Abstract: Provided herein are processes for the separation of acetonitrile from low-purity feedstock streams. The provided processes are particularly useful for isolating acetonitrile at high purity from chemical manufacturing waste streams that include methanol, water, and allyl alcohol.

Abstract: A method for tuning characteristics of a polyamide nanofiber nonwoven comprising the step of targeting a specific average nanofiber diameter and/or a specific relative viscosity for the polyamide nanofiber nonwoven. The specific average nanofiber diameter is within a range from 100 nm to 1000 nm and/or the specific relative viscosity is within a range from 5 to 75, e.g., from 15 to 50. The process further comprises the steps of extruding a polyamide composition having a moisture content with a pressurized gas through a fiber forming channel having a channel temperature to form the polyamide nanofiber nonwoven having the target average nanofiber diameter and/or relative viscosity and controlling the moisture content, the pressure of pressurized gas, and/or the channel temperature based on the specific average nanofiber diameter and/or the specific relative viscosity.

Abstract: A process for converting caprolactam to aminocapronitrile, the process comprising contacting a caprolactam feed with ammonia and an aluminosilicate zeolite catalyst to produce an aminocapronitrile product, wherein the catalyst comprises less than 5 wt. % of an active metal, and wherein conversion is greater than 50% and selectivity for aminocapronitrile is greater than 91%.

Abstract: A flame retardant polyamide composition comprising a polyamide, a non-halogenated, phosphinate-based flame retardant, an impact modifier comprising an alkene/acrylate copolymer/terpolymer, a flame retardant synergist and an optional reinforcing agent. The flame retardant polyamide composition demonstrates a passing value for a glow wire end product test as measured by IEC 60695-2-11, a passing value for a glow wire ignition test as measured by IEC-60695-2-13:201; a passing value (V0 rating) for UL94 performance at 0.8 mm; and an elongation at break greater than 2.7%, as measured by to ISO Test No. 527:2012.

Abstract: The present disclosure relates to a nonwoven polyamide structure having antimicrobial properties comprising: nonwoven polyamide fibers comprising less than 4000 ppm zinc dispersed within the nonwoven polyamide fibers; and less than 2000 ppm phosphorus. The fibers have an average fiber diameter of less than 25 microns; and the polyamide structure demonstrates a Staphylococcus aureus reduction of at least 90%, as measured by ISO 20743-13.

Abstract: An AM/AV fabric, comprising base fibers comprising a base polymer composition comprising a base polymer; and short AM/AV fibers comprising an AM/AV polymer composition comprising an AM/AV polymer and an AM/AV compound. The fabric has a charge and demonstrates a particle efficiency greater than 20% when measured in accordance with TSI 8130A test system at 10.5 ft/min face velocity, and a Klebsiella pneumoniae efficacy log reduction greater than 1.5, as measured in accordance with ASTM E3160 (2018).

Abstract: Provided herein are processes for purifying TCH in a feed stream, such as an adiponitrile process stream. The processes include a first separating step of separating the adiponitrile process stream to form a first overhead stream comprising low-boiling components and high-boiling components and a first bottoms stream comprising high-boiling components. The processes also include a second separating step of separating the first overhead stream in one or more distillation columns to form a lights stream comprising low-boiling components, a heavies stream comprising high-boiling components, and a TCH stream.

Abstract: A low-halogen flame retardant thermoplastic polyamide composition providing improved mechanical and electrical stability at elevated temperatures, where the thermoplastic composition comprises a polyamide resin; a non-halogen flame retardant; a heat stabilizer containing a copper halide and an organophosphorus compound; an optional lubricant and/or mold release agent; and an optional colorant.

Abstract: A base polyamide composition comprising a nylon mixture having caprolactam units from 1 wppb to 50 wppm catalyst composition; and greater than 0.75 wt % residual caprolactam, wherein the base polyamide composition has a delta end group level ranging from 30 ?eq/gram to 90 ?eq/gram.

Abstract: An antistripping composition, comprising a first triamine compound or a second amine compound, and less than 1 wt % of a nitrile compound. When the antistripping composition is used in a bitumen composition, the bitumen composition demonstrates 50% or more retained coating as measured according to AASHTO T 283 (2022), and a tensile strength ratio of at least 80% when measured according to ASTM D 3625 (2020).

Abstract: A copolyamide composition comprising a statistical copolyamide containing 70-99 wt % of diamine and dicarboxylic acid repeat units and 1-30 wt % of lactam or AA-BB repeat units, whereby incorporation of the comonomer lactam or AA-BB unit reduces the crystallization rate (longer crystallization times) while maintaining (1) high melting point, (2) low potential plate out, (3) low oxygen permeation, (4) high tensile strength and (5) puncture/tear resistance.

