Patents Assigned to Ashland Oil, Inc.
  • Patent number: 4744883
    Abstract: In a reduced crude conversion the catalyst is regenerated with mixture of oxygen-enriched gas and H.sub.2 O either as steam or preferably as water to provide additional expansion and facilitate fluidization, while converting coke on catalyst to CO and H.sub.2 with minimum CO.sub.2 formation. The CO can be combined with hydrogen to produce methane, methanol or Fischer-Tropsch liquid hydrocarbons or can be passed through the reduced crude conversion operation as lift gas, or as cooling medium or subjected to water-gas shift to produce additional H.sub.2.
    Type: Grant
    Filed: June 16, 1986
    Date of Patent: May 17, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger, Jr.
  • Patent number: 4743672
    Abstract: A sag resistant two component polyurethane adhesive comprising a first polyisocyanate component and a second component comprising a polyol, a poly(alkylene oxide) polyamine and a polyurethane catalyst is described.
    Type: Grant
    Filed: February 26, 1987
    Date of Patent: May 10, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4740539
    Abstract: A two component structural adhesive which is composed of a mixture of an epoxy component which comprises a polyepoxide and a polyisocyanate and a hardener component which comprises a long chain, flexible polyamine and an epoxy resin homopolymerization catalyst is described.
    Type: Grant
    Filed: April 21, 1986
    Date of Patent: April 26, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4739031
    Abstract: A process for preparing novel poly(arylene ether-amide) polyols and their use in the formation of polyurethanes wherein the poly(arylene ether-amide) polyols are formed by reaction of a bicyclic amide acetal with a polyphenolic compound are described.
    Type: Grant
    Filed: May 12, 1987
    Date of Patent: April 19, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4737564
    Abstract: A process for preparing polymeric compositions which may be used in applications such as reaction injection molding (RIM), composites, adhesives, coatings, tooling compounds and the like which comprises the polymerization of a mixture of a polyisocyanate and a polyepoxide in the presence of a catalytic amount of a polyphenate salt of triethylene diamine at a temperature in the range of from about ambient temperature to about 150.degree. C. is described.
    Type: Grant
    Filed: June 25, 1987
    Date of Patent: April 12, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4737574
    Abstract: A process for preparing thermoset polymers at an improved rate by copolymerizing a bisoxazoline with a polythiol compound in the presence of a catalytic amount of an alkali metal or an alkaline earth metal cationic complex of formula MX.sub.n wherein M represents lithium, potassium, sodium, magnesium, calcium or zinc, X represents BF.sub.4, BPh.sub.4, ClO.sub.4, PF.sub.6, SbF.sub.6 or AsF.sub.6 is described.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: April 12, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4737565
    Abstract: A composition comprising a mixture of a polyepoxide, an isocyanate and a salt of a polyamine and a polyhydric phenol and a process for curing said composition by heating it to a temperature in the range of from about 80.degree. C. to about 150.degree. C. are described.
    Type: Grant
    Filed: April 9, 1987
    Date of Patent: April 12, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4737572
    Abstract: A process for preparing thermoset polymers at an improved rate by copolymerizing a bisoxazoline with a compound having both thiol and carboxylic acid groups in the presence of a catalytic amount of an alkali metal or an alkaline earth metal cationic complex of formula MX.sub.n wherein M represents lithium, potassium, sodium, magnesium, calcium or zinc, X represents BF.sub.4, BPh.sub.4, ClO.sub.4, PF.sub.6, SbF.sub.6 or AsF.sub.6 is described.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: April 12, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4733004
    Abstract: A process for the esterification of an olefinically unsaturated carboxylic acid, such as methacrylic acid, with a lower alkanol, such as methanol, to form the corresponding ester over a solid cationic catalyst in which the carboxylic acid is used in excess of the alkanol on a molar basis, the improvement which comprises: (A) employing a hydraulically fluidized solid catalyst reactor for the continuous esterification reaction, (B) including in the esterification reaction a solvent which is a hydrocarbon having from 6 to 15 carbon atoms, (C) passing the effluent from the esterification reactor into a first distillation column in which the ester product and water by-product are taken overhead, (D) taking the unesterified carboxylic acid, solvent, and heavies from the bottom of the first distillation column, (E) separating the water from the ester in the overhead from (C) and recoverying the ester product, (F) separating heavies from the carboxylic acid-solvent from (D) in a second distillation column, (G) recycl
    Type: Grant
    Filed: June 23, 1986
    Date of Patent: March 22, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Ralph F. Pascoe
  • Patent number: 4732945
    Abstract: Disclosed is a new partial capping synthesis wherein resinous mixtures containing controlled amounts of phenolic hydroxyl and/or mercapto functionality, and aliphatic hydroxyl functionality are synthesized. Such synthesis comprises providing one or more resins which in total contain aliphatic primary and/or secondary hydroxyl functionality and oxirane functionality. A single resin or blend of resins may provide the requisite functionality. The one or more resins then are reacted with a carboxyl-functional capping agent bearing phenolic hydroxyl functionality and/or mercapto functionality. This reaction is conducted under reaction conditions and for a time such that the carboxyl functionality of the capping agent selectively reacts with the oxirane functionality of the one or more resins to produce a resinous product containing aliphatic hydroxyl functionality and containing phenolic hydroxyl functionality and/or mercapto functionality.
