Patents Represented by Attorney, Agent or Law Firm Wayne C. Jaeschke
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Patent number: 5588809Abstract: Metering pumps for the metered feed of liquids are fitted with an intake valve built into an intake line from an intake container, a pump chamber downstream of it with a pumping component altering its displacement volume, a pressure valve leading to the metering connector and a vent and by-pass valve built into a return line leading to the intake container. In order to keep the quality of by-passed metering liquid as small as possible while maintaining adequate venting, there is valve chamber between the pressure valve and the pump chamber and separated from the latter by a return valve and a movable control wall, in which is incorporated the vent controlled by the control wall, opening on the suction stroke of the pumping component and closing on its delivery stroke. .There is also preferably in the valve chamber a prestressed displacement wall altering the volume of the valve chamber in the opposite direction to that of the control wall.Type: GrantFiled: August 7, 1995Date of Patent: December 31, 1996Assignee: Lang Apparatebau GmbHInventors: Joachim Klein, Herbert Hunklinger
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Patent number: 5589230Abstract: A polymerizable curable molding composition comprising (A) 100 parts by weight of an unsaturated epoxyester resin with an acid value below 3.0, (B) 10 to 40 parts by weight of a polymerizable monomer selected from the group consisting of phenoxyethyl acrylate, 2-acroyloxyethyl-2-hydroxypropyl phthalate and mixtures thereof and (C) 1 to 5 parts by weight of a mixture of hydroxyketone oligomer and 2-hydroxy-2-methyl-1-phenylpropan-1-one. The molding composition also preferably comprises 0.5 to 5 parts by weight of polystyrene microbeads. Also provided are a molding process using the polymerizable curable molding composition and a coating process using the polymerizable curing molding composition, each process being characterized by combined exposure of the composition to UV radiation and heating.Type: GrantFiled: April 7, 1995Date of Patent: December 31, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Yoshitami Yamamura, Nobuhiko Morimoto, Nobuyuki Tanaka
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Patent number: 5587063Abstract: Anodized aluminum surfaces are electrolytically colored using alternating current in a process in which two different coloring baths are sequentially employed. One bath contains copper(II) ions and an additive which improves throwing power thereby providing uniform distribution of the depth of color. The other bath contains tin(II) ions, silver ions, or both tin(II) and silver ions. If tin(II) ions are included, additives which stabilize tin(II) ions and improve throwing power are also included. Either bath may be used first. The use of two separate coloring baths provides colored aluminum surfaces which have excellent resistance to corrosion. Workpieces with reddish-gold hues and darker tones can be produced.Type: GrantFiled: July 28, 1995Date of Patent: December 24, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Peter Kuhm, Christine Schroeder, Volker Sander, Juergen Lindener, Loert De Riese-Meyer
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Patent number: 5587104Abstract: Free-flowing and storable granular compacts containing ingredients of detergent or cleaning compositions in concentrated form are prepared by(1) preparing an adhesively bound dry premix containing(a) fine-particle detergent ingredients substantially free of binding or adhesive properties, and(b) fine-particle detergent ingredients having binding or adhesive properties, and optionally, detergent ingredients which are liquid at room temperature, to form a substantially homogeneous premix, and(2) press-molding the premix at a temperature of from about 40.degree. C. to 80.degree. C. in the substantial absence of shear forces whereby air is microdispersed in the resultant compacts.Type: GrantFiled: September 8, 1993Date of Patent: December 24, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Christiane Zeise, Wilfried Raehse, Jochen Jacobs, Juergen Hoffmeister
