Abstract: There is disclosed a catalyst, which catalyst comprises a hydrogenation component comprising chromium, molybdenum, and at least one metal of Group VIII, a crystalline molecular sieve zeolite, and a porous refractory inorganic oxide. Suitable molecular sieve zeolites are those having pore diameters of at least 5 .ANG. (0.5 nm) and containing exchangeable cations, for example, faujasite crystalline aluminosilicates, mordenite crystalline aluminosilicates, ZSM crystalline aluminosilicates, and AMS crystalline metallosilicates.There are also disclosed processes for the hydrodenitrogenation and hydrocracking of a hydrocarbon stream containing a substantial amount of nitrogen compounds, which processes comprise contacting said stream under suitable conditions and in the presence of hydrogen with the aforesaid catalyst.
Type:
Grant
Filed:
April 19, 1982
Date of Patent:
October 9, 1984
Assignee:
Standard Oil Company (Indiana)
Inventors:
A. Martin Tait, Thomas D. Nevitt, Albert L. Hensley, Jr.
Abstract: A catalyst, a process for preparing said catalyst, and a process for producing purified terephthalic acid, wherein 4-carboxybenzaldehyde is reduced to very low levels, wherein said catalyst is prepared by contacting a solution of a suitable palladium salt in an organic solvent with a suitable activated carbon support, wherein said palladium salt is reduced to palladium metal crystallites by said activated carbon support. Purified terephthalic acid is prepared by hydrogenating crude terephthalic acid in the presence of said catalyst.
Abstract: Ammonium nitrate shale oil explosives are provided which are effective, powerful, inexpensive, and safe. The explosives contain about 2% to 10% by weight shale oil and about 90% to 98% by weight ammonium nitrate. The shale oil can be whole shale oil or heavy shale oil containing from 0.1% to 65% by weight oil shale dust. The ammonium nitrate is preferably in the form of explosive grade ammonium nitrate prills.
Type:
Grant
Filed:
October 24, 1983
Date of Patent:
October 9, 1984
Assignees:
Standard Oil Company (Indiana), Gulf Oil Corp.
Abstract: Novel crystalline copolymers having heat deflection temperatures in excess of 305.degree. C. and prepared from hexamethylene diamine, trimethylhexamethylene diamine and either mixtures of terephthalic acid and adipic acid or mixtures of terephthalic acid, isophthalic acid and adipic acid. The high heat deflection of these polyamides enables them to be used in applications such as a hood for an automobile, a shroud for a lawn mower, chain saw guards and in electrical connection applications.
Abstract: Anti-friction additives for lubricating oil are prepared by reacting a sulfurized organic compound having an active hydrogen or potentially active hydrogen with a molybdenum halide. The resulting product has friction reducing properties at least as good as currently available phosphorus-containing additives.
Abstract: Raw oil shale is retorted to liberate an effluent product stream. Ammonia is withdrawn from the product stream and reacted to produce ammonium nitrate. Shale oil is separated from the product stream and mixed with 90% to 98% by weight ammonium nitrate to produce explosives. The shale oil can be whole shale oil or heavy shale oil containing from 0.1% to 65% by weight oil shale dust. The ammonium nitrate is preferably in the form of explosive grade ammonium nitrate prills. The shale oil is preferably heated before being mixed with the ammonium nitrate to make the shale oil more blendable.
Type:
Grant
Filed:
October 24, 1983
Date of Patent:
October 2, 1984
Assignees:
Standard Oil Company (Indiana), Gulf Oil Corp.
Abstract: Instead of total base number of about 30 for an alkaline earth metal sulfonate prepared by reacting up to 200 molar excess of alkaline earth metal compound at a temperature above 104.degree. C. with an alkylbenzene sulfonic acid in the presence of from 0.5 to 10 weight parts of water per 1.0 weight part of alkaline earth metal compound under a pressure of from 2 to 10 atmospheres an oil-soluble magnesium-alkylbenzene sulfonate of total base number of 400 and higher is obtained by reacting at least on 8.5 to 1.0 molar ratios of magnesium oxide to ammonium alkylbenzene sulfonate at a temperature of from 100.degree. C. to 130.degree. C. under autogeneous pressure in the presence of at least 1.1 weight parts of water and 0.3 to 0.5 of methanol per weight part of magnesium oxide. After decompressing and removing water and methanol, the product high base number magnesium alkylbenzene sulfonate is obtained.
Abstract: An amorphous, oil soluble ethylene/propylene/CO polymer having a mole ratio of ethylene to propylene from about 35:65 to 60:40 and lube oil compositions comprising said polymers.