Abstract: This disclosure relates to a process for producing treated AM/AV fibers comprising treating, with an alkali composition, base AM/AV fibers comprising a polymer composition comprising a polymer and an AM/AV compound to form treated AM/AV fibers. The treated AM/AV fibers demonstrate a Klebsiella pneumonia log reduction greater than 1.5, as determined via ISO20743:2013.

Abstract: A method of producing a polyamide elastomer comprising feeding a salt solution having a solids content of greater than or equal to 80% to a reactor having a phosphorous containing catalyst having a phosphorous level from 5 to 1000 part by million based on the total weight of the catalyst, feeding a polyether amine to the reactor, and reducing the pressure in the reactor once a target temperature is reached to polymerize the salt solution and the polyether amine to form the polyamide elastomer. The polyamide elastomer has particular uses as a cable tie and demonstrates improved cold-temperature applications while maintaining high strength, good flammability rating, and excellent processability.

Abstract: A process for producing acetonitrile, the process comprising: treating a feedstock stream comprising methanol, allyl alcohol, oxazole, acetonitrile, water, and hydrogen cyanide to remove hydrogen cyanide and produce an acetonitrile stream comprising less than 1 wt. % hydrogen cyanide. The process further comprises the step of distilling the acetonitrile stream in a first distillation column to produce a first distillate comprising oxazole and methanol; a first intermediate acetonitrile stream comprising acetonitrile and oxazole and less than 1 wt % allyl alcohol; a first bottoms stream comprising allyl alcohol and water. The process further comprises the step of purifying the first intermediate acetonitrile stream to produce an acetonitrile product stream and a recycle stream comprising allyl alcohol.

Abstract: A terpolymer composition is described that contains a statistical amount of 50-98 wt % of a first repeating AA-BB comonomer unit; 1-25 wt % of a second repeating AA-BB comonomer unit; and 1-25 wt % of a repeating lactam comonomer unit or 1-25 wt % of a third repeating AA-BB comonomer unit, where the terpolymer composition exhibits a high melting point similar to that of PA66 while also exhibiting a significantly reduced crystallization rate and crystallization temperature.

Abstract: The present invention relates to catalyst compositions containing a mixed oxide catalyst of formula (I) or formula (II) as described herein, their preparation, and their use in a process for ammoxidation of various organic compounds to their corresponding nitriles and to the selective catalytic oxidation of excess NH3 present in effluent gas streams to N2 and/or NOx.

Abstract: Provided herein are processes for purifying TCH in a feed stream, such as an adiponitrile process stream. The processes include a first separating step of separating the adiponitrile process stream to form a first overhead stream comprising low-boiling components and high-boiling components and a first bottoms stream comprising high-boiling components. The processes also include a second separating step of separating the first overhead stream in one or more distillation columns to form a lights stream comprising low-boiling components, a heavies stream comprising high-boiling components, and a TCH stream.

Abstract: The present disclosure relates to a process for stabilizing an antimony ammoxidation catalyst in an ammoxidation process. The process may comprise providing an antimony ammoxidation catalyst to a reactor; reacting propylene with ammonia and oxygen in the fluidized bed reactor in the presence of the antimony ammoxidation catalyst to form a crude acrylonitrile product; and adding an effective amount of an antimony-containing compound to the antimony ammoxidation catalyst to maintain catalyst conversion and selectivity; wherein the antimony-containing compound has a melting point less than 375° C. The present disclosure also relates to catalyst compositions and additional processes using the antimony ammoxidation catalyst stabilized by an antimony-containing compound.

Abstract: The present disclosure relates to a nonwoven polyamide structure having antimicrobial properties comprising: nonwoven polyamide fibers comprising less than 4000 ppm zinc dispersed within the nonwoven polyamide fibers; and less than 2000 ppm phosphorus. The fibers have an average fiber diameter of less than 25 microns; and the polyamide structure demonstrates a Staphylococcus Aureus reduction of at least 90%, as measured by ISO 20743-13.

Abstract: A copolyamide composition comprising a statistical copolyamide containing 70-99 wt % of diamine and dicarboxylic acid repeat units and 1-30 wt % of lactam or AA-BB repeat units, whereby incorporation of the comonomer lactam or AA-BB unit reduces the crystallization rate (longer crystallization times) while maintaining (1) high melting point, (2) low potential plate out, (3) low oxygen permeation, (4) high tensile strength and (5) puncture/tear resistance.