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Patent number: 5585340Abstract: An effective phosphate free and organic solvent free aqueous acidic cleaner for soiled plastic surfaces is a low foaming aqueous solution or dispersion that consists essentially of water and:(A) hydroxycarboxylic and/or dicarboxylic acid or acids;(B) nonionic surfactant; and, optionally, one or more of the following:(C) salts including anions of hydroxycarboxylic and/or dicarboxylic acid or acids, preferably anions of the same acid or acids as specified for part (A); and(D) a sufficient amount of hydrotrope material to produce a stable homogeneous solution or dispersion of components (A) through (C) in water; and(E) a sufficient amount of a biocidal material to inhibit growth of any bacteria and/or fungi that may be present in the composition.Type: GrantFiled: November 21, 1994Date of Patent: December 17, 1996Assignee: Henkel CorporationInventor: Theodore D. Held, III
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Patent number: 5584946Abstract: The invention concerns a method of pretreating aluminum or aluminum alloy surfaces before application of a permanent corrosion-protective conversion coating treatment, in particular before phosphating in acidic phosphating baths containing zinc, a chromating treatment, or a chromate free treatment. The method is characterized in that the surfaces are brought into contact with acidic aqueous treatment solutions containing complex fluorides of the elements boron, silicon, titanium, zirconium, or hafnium, alone or in mixtures with each other, at total concentrations between 100 and 4000 mg/L and at a pH between 0.3 and 3.5. Following the pretreatment, the aluminum or aluminum alloy parts may, after shaping if necessary, be joined by adhesive bonding and/or welding to each other or to parts made of steel, zinc plated and/or zinc alloy plated steel, and/or aluminum or aluminum alloy plated steel.Type: GrantFiled: November 22, 1995Date of Patent: December 17, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Uwe Karmaschek, Achim Roland, Hubert Vennschott, Harald Wennemann
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Patent number: 5584944Abstract: A lubricant and surface conditioner for formed metal surfaces, particularly aluminum and tin beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. The conditioner includes a water-soluble organic material selected from amine oxides and quaternary ammonium salts, fluozirconate, fluohafnate, or fluotitanate ion, and preferably also phosphate and nitrate ions. Good resistance to damaging the friction reducing effect by overheating and to staining of the domes of treated containers during pasteurization can be achieved.Type: GrantFiled: June 2, 1995Date of Patent: December 17, 1996Assignee: Henkel CorporationInventors: James P. Bershas, Timm L. Kelly, Gary L. Rochfort, Henry A. Rossmaier
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Patent number: 5584943Abstract: A lubricant and surface conditioner for formed metal surfaces, particularly beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. An aqueous composition for forming the conditioner by contact with metal surfaces includes a water-soluble organic material selected from a phosphate ester, alcohol, fatty acid including mono-, di-, tri-, and polyacids; fatty acid derivatives such as salts, hydroxy acids, amides, esters, ethers and derivatives thereof; and mixtures thereof and at least one of the elements selected from zirconium, titanium, cerium, aluminum, iron, tin, vanadium, tantalum, niobium, molybdenum, tungsten, and hafnium in metallic or ionic form. In order to avoid formation of sludge in the aqueous lubricant and surface conditioner forming composition, the composition should contain as little as possible of materials containing phenanthrene rings, such as conventional surfactants made by ethoxylating rosin.Type: GrantFiled: December 22, 1994Date of Patent: December 17, 1996Assignee: Henkel CorporationInventors: Richard D. Banaszak, Timm L. Kelly, Gary L. Rochfort
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Patent number: 5582934Abstract: The present invention relates to compositions and methods for improving the performance of lead-acid storage batteries, and reducing corrosion in lead-acid storage batteries, including the plates, terminals, posts, and cables. Compositions of the invention include cathodic inhibitors and solutions of cathodic inhibitors.Type: GrantFiled: May 17, 1995Date of Patent: December 10, 1996Assignee: Henkel CorporationInventor: Lester Steinbrecher
