Patents Represented by Attorney W. J. Lee
  • Patent number: 4472362
    Abstract: Crystalline 2-layer lithium aluminate, especially when carried in an ion exchange resin, is regenerated for use as an extractor for Li.sup.+ values in aqueous solution, said regeneration being done by using an aqueous wash containing at least about 800 ppm Li.sup.+ ion.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: September 18, 1984
    Assignee: The Dow Chemical Company
    Inventor: John L. Burba, III
  • Patent number: 4470608
    Abstract: Flexible, resilient gasketing material with auxiliary resiliency means, such as protuberances (ridges or beads) and internally-positioned spring means. The gaskets may be straight or curved or made into continuous forms such as rectangles, triangles, ovals, or circles. Preferably the gaskets are flanged.
    Type: Grant
    Filed: September 1, 1983
    Date of Patent: September 11, 1984
    Assignee: The Dow Chemical Company
    Inventor: Charles M. Warren
  • Patent number: 4464238
    Abstract: Porous separators for electrolytic processes are designed which are characterized by an N.sub.mac t value, where N.sub.mac is the ratio of the resistance (r) of the electrolyte-saturated separator to the resistance (r.sub.o) of an equivalent volume of electrolyte and t is the thickness, in inches, of the separator. The N.sub.mac value is referred to here as the MacMullin Number.
    Type: Grant
    Filed: May 9, 1983
    Date of Patent: August 7, 1984
    Assignee: The Dow Chemical Company
    Inventors: Donald L. Caldwell, Kenneth A. Poush
  • Patent number: 4464348
    Abstract: Cobalt values are extracted from Co-containing ores or minerals by using an aqueous solution containing a reducing agent (e.g., hydrazine hydrosulfate). The leachant substantially rejects nickel values, thus cobalt is extracted which is substantially free of nickel.
    Type: Grant
    Filed: January 10, 1983
    Date of Patent: August 7, 1984
    Assignee: The Dow Chemical Company
    Inventor: John L. Burba, III
  • Patent number: 4461714
    Abstract: The bayerite form of crystalline alumina, Al(OH).sub.3, contained within a macroporous ion exchange resin is converted to the gibbsite form of Al(OH).sub.3 by reaction with hot MgX.sub.2, where X is halide, followed by water-washing the MgX.sub.2 portion from the product, thereby causing the conversion of bayerite to the gibbsite form of crystalline Al(OH).sub.3. The gibbsite form may then be reacted with hot LiX solution, where X is anion, to form crystalline 2-layer LiX.2Al(OH).sub.3.nH.sub.2 O.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: July 24, 1984
    Assignee: The Dow Chemical Company
    Inventor: John L. Burba, III
  • Patent number: 4460407
    Abstract: Molten magnesium alloy is stirred under a substantially inert atmosphere as it is cooled to freezing, thereby forming discrete solid particles of the alloy. The process may be carried out batch-wise or continuously.
    Type: Grant
    Filed: December 20, 1982
    Date of Patent: July 17, 1984
    Assignee: The Dow Chemical Company
    Inventor: Earl K. Keith
  • Patent number: 4454272
    Abstract: Extrusion-cast films of high molecular weight, linear low density ethylene copolymers which inherently have high block and low slip characteristics are compounded with a minor amount of a secondary fatty acid amide and a finely-divided natural inorganic, e.g., silica, before being extrusion-cast as a thin film, the additives serving to substantially reduce the block and increase the slip characteristics of the film.
    Type: Grant
    Filed: May 16, 1983
    Date of Patent: June 12, 1984
    Assignee: The Dow Chemical Company
    Inventors: Osborne K. McKinney, David P. Flores
  • Patent number: 4446252
    Abstract: Novel anion exchange resin composites having hydrous chromium III oxide (Cr.sub.2 O.sub.3.nH.sub.2 O) incorporated therein are useful in removing a wide array of polyvalent metal cations from aqueous solution.
