Abstract: The present disclosure relates generally to processes for recovering tricyanohexane (TCH) via purification of by-product or co-product streams of adiponitrile production. In particular, the present disclosure relates to a process for purifying tricyanohexane (TCH), the process having the steps of (a) separating an adiponitrile process stream comprising adiponitrile and TCH to form a first overhead lights stream comprising low-boiling components and high-boiling components and a first bottoms heavies stream comprising high-boiling components and solid impurities; and (b) separating the first overhead lights stream in a distillation column to form a second overhead lights stream comprising low-boiling components, a second bottoms heavies stream comprising high-boiling components, and a TCH stream comprising TCH and less than 10 wt. % impurities; wherein the distillation column is a low pressure distillation column.
Abstract: Reaction pathways and conditions for the production of nitrogen-containing chelators, such as a glycine derivative, with reduction of ammonia byproducts. In particular, the present disclosure describes a process for the production of a nitrile intermediate by reacting a tetra-amino compound or dinitrile compound with an aldehyde and a hydrogen cyanide to form the nitrile intermediate. The nitrile intermediate may then be further processed to produce chelators at a high yield and/or a high purity.
Abstract: A nanofiber nonwoven product is disclosed which comprises a polyamide with a relative viscosity from 2 to 330, spun into nanofibers with an average diameter of less than 1000 nanometers (1 micron). In general, the inventive products are prepared by: (a) providing a polyamide composition, wherein the polyamide has a relative viscosity from 2 to 330; (b) melt spinning the polyamide composition into a plurality of nanofibers having an average fiber diameter of less than 1 micron, followed by (c) forming the nanofibers into the product.
Abstract: The present disclosure relates to polymer resins, fibers, and yarns with permanent antimicrobial activity, and a method of producing the same. In one embodiment, the antimicrobial polymer resin comprises a polymer having less than 2500 ppm of zinc dispersed within the polymer, less than 1000 ppm of phosphorus, wherein the weight ratio of zinc to phosphorus is at least 1.3:1 or less than 0.64:1.
Abstract: Corrosion inhibitor compositions for reducing the corrosive effect of acidic environments on metallic substrates are provided herein. In particular, the present disclosure describes corrosion inhibitor compositions comprising a condensation product of a trifunctional amine and a fatty acid. The present disclosure also describes methods of preparing and of using such corrosion inhibitor compositions.
Abstract: An impact-modified polyamide composition comprising from 5 wt % to 85 wt % of polyamide polymer; from 10 wt % to 60 wt % glass fiber; from 3 wt % to 30 wt % of an impact modifier; and a melt stabilizer at a concentration less than 5 wt %; wherein the weight ratio of the impact modifier to the melt stabilizer ranges from 1.0:1 to 100:1; and wherein the polyamide composition demonstrates an un-notched Charpy impact energy loss at 23° C. that is greater than 80 kJ/m2 and a tensile strength greater than 135 MPa.
Abstract: A base polyamide composition comprising a nylon mixture having caprolactam units from 1 wppb to 50 wppm catalyst composition; and greater than 0.75 wt % residual caprolactam, wherein the base polyamide composition has a delta end group level ranging from 30 ?eq/gram to 90 ?eq/gram.
Abstract: A terpolymer composition is described that contains a statistical amount of 50-98 wt % of a first repeating AA-BB comonomer unit; 1-25 wt % of a second repeating AA-BB comonomer unit; and 1-25 wt % of a repeating lactam comonomer unit or 1-25 wt % of a third repeating AA-BB comonomer unit, where the terpolymer composition exhibits a high melting point similar to that of PA66 while also exhibiting a significantly reduced crystallization rate and crystallization temperature.
