Abstract: A method of preparing poly(isopropenylphosphonic acid) is disclosed, which provides a high yield with low initiator charge. The method comprises preparing poly(isopropenylphosphonic acid) by polymerizing a mixture of isopropenylphosphonic acid and isopropenylphosphonic acid anhydride, preferably in an aqueous solution.
Type:
Grant
Filed:
May 9, 1995
Date of Patent:
May 21, 1996
Assignee:
Betz Laboratories, Inc.
Inventors:
Michael A. Cady, William S. Carey, Andrew Solov
Abstract: An emulsion cleaner formulation is provided which is free of toxic or hazardous materials listed under SARA 313. The emulsion cleaner formulation employs a blend of triethanolamine soap of tall oil fatty acid, polyethylene glycol (400) dioleate and polyethylene glycol (400) monooleate as a stabilizing agent. The emulsion cleaner may also include a nonionic surfactant. The emulsion cleaner also includes both oil soluble and water soluble rust inhibitors.
Abstract: A water soluble isopropenylphosphonic acid copolymer composition and method of use thereof are disclosed. The copolymer comprises repeat units (a) of the formula: ##STR1## wherein X=OH or OM, wherein M is a cation, and repeat units (b) of the formula: ##STR2## wherein R.sub.1 and R.sub.2 are independently hydrogen, C.sub.1-10 linear or branched alkyl, phenyl or alkyl substituted phenyl. The copolymers are effective in inhibiting the precipitation of scale forming salts and also act to inhibit corrosion in boiler water systems.
Abstract: Agglomerating agent and method for use in heap leaching of mineral bearing ores. Cationic polymers alone or in combination with cement or lime are highly effective agglomerating agents in acidic or alkaline leaching operations. The cationic polymers are preferably graft copolymers, block copolymers or linear copolymers of acrylamide and diallyl dimethyl ammonium chloride.
Type:
Grant
Filed:
September 6, 1994
Date of Patent:
April 30, 1996
Assignee:
Betz Laboratories, Inc.
Inventors:
David M. Polizzotti, Wen P. Liao, Donald C. Roe
Abstract: A method of providing color to a polyacrylamide based, dried-in-place, non-chromate conversion coating is provided. The addition of a phthalo green pigment and optionally a nonionic surfactant to an aqueous, dried-in-place conversion coating treatment solution provides for a colored conversion coating without adversely affecting the corrosion resistance or adhesion properties of the conversion coating.
Type:
Grant
Filed:
December 14, 1993
Date of Patent:
April 9, 1996
Assignee:
Betz Laboratories, Inc.
Inventors:
Jiangbo Ouyang, Philip D. Deck, William L. Harpel, Bruce V. Haberle
Abstract: A foam carrier for a dust control agent and a biological control agent is provided to control fugitive dust dissemination and biological activity in bulk/granular solids.
Type:
Grant
Filed:
January 17, 1995
Date of Patent:
March 19, 1996
Assignee:
Betz Laboratories, Inc.
Inventors:
Donald C. Roe, Dwight P. Davis, Kevin C. Manning, Edmund J. Bockowski
Abstract: A process for measuring the coating weight of a dried-in-place non-chromate polyacrylamide/surfactant based conversion coating is disclosed. An ammonium hexafluorotitanate tracer added to such a conversion coating was found to not adversely affect coating properties. The tracer was found to remain proportional to the polymer matrix when the coating was analyzed by X-ray fluorescence.
Abstract: Disclosed is a method of inhibiting the formation of scales such as barium and strontium sulfate in low pH aqueous system. The method involves treating the aqueous system with a scale control treatment including polyepoxysuccinic acid. Typical low pH aqueous systems where the present invention is particularly useful are oilfield produced water, resin bed water softeners during acid regeneration operations.
Abstract: Apparatus and method are provided for on-line cleaning of the tubes of a heat exchanger. Tube cleaners are comprised of two members, a rigid flotation member and an elastomeric cleaning member. The cleaner has a selected density to allow uniform distribution through the tubes and to allow recovery by surface extraction or by strainers. Pressures as the cleaner enters or flows along a tube may be measured and selected.
Abstract: An agglomerating agent for use in the heap leaching of mineral bearing ores is disclosed. The agglomerating agent is a polyvinyl alcohol of moderate to high molecular weight which is partially or fully hydrolyzed. The polyvinyl alcohol agglomerating agent can be used alone or in combination with cement or lime in acidic or alkaline heap leaching operations.
Abstract: A black, no-rinse conversion coating on metal surfaces is provided. The treatment of a metal such as aluminum or aluminum alloys with a composition of hexavalent chromium, an acrylic/itaconic modified styrene butyl acrylate polymer resin, a fluoacid, and carbon black results in a black no-rinse conversion coating.
Abstract: A cleaning and passivation treatment for metal surfaces which is essentially phosphate free and resistant to foaming in soft water is disclosed. The treatment solution includes relatively water insoluble surfactants without the use of conventional hydrotropes. The treatment solution includes an aqueous solution of monoethanolamine, boric acid, a non-ionic surfactant having a cloud point below about 25.degree. C. and a hydrotropic coupling agent preferably a combination of caprylic acid and capric acid.
Abstract: A method of inhibiting scale formation in acidic aqueous systems where metal ions such as Al.sup.+3 and Fe.sup.+3 are present by employing a polyepoxysuccinic acid in combination with a metal ion binding material.
Type:
Grant
Filed:
October 20, 1994
Date of Patent:
November 21, 1995
Assignee:
Betz PaperChem, Inc.
Inventors:
Davor F. Zidovec, Alexander D. Fisher, deceased
Abstract: A non-chromate conversion coating for metal surfaces such as aluminum, steel, galvanized steel and zinc-aluminum steel consisting of an aqueous solution of a cationic polymer, an alkaline aqueous silicate and an organofunctional silane.
Type:
Grant
Filed:
October 31, 1994
Date of Patent:
September 19, 1995
Assignee:
Betz Laboratories, Inc.
Inventors:
Deborah L. Purnell, Brenda S. Morris, David W. Reichgott
Abstract: A process for measuring the coating weight of a dried-in-place non-chromate polyacrylamide/surfactant based conversion coating is disclosed. An ammonium hexafluorotitanate tracer added to such a conversion coating was found to not adversely affect coating properties. The tracer was found to remain proportional to the polymer matrix when the coating was analyzed by X-ray fluorescence.
Abstract: A black, no-rinse conversion coating on metal surfaces is provided. The treatment of a metal such as aluminum or aluminum alloys with a composition of hexavalent chromium, a modified styrene acrylic resin, carbon black thickeners, surfactants and coalescents results in a black no-rinse conversion coating. The black coating provides corrosion resistance and is resistant to gasoline, hot oil and ethylene glycol. The coating solution is particularly effective on complex shapes having closely spaced parts such as automotive radiators or condensers.
Abstract: Method for inhibiting dust emissions from hot (>150.degree. F.) substrates are provided which comprise adding to the substrate an aqueous solution of sodium silicate.
Abstract: A non-chromium conversion coating for metal surfaces such as aluminum, steel, galvanized steel and zinc-aluminum steel consisting of an aqueous solution of an anionic polyacrylamide copolymer, an inorganic silicate and an organofunctional silane.
Type:
Grant
Filed:
October 15, 1993
Date of Patent:
May 2, 1995
Assignee:
Betz Laboratories, Inc.
Inventors:
Brenda S. Morris, Jiangbo Ouyang, David W. Reichgott
Abstract: A method of inhibiting the formation and deposition of scale in the production of hydrocarbons from subterranean reservoirs. The method is particularly effective at inhibiting the formation and deposition of calcium and barium scales in the produced waters of hydrocarbon recovery operations. The method comprises introducing into the produced water a polyepoxysuccinic acid of the general formula: ##STR1## where n ranges from about 2 to about 11, M is hydrogen or a water soluble cation such as Na.sup.+, NH.sub.4.sup.+, K.sup.+ and R is hydrogen, C.sub.1-4 alkyl or C.sub.1-4 substituted alkyl.