Abstract: Provided herein are polymer films including a polyamide composition of PA6 and PA66/6. The provided films are particularly useful as packaging materials as they exhibit improved toughness, e.g., puncture and impact resistance, relative to that of conventional films that include only PA6 as a polyamide component. Also provided are methods for making the provided films, and articles that include the provided films.

Abstract: A filter or mask structure, comprising a first face layer comprising a polymer and having a face basis weight, a second outer layer comprising a polymer and having an outer basis weight less than 34 gsm, and a third outer layer comprising a polymer and having a third basis weight and disposed between the first face layer and the second outer layer. At least one of the layers further comprises an AM/AV compound. The mask structure demonstrates an Escherichia coli efficacy log reduction greater than 4.0, as measured in accordance with ASTM E3160 (2018) and a particulate filtration efficiency greater than 90%, as measured in accordance with ASTM F2299-03R17.

Abstract: The present disclosure relates to fluid bed processes that utilize silica particles as a fluidization aid. The process comprises reacting one or more reactants in a reactor comprising a fluid bed to form a product. The fluid bed comprises a catalyst composition comprising a catalyst and an inert additive composition comprising silica particles from 0.5 wt % to 30 wt %, based on the total weight of the catalyst composition. The silica particles are discrete, inert particles that are mixed with the catalyst in the fluid bed.

Abstract: Flame retardant thermoplastic polyamide compositions are described that provide a superior combination of glow wire ignition and elongation/toughness properties, comprising a polyamide resin; a bromine-containing flame retardant; a hindered phenolic heat stabilizer; and optionally at least one of a flame retardant synergist, a plasticizer, a lubricant, a mold release agent, an acid scavenger and a colorant.

Abstract: A polymer composition having antimicrobial properties, the composition comprising from 50 wt % to 99.99 wt % of a polymer, from 10 wppm to 900 wppm of zinc, less than 1000 wppm of phosphorus, and less than 10 wppm coupling agent and/or surfactant, wherein zinc is dispersed within the polymer; and wherein fibers formed from the polymer composition demonstrate a Klebsiella pneumonia log reduction greater than 0.90, as determined via ISO20743:2013 and/or an Escherichia coli log reduction greater than 1.5, as determined via ASTM E3160 (2018).

Abstract: Provided is a textile made of filament yarn comprising a polymer composition that is durable and reusable having permanent or near-permanent antiviral properties and that includes a polymer, a metal ion, preferably a zinc and/or copper ion, and an optional phosphorus compound, wherein fibers and/or fabric formed from the polymer composition demonstrate antiviral properties and wherein the polymer is hygroscopic. The present disclosure also describes methods of forming the polymer compositions and methods of preparing fibers from the polymer composition.

Abstract: A polymer composition for molded products having antimicrobial and/or antiviral properties comprising from 50 wt. % to 99.9 wt. % of a polymer, from 0.01 wt % to 10 wt % zinc, optionally from a zinc compound, less than 1 wt % of a phosphorus compound, and from 0 wt % to 20 wt % molding additives, wherein a molded product formed from the polymer composition demonstrates a Staphylococcus aureus log reduction greater than 1.0, as determined via ISO 22196:2011.

Abstract: A method for tuning characteristics of a polyamide nanofiber nonwoven comprising the step of targeting a specific average nanofiber diameter and/or a specific relative viscosity for the polyamide nanofiber nonwoven. The specific average nanofiber diameter is within a range from 100 nm to 1000 nm and/or the specific relative viscosity is within a range from 5 to 75, e.g., from 15 to 50. The process further comprises the steps of extruding a polyamide composition having a moisture content with a pressurized gas through a fiber forming channel having a channel temperature to form the polyamide nanofiber nonwoven having the target average nanofiber diameter and/or relative viscosity and controlling the moisture content, the pressure of pressurized gas, and/or the channel temperature based on the specific average nanofiber diameter and/or the specific relative viscosity.

Abstract: A process for producing a high-purity acetonitrile product from a low-purity acetonitrile feedstock streams. In particular, the present disclosure relates to a process for producing a sales-grade, high purity acetonitrile by (a) distilling the feedstock stream in a to yield a crude acetonitrile stream, (b) treating the crude acetonitrile stream to produce an intermediate acetonitrile stream, (c) purifying the intermediate acetonitrile stream in a pressure swing distillation system to produce a recycle stream and an acetonitrile product stream, (d) recycling the recycle stream to the first distillation column, and (e) distilling the acetonitrile product stream to yield a purified acetonitrile product stream of at least 98 wt. % acetonitrile.

