Patents Represented by Attorney W. J. Lee
  • Patent number: 4415691
    Abstract: Extrusion-cast films of high molecular weight, linear, low density ethylene copolymers which inherently have high block and high cling characteristics are compounded with a minor amount of a low molecular weight organic, such as a polyglycol, before being extrusion-cast as a thin film, the low molecular weight organic serving to substantially reduce the block, but retaining high cling characteristics.
    Type: Grant
    Filed: March 18, 1982
    Date of Patent: November 15, 1983
    Assignee: The Dow Chemical Company
    Inventors: James A. Allen, George W. Knight, Morris S. Edmondson
  • Patent number: 4415678
    Abstract: Preparation and use of novel cation exchange composites are described, said composites comprising polymers having sulfonic acid functional groups which have ionically attached thereto, in the resin phase, amorphous polymer hydrous zirconium oxide groups. These compositions are useful, e.g., for removing sulfate values from NaCl brine.
    Type: Grant
    Filed: October 2, 1981
    Date of Patent: November 15, 1983
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4415677
    Abstract: Macroporous cation exchange resins with sulfonic acid functional groups having polymeric zirconium hydrous oxide contained therein are useful in substantially removing SO.sub.4.sup.= ions from metal salt solutions.
    Type: Grant
    Filed: October 2, 1981
    Date of Patent: November 15, 1983
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4412055
    Abstract: Phosphonopolyester oligomers are prepared from hydroxyalkylated 2,2',-bis(3-allylphenyl-4-hydroxy) alkanes and phosphonyl dihalides. The oligomers are useful in the preparation of polyester resins, epoxy resins, and polyurethanes.
    Type: Grant
    Filed: September 27, 1982
    Date of Patent: October 25, 1983
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4410356
    Abstract: Salt-coated Mg granules are prepared by continuously and simultaneously feeding to a mixer a flow of molten Mg and a flow of molten salt at a predetermined ratio to provide up to about 68% molten Mg in the mixture, thereby dispersing the molten Mg as globules in the salt, continuously withdrawing the molten mixture from the mixer at a point distal to that of the feed, freezing the mixture, and milling the frozen mixture to pulverize the salt matrix and recovering salt-coated Mg particles therefrom.
    Type: Grant
    Filed: November 8, 1982
    Date of Patent: October 18, 1983
    Assignee: The Dow Chemical Company
    Inventor: Edward J. Skach, Jr.
  • Patent number: 4405576
    Abstract: Macroporous cation exchange resins with sulfonic acid functional groups having polymeric hydrous zirconium oxide and polyacrylic acid contained therein are useful in substantially removing sulfate, borate, bicarbonate and/or phosphate ions from alkali metal salt solutions.
    Type: Grant
    Filed: October 2, 1981
    Date of Patent: September 20, 1983
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4405574
    Abstract: Alkaline earth metal ions, e.g., Mg.sup.++ and/or Ca.sup.++, are removed from alkali metal brines, e.g., NaCl, by use of a particulate, macroporous, anion exchange resin containing the in-situ reaction product of polymeric, amorphous, hydrous zirconium oxide and a source of PO.sub.4 ions, e.g., H.sub.3 PO.sub.4.
    Type: Grant
    Filed: October 2, 1981
    Date of Patent: September 20, 1983
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4394474
    Abstract: Extrusion-cast films of high molecular weight, linear low density ethylene copolymers which inherently have high block and low slip characteristics are compounded with a minor amount of a secondary fatty acid amide and a finely-divided natural inorganic, e.g., silica, before being extrusion-cast as a thin film, the additives serving to substantially reduce the block and increase the slip characteristics of the film.
