    Assignee: Henkel Corporation
    Inventors: Allan H. Jevne, Gerald L. Schwebke
  • Patent number: 4152396
    Abstract: Process for treating aqueous acidic solutions of cobalt and nickel values using certain fluorinated .beta.-diketones wherein the cobalt values are preferentially stripped from the loaded organic phase. Variations include preferential extraction of cobalt values, recovery of nickel from the raffinate and a second stripping step to recover nickel from the loaded organic.
    Type: Grant
    Filed: November 21, 1975
    Date of Patent: May 1, 1979
    Assignee: Henkel Corporation
    Inventors: Kenneth D. MacKay, John P. McDonald
  • Patent number: 4141747
    Abstract: A large granule starch protective material for pressure sensitive microencapsulated coatings, particularly carbonless copy duplicating paper. A previously dried cereal starch selected from the group consisting of wheat, barley and rye is subjected to wet process separation to obtain a large granule starch from the starching starch, which has a characteristic particle size distribution including smaller granules ranging in size from 2 microns to about 16 microns, and a second group of larger granules, mostly ranging in size from 16 microns to about 35 microns.
    Type: Grant
    Filed: August 4, 1977
    Date of Patent: February 27, 1979
    Assignee: General Mills Chemicals, Inc.
    Inventor: Roland W. Best
  • Patent number: 4139505
    Abstract: Enlarged granule starch useful as a protective stilt material in microencapsulated coatings to prevent premature rupture of the microcapsules. Starch granules are increased in size by alkali-swelling of the granules in aqueous slurry. The enlarged granules are then crosslinked to aid in preserving the enlarged granular form through subsequent aqueous coating applications and thermal drying steps. A combination of hydrocyclone starch granule sizing and granule treatment employing alkali-swelling and crosslinking substantially improves the yield of usable large granule stilt materials obtainable from prime grade wheat starch, and other bimodal granular starches such as barley and rye.
    Type: Grant
    Filed: November 4, 1977
    Date of Patent: February 13, 1979
    Assignee: General Mills Chemicals, Inc.
    Inventors: Saul Rogols, John W. Salter
  • Patent number: 4128600
    Abstract: Curable resin compositions are prepared containing a radiation-sensitive reactive diluent and a saturated polyol. Curing is accomplished by mixing the reactive diluent and the polyol with a polyisocyanate, followed by exposure of the resultant composition to radiation to polymerize the reactive diluent and then, by thermal curing, to form the hydroxyisocyanate (urethane) linkage. The fully cured resin composition is described as interpenetrated or one in which there is no cross-linking between the reactive diluent and urethane linked co-polymer. The interpenetrated resin compositions form tough and hard coatings on various substrates.
    Type: Grant
    Filed: January 14, 1977
    Date of Patent: December 5, 1978
    Assignee: General Mills Chemicals, Inc.
    Inventors: Earl Skinner, Marvin Emeott, Allan Jevne
  • Patent number: 4128493
    Abstract: Process of extracting metals using organic solvent solutions of salts of hydrogen ion exchange agents and quaternary ammonium compounds. Organic solvent solutions of such quaternary ammonium salts of hydrogen ion exchange agents.
    Type: Grant
    Filed: August 8, 1977
    Date of Patent: December 5, 1978
    Assignee: General Mills Chemicals, Inc.
    Inventors: Kenneth D. MacKay, Edgar R. Rogier
  • Patent number: 4128631
    Abstract: This invention relates to a method of imparting a highly lubricated feel to keratinous substrates such as skin or hair or upon mucous membranes. The method is useful in obtaining the desired effect from diverse personal care products as hand and body creams, soap bars, suntan lotion, pre-electric shave skin conditioners, after shave lotions, lip balms, cold creams, bubble baths, cleansing and lotion pads, douches and vaginal lubricants.
    Type: Grant
    Filed: February 16, 1977
    Date of Patent: December 5, 1978
    Assignee: General Mills Chemicals, Inc.
    Inventors: Larry D. Lundmark, Allan Melby, Ho-Ming Chun
  • Patent number: 4126640
    Abstract: There is disclosed a class of N-alkylpolyamines and their use as curing agents for epoxy resins, and in particular to such polyamines having the formula R--[NH(CH.sub.2).sub.x ].sub.y --NHR' where R is an aliphatic hydrocarbon radical having from 5 through 8 carbon atoms, R' is H, R or R", x is an integer of 2 or 3 and y is an integer of 2-4. A monoepoxide adduct of the monoalkyl substituted polyamine is also disclosed wherein R" may then become an aliphatic substituent (2-14 carbon atoms) which may contain (a) an oxygen atom, (b) a hydroxyl group or (c) an aromatic substituent such as a phenyl ring.
    Type: Grant
    Filed: August 1, 1977
    Date of Patent: November 21, 1978
    Assignee: General Mills Chemicals, Inc.