    Type: Grant
    Filed: July 30, 1982
    Date of Patent: May 1, 1984
    Assignee: The Dow Chemical Company
    Inventor: Alvin F. Beale, Jr.
  • Patent number: 4446201
    Abstract: Crystalline transition metal aluminates conforming generally to the formulaMA.sub.a.sup.v Z.sub.b.sup.v.nAl(OH).sub.3.mH.sub.2 Owhere M is a transition metal having a valence charge of +2 selected from the group consisting of Cu, Zn, Mn, Fe, Co, and Ni, where AZ represents negative valence ions or radicals, v is a negative valence of 1, 2, or 3, n is a value to provide a mol ratio of Al/M of at least 1/1, preferably at least 1.5/1, and m is an integer of from zero to the maximum for waters of hydration, with (va)+(vb) equal to 2, are prepared in alkaline aqueous medium wherein transition metal compounds are caused to form adducts with amorphous hydrous alumina, Al(OH).sub.3, said adducts forming crystals when heated, said aluminates being useful, e.g., as ion exchangers and as spinel precursors among other things.
    Type: Grant
    Filed: May 13, 1983
    Date of Patent: May 1, 1984
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4442227
    Abstract: Hypochlorite ions in aqueous solution are catalytically decomposed by the action of a poly-metal spinel of cobalt preferably coated on an inert, stable support. The spinel catalyst may contain dispersed therein, optionally, other "modifier" metal oxides which contribute better adherence of the spinel to the substrate and improve the toughness of the spinel coating. The substituted cobalt spinel conforms generally to the empirical formulaM.sub.x N.sub.y Co.sub.3-(x+y) O.sub.4where zero<x.ltoreq.1; zero.ltoreq.y.ltoreq.0.5; M is at least one metal of Periodic Table Groups IB, IIA, and IIB; N is at least one metal from Group IA; and zero<(x+2y).ltoreq.1.
    Type: Grant
    Filed: October 18, 1982
    Date of Patent: April 10, 1984
    Assignee: The Dow Chemical Company
    Inventor: Donald L. Caldwell
  • Patent number: 4435264
    Abstract: Backfills for magnesium galvanic anodes are prepared by blending calcium sulfite, B(OH).sub.3, and bentonite, wherein the bentonite contains a substantial amount of alkaline earth metal bentonite, such as calcium-bentonite.
    Type: Grant
    Filed: March 1, 1982
    Date of Patent: March 6, 1984
    Assignee: The Dow Chemical Company
    Inventor: Philip Y. Lau
  • Patent number: 4435263
    Abstract: A magnesium anode backfill composition is prepared by mixing calcium sulfite, bentonite, and at least one compound selected from the group comprising sodium alkylates and sodium dialkyldithiocarbamates, wherein said bentonite contains a substantial amount of alkaline earth metal bentonite, such as calcium-bentonite.
    Type: Grant
    Filed: March 1, 1982
    Date of Patent: March 6, 1984
    Assignee: The Dow Chemical Company
    Inventor: Philip Y. Lau
  • Patent number: 4434138
    Abstract: The density and capacity of macroporous ion exchange resins are increased by incorporating therein at least one of titania hydrate, zirconia hydrate, hydrated titanium phosphorous, and hydrated zirconium phosphate hydrates. Such resin composites are useful, e.g., in removing uranium values from aqueous solutions.
    Type: Grant
    Filed: October 2, 1981
    Date of Patent: February 28, 1984
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4430315
    Abstract: Hypochlorite ions in aqueous solution are catalytically decomposed by the action of a poly-metal spinel of cobalt preferably coated on an inert, stable support. The spinel catalyst may contain dispersed therein, optionally, other "modifier" metal oxides which contribute better adherence of the spinel to the substrate and improve the toughness of the spinel coating. The substituted cobalt spinel conforms generally to the empirical formulaM.sub.x N.sub.y Co.sub.3-(x+y) O.sub.4where zero<x.ltoreq.1; zero.ltoreq.y.ltoreq.0.5; M is at least one metal of Periodic Table Groups IB, IIA, and IIB; N is at least one metal from Group IA; and zero<(x+2y).ltoreq.1.