Abstract: A hydrolysis resistant polyamide composition comprising from 50 wt % to 80 wt % polyamide polymer having a theoretical amine end group content of at least 55 ?eq/gram; and from 25 wt % to 60 wt % glass fibers. The weight ratio of polyamide polymer to glass fibers ranges from 0.5:1 to 4.0:1. The polyamide composition comprises less than 0.06 wt % copper; and/or from 1 ppb to 0.24 wt % non-copper metal halide compound. The polyamide composition, when hydrolysis aged for 500 hours at 130° C., demonstrates an impact resilience greater than 40 kJ/m2, as measured at 23° C.
Abstract: A nanofiber nonwoven product is disclosed which comprises a polyamide with a relative viscosity from 2 to 330, spun into nanofibers with an average diameter of less than 1000 nanometers (1 micron). In general, the inventive products are prepared by: (a) providing a polyamide composition, wherein the polyamide has a relative viscosity from 2 to 330; (b) melt spinning the polyamide composition into a plurality of nanofibers having an average fiber diameter of less than 1 micron, followed by (c) forming the nanofibers into the product.
Abstract: Provided herein are processes for the separation of acetonitrile from low-purity feedstock streams. The provided processes are particularly useful for isolating acetonitrile at high purity from chemical manufacturing waste streams that include methanol, water, and allyl alcohol.
Abstract: A tri-carboxylic compound of Formula (IA) optionally in combination with a compound of Formula (IIA) behaves as a low-VOC, low odor coalescing agent, while a tri-carboxylic compound of Formula (IA) in combination with a compound of Formula (IIB), or alternatively, a tri-carboxylic compound of Formula (IB) in combination with a compound of Formula (IIA) exhibits dual coalescing and plasticizing properties. A tri-carboxylic compound of Formula (IB) optionally in combination with a compound of Formula (IIB) behaves as low-VOC, low odor plasticizing agent.
Abstract: A non-halogenated flame retardant polyamide composition is disclosed which comprises a polyamide, a non-halogenated flame retardant, and a synergist. The polyamide may have a ratio of carboxylic acid to amine end groups of greater than 1.8. Products formed from the composition are also disclosed. The polyamide may comprise nylon 6,6.
Abstract: A terpolymer composition is described that contains a statistical amount of 50-98 wt % of a first repeating AA-BB comonomer unit; 1-25 wt % of a second repeating AA-BB comonomer unit; and 1-25 wt % of a repeating lactam comonomer unit or 1-25 wt % of a third repeating AA-BB comonomer unit, where the terpolymer composition exhibits a high melting point similar to that of PA66 while also exhibiting a significantly reduced crystallization rate and crystallization temperature.
Abstract: A filter comprising a nanofiber nonwoven product is disclosed which comprises a polyamide with a relative viscosity from 2 to 330, spun into nanofibers with an average diameter of less than 1000 nanometers (1 micron). In general, the inventive products are prepared by: (a) providing a polyamide composition, wherein the polyamide has a relative viscosity from 2 to 330; (b) melt spinning the polyamide composition into a plurality of nanofibers having an average fiber diameter of less than 1 micron, followed by (c) forming the nanofibers into the product.
Abstract: A method for measuring the attraction propensity of fabric including the steps of charging a neutralized test fabric, optionally by contacting with a charging fabric, presenting the charged test fabric a predetermined distance from a static-influenced agent such that at least a portion of the static-influenced agent attaches to the charged test fabric, and determining the quantity of attached static-influenced agent.
Abstract: Clay stabilization compositions include one or a plurality of triamino compounds and/or derivatives thereof, fluids containing an effective amount of the clay stabilization compositions and methods for making and using same.
Abstract: A base polyamide composition comprising a nylon mixture having caprolactam units from 1 wppb to 50 wppm catalyst composition; and greater than 0.75 wt % residual caprolactam, wherein the base polyamide composition has a delta end group level ranging from 30 ?eq/gram to 90 ?eq/gram.
Abstract: Disclosed herein are drilling fluid compositions suitable for use, for example, in drilling a well bore through a subterranean formation and other oil and gas operations. The drilling fluid compositions of the present disclosure include the condensation product of a trifunctional amine and a fatty acid and an oil base fluid. The present disclosure also described processes for preparing drilling fluid compositions.