    Type: Grant
    Filed: April 21, 1981
    Date of Patent: July 19, 1983
    Assignee: The Dow Chemical Company
    Inventors: Osborne K. McKinney, David P. Flores
  • Patent number: 4392961
    Abstract: Preparations and uses are shown for novel crystalline aluminates which conform generally to the empirical formulaMgA.sub.a.sup.v Z.sub.b.sup.v.nAl(OH).sub.3.mH.sub.2 OwhereinA and Z represent negative-valence ions or radicals selected from the group comprising hydroxyl, halide, inorganic acid, and organic acid,n is a value of from about 1 to about 2,v is a negative valence of 1, 2, or 3,a and b each have values of from zero to 2, with (va)+(vb) equal to 2, and withm being a value of zero or more.
    Type: Grant
    Filed: March 22, 1982
    Date of Patent: July 12, 1983
    Assignee: The Dow Chemical Co.
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4392979
    Abstract: Preparations and uses are shown for novel crystalline aluminates which conform generally to the empirical formulaMgA.sub.a.sup.v Z.sub.b.sup.v.nAl(OH).sub.3.mH.sub.2 Owhere A and Z represent negative-valence ions or radicals selected from the group comprising hydroxyl, halide, inorganic acid, and organic acid,n is a value of from about 1 to about 2,v is a negative valence of 1, 2, or 3,a and b each have values of from zero to 2,with (va)+(vb) equal to 2, andwith m being a value of zero or more.
    Type: Grant
    Filed: March 22, 1982
    Date of Patent: July 12, 1983
    Assignee: Dow Chemical Co.
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4392980
    Abstract: Crystalline transition metal aluminates conforming generally to the formulaMA.sub.a.sup.v Z.sub.b.sup.v.nAl(OH).sub.3.mH.sub.2 Owhere M is a transition metal having a valence charge of +2 selected from the group consisting of Cu, Zn, Mn, Fe, Co, and Ni, where AZ represents negative valence ions or radicals, v is a negative valence of 1, 2, or 3, n is a value to provide a mol ratio of Al/M of at least 1/1, preferably at least 1.5/1, and m is an integer of from zero to the maximum for waters of hydration, with (va)+(vb) equal to 2, are prepared in alkaline aqueous medium wherein transition metal compounds are caused to form adducts with amorphous hydrous alumina, Al(OH).sub.3, said adducts forming crystals when heated, said aluminates being useful, e.g., as ion exchangers and as spinel precursors among other things.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: July 12, 1983
    Assignee: The Dow Chemical Co.
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4391693
    Abstract: Chlor-alkali electrolytic membrane cells are provided with means for flowing catholyte from cell-to-cell sequentially, and means for flowing anolyte from cell-to-cell sequentially.
    Type: Grant
    Filed: October 29, 1981
    Date of Patent: July 5, 1983
    Assignee: The Dow Chemical Company
    Inventor: John R. Pimlott
  • Patent number: 4384887
    Abstract: Small rotund magnesium (or Mg alloy) granules dispersed in a friable salt matrix are obtained by preparing a molten salt mixture containing molten magnesium (or Mg alloy), stirring to effect good dispersion, and cooling the molten mixture to effect freezing of the magnesium (or Mg alloy) as small rotund globules dispersed in a solid friable salt matrix.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: May 24, 1983
    Assignee: The Dow Chemical Co.
    Inventors: Edward J. Skach, Jr., George B. Cobel
  • Patent number: 4385044
    Abstract: A side-stream portion of a Stretford Process solution is taken from the main-stream in order to reduce the amount of deleterious side-products in the solution and the ADA values and vanadium values are salvaged from the side-stream by taking up the ADA values on activated charcoal and the vanadium values in an anion exchange resin. The ADA and vanadium values are recovered for re-cycling back to the Stretford Process.
    Type: Grant
    Filed: September 8, 1981
    Date of Patent: May 24, 1983
    Assignee: The Dow Chemical Company
    Inventor: Richard A. Wolcott
  • Patent number: 4381349
    Abstract: Formation of hydrous alumina in the reticules of a weak-base anion exchange resin, wherein AlCl.sub.3 has been precipitated as hydrous alumina by reaction with ammonia, is improved by employing a subsequent treatment with HCl or with NH.sub.4 Cl and HCl to convert the exchange resin to the chloride form, thereby increasing the reticular volume of the resin, thus permitting subsequent precipitation of additional hydrous alumina therein.