    Type: Grant
    Filed: October 15, 1986
    Date of Patent: March 22, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Laurence G. Dammann
  • Patent number: 4728737
    Abstract: A two component adhesive formulation comprising a mixture of A. an epoxy component comprising an epoxy resin and an additive selected from the group consisting of (a) a polyisocyanate, (b) a carboxylic anhydride and (c) a compound having unsaturated carbon-carbon bonds capable of undergoing Michael addition reaction with amines, and B. a hardner component for curing component A comprising a mixture of amido amines, primary and secondary amines having tertiary amine groups or ether groups in their backbone, and bisphenol-A is described.
    Type: Grant
    Filed: January 21, 1986
    Date of Patent: March 1, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4728384
    Abstract: The process for preparing an adhesive composition comprising mixing(a) an epoxy resin component composed of an epoxy resin and the partial reaction product of a polyepoxide with a phenolic compound, with(b) a hardener component composed of a primary and secondary amine containing polyamine or a poly amido-amine and a tertiary amine containing epoxy curing catalyst is described.
    Type: Grant
    Filed: June 23, 1986
    Date of Patent: March 1, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4728710
    Abstract: An improved antifoaming two component polyurethane adhesive comprising a first component composed of a polyisocyanate prepolymer and a second component composed of a polyol, a poly amine and a bicyclic amide acetal is described.
    Type: Grant
    Filed: November 28, 1986
    Date of Patent: March 1, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4728416
    Abstract: A process is disclosed for the catalytic cracking of gas oils with an additional nickel and vanadium metals-containing heavy feedstock. Included is regeneration of the catalyst by burning off coke.
    Type: Grant
    Filed: April 28, 1981
    Date of Patent: March 1, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: George D. Myers, deceased
  • Patent number: 4726868
    Abstract: Fast curing adhesives which are free of solvent and have high heat resistant bonding strength composed of mixtures of polyols, polyepoxides and polyisocyanates are described.
    Type: Grant
    Filed: May 30, 1986
    Date of Patent: February 23, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Anil B. Goel, Harvey J. Richards, Robert A. Grimm
  • Patent number: 4724892
    Abstract: An adhesive paste composition containing in admixture a resin component, a hardener component, a hydrophobic filler component and a curing agent. The resin component includes a polyol having at least two hydroxyl groups and the hardener component includes a liquid polyisocyanate containing at least two isocyanate groups. The admixture may be made by mixing together a premixed resin component contianing a filler and a catalyst and a premixed hardener component containing a hydrophobic filler. The fluid in the resin component, the hardener component, or both may be a thixotropic agent.
    Type: Grant
    Filed: April 30, 1987
    Date of Patent: February 16, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: James T. Schneider, Albert L. Haugse
  • Patent number: 4721767
    Abstract: An improved process for the copolymerization of a mixture of a bicyclic amide acetal and a polyisocyanate comprising carrying out the copolymerization reaction at a temperature in the range of from about ambient temperature up to about 200.degree. C. in the presence of a catalytic amount of a salt of a metal selected from the group consisting of bismuth, lead, mercury, copper, vanadium, cobalt, nickel, potassium, zinc and antimony is described.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: January 26, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4720477
    Abstract: An H-Coal Process hydrogenation operation and catalyst life is substantially improved when using colloidal particles of catalyst comprising a colloidal matrix of silica, alumina, titania and combinations thereof coated with hydrogenating components selected from cobalt, molybdenum, nickel, tungsten and combinations thereof. The colloidal catalyst activity may be altered by alkaline promoters, other metals and acidic promoters.
    Type: Grant
    Filed: July 23, 1986
    Date of Patent: January 19, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger, Jr.
  • Patent number: 4716958
    Abstract: An apparatus for upgrading residual portions of crude oils comprising metal contaminants and Conradson Carbon contributing components by the combination of thermal visbreaking with fluid inert solids and catalytic upgrading of naphtha and higher boiling components of thermal visbreaking in separate systems of riser conversion and solids regeneration includes an external solids heat exchange apparatus arrangement utilized to partially cool hot regenerated solids utilized in the solids regeneration systems.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: January 5, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Paul W. Walters, Lloyd E. Busch, Oliver J. Zandona
  • Patent number: 4711643
    Abstract: Improved stabilizers for use in coal-oil mixtures are disclosed and comprise quaternary ammonium hydroxides, preferably they are formed by the reaction of a molar excess of sodium hydroxide or lithium hydroxide with a quaternary ammonium salt.
    Type: Grant
    Filed: December 14, 1981
    Date of Patent: December 8, 1987
    Assignee: Ashland Oil, Inc.
    Inventors: Paul C. Kemp, Walter Lyons