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Patent number: 5583167Abstract: Provided are epoxy curing agents comprising the reaction product of reactants consisting essentially of an alkylene polyamine having less than about 12 carbon atoms, an aromatic mono-glycidyl ether having less than about 18 carbon atoms, and a diglycidyl ether of an aromatic diol having an average degree of oligomerization of less than about 3.5, wherein the ratio of primary amine equivalents of said alkylene polyamine to the total epoxide equivalents of said aromatic glycidyl ether and said diglycidyl ether of an aromatic diol is not essentially less than one, and the ratio of epoxide equivalents of said aromatic mono-glycidyl ether to epoxide equivalents of said diglycidyl ether of an aromatic diol is greater than one.Type: GrantFiled: June 30, 1993Date of Patent: December 10, 1996Assignee: Henkel CorporationInventors: Jason L. Chou, Shailesh Shah, Brian G. Jewell, Robert M. Moon
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Patent number: 5580850Abstract: Described are detergent mixtures containing (a) quaternarized fatty-acid alkanolamine esters of formula (I), in which R.sup.1 CO is an aliphatic acyl group with 6 to 22 carbon atoms and 0 or 1 double bonds, Z is an ethylene or isopropylene group, EO is a CH.sub.2 CH.sub.2 O-- unit, (m+n+p) is a number from 1 to 10 and X is a halide, a methosulphate or an alkylphosphate anion, plus (b) other anionic, non-ionic and/or amphoteric or zwitterionic surfactants. Such mixtures have a high foaming power, are easily concentrated and have a long shelf life.Type: GrantFiled: March 23, 1995Date of Patent: December 3, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Joaquim Bigorra Llosas, Esther Prat Queralt, Oriol Ponsati Obiols
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Patent number: 5578642Abstract: There is provided a composition and process for preparing self-emulsifying or emollient agents comprising reacting from about 1 mole of azelaic acid with from about 1 to about 1.25 moles of a C12-18 fatty alcohol to form an azelaic acid monoester having the general formula I-IV: ##STR1## wherein R is a C12-18 fatty alcohol, and the product contains from about 40 to about 50 weight percent of (I), from about 50 to about 60 weight percent of (II), from about 1 to about 2 weight percent of (III), and from about 0 to about 1 weight percent of (IV), all weights being based on the weight of said self-emulsifying or emollient agent.Type: GrantFiled: August 17, 1994Date of Patent: November 26, 1996Assignee: Henkel CorporationInventors: Barry A. Salka, Bruce W. Gesslein, Norman Milstein
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Patent number: 5578560Abstract: An aqueous detergent composition containing: (a) from 12 to 15% by weight of a nonionic surfactant selected from the group consisting of alkyl oligoglycosides, alkenyl oligoglycosides, and mixtures thereof; (b) from 20 to 30% by weight of an alkyl sulfate; (c) from 40 to 60% by weight of an alkyl ether sulfate, and (d) from 12 to 15% by weight of a component selected from the group consisting of amphoteric surfactants, zwitterionic surfactants, and mixtures thereof, all weights being based on the solids content of the composition.Type: GrantFiled: April 13, 1995Date of Patent: November 26, 1996Assignee: Henkel CorporationInventors: Brigitte Giesen, Guenter Kreienfeld, Andreas Syldath, Karl-Heinz Schmid
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Patent number: 5578558Abstract: Hydraulic oils containing as a base oil at least one Guerbet alcohol of the formula R--OH in which R is a single branched radical containing from 24 to 44 carbon atoms and having an iodine value of from 20 to 150.Type: GrantFiled: February 8, 1996Date of Patent: November 26, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Gerhard Mueller, Frank Bongardt, Matthias Fies, Peter Daute
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Patent number: 5578199Abstract: A system automated for providing at least periodic removal of metal ions and contaminants from a chemical bath, consists of a microprocessor programmed for controlling fluid circuits of pumps and valves, for in one state of operation circulating a first predetermined quantity of the chemical bath from a first tank, through an ion exchange column, and back to the first tank; for in a second state of operation circulating deionized water from a second tank into the IEX column for displacing residual chemical bath therefrom for return to the first tank; for in a third state of operation circulating deionized water through the IEX column, and discharging the rinse water from a waste port; for in a fourth state of operation circulating regenerant acid through the ion exchange column, and discharging the used acid from a waste port; for in a fifth state of operation circulating deionized water through the IEX column for rinsing acid regenerant therefrom and discharging the same out of a waste port; and for in a sixType: GrantFiled: November 7, 1994Date of Patent: November 26, 1996Assignee: Henkel CorporationInventors: William G. Kozak, Joseph C. Topping