    Type: Grant
    Filed: November 19, 1979
    Date of Patent: April 26, 1983
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4376030
    Abstract: Electrolytic cell ion-exchange membranes, comprising fluoropolymers having pendant sulfonic acid functional groups and/or carboxylic acid functional groups, are treated with primary, secondary, and/or tertiary amines to provide dimensional stability and other improvements to the membranes. The treatment with amines provides easily-disassociable amines salts which are leached out by an aqueous leachant, e.g., cell electrolyte, thereby providing sulfonic acid groups and/or carboxylic acid groups to function as ion exchange sites in the membrane during subsequent cell operation.
    Type: Grant
    Filed: March 4, 1981
    Date of Patent: March 8, 1983
    Assignee: The Dow Chemical Company
    Inventors: Bobby R. Ezzell, Harry S. Burney, Jr., Marius W. Sorenson
  • Patent number: 4376100
    Abstract: A resin/aluminate composite which has been substantially loaded with Li.sup.+ values by being contacted with a contaminated, Li.sup.+ -containing aqueous solution, is pre-washed with a substantially pure, concentrated NaCl brine to remove the contaminants without removing the Li.sup.+ values, then is washed with water to leach out much, but not all, of the Li.sup.+ values. The resin/aluminate composite comprises a macroporous anion exchange resin having crystalline LiX.2Al(OH).sub.3 dispersed therein, where X is halide.
    Type: Grant
    Filed: November 23, 1981
    Date of Patent: March 8, 1983
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4369105
    Abstract: Electroconductive substrates are coated with an interface layer and then with cobalt oxide spinels conforming substantially to the empirical formulaM.sub.x Z.sub.y Co.sub.3-(x+y) O.sub.4where M represents at least one metal from the Groups IB, IIA, IIB, where Z represents at least one metal from Group IA where x is equal to or greater than zero but not greater than 1, where y is equal to or greater than zero but not greater than 0.5, and where (x plus 2y) is equal to or greater than zero but not greater than 1. The composites are prepared by thermally oxidizing metal oxide precursors in-situ on the substrate, including, optionally, modifier metal oxide materials as a separate dispersed phase in the contiguous spinel structure. The interface layer comprises at least one oxide of Pb, Sn, Sb, Al, In, or mixtures of these.
    Type: Grant
    Filed: March 25, 1981
    Date of Patent: January 18, 1983
    Assignee: The Dow Chemical Company
    Inventors: Donald L. Caldwell, Mark J. Hazelrigg, Jr.
  • Patent number: 4368110
    Abstract: Electroconductive substrates are coated with substituted cobalt oxide spinels conforming substantially to the empirical formulaM.sub.x Z.sub.y Co.sub.3-(x+y) O.sub.4where M and Z each represent at least one metal from the Groups IB, IIA, IIB, where x and y each, independently are values greater than zero but less than 1, and where x plus y is not greater than 1. The composites are prepared by thermally oxidizing metal oxide precursors in-situ on the substrate, including, optionally, modifier metal oxide materials as a separate dispersed phase in the contiguous spinel structure. The composites are useful, e.g., as an anode material in an electrolytic cell.
    Type: Grant
    Filed: March 25, 1981
    Date of Patent: January 11, 1983
    Assignee: The Dow Chemical Company
    Inventors: Donald L. Caldwell, Mark J. Hazelrigg, Jr.
  • Patent number: 4366261
    Abstract: Novel anion exchange resin composites having hydrous chromium III oxide (Cr.sub.2 O.sub.3. nH.sub.2 O) incorporated therein are useful in removing a wide array of polyvalent metal cations from aqueous solution.
    Type: Grant
    Filed: March 27, 1981
    Date of Patent: December 28, 1982
    Assignee: The Dow Chemical Company
    Inventor: Alvin F. Beale, Jr.