    Inventor: Don E. Floyd
  • Patent number: 4123397
    Abstract: A method of agglomerating and desolventizing starch-hydrolyzed polyacrylonitrile graft copolymer using atomized, liquid water.
    Type: Grant
    Filed: June 15, 1977
    Date of Patent: October 31, 1978
    Assignee: General Mills Chemicals, Inc.
    Inventor: Duane A. Jones
  • Patent number: 4100163
    Abstract: Certain sulfonamidoquinolines and metal complexes thereof both of which are soluble in essentially water-immiscible organic solvents. The sulfonamidoquinolines have the structural formula ##STR1## where the R, R.sup.1 and R.sup.2 groups and m and n are as defined in the specification and claims hereof. Solutions of the sulfonamidoquinolines and the metal complexes thereof in essentially water-immiscible organic solvents.
    Type: Grant
    Filed: January 26, 1976
    Date of Patent: July 11, 1978
    Assignee: General Mills Chemicals, Inc.
    Inventor: Michael J. Virnig
  • Patent number: 4071467
    Abstract: Self-complexing galactomannan gum blends which exhibit delayed gelling at acidic pH levels.
    Type: Grant
    Filed: November 1, 1976
    Date of Patent: January 31, 1978
    Assignee: General Mills Chemicals, Inc.
    Inventor: Robert Nordgren
  • Patent number: 4065422
    Abstract: This invention relates to compositions which may be used on keratinous substrates such as skin or hair or upon mucous membranes to impart a highly lubricated feel thereon. Such compositions have utility in diverse personal care products as hand and body creams, soap bars, suntan lotion, preelectric shave skin conditioners, after shave lotions, lip balms, cold creams, bubble baths, cleansing and lotion pads, and household cleaning products as well as many other similar compositions.
    Type: Grant
    Filed: February 16, 1977
    Date of Patent: December 27, 1977
    Assignee: General Mills Chemicals, Inc.
    Inventors: Larry D. Lundmark, Allan Melby, Ho-ming Chun
  • Patent number: 4065627
    Abstract: High molecular weight radiation curable ester-diethers, ester-monoethers and their diisocyanate derivatives.
    Type: Grant
    Filed: September 27, 1976
    Date of Patent: December 27, 1977
    Assignee: General Mills Chemicals, Inc.
    Inventor: Stuart A. Harrison
  • Patent number: 4065502
    Abstract: New .beta.-diketones of the structure ##STR1## where R is phenyl or alkyl substituted phenyl, R' is alkyl, alkyl substituted phenyl or chloro substituted phenyl and R" is H or --CN with the provisos that; (1) when R is phenyl, R' is a branched chain alkyl group of at least seven carbon atoms and (2) when R is alkyl substituted phenyl, the number of carbon atoms in the alkyl substituent or substituents is at least 7 and at least one such alkyl substituent is branched chain. Process of recovering copper and nickel from their aqueous solutions by the use of the new .beta.-diketones.
    Type: Grant
    Filed: December 1, 1975
    Date of Patent: December 27, 1977
    Assignee: General Mills Chemicals, Inc.
    Inventors: Kenneth D. MacKay, Edgar R. Rogier
  • Patent number: 4065455
    Abstract: Compounds of the structure ##STR1## where X is Cl or Br, R is a branched chain alkyl or alkenylradical containing about 8 to 20 carbon atoms and R.sub.1, R.sub.2 and R.sub.3 are hydrogen or alkyl groups of 1 to 4 carbon atoms. The new compounds find use in extraction of metals.
    Type: Grant
    Filed: March 4, 1974
    Date of Patent: December 27, 1977
    Assignee: General Mills Chemicals, Inc.
    Inventor: Phillip L. Mattison
  • Patent number: 4060507
    Abstract: Disclosed are novel aminopolyamide-acrylamide-glyoxal resins useful as a sizing agent for paper having low water absorption, a desirable property for sized paper. The products are water dispersible and/or soluble and also find utility in printing inks, textile treatment and cosmetic or beauty aid compositions. The aminopolyamide is the condensation product of a polymeric fat acid and polyalkylene polyamine.
    Type: Grant
    Filed: August 1, 1975
    Date of Patent: November 29, 1977
    Assignee: General Mills Chemicals, Inc.
    Inventors: Don E. Floyd, Demetri Potente
  • Patent number: 4058585
    Abstract: Process of extracting metals using organic solvent solutions of salts of hydrogen ion exchange agents and quaternary ammonium compounds. Organic solvent solutions of such quaternary ammonium salts of hydrogen ion exchange agents.
    Type: Grant
    Filed: November 10, 1975
    Date of Patent: November 15, 1977
    Assignee: General Mills Chemicals, Inc.
    Inventors: Kenneth D. MacKay, Edgar R. Rogier