Patents Represented by Attorney W. J. Lee
  • Patent number: 4366042
    Abstract: Electroconductive substrates are coated with substituted cobalt oxide spinels conforming substantial to the empirical formulaM.sub.x Z.sub.y Co.sub.3-(x+y) O.sub.4where M comprises at least one metal from the Groups IB, IIA, IIB, where Z comprises at least one metal from Group IA, where x is equal to or greater than zero but less than one, where y is greater than zero but not greater than 0.5, and where x plus 2y is not greater than 1. The composites are prepared by thermally oxidizing metal oxide precursors in-situ on the substrate, including, optionally, modifier metal oxide materials as a separate dispersed phase in the continuous spinel structure.
    Type: Grant
    Filed: March 25, 1981
    Date of Patent: December 28, 1982
    Assignee: The Dow Chemical Company
    Inventors: Donald L. Caldwell, Mark J. Hazelrigg, Jr.
  • Patent number: 4364909
    Abstract: Removal of Ca.sup.++ values from MgCl.sub.2 brine is accomplished by use of a crystalline zeolite structure of the empirical formula Na.sub.12 [(AlO.sub.2).sub.12 (SiO.sub.2).sub.12 ].nH.sub.2 O, where nH.sub.2 O represents waters of hydration.
    Type: Grant
    Filed: March 16, 1981
    Date of Patent: December 21, 1982
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4362533
    Abstract: The flow properties of petroleum distillate fuel oils at low temperature are improved by adding a pour point depressant amount of certain terpolymers of ethylene, vinyl acetate and styrene, particularly characterized as having more uniform macromolecular composition and distribution of monomer constituent units polymerized in the terpolymer macromolecules, made by terpolymerization under steady state conditions and pressure at least 1000 atmospheres and temperature at least 200.degree. C.
    Type: Grant
    Filed: December 13, 1976
    Date of Patent: December 7, 1982
    Assignee: The Dow Chemical Company
    Inventor: Nash A. Kidd
  • Patent number: 4359344
    Abstract: Salt is removed from salt-coated or salt-contaminated Mg particles by leaching the salt with an alkaline aqueous wash, e.g., NaOH, then removing water from the Mg particles by using a water-miscible, inert, evaporatable, non-aqueous liquid, e.g. acetone.
    Type: Grant
    Filed: October 16, 1981
    Date of Patent: November 16, 1982
    Assignee: The Dow Chemical Company
    Inventor: Edward J. Skach, Jr.
  • Patent number: 4348296
    Abstract: Porous substrates containing seeds of hydrous crystalline alumina are contacted with an aqueous solution of alkaline aluminate, thereby causing additional crystalline hydrous alumina to grow on the seeds within the pores of the substrate.
    Type: Grant
    Filed: December 18, 1980
    Date of Patent: September 7, 1982
    Assignee: The Dow Chemical Company
    Inventors: William C. Bauman, John M. Lee, John L. Burba, III
  • Patent number: 4348295
    Abstract: Crystalline hydrous aluminas, Al(OH).sub.3, are reacted with LiX, where X is anion, under appropriate conditions to prepare crystalline compounds conforming substantially to the empirical formulaLiX.2Al(OH).sub.3.nH.sub.2 Owhere X is anion and nH.sub.2 O represents waters of hydration. Depending on the beginning hydrous alumina, some of the crystalline compounds are of a novel 2-layer unit cell structure and some of a 3-layer unit cell structure.
    Type: Grant
    Filed: December 18, 1980
    Date of Patent: September 7, 1982
    Assignee: The Dow Chemical Company
    Inventor: John L. Burba, III
  • Patent number: 4348297
    Abstract: Crystalline LiOH.2Al(OH.sub.3.nH.sub.2 O is reacted in aqueous solution with anions (A) having a valence of 1, 2, or 3 to form novel lithium aluminates conforming substantially to the empirical formula(LiA.sub.x).sub.y.2Al(OH).sub.3.nH.sub.2 Owhere n is the number of waters of hydration, y is the number of lithium atoms present for each 2Al atoms, A has a negative valence of 1, 2, or 3, and x is the reciprocal of the valence of A.
