Abstract: A propylene polymerization catalyst is formed by incorporation into a catalytic mixture, comprising a transition metal compound and an organoaluminum compound, effective amounts of Group Va or Group VII oxygen mineral acids whereby the amount of n-hexane-soluble polymeric product is decreased.
Abstract: Physical blends of branched polyphenylene and polyphenylene sulfide exhibit superior flexural strength and flexural modulus properties after high-temperature aging to either component alone.
Abstract: In an alpha-olefin polymerization process using a transition metal halide-aluminum alkyl catalyst system, addition of minor, effective amounts of aromatic amines or amine N-oxides substituted with electron withdrawing groups decreases the amount of low molecular weight or amorphous polymer produced.
Abstract: Thermoplastic polymer particles are converted to pellets by depositing the powder onto a moving platform, melting the particles and transferring the melted polymer to a pelletizer.
Type:
Grant
Filed:
December 29, 1977
Date of Patent:
February 19, 1980
Assignee:
Standard Oil Company a corporation of Indiana
Abstract: Limiting final conversion of monomer to polymer in a multiple stage, vinyl aromatic-rubber mass polymerization system to about 50 to about 89 percent produces a polymer with increased impact strength and decreases residence time, thereby increasing the production capacity of the system.
Abstract: An improved method for separating branched polyphenylene from a polymerization reaction mixture is disclosed which improves polymer properties. The contents of a high pressure polymerization reactor are discharged into one or more devolatilizing units which draw off and recycle low molecular weight unreacted species and separate high molecular weight branched polyphenylene.
Abstract: An asbestos-free sealant composition comprises cotton fiber, amorphous polypropylene and butyl rubber incorporated into a base stock comprising an inorganic filler and a suitable binder.
Abstract: A propylene polymerization catalyst is formed by incorporation into a catalytic mixture, comprising a transition metal compound and an organoaluminum compound, effective amounts of hexavalent sulfur mineral acid or anhydride whereby the amount of n-hexane-soluble polymeric product is decreased.
Abstract: Diisocyanate-modified polyesters formed by heating 100 parts of a polyester with about 2 to 10 parts of a diisocyante to above about 260.degree. C. are useful as superior hot melt adhesives and as durable coatings.
Abstract: A low density, flame-resistant foamed composition is formed by heating a thorough mixture of branched polyphenylene and an inorganic fiber to above about 800.degree. F.
Abstract: Block copolymers containing styrene, alpha-methylstyrene, 3,4-dimethyl-alpha-methylstyrene and lauryl methacrylate are useful as viscosity index improvers in lubricating oils.
Abstract: Adding a finely divided oxide to a terminal olefin polymerization catalyst comprising a hydrocarbon-soluble transition metal compound and a Group II or III metal organic compound reduces the amount of fibrous polymer produced.
Abstract: A composite formed at relatively low temperature from branched polyphenylene and mica exhibits excellent mechanical properties after heat aging.
Abstract: Solid aromatic polymers, such as branched polyphenylenes, are reacted with a reactive gas such as a NO.sub.2 -N.sub.2 O.sub.4 mixture, chlorine and sulfur trioxide without solvent or catalyst. The extent of reaction depends on reaction time and temperature and on the concentration of the reactive gas.
Type:
Grant
Filed:
April 29, 1976
Date of Patent:
November 22, 1977
Assignee:
Standard Oil Company (Indiana)
Inventors:
Eli W. Blaha, Sandra K. Koster, Chen-Shen Wang
Abstract: A reactive additive is disclosed to improve flexibility and toughness in polyester and vinyl aromatic polymeric compositions. The additive is formed as the reaction product of a polyfunctional acid or anhydride, a glycol, an unsaturated acid and a mono alcohol.
Abstract: A binder composition useful in solventless, solvent based and water emulsifiable sealants and adhesives comprises poly(alpha-methylstyrene), polybutene and a polystyrene/elastomer block copolymer.
Type:
Grant
Filed:
May 12, 1975
Date of Patent:
August 16, 1977
Assignee:
Standard Oil Company (Indiana)
Inventors:
Victor V. Raimondi, Roy A. Fox, Casey E. Piorkowski
Abstract: Amide-imide type polymers containing amide derivatives of 4-carboxy-phthalimide aliphatic carboxylic acids are useful as wire coatings and in film and molding applications.
Type:
Grant
Filed:
January 24, 1975
Date of Patent:
August 9, 1977
Assignee:
Standard Oil Company (Indiana)
Inventors:
Steven E. Lindberg, Kerford A. Marchant, Jr., Richard E. Van Strien
Abstract: Powder coating a substrate with a polyolefin or preferably a polyolefin-polycarbonamide blend before contacting the substrate with a plastic resin creating a plastic-substrate seal, inhibits liquid and vapor transmission through the seal. The application of this invention to battery terminal bushings prevents unsightly corrosion about the battery terminal which is caused by "wicking" of battery acid.
Type:
Grant
Filed:
November 29, 1974
Date of Patent:
November 16, 1976
Assignee:
Standard Oil Company (Indiana)
Inventors:
Ivor R. Fielding, Wassily Poppe, Michael M. Schwartz, James P. Whelan
Abstract: Addition of very small amounts of bromine or bromine-containing compounds in the preparation of rubber-modified vinyl aromatic polymers increase their impact resistance.