Abstract: A centrifugal drying and dedusting process is provided to dedust heavy oil derived from solid hydrocarbon-containing material such as oil shale, coal or tar sand. In the process, heavy oil laden with particulates derived from the solid hydrocarbon-containing material is centrifuged into a dedusted stream of heavy oil and a dust laden centrifuge sludge. The dedusted stream of oil can be further dedusted in a desalter, after being first mixed with fresh water, to form a purified, highly dedusted, effluent stream of heavy oil. Dust laden water from the desalter is centrifuged into a dedusted stream of water and a dewatered centrifuge sludge. The dedusted stream of water is recycled upstream of the desalter and mixed with the influent oil stream. Desirably, the centrifuges sludges are mixed, heated, dried and separated into another dedusted stream of oil and a powdery, dust-enriched residual stream which can be combusted in a lift pipe for use as heat carrier material in the dryer and retort.
Abstract: A heat treatment for live yeast cell slurries and pastes, which comprises heating the slurry or paste at a temperature of about 60.degree. C. or greater for a sufficient period of time, increases the fluidity of the slurry or paste and allows more highly concentrated suspensions to be processed than otherwise possible.
Abstract: The catalyst comprises a physical particle-form mixture of a Component A, a Component B, and a Component C, said Component A comprising at least one Group VIII noble metal, preferably platinum, deposed on a solid catalyst support material providing acidic catalytic sites, said Component B comprising a small amount of a non-noble metal of Group VIII selected from cobalt, nickel, and mixtures thereof, preferably cobalt, on a solid catalyst support material providing acidic catalytic sites, said Component C comprising a small amount of gallium deposed on a solid catalyst support material providing acidic catalytic sites, and said catalyst having been prepared by thoroughly and intimately blending finely-divided particles of said Components A, B, and C to provide a thoroughly-blended composite.The catalyst can be employed suitably in a hydrocarbon conversion process.
Type:
Grant
Filed:
September 16, 1983
Date of Patent:
September 4, 1984
Assignee:
Standard Oil Company (Indiana)
Inventors:
Cecelia M. Sorrentino, Regis J. Pellet, Ralph J. Bertolacini
Abstract: An improved method and machine for reclaiming in an on-line configuration both oriented and unoriented film produced on an extrusion line, in general, and an improved means within an on-line reclaim system for transferring both virgin resin and chopped reclaim to an in-line extruder, in particular, are disclosed.
Abstract: A process for recovery of vanadium and molybdenum from a feed material containing compounds of these metals by reacting at an effective pH an aqueous solution of vanadate and molybdate anions with a quaternary ammonium surfactant dissolved in an organic solvent which is immiscible with water and separating a vanadate anion rich phase from a molybdate anion rich phase.
Abstract: A process for producing a purified terephthalic acid which comprises reacting in a liquid phase a mixture of hydrogen and crude terephthalic acid, a palladium/rhodium catalyst on a porous carbonaceous support wherein the catalyst compound is prepared by adsorbing palladium on the support from a complex salt formed in the presence of an amine and acetic acid, followed by deposition of rhodium from a solution of sodium hexanitritorhodate.
Abstract: Lubricating oil composition comprising the reaction product of a phenolic compound, a molybdenum, an amine and sulfur or a sulfur-yielding compound. Preferably, molybdenum oxide, an alkyl-substituted phenol having an alkyl side chain of at least 9 carbon atoms, an amine having at least one aliphatic hydrocarbon-based radical or aliphatic-substituted aromatic radical and elemental sulfur are reacted to produce the reaction product of the invention.
Abstract: A catalyst and process for purifying crude terephthalic acid wherein the catalyst is prepared by contacting a carbonaceous support with an aqueous solution of sodium tetranitropalladate.
Abstract: Flow properties of polyamide-imide polymers are improved by the addition of amorphous polyamides. These polymers are useful as engineering resins, laminates, and molded objects.
Abstract: A plugging apparatus is provided to reliably plug a bottomless blast hole in underground oil shale retorts and oil and gas wells. The plugging apparatus has a special electrically powered sequencer which automatically lowers and releases a bag of cementatious slurry, supported by a drainpipe-reinforced concrete disc, from a canister to form a composite blasting plug in the blast hole.
Type:
Grant
Filed:
June 30, 1982
Date of Patent:
August 14, 1984
Assignees:
Standard Oil Company (Indiana), Gulf Oil Corporation
Abstract: An improved process is provided for blasting in situ oil shale retorts, and oil and gas wells. In the process, a specially formed concrete plug is installed at a desired depth in a bottomless blast hole and an explosive charge is placed upon the plug and detonated to blast the underground formation. The plug is accurately and reliably set by lowering a canister, which releasably houses a bag support assembly supporting a bag of concrete slurry, to a desired depth into the blast hole. The bag support assembly and bag of wet concrete are subsequently dropped a fixed distance below the canister. The bag of concrete expands, dries, and hardens against the walls of the blast hole to form a permanent stationary plug across the blast hole. In the preferred process, the bag support assembly is formed by casting a concrete disc around a drainpipe, and the bag support assembly is lowered and released from the canister with the aid of an electrically powered sequencer.
Type:
Grant
Filed:
June 30, 1982
Date of Patent:
August 14, 1984
Assignees:
Standard Oil Company (Indiana), Gulf Oil Corporation