Abstract: Described herein is an improved conversion of nitrous oxide (N2O) present as a by-product in a chemical process to NOx which can be further converted to a useful compound or material, such as nitric acid.

Abstract: The present disclosure relates to a process for stabilizing an antimony ammoxidation catalyst in an ammoxidation process. The process may comprise providing an antimony ammoxidation catalyst to a reactor; reacting propylene with ammonia and oxygen in the fluidized bed reactor in the presence of the antimony ammoxidation catalyst to form a crude acrylonitrile product; and adding an effective amount of an antimony-containing compound to the antimony ammoxidation catalyst to maintain catalyst conversion and selectivity; wherein the antimony-containing compound has a melting point less than 375° C. The present disclosure also relates to catalyst compositions and additional processes using the antimony ammoxidation catalyst stabilized by an antimony-containing compound.

Abstract: A sound absorbing multi-layer composite for a vehicle that reduces sounds along an acoustic path is configured with a non-foam polymeric layer and a face layer for dissipating sound energy. Also, the face layer may be made of a nonwoven polymer comprising at least 60% of a polyamide containing an aliphatic diamine having 6 or more carbon atoms and an aliphatic diacid having 6 or more carbon atoms. The weighted overall average fiber diameter of the composite is from 2 microns to 25 microns.

Abstract: Provided herein are antistripping compositions which may be used, for example, as additives to bitumen compositions such as asphalt concrete to prevent or reduce susceptibility to water damage. In particular, the antistripping compositions of the present disclosure have a triamine component and a nitrile component. Also provided herein are bitumen compositions, such as asphalt, having a portion of the described antistripping compositions as an additive.

Abstract: The present disclosure relates to polyamide compositions and resulting injection-molded articles that can be plated, e.g., metal coated, to form aesthetic injection-molded articles. The polyamide compositions may include from 45 wt. % to 75 wt. % of an polyamide, from 2 wt. % to 40 wt. % of an etchable filler, from 10 wt. % to 40 wt. % of a semi-structural mineral, and optionally from 0.1 wt. % to 13 wt. % of additive. The polyamide composition imparts very good surface appearance to injection-molded articles that are substantially free of visual defects.

Abstract: A method of removing from a surface a solid sulfur-containing impurity composition comprising a sulfur-containing compound, the method comprising the step of dissolving sulfur-containing compound in the sulfur-containing impurity composition with a nitrile compound to form a treated sulfur-containing impurity composition comprising less than 99.5 wt % sulfur-containing compound, based on the total weight of the treated sulfur-containing impurity composition.

Abstract: The present disclosure relates to polyamide compositions and resulting injection-molded articles that can be plated, e.g., metal coated, to form structurally aesthetic injection-molded articles. The polyamide compositions may include from 40 wt. % to 80 wt. % of a polyamide, from 0.5 wt. % to 40 wt. % of an etchable filler, from 5 wt. % to 30 wt. % of glass fiber, optionally less than 40 wt. % of a semi-structural mineral, and optionally from 0.1 wt. % to 13 wt. % of additive. The polyamide composition imparts very good surface appearance and excellent mechanical properties to injection-molded articles that are substantially free of visual defects.

Abstract: Provided herein are processes for the separation of acetonitrile from low-purity feedstock streams. The provided processes are particularly useful for isolating acetonitrile at high purity from chemical manufacturing waste streams that include methanol, water, and allyl alcohol.

Abstract: A process for producing acetonitrile, the process comprising: treating a feedstock stream comprising methanol, allyl alcohol, oxazole, acetonitrile, water, and hydrogen cyanide to remove hydrogen cyanide and produce an acetonitrile stream comprising less than 1 wt. % hydrogen cyanide. The process further comprises the step of distilling the acetonitrile stream in a first distillation column to produce a first distillate comprising oxazole and methanol; a first intermediate acetonitrile stream comprising acetonitrile and oxazole and less than 1 wt % allyl alcohol; a first bottoms stream comprising allyl alcohol and water. The process further comprises the step of purifying the first intermediate acetonitrile stream to produce an acetonitrile product stream and a recycle stream comprising allyl alcohol.

Abstract: Provided herein are filter media structures having antimicrobial and/or antiviral properties. In particular, the present disclosure describes filter media structures having a first layer with an electret web and a second layer that demonstrates biological-reducing properties. In some cases, the first layer is formed from polypropylene (e.g., spunbond) and the second layer is formed from a plurality of fibers of a polyamide composition (e.g., meltblown).

