Abstract: Extrusion-cast films of high molecular weight, linear, low density ethylene copolymers which inherently have high block and high cling characteristics are compounded with a minor amount of a low molecular weight organic, such as a polyglycol, before being extrusion-cast as a thin film, the low molecular weight organic serving to substantially reduce the block, but retaining high cling characteristics.
Type:
Grant
Filed:
March 18, 1982
Date of Patent:
November 15, 1983
Assignee:
The Dow Chemical Company
Inventors:
James A. Allen, George W. Knight, Morris S. Edmondson
Abstract: Preparation and use of novel cation exchange composites are described, said composites comprising polymers having sulfonic acid functional groups which have ionically attached thereto, in the resin phase, amorphous polymer hydrous zirconium oxide groups. These compositions are useful, e.g., for removing sulfate values from NaCl brine.
Abstract: Macroporous cation exchange resins with sulfonic acid functional groups having polymeric zirconium hydrous oxide contained therein are useful in substantially removing SO.sub.4.sup.= ions from metal salt solutions.
Abstract: Phosphonopolyester oligomers are prepared from hydroxyalkylated 2,2',-bis(3-allylphenyl-4-hydroxy) alkanes and phosphonyl dihalides. The oligomers are useful in the preparation of polyester resins, epoxy resins, and polyurethanes.
Abstract: Salt-coated Mg granules are prepared by continuously and simultaneously feeding to a mixer a flow of molten Mg and a flow of molten salt at a predetermined ratio to provide up to about 68% molten Mg in the mixture, thereby dispersing the molten Mg as globules in the salt, continuously withdrawing the molten mixture from the mixer at a point distal to that of the feed, freezing the mixture, and milling the frozen mixture to pulverize the salt matrix and recovering salt-coated Mg particles therefrom.
Abstract: Macroporous cation exchange resins with sulfonic acid functional groups having polymeric hydrous zirconium oxide and polyacrylic acid contained therein are useful in substantially removing sulfate, borate, bicarbonate and/or phosphate ions from alkali metal salt solutions.
Abstract: Alkaline earth metal ions, e.g., Mg.sup.++ and/or Ca.sup.++, are removed from alkali metal brines, e.g., NaCl, by use of a particulate, macroporous, anion exchange resin containing the in-situ reaction product of polymeric, amorphous, hydrous zirconium oxide and a source of PO.sub.4 ions, e.g., H.sub.3 PO.sub.4.
Abstract: Extrusion-cast films of high molecular weight, linear low density ethylene copolymers which inherently have high block and low slip characteristics are compounded with a minor amount of a secondary fatty acid amide and a finely-divided natural inorganic, e.g., silica, before being extrusion-cast as a thin film, the additives serving to substantially reduce the block and increase the slip characteristics of the film.
Abstract: Preparations and uses are shown for novel crystalline aluminates which conform generally to the empirical formulaMgA.sub.a.sup.v Z.sub.b.sup.v.nAl(OH).sub.3.mH.sub.2 OwhereinA and Z represent negative-valence ions or radicals selected from the group comprising hydroxyl, halide, inorganic acid, and organic acid,n is a value of from about 1 to about 2,v is a negative valence of 1, 2, or 3,a and b each have values of from zero to 2, with (va)+(vb) equal to 2, and withm being a value of zero or more.
Abstract: Preparations and uses are shown for novel crystalline aluminates which conform generally to the empirical formulaMgA.sub.a.sup.v Z.sub.b.sup.v.nAl(OH).sub.3.mH.sub.2 Owhere A and Z represent negative-valence ions or radicals selected from the group comprising hydroxyl, halide, inorganic acid, and organic acid,n is a value of from about 1 to about 2,v is a negative valence of 1, 2, or 3,a and b each have values of from zero to 2,with (va)+(vb) equal to 2, andwith m being a value of zero or more.
Abstract: Crystalline transition metal aluminates conforming generally to the formulaMA.sub.a.sup.v Z.sub.b.sup.v.nAl(OH).sub.3.mH.sub.2 Owhere M is a transition metal having a valence charge of +2 selected from the group consisting of Cu, Zn, Mn, Fe, Co, and Ni, where AZ represents negative valence ions or radicals, v is a negative valence of 1, 2, or 3, n is a value to provide a mol ratio of Al/M of at least 1/1, preferably at least 1.5/1, and m is an integer of from zero to the maximum for waters of hydration, with (va)+(vb) equal to 2, are prepared in alkaline aqueous medium wherein transition metal compounds are caused to form adducts with amorphous hydrous alumina, Al(OH).sub.3, said adducts forming crystals when heated, said aluminates being useful, e.g., as ion exchangers and as spinel precursors among other things.