    Type: Grant
    Filed: December 18, 1980
    Date of Patent: September 7, 1982
    Assignee: The Dow Chemical Company
    Inventors: William C. Bauman, John M. Lee
  • Patent number: 4347327
    Abstract: An anion exchange resin, containing Al(OH).sub.3 suspended therein, is reacted with aq. LiOH to form microcrystalline LiOH.2Al(OH).sub.3 which is then reacted with a halogen acid or halide salt to form microcrystalline LiX.2Al(OH).sub.3. The resin, after having a portion of the LiX eluted by using an aqueous wash, is used to recover Li.sup.+ values from aqueous brines.
    Type: Grant
    Filed: November 19, 1979
    Date of Patent: August 31, 1982
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4333846
    Abstract: Crystalline transition metal aluminates conforming generally to the formulaMA.sub.a.sup.v Z.sub.b.sup.v.nAl(OH).sub.3.mH.sub.2 Owhere M is a transition metal having a valence charge of +2 selected from the group consisting of Cu, Zn, Mn, Fe, Co, and Ni, where AZ represents negative valence ions or radicals, v is a negative valence of 1, 2, or 3, n is a value to provide a mol ratio of Al/M of at least 1/1, preferably at least 1.5/1, and m is an integer of from zero to the maximum for waters of hydration, with (va)+(vb) equal to 2, are prepared in alkaline aqueous medium wherein transition metal compounds are caused to form adducts with amorphous hydrous alumina, Al(OH).sub.3, said adducts forming crystals when heated, said aluminates being useful, e.g., as ion exchangers and as spinel precursors among other things.
    Type: Grant
    Filed: September 4, 1980
    Date of Patent: June 8, 1982
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4331711
    Abstract: Salt-coated magnesium particles, useful as desulfurizing agents in steel making, are prepared by impacting onto magnesium particles a very fine salt powder, such as in a ball-mill, then screening to obtain 10-65 mesh size particles containing about 80% to about 95% Mg by weight.
    Type: Grant
    Filed: August 25, 1978
    Date of Patent: May 25, 1982
    Assignee: The Dow Chemical Company
    Inventors: Edward J. Skach, Jr., Marshall P. Neipert
  • Patent number: 4327009
    Abstract: Extrusion-cast films of high molecular weight, linear, low density ethylene copolymers which inherently have high block and high cling characteristics are compounded with a minor amount of a low molecular weight organic, such as a polyglycol, before being extrusion-cast as a thin film, the low molecular weight organic serving to substantially reduce the block, but retaining high cling characteristics.
    Type: Grant
    Filed: September 29, 1980
    Date of Patent: April 27, 1982
    Assignee: The Dow Chemical Company
    Inventors: James A. Allen, George W. Knight, Morris S. Edmondson
  • Patent number: 4326961
    Abstract: Preparations and uses are shown for novel crystalline aluminates which conform generally to the empirical formulaMgA.sub.a.sup.V Z.sub.b.sup.v .multidot.nAl(OH).sub.3 .multidot.mH.sub.2 OwhereA and Z represent negative-valence ions or radicals selected from the group comprising hydroxyl, halide, inorganic acid, and organic acid,n is a value of from about 1 to about 2,v is a negative valence of 1, 2, or 3,a and b each have values of from zero to 2, with (va)+(vb) equal to 2, and with m being a value of zero or more.
    Type: Grant
    Filed: September 4, 1980
    Date of Patent: April 27, 1982
    Assignee: The Dow Chemical Company
    Inventors: John M. Lee, William C. Bauman
  • Patent number: 4321065
    Abstract: Particles of crystalline LiX.multidot.2A1(OH).sub.3 .multidot.nH.sub.2 O, where X is a monovalent, divalent, or trivalent anion, especially chlorine, are useful in gas chromatography in separating hydrocarbons according to boiling point ranges.
    Type: Grant
    Filed: December 18, 1980
    Date of Patent: March 23, 1982
    Assignee: The Dow Chemical Company
    Inventor: John L. Burba, III
  • Patent number: 4313805
    Abstract: Improvements in electrolytic chlor-alkali membrane cells, operated with cell-to-cell catholyte series flow, are obtained by the use, as membranes, of fluoropolymers containing pendant functional groups on the cathode side which are less hydrophilic than sulfonic acid groups. Preferably the functional groups on the catholyte side of the membrane absorb about 5 to about 12 moles of H.sub.2 O per functional group whereas the functional groups on the anolyte side of the membrane absorb more, generally, about 15 to about 30 moles of H.sub.2 O per functional group.