Abstract: A polyamide composition comprising from 45 wt % to 95 wt % of polyamide polymer and from 5 wt % to 55 wt % of a modifier comprising a C18-44 dimer acid or a C18-44 dimer amine or a combination thereof. A number average molecular weight of the polyamide polymer is less than 30,000 g/mol. The polyamide composition has a chemical resistance, as measured by exposure to HCl (10%) for 14 days at 58° C., resulting in a weight loss of less than 3.0 wt %; and a moisture uptake of less than about 2.0 wt % moisture at 95% RH. A process for preparing the polyamide composition is also disclosed.

Abstract: The present disclosure relates the polymer compositions, fibers, and yarns having near-permanent antimicrobial activity, and a method of producing the same. In one embodiment, the antimicrobial polymer composition from 50 wt % to 99.9 wt % of a polymer, from 5 wppm to 1000 wppm of zinc, and from 0.005 wt % to 1 wt % of phosphorus, wherein fibers formed from the polymer composition demonstrate a zinc retention rate of greater than 20% when tested in a dye bath test.

Abstract: The present disclosure relates to a process for stabilizing an antimony ammoxidation catalyst in an ammoxidation process. The process may comprise providing an antimony ammoxidation catalyst to a reactor; reacting propylene with ammonia and oxygen in the fluidized bed reactor in the presence of the antimony ammoxidation catalyst to form a crude acrylonitrile product; and adding an effective amount of an antimony-containing compound to the antimony ammoxidation catalyst to maintain catalyst conversion and selectivity; wherein the antimony-containing compound has a melting point less than 375° C. The present disclosure also relates to catalyst compositions and additional processes using the antimony ammoxidation catalyst stabilized by an antimony-containing compound.

Abstract: Reaction pathways and conditions for the production of nitrogen-containing chelators, such as a glycine derivative, as described herein. In particular, the present disclosure describes a process for the production of a nitrile intermediate by reacting a tetra-amino compound with an aldehyde and a hydrogen cyanide to form the nitrile intermediate. The nitrile intermediate may then be further processed to produce the chelators at a high yield and/or a high purity.

Abstract: Reaction pathways and conditions for the production of nitrogen-containing chelators, such as a glycine derivative, are described herein. In particular, the present disclosure describes a process for the production of a nitrile intermediate by reacting a tetra-amino compound with an aldehyde and a hydrogen cyanide to form the nitrile intermediate. The nitrile intermediate may then be further processed to produce the chelators at a high yield and/or a high purity.

Abstract: Reaction pathways and conditions for the production of nitrogen-containing chelators, such as a glycine derivative, are described herein. In particular, the present disclosure describes a process for the production of a nitrile intermediate at a high yield and/or purity. This process includes reacting a dinitrile compound with an aldehyde and a hydrogen cyanide to form the nitrile intermediate. The nitrile intermediate may then be further processed to produce the chelators at a high yield and/or a high purity.

Abstract: Clay stabilization compositions include one or a plurality of triamino compounds and/or derivatives thereof, fluids containing an effective amount of the clay stabilization compositions and methods for making and using same.

Abstract: The present disclosure relates the polymer compositions, fibers, and yarns having near-permanent antimicrobial activity, and a method of producing the same. In one embodiment, the antimicrobial polymer composition from 50 wt % to 99.9 wt % of a polymer, from 5 wppm to 1000 wppm of zinc, and from 0.005 wt % to 1 wt % of phosphorus, wherein fibers formed from the polymer composition demonstrate a zinc retention rate of greater than 20% when tested in a dye bath test.

Abstract: Provided herein are polyamide compositions including one or more semi-crystalline polyamides and either an amorphous polyamide or a semi-crystalline copolyamide such as PA66/6. The provided compositions are particularly useful as vibration isolators more effective at high-temperature noise and harshness damping than conventional polyamide compositions. Also provided are methods for making the provided compositions, and articles that include the provided compositions.

Abstract: A method for tuning characteristics of a polyamide nanofiber nonwoven comprising the step of targeting a specific average nanofiber diameter and/or a specific relative viscosity for the polyamide nanofiber nonwoven. The specific average nanofiber diameter is within a range from 100 nm to 1000 nm and/or the specific relative viscosity is within a range from 5 to 75, e.g., from 15 to 50. The process further comprises the steps of extruding a polyamide composition having a moisture content with a pressurized gas through a fiber forming channel having a channel temperature to form the polyamide nanofiber nonwoven having the target average nanofiber diameter and/or relative viscosity and controlling the moisture content, the pressure of pressurized gas, and/or the channel temperature based on the specific average nanofiber diameter and/or the specific relative viscosity.