Abstract: Method and composition for sealing of a phosphate conversion coating is disclosed. The method includes contacting a phosphate conversion coating with an acidic aqueous solution of substituted iminodimethylene diphosphonic acids represented, as a class, by the formula R1--N--(CH.sub.2 --PO.sub.3 H.sub.2).sub.2 where R1 is a Z, alkyl or aryl moiety having a carbon chain up to the length where solubility in an acidic aqueous solution is lost. Z is ##STR1## where R2 and R3 are hydrogen, alkyl, aryl, or phosphono alkyl moieties, m is from 1 to 3 and Cn is a methylene carbon chain up to the length where solubility in an acidic aqueous solution is lost, and water soluble salts thereof. Preferably, R1 is methyl through octyl, benzyl, or diethylenediaminotrimethylene triphosphonic acid. The substituted iminodimethylene diphosphonic acid is applied as an aqueous bath with a pH of from about 3.3 to 4.0. The substituted iminodimethylene diphosphonic acid may dry in place or be followed by a deionized water rinse.
Abstract: A method of inhibiting manganese deposition in open, recirculating aqueous systems is disclosed. A water soluble acrylic acid/allyl hydroxy propyl sulfonate ether copolymer having repeat units characterized by the structural formula: ##STR1## wherein M is a water soluble cation, the molar ratio x:y is from about 3:1 to about 6:1 and the number average molecular weight of the copolymer is from about 5,000 to about 10,000, preferrably with an organic phosphonate is added to the aqueous system. The organic phosphonate is preferably hydroxy ethylidene diphosphonic acid, diethylene triamine penta-(methylene phosphonic acid) or blends thereof. The copolymer or copolymer and phosphonic acid is effective in inhibiting the deposition of manganese in aqueous systems.
Type:
Grant
Filed:
February 1, 1989
Date of Patent:
February 13, 1990
Assignee:
Betz Laboratories, Inc.
Inventors:
Brown J. Michael, Stevn P. Sherwood, E. Paul Holder
Abstract: A method of suppressing dust generation emanating from cement clinker by applying a foamed water/surfactant solution thereto. The solution comprises a low salt tolerant anionic surfactant.
Abstract: This invention relates to an improved press felt conditioning treatment which controls the deposition of polymerically flocculated particulate substances in a press felt. The treatment comprises applying to the felt an effective inhibiting amount of a conditioner comprising a relatively low molecular weight organic, anionic polymer and at least one hydrophilic, nonionic or anionic surfactant. The polymer preferrably has an acrylic acid or methacrylic acid functionality and is preferrably selected from the group consisting of homopolymers of acrylic acid, a methacrylic acid/polyethylene glycol allyl ether copolymer, a homopolymer of methacrylic acid, an acrylic acid/polyethylene glycol allyl ether copolymer, and an acrylic acid/1-allyloxy-2-hydroxypropane sulfonic acid copolymer.
Type:
Grant
Filed:
November 9, 1988
Date of Patent:
January 23, 1990
Assignee:
Betz Laboratories, Inc.
Inventors:
Daniel J. Barnett, Abdul Q. Khan, Patricia R. Keen
Abstract: This invention relates to processes and compositions for stabilizing distillate fuel oil which comprises adding to the distillate fuel oil an effective stabilizing amount of a mixture of (a) a phosphite compound having the formula ##STR1## wherein R, R' and R" are the same or different and are alkyl, aryl, alkaryl or aralkyl groups and these groups may contain oxygen and/or nitrogen, or R and R' may be hydrogen and (b) an effective stabilizing amount of: an organic compound containing a tertiary amine having the formula T.sub.3 N, wherein the three T groups are the same or different and are alkyl, cycloalkyl, arly, alkyaryl, or aralkyl such that these groups may contain oxygens or additional nitrogens and each T group has from 1 to about 20 carbon atoms; or the reaction product of tallow amine and epichlorohydrin. The weight ratio of (a):(b) is from about 1:50 to about 100:1.
Abstract: This invention relates to a process for inhibiting white pitch deposition in felts of a papermaking system including adding to the felts an effective inhibiting amount of an organic, anionic polyelectrolyte. The molecular weight of the polyelectrolyte is preferably from about 1,000 to 100,000. The polyelectrolyte is selected from the group consisting of polyacrylic acid, polmethacrylic acid, acrylic acid/polyethylene glycol allyl ether copolymers, methacrylic acid/polyethylene glycol allyl ether copolymers, acrylic acid/1-allyloxy-2-hydroxypropane sulfonic acid copolymers. The use of these polyelectrolytes in combination with surfactants provides an especially effective white pitch inhibiting and total felt conditioning process when applied to the felt.
Type:
Grant
Filed:
July 29, 1988
Date of Patent:
August 29, 1989
Assignee:
Betz Laboratories, Inc.
Inventors:
Daniel J. Barnett, Daniel L. Michalopoulos
Abstract: This invention relates to processes for inhibiting the degradation, particulate and gum formation of distillate fuel oils prior to or during processing which comprises adding to the distillate fuel oil an effective inhibiting amount of a mixture of (a) a phosphite compound having the formula ##STR1## wherein R, R' and R" are the same or different and are alkyl, aryl, alkaryl or aralkyl groups, and (b) an effective amount of hydroxylamine, having the formula. ##STR2## wherein R.sup.III and R.sup.IV are the same or different and are hydrogen, alkyl, aryl, alkaryl or aralkyl groups, wherein the weight ratio of (a):(b) is from about 1:10 to about 10:1.
Abstract: A method for treatment of boiler waters is disclosed. The method comprises a synergetic combination of a methacrylic acid-containing polymer with a strongly interacting nonionic surfactant, together with a chelant and/or a phosphate-generating species. The method is particularly effective when the surfactant is an alkoxylated alkylphenol or an alkoxylated alkylphenol ether.
Abstract: This invention relates to processes and compositions for color stabilized distillate fuel oils which comprises an effective color stabilizing amount of (a) a tertiary amine having the formula ##STR1## wherein R and R' are the same or different alkyl groups having one to about six carbon atoms, and (b) a hydroxylamine having the formula ##STR2## wherein R and R' are the same or different and are hydrogen, alkyl, alkaryl or aralkyl groups, wherein the weight ratio of (a):(b) is from about 1:1 to about 99.7:0.3. Preferably, the alkyl, alkaryl and aralkyl groups of the hydroxylamine have from one to about twenty carbon atoms. It is further preferred that (a) is N,N-dimethylcyclohexylamine and (b) is N,N-diethylhydroxylamine.
Abstract: A method of suppressing dust generation emanating from cement clinker dust by applying a foamed dust control treatment thereto. The foam is provided with an effective defoaming agent which, upon slurrying of the clinker and other ingredients (e.g., sand, gypsum, aggregate) to form the desired mortar, inhibits foam formation in the mortar, thus not significantly increasing air entrapped in the slurried mortar.
Abstract: Minor amounts of water insoluble elastomeric polymers are combined with oil. The combination is sprayed or applied in a foam carrier to dust particles to inhibit dissemination thereof which would otherwise occur by windage or transit motion and the like.