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Patent number: 5575918Abstract: A process for the separation of naphthalenesulfonate-based carbonyl condensates from water is provided. The process comprises contacting a mixture comprised of water and a naphthalenesulfonate-based carbonyl condensate (preferably a material selected from the group consisting of formaldehyde condensates of naphthalenesulfonic acids, formaldehyde condensates of lower-alkyl substituted naphthalenesulfonic acids, and mixtures of two or more of such materials) with a liquid organic phase comprised of a lipophilic non-quaternary amine to form an aqueous phase depleted with respect to said mixture of naphthalenesulfonate-based carbonyl condensate and a liquid organic phase enriched in naphthalenesulfonate-based carbonyl condensate. The process further comprises separating said aqueous phase depleted with respect to said mixture of naphthalenesulfonate-based carbonyl condensate and said liquid organic phase enriched with respect to naphthalenesulfonate-based carbonyl condensate.Type: GrantFiled: February 28, 1995Date of Patent: November 19, 1996Assignee: Henkel CorporationInventors: Michael J. Virnig, Phillip L. Mattison, Keith E. Weerts
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Patent number: 5576367Abstract: Liquid polyester plasticizers, having a hydroxyl value of at least 25, are incorporated into vinyl resins, such as PVC, which are formed into gaskets for use on appliances made from textured coil stock, especially refrigerators or freezers. These plasticizers have no detrimental effect on the relatively soft surface coatings on such appliances.Type: GrantFiled: January 3, 1990Date of Patent: November 19, 1996Assignee: Henkel CorporationInventors: William L. O'Brien, William J. Mertz
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Patent number: 5576284Abstract: A disinfectant-containing hard surface cleaner composition having increased bacteria count-reducing efficacy is provided by adding thereto a mixture of an alkyl or alkenyl oligoglycoside and certain C.sub.8 -C.sub.18 alkyl ethers.Type: GrantFiled: September 26, 1994Date of Patent: November 19, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Gregory van Buskirk, Karl-Heinz Disch, Carsten Friese, Eva Kiewert, Birgit Middelhauve
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Patent number: 5576470Abstract: A compound of the general formula (I) ##STR1## wherein R is alkyl from about 4 to about 22 carbon atoms, R.sup.1 and R.sup.2 independently of one another are alkyl from about 1 to about 22 carbon atoms, X is either sulphur or oxygen, Y is --C.sub.2 H.sub.4 O-- or --C.sub.3 H.sub.6 O-- or a mixture of --C.sub.2 H.sub.4 O and --C.sub.3 H.sub.6 O--, m is a number from about 1 to about 20, n is a number from about 1 to about 6, p is a number from 2 to 4, q is a number from 0 to about 2 and r is a number from 0 to about 2, with q+r+p being the integer 4. This invention is also directed m the method for treating fibers by applying this compound.Type: GrantFiled: August 29, 1994Date of Patent: November 19, 1996Assignee: Henkel CorporationInventors: F. Norman Tuller, Michael E. Allen
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Patent number: 5576425Abstract: The aliphatic primary alcohols are reacted with a glycose, more especially glucose, in the presence of an acidic catalyst in certain process steps so that particularly light-colored and alkali-stable alkyl glucosides are obtained after a subsequent, compulsory bleaching step, which represents an improvement over known direct synthesis processes. The process may be carried out both on a laboratory scale and also on an industrial production scale.Type: GrantFiled: July 25, 1994Date of Patent: November 19, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Karlheinz Hill, Manfred Biermann, Henry Rossmaier, Rainer Eskuchen, Willi Wuest, Josef Wollmann, Andreas Bruns, Guenter Hellmann, Karl-Heinz Ott, Walter Winkle, Klaus Wollmann