Abstract: A nanofiber nonwoven product is disclosed which comprises a polyamide with a relative viscosity from 2 to 330, spun into nanofibers with an average diameter of less than 1000 nanometers (1 micron). In general, the inventive products are prepared by: (a) providing a polyamide composition, wherein the polyamide has a relative viscosity from 2 to 330; (b) melt spinning the polyamide composition into a plurality of nanofibers having an average fiber diameter of less than 1 micron, followed by (c) forming the nanofibers into the product.

Abstract: An electrolyte solution comprising an ionic component, a base solvent, and an additive package. The additive package comprises a trinitrile compound and a cyclic carbonate. The electrolyte solution comprises symmetric linear carbonate in an amount greater than 19 wt %, based on the total weight of the electrolyte solution.

Abstract: The present disclosure relates to fluid bed processes that utilize silica particles as a fluidization aid. The process comprises reacting one or more reactants in a reactor comprising a fluid bed to form a product. The fluid bed comprises a catalyst composition comprising a catalyst and an inert additive composition comprising silica particles from 0.5 wt % to 30 wt %, based on the total weight of the catalyst composition. The silica particles are discrete, inert particles that are mixed with the catalyst in the fluid bed.

Abstract: The present disclosure relates generally to processes for recovering tricyanohexane (TCH) via purification of by-product or co-product streams of adiponitrile production. In particular, the present disclosure relates to a process for purifying tricyanohexane (TCH), the process having the steps of (a) separating an adiponitrile process stream comprising adiponitrile and TCH to form a first overhead lights stream comprising low-boiling components and high-boiling components and a first bottoms heavies stream comprising high-boiling components and solid impurities; and (b) separating the first overhead lights stream in a distillation column to form a second overhead lights stream comprising low-boiling components, a second bottoms heavies stream comprising high-boiling components, and a TCH stream comprising TCH and less than 10 wt. % impurities; wherein the distillation column is a low pressure distillation column.

Abstract: A process for producing a TCH stream, the process comprising: separating, in a first column, an adiponitrile process stream comprising TCH and optionally adiponitrile, to form an adiponitrile stream comprising greater than 5 wt. % adiponitrile and a first TCH stream comprising TCH, and optionally a heavies stream comprising high-boiling components and solid impurities; and optionally purifying the first TCH stream, via one or more columns, to form a purified TCH stream comprising greater than 50 wt. % TCH; wherein the first column is operated at a pressure drop less than 25 mmHg.

Abstract: The present disclosure relates to a process for preparing fibers and/or fabrics having antimicrobial properties, the process comprising: determining an operating pressure limit; calculating an amount of zinc based on the operating pressure limit; forming a polyamide composition comprising: polyamide; and the calculated amount of zinc; forming fibers from the polyamide composition, wherein the forming is conducted at an operating pressure below the operating pressure limit.

Abstract: The disclosure relates to the cyanocarbon compositions and processes for producing the same. The cyanocarbon compositions comprise tricyanohexane and one or more coproducts of the tricyanohexane production reaction. Exemplary coproducts include tetracyano compounds, cyanoalkenes, cyanooximes, cyanoamides, and combinations thereof.

Abstract: The present invention relates to catalyst compositions containing a mixed oxide catalyst of formula (I) or formula (II) as described herein, their preparation, and their use in a process for ammoxidation of various organic compounds to their corresponding nitriles and to the selective catalytic oxidation of excess NH3 present in effluent gas streams to N2 and/or NOx.

Abstract: Corrosion inhibitor compositions for reducing the corrosive effect of acidic environments on metallic substrates are provided herein. In particular, the present disclosure describes corrosion inhibitor compositions comprising a condensation product of a trifunctional amine and a fatty acid. The present disclosure also describes methods of preparing and of using such corrosion inhibitor compositions.

Abstract: The present disclosure relates to a process for preparing polymers using a plug flow reactor. The process includes providing an aqueous monomer solution comprising amide monomers; evaporating the aqueous monomer solution to form a concentrated monomer solution; and polymerizing the concentrated monomer solution in a plug flow reactor comprising a shell side and a tube side to form a first process fluid comprising polymers. The concentrated monomer solution flows on the shell side from the inlet to the outlet.

Abstract: A low-halogen flame retardant thermoplastic polyamide composition providing improved mechanical and electrical stability at elevated temperatures, where the thermoplastic composition comprises a polyamide resin; a non-halogen flame retardant; a heat stabilizer containing a copper halide and an organophosphorus compound; an optional lubricant and/or mold release agent; and an optional colorant.