Abstract: Chlor-alkali electrolytic membrane cells are provided with means for flowing catholyte from cell-to-cell sequentially, and means for flowing anolyte from cell-to-cell sequentially.
Abstract: Small rotund magnesium (or Mg alloy) granules dispersed in a friable salt matrix are obtained by preparing a molten salt mixture containing molten magnesium (or Mg alloy), stirring to effect good dispersion, and cooling the molten mixture to effect freezing of the magnesium (or Mg alloy) as small rotund globules dispersed in a solid friable salt matrix.
Abstract: A side-stream portion of a Stretford Process solution is taken from the main-stream in order to reduce the amount of deleterious side-products in the solution and the ADA values and vanadium values are salvaged from the side-stream by taking up the ADA values on activated charcoal and the vanadium values in an anion exchange resin. The ADA and vanadium values are recovered for re-cycling back to the Stretford Process.
Abstract: Formation of hydrous alumina in the reticules of a weak-base anion exchange resin, wherein AlCl.sub.3 has been precipitated as hydrous alumina by reaction with ammonia, is improved by employing a subsequent treatment with HCl or with NH.sub.4 Cl and HCl to convert the exchange resin to the chloride form, thereby increasing the reticular volume of the resin, thus permitting subsequent precipitation of additional hydrous alumina therein.
Abstract: Electrolytic cell ion-exchange membranes, comprising fluoropolymers having pendant sulfonic acid functional groups and/or carboxylic acid functional groups, are treated with primary, secondary, and/or tertiary amines to provide dimensional stability and other improvements to the membranes. The treatment with amines provides easily-disassociable amines salts which are leached out by an aqueous leachant, e.g., cell electrolyte, thereby providing sulfonic acid groups and/or carboxylic acid groups to function as ion exchange sites in the membrane during subsequent cell operation.
Type:
Grant
Filed:
March 4, 1981
Date of Patent:
March 8, 1983
Assignee:
The Dow Chemical Company
Inventors:
Bobby R. Ezzell, Harry S. Burney, Jr., Marius W. Sorenson
Abstract: A resin/aluminate composite which has been substantially loaded with Li.sup.+ values by being contacted with a contaminated, Li.sup.+ -containing aqueous solution, is pre-washed with a substantially pure, concentrated NaCl brine to remove the contaminants without removing the Li.sup.+ values, then is washed with water to leach out much, but not all, of the Li.sup.+ values. The resin/aluminate composite comprises a macroporous anion exchange resin having crystalline LiX.2Al(OH).sub.3 dispersed therein, where X is halide.
Abstract: Electroconductive substrates are coated with an interface layer and then with cobalt oxide spinels conforming substantially to the empirical formulaM.sub.x Z.sub.y Co.sub.3-(x+y) O.sub.4where M represents at least one metal from the Groups IB, IIA, IIB, where Z represents at least one metal from Group IA where x is equal to or greater than zero but not greater than 1, where y is equal to or greater than zero but not greater than 0.5, and where (x plus 2y) is equal to or greater than zero but not greater than 1. The composites are prepared by thermally oxidizing metal oxide precursors in-situ on the substrate, including, optionally, modifier metal oxide materials as a separate dispersed phase in the contiguous spinel structure. The interface layer comprises at least one oxide of Pb, Sn, Sb, Al, In, or mixtures of these.
Type:
Grant
Filed:
March 25, 1981
Date of Patent:
January 18, 1983
Assignee:
The Dow Chemical Company
Inventors:
Donald L. Caldwell, Mark J. Hazelrigg, Jr.
Abstract: Electroconductive substrates are coated with substituted cobalt oxide spinels conforming substantially to the empirical formulaM.sub.x Z.sub.y Co.sub.3-(x+y) O.sub.4where M and Z each represent at least one metal from the Groups IB, IIA, IIB, where x and y each, independently are values greater than zero but less than 1, and where x plus y is not greater than 1. The composites are prepared by thermally oxidizing metal oxide precursors in-situ on the substrate, including, optionally, modifier metal oxide materials as a separate dispersed phase in the contiguous spinel structure. The composites are useful, e.g., as an anode material in an electrolytic cell.
Type:
Grant
Filed:
March 25, 1981
Date of Patent:
January 11, 1983
Assignee:
The Dow Chemical Company
Inventors:
Donald L. Caldwell, Mark J. Hazelrigg, Jr.
Abstract: Novel anion exchange resin composites having hydrous chromium III oxide (Cr.sub.2 O.sub.3. nH.sub.2 O) incorporated therein are useful in removing a wide array of polyvalent metal cations from aqueous solution.