    Type: Grant
    Filed: March 3, 1980
    Date of Patent: February 2, 1982
    Assignee: The Dow Chemical Company
    Inventors: Harry S. Burney, Bobby R. Ezzell
  • Patent number: 4308363
    Abstract: Halogenation of organic polymers having pendant anhydride groups as such, or when said halogenation is followed by reaction of the pendant anhydride groups with nucleophiles, yields novel halogenated derivatives of said polymers.
    Type: Grant
    Filed: April 3, 1980
    Date of Patent: December 29, 1981
    Assignee: The Dow Chemical Company
    Inventor: Walter L. Vaughn
  • Patent number: 4302563
    Abstract: Synthetic polymers containing at least one cyclobutanone group of the formula ##STR1## wherein R.sup.1 to R.sup.4 are selected from the class consisting of alkyl, aryl, halogen, and hydrogen radicals are prepared by reacting in an inert organic solvent a conjugated diene polymer having unsaturated bonds in the main or side chain with a ketone of the formula ##STR2## Such polymers are useful as adhesives and flexibilizers, and they can be readily cross-linked to form elastomeric coatings with good solvent resistance.
    Type: Grant
    Filed: April 3, 1980
    Date of Patent: November 24, 1981
    Assignee: The Dow Chemical Company
    Inventor: Walter L. Vaughn
  • Patent number: 4291001
    Abstract: Improvements are made in the process wherein Li.sup.+ values are recovered from dilute aqueous solution by the use of an anion exchange resin composite containing crystalline LiX.2Al(OH).sub.3, where X is halide. The improvements derive from enriching the Li.sup.+ containing solution with a non-competing metal salt (e.g., NaCl) prior to the Li.sup.+ removal, thereby achieving higher Li.sup.+ loading of the resin composite and obtaining more concentrated eluates.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: September 22, 1981
    Assignee: The Dow Chemical Company
    Inventors: Wendy J. Repsher, Kirby T. Rapstein
  • Patent number: 4279641
    Abstract: Small rotund magnesium (or Mg alloy) granules dispersed in a friable salt matrix are obtained by preparing a molten salt mixture containing molten magnesium (or Mg alloy), stirring to effect good dispersion, and cooling the molten mixture to effect freezing of the magnesium (or Mg alloy) as small rotund globules dispersed in a solid friable salt matrix.
    Type: Grant
    Filed: November 14, 1979
    Date of Patent: July 21, 1981
    Assignee: The Dow Chemical Company
    Inventors: Edward J. Skach, Jr., George B. Cobel
  • Patent number: 4273626
    Abstract: In an electrolytic chlor-alkali cell, or bank of cells, having a plurality of electrolyte compartments containing electrode pairs (anodes and cathodes) and wherein a hydraulically-impermeable membrane separates the electrolyte compartments into catholyte portions and anolyte portions, said cell or cells being employed to produce chlorine at the anodes and caustic and hydrogen at the cathodes by the electrolysis of an aqueous alkali metal chloride electrolyte, improved operation is attained by flowing anolyte liquor from anolyte portion to anolyte portion, sequentially, while simultaneously, and in the opposite direction, flowing catholyte liquor from catholyte portion to catholyte portion, sequentially. The membrane substantially prevents Cl.sup.- from entering the catholyte liquor from the anolyte, and a high purity caustic, substantially free of salt, is produced.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: June 16, 1981
    Assignee: The Dow Chemical Company
    Inventors: Bobby R. Ezzell, Marius W. Sorenson
  • Patent number: 4269675
    Abstract: In an electrolytic chlor-alkali cell, or bank of cells, having a plurality of electrolyte compartments containing electrode pairs (anodes and cathodes) and wherein a hydraulically-impermeable membrane separates the electrolyte compartments into catholyte portions and anolyte portions, said cell or cells being employed to produce chlorine at the anodes and caustic at the cathodes by the electrolysis of an aqueous alkali metal chloride electrolyte, wherein said cathodes are operable as oxygen-depolarized cathodes and are effective in substantially avoiding formation of hydrogen at said cathodes, improved operation is attained by flowing anolyte liquor from anolyte portion to anolyte portion, sequentially, and/or flowing catholyte liquor from catholyte portion to catholyte portion, sequentially. The membrane substantially prevents Cl.sup.- from entering the catholyte liquor from the anolyte, and a high purity caustic, substantially free of salt, is produced.
    Type: Grant
    Filed: November 19, 1979
    Date of Patent: May 26, 1981
    Assignee: The Dow Chemical Company
    Inventors: Bobby R. Ezzell, Marius W. Sorenson