    Type: Grant
    Filed: December 28, 1981
    Date of Patent: February 7, 1984
    Assignee: The Dow Chemical Company
    Inventor: Donald L. Caldwell
  • Patent number: 4430289
    Abstract: Blown films of LLDPE having reduced block and increased slip are provided by incorporating into the polymer, before blowing into films, effective amounts of certain fatty acid amides and inorganic materials which provide fast bloom, thereby obtaining an expedient effect of the additives on the surface properties of the blown film.
    Type: Grant
    Filed: April 5, 1982
    Date of Patent: February 7, 1984
    Assignee: The Dow Chemical Company
    Inventors: Osborne K. McKinney, David P. Flores
  • Patent number: 4430311
    Abstract: Formation of hydrous alumina in the reticules of a weak-base anion exchange resin, wherein AlCl.sub.3 has been precipitated as hydrous alumina by reaction with ammonia, is improved by employing a subsequent treatment with HCl or with NH.sub.4 Cl and HCl to convert the exchange resin to the chloride form, thereby increasing the reticular volume of the resin, thus permitting subsequent precipitation of additional hydrous alumina therein.
    Type: Grant
    Filed: April 22, 1983
    Date of Patent: February 7, 1984
    Assignee: The Dow Chemical Co.
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4430097
    Abstract: Particles of crystalline LiX.multidot.2Al(OH).sub.3 .multidot.nH.sub.2 O, where X is a monovalent, divalent, or trivalent anion, especially chlorine, are useful in separating hydrocarbons according to boiling point ranges.
    Type: Grant
    Filed: March 22, 1982
    Date of Patent: February 7, 1984
    Assignee: The Dow Chemical Co.
    Inventor: John L. Burba, III
  • Patent number: 4428805
    Abstract: Electroconductive substrates for use as oxygen electrodes are coated with an optional interface layer and then with cobalt oxide spinels conforming substantially to the empirical formulaM.sub.x Z.sub.y CO.sub.3.sbsb.-(x+y) O.sub.4where M represents at least one metal from the Groups IB, IIA, IIB, where Z represents at least one metal from Group IA where x is equal to or greater than zero but not greater than 1, where y is equal to or greater than zero but not greater than 0.5, and where (x plus 2y) is equal to or greater than zero but not greater than 1. The composites are prepared by thermally oxidizing metal oxide precursors in-situ on the substrate, including, optionally, modifier metal oxide materials as a separate dispersed phase in the contiguous spinel structure. The interface layer comprises at least one oxide of Pb, Sn, Sb, Al, In, or mixtures of these. The electrodes are used as the anodic means in an electrolysis cell wherein oxygen is produced by electrolyzing an oxygen-containing electrolyte.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: January 31, 1984
    Assignee: The Dow Chemical Co.
    Inventors: Donald L. Caldwell, Mark J. Hazelrigg, Jr.
  • Patent number: 4427517
    Abstract: A mixture of CaSO.sub.3 and bentonite, where the bentonite contains a substantial amount of alkaline earth metal bentonite, e.g., Ca-bentonite, is useful as a backfill composition for underground magnesium galvanic anodes. The backfill may optionally, and beneficially, contain sodium sulfite.
    Type: Grant
    Filed: March 1, 1982
    Date of Patent: January 24, 1984
    Assignee: The Dow Chemical Company
    Inventor: Philip Y. Lau
  • Patent number: 4426272
    Abstract: Diaphragms for use in electrolytic cells, e.g., chlor-alkali cells, are beneficially prepared using pulverized expanded vermiculite in place of the historically popular asbestos.
    Type: Grant
    Filed: May 10, 1982
    Date of Patent: January 17, 1984
    Assignee: The Dow Chemical Company
    Inventor: Richard A. Hanmer