Abstract: A method of fabricating a metal-oxide-metal (MOM) capacitor, comprising the following steps. A bottom metal layer is deposited. A high dielectric constant oxide insulator is deposited layer over the bottom metal layer. The structure is annealed in an oxidizing ambient to cause the exposed bottom metal to form a metal oxide partially filling the one or more pin hole defects to repair those pin hole defects. An upper oxide conductor layer is then deposited over the high dielectric constant oxide insulator layer. An upper metal layer is deposited over said upper oxide conductor layer.

Abstract: A method of forming interconnect structures in a semiconductor device, comprising the following steps. A semiconductor structure is provided. In the first embodiment, at least one metal line is formed over the semiconductor structure. A silicon-rich carbide barrier layer is formed over the metal line and semiconductor structure. Finally, a dielectric layer, that may be fluorinated, is formed over the silicon-rich carbide layer. In the second embodiment, at least one fluorinated dielectric layer, that may be fluorinated, is formed over the semiconductor structure. The dielectric layer is patterned to form an opening therein. A silicon-rich carbide barrier layer is formed within the opening. A metallization layer is deposited over the structure, filling the silicon-rich carbide barrier layer lined opening. Finally, the metallization layer may be planarized to form a planarized metal structure within the silicon-rich carbide barrier layer lined opening.

Abstract: A method for forming dual-damascene type conducting interconnects with non-metallic barriers that protect said interconnects from fluorine out-diffusion from surrounding low-k, fluorinated dielectric materials. One embodiment of the method is particularly suited for forming such interconnects in microelectronics fabrications of the sub 0.15 micron generation.

Abstract: A method for shallow trench isolation formation having a thick un-biased HDP USG liner layer to reduce HDP-CVD induced defects is described. Trenches are etched through an etch stop layer into a semiconductor substrate. The semiconductor substrate is thermally oxidized to form a thermal liner layer within the isolation trenches. The isolation trenches are filled using a high density plasma chemical vapor deposition process (HDP-CVD) having a deposition component and a sputtering component wherein the HDP-CVD process comprises: first depositing a first liner layer overlying the thermal liner layer wherein no bias power is supplied during the first depositing step and wherein the first liner layer has a thickness of between 200 and 400 Angstroms, second depositing a second liner layer using low bias power, and third depositing a gap filling layer overlying the second liner layer to fill the isolation trenches. The gap filling layer is polished back overlying the etch stop layer.

Abstract: A method of forming a boron carbide layer for use as a barrier and an etch-stop layer in a copper dual damascene structure, and the structure itself are disclosed. In addition to providing a good barrier to copper diffusion, good insulating properties, high etch selectivity with respect to dielectric insulators, boron carbide also provides good electrical characteristics because of its low dielectric constant of less than 5. The amorphous boron carbide is formed in a PECVD chamber by introducing a boron source gas such as B2H6, B5H9+, and carbon source gas such as CH4 and C2H6 at a deposition temperature of about 400° C. Any one, or any combination of the passivation, etch-stop, cap layers of the damascene structure can comprise boron carbide.

Abstract: An endpoint detection system for copper stripping using a colorimetric analysis of the change in concentration of a component is described. Wet copper stripping chemicals are used to strip copper from a wafer whereby an eluent is produced. The eluent is continuously analyzed by colorimetric analysis for the presence of copper. The copper stripping process is stopped when the presence of copper is no longer detected. Also novel compounds or chemicals for use in an endpoint detection system for copper stripping using a colorimetric analysis of the change in concentration of the novel compounds or chemicals are described. A composition of matter that serves as an indicator of the presence of copper by colorimetric analysis comprises: 1) Fast Sulphon Black F indicator and an ammonium ion-containing solution or 2) a complexing agent, comprising a diamine, an amine macrocycle, or a monoamine.

Abstract: A new process for fabricating an alternating phase-shifting photomask having an alignment monitor is described. An opaque layer is provided overlying a substrate. The opaque layer is patterned to provide a mask pattern. A phase-shifting pattern is formed on the substrate wherein a portion of the phase-shifting pattern comprises an alignment monitor whereby alignment between the mask pattern and the phase-shifting pattern can be tested.

Abstract: A method of forming a conductive cap layer over a metal bonding pad comprises the following steps. A semiconductor structure is provided having an exposed, recessed metal bonding pad within a layer opening. The layer has an upper surface. The exposed metal bonding pad is treated with a solution containing soluble metal ions to form a conductive cap over the metal bonding pad. The conductive cap layer is comprised of the solution metal and has a predetermined thickness. An external bonding element may then be bonded to the conductive cap, forming an electrical connection with the metal bonding pad.

Abstract: A novel structured for a diode-like PID protection (DLPP) device structure and process are described. An N-well, three associate N+ regions and a P+ region are formed on a P substrate. The DLPP is structured as a butting diode with a polysilicon gate above the butting region. The gate is connected to a metal antenna element and to the zener like trigger element of the device. The N-well functions as a resistor and capacitor buffer between the poly gate and antenna and the substrate. The antenna picks up a portion of the plasma charge to provide a gate voltage. There is an inversion layer or accumulation layer for positive or negative plasma charge formed under the poly gate. The junction of the effective zener diode is found in the interface between the N-type inversion layer and P+, or N+ and P-type accumulation layer. Changing the shape and the size of the antenna changes the gate voltage, and subsequently the trigger voltage of the DLPP.

Abstract: A new method of etching metal lines using fluorine-doped silicate glass as a hard mask is described. Semiconductor device structures are provided in and on a semiconductor substrate. The semiconductor device structures are covered with an insulating layer. A metal layer is deposited overlying the insulating layer. A layer of fluorine-doped silicate glass is deposited overlying the metal layer wherein the fluorine-doped silicate glass layer acts as a hard mask. The hard mask is covered with a layer of photoresist. The photoresist layer is exposed to actinic light and developed and patterned to form the desired photoresist mask. The hard mask is etched away where it is not covered by the photoresist mask leaving a patterned hard mask.

Abstract: A method for forming a transistor having low overlap capacitance by forming a microtrench at the gate edge to reduce effective dielectric constant is described. A gate electrode is provided overlying a gate dielectric layer on a substrate and having a hard mask layer thereover. An oxide layer is formed overlying the substrate. First spacers are formed on sidewalls of the gate electrode and overlying the oxide layer. Source/drain extensions are implanted. Second spacers are formed on the first spacers. Source/drain regions are implanted. A dielectric layer is deposited overlying the gate electrode and the oxide layer and planarized to the hard mask layer whereby the first and second spacers are exposed. The exposed second spacers and underlying oxide layer are removed. The exposed substrate underlying the second spacers is etched into to form a microtrench undercutting the gate oxide layer at an edge of the gate electrode.

Abstract: A method of stably and uniformly erasing a non-volatile memory or memory array in a gate insulator in which carrier-trapping sites for carrier storage are furnished is described. A first method of the invention is the application of a discharge pulse(s) to a gate after erasure where the discharge pulse(s) discharges unstable holes injected into the gate insulator. A second method of the invention is injection of electrons into the trap sites of all the cells in a memory array to be erased before erasure. This makes Vth distribution across the memory array uniform after erasure. A third method of the invention is a reduced bias approach to erase stably the electrons stored in the trap sites. This includes not only literally “erase,” but also “annihilate or neutralize” trapped electron charge by hole charge.

Abstract: A method for a self aligned TX with elevated source/drain (S/D) regions on an insulated layer (oxide) by forming a trench along side the STI and filling the trench with oxide. STI regions are formed in a substrate. A gate structure is formed. LDD regions are formed adjacent to the gate structure in the substrate. Spacers are formed on the sidewall of the gate structure. We etch S/D trenches between the STI regions and the first spacers. The S/D trenches are filled with a S/D insulating layer. Elevated S/D regions are formed over the S/D insulating layer and the LDD regions. A top isolation layer is formed over the STI regions. The invention builds the raised source/drain (S/D) regions on an insulating layer and reduces junction leakage and hot carrier degradation to gate oxide.

Abstract: A method of bonding a bonding element to a metal bonding pad, comprising the following steps. A semiconductor structure having an exposed metal bonding pad within a passivation layer opening is provided. The bonding pad has an upper surface. A bonding element is positioned to contact the bonding pad upper surface. A bonding solution is applied within the passivation layer opening, covering the bonding pad and a portion of the bonding element. The structure is annealed by heating said bonding element to selectively solidify the bonding solution proximate said contact of said bonding element to said bonding pad, bonding the bonding element to the bonding pad.

Abstract: A new method for forming a dual-metal gate CMOS transistors is described. An NMOS and a PMOS active area of a semiconductor substrate are separated by isolation regions. A nitride layer is deposited overlying a gate dielectric layer and patterned to form a first dummy gate in each of the active areas. First ions are implanted to form source/drain regions in each of the active areas not covered by the first dummy gates. The first dummy gates are isotropically etched to form second dummy gates thinner than the first dummy gates. Second ions are implanted to form lightly doped source/drain regions in each of the active areas not covered by the second dummy gates. Dielectric spacers are formed on sidewalls of the second dummy gates and the source/drain regions are silicided. A dielectric layer is deposited and planarized to the second dummy gates. Thereafter, the second dummy gates are removed, leaving gate openings in the dielectric layer. A mask is formed over the PMOS active area.

Abstract: A method for forming a void-free epitaxial cobalt silicide (CoSi2) layer on an ultra-shallow source/drain junction. A patterned silicon structure is cleaned using HF. A first titanium layer, a cobalt layer, and a second titanium layer are successively formed on the patterned silicon substrate. The patterned silicon substrate is annealed at a temperature of between about 550° C. and 580° C. in a nitrogen ambient at atmospheric pressure; whereby the cobalt migrates downward and reacts with the silicon structure to form a CoSi2/CoSi layer, and the first titanium layer migrates upward and the first titanium layer and the second titanium layer react with the nitrigen ambient to form TiN. The TiN and unreacted cobalt are removed. The silicon structure is annealed at a temperature of between about 825° C. and 875° C. to convert the CoSi2/CoSi layer to a CoSi2 layer. The CoSi2 layer can optionally be implanted with impurity ions which are subsequently diffused to form ultra-shallow junctions.

Abstract: A method for forming a CMOS transistor gate with a self-aligned channel implant. A semiconductor structure having a first active area is provided. A first insulating layer is formed on the semiconductor structure, and a second insulating layer is formed on the first insulating layer. The second insulating layer is patterned using a poly reverse mask and an etch selective to the first insulating layer to form a first channel implant opening, and the poly reverse mask is removed. A first channel implant mask is formed exposing the first channel implant opening. Impurity ions are implanted through the first channel implant opening to form a first threshold adjust region and a first anti-punchthrough region. A gate layer is formed over the semiconductor structure, and the first gate layer is planarized to form a gate electrode. The second insulating layer is removed, and lightly doped source and drain regions, sidewall spacers and source and drain regions can be formed adjacent the gate electrode.

Abstract: A method of manufacturing a shallow trench isolation (STI) with an air gap that is formed by decomposing an organic filler material through a cap layer. A pad layer and a barrier layer are formed over the substrate. The pad layer and the barrier layer are patterned to form a trench opening. We form a trench in substrate by etching through the trench opening. A first liner layer is formed on the sidewalls of the trench. A second liner layer over the barrier layer and the first liner layer. A filler material is formed on the second liner layer to fill the trench. In an important step, a cap layer is deposited over the filler material and the second liner layer. The filler material is subjected to a plasma and heated to vaporize the filler material so that the filler material diffuses through the cap layer to form a gap. An insulating layer is deposited over the cap layer. The insulating layer is planarized. The barrier layer is removed.

Abstract: A method for forming a gate dielectric having regions with different dielectric constants. A dummy dielectric layer is formed over a semiconductor structure. The dummy dielectric layer is patterned to form a gate opening. A high-K dielectric layer is formed over the dummy dielectric and in the gate opening. A low-K dielectric layer is formed on the high-K dielectric layer. Spacers are formed on the low-K dielectric layer at the edges of the gate opening. The low-K dielectric layer is removed from the bottom of the gate opening between the spacers. The spacers are removed to form a stepped gate opening. The stepped gate opening has both a high-K dielectric layer and a low-K dielectric layer on the sidewalls and at the edges of the bottom of the gate opening and only a high-k dielectric layer in the center of the bottom of the stepped gate opening. A gate electrode is formed in the stepped gate opening.

Abstract: A method for forming an electrostatic discharge device using silicon-on-insulator technology is described. An N-well is formed within a silicon semiconductor substrate. A P+ region is implanted within a portion of the N-well and an N+ region is implanted within a portion of the semiconductor substrate not occupied by the N-well. An oxide layer is formed overlying the semiconductor substrate and patterned to form openings to the semiconductor substrate. An epitaxial silicon layer is grown within the openings and overlying the oxide layer. Shallow trench isolation regions are formed within the epitaxial silicon layer extending to the underlying oxide layer. Gate electrodes and associated source and drain regions are formed in and on the epitaxial silicon layer between the shallow trench isolation regions. An interlevel dielectric layer is deposited overlying the gate electrodes. First contacts are opened through the interlevel dielectric layer to the